[go: up one dir, main page]

0% found this document useful (0 votes)
96 views32 pages

IAS Chemistry Atomic Structure Question Bank and MS

Download as rtf, pdf, or txt
Download as rtf, pdf, or txt
Download as rtf, pdf, or txt
You are on page 1/ 32

IAS Chemistry Revision Questions – Topic 2 Atomic structure

Q2.This question is about atomic structure and gases.


(a)  Chlorine exists as two isotopes with mass numbers 35 and 37.
(i)  State the number and type of each of the particles in the nucleus of a chlorine-35 atom.
(2)
.............................................................................................................................................

.............................................................................................................................................
(ii)  Complete the electronic configuration of a chloride ion, Cl−, using the s, p, d notation.
(1)
1s2 .....................................................................................................................................
(iii)  A sample of chlorine contains 75.53 % of chlorine-35 atoms.
Calculate the relative atomic mass of this sample of chlorine.
Give your answer to two decimal places.
(2)

(b)  Fluorine has one naturally occurring isotope with mass number 19.
Chlorine and fluorine react to form chlorine trifluoride, ClF3 .
(i)  Draw a dot-and-cross diagram to show the bonding in a molecule of chlorine trifluoride.
Show the outer shell electrons only.
(2)

(ii)  State, in terms of electrons, what is unusual about the dot-and-cross diagram you have drawn.
(1)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

Q3.
 
This question is about copper and its compounds.

(a)  Complete the electronic configurations of Cu and Cu2+.


(2)
Cu [Ar] .............................................................................................................................................

Cu2+ [Ar] .............................................................................................................................................

(b)  A sample of copper contains the isotopes 63Cu and 65Cu.


(i)  Complete the table to show the numbers of subatomic particles in the atoms of these two isotopes
of copper.
(2)

(ii)  Explain the term isotopes, using the information in the table.


(2)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................
(iii)  State why the two isotopes of copper have the same chemical reactions.
(1)
.............................................................................................................................................

.............................................................................................................................................

Q4.
 
Answer the question with a cross in the box you think is correct . If you change your mind
about an answer, put a line through the box and then mark your new answer with a cross .
The mass spectrum of a sample of silicon is shown.

What is the best estimate for the relative atomic mass of silicon in this sample?
   A    28.0
   B    28.2
   C    28.8
   D    29.0

 
(Total for question = 1 mark)
 
Q6.
 Answer the question with a cross in the box you think is correct . If you change your mind
about an answer, put a line through the box and then mark your new answer with a cross .
The mass spectrum of a sample of an element has only two peaks.
What is the approximate relative atomic mass of the element in this sample?
   A    191.5
   B    192.0
   C    192.5
   D    193.0

 
(Total for question = 1 mark)
 Q9.
 

A sample of neon contains the following isotopes.

What is the relative atomic mass of neon to two decimal places?


(1)
   A    20.00
   B    20.09
   C    20.18
   D    21.00

 
(Total for question = 1 mark)
 
Q10.
 
This question is about the element sulfur.

(a)  Complete the diagram to show the electronic configuration for a sulfur atom in the ground state.
       Include labels for each subshell.
(2)

(b)  Write an equation for the first ionisation energy of sulfur.


       Include state symbols.
(2)

(c)  Explain why the first ionisation energy of sulfur is less than the first ionisation energies of both
phosphorus and chlorine.
(3)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

(d)  A sample of sulfur contains four isotopes.

(i)  State what is meant by the term isotopes, in terms of subatomic particles.


(2)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................
(ii)  Calculate the relative atomic mass of sulfur in this sample.
Give your answer to two decimal places.
(2)

Q11.
 

This question is about the structure of atoms.

(a)  State what is meant by the term orbital.


(2)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................
(b)  State the shape of an s orbital and the shape of a p orbital.
(1)

.............................................................................................................................................

.............................................................................................................................................

(c)  Describe what can be deduced about the electronic structure of sodium from its successive ionisation
energies.
(3)
.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

(d)  (i)  The log of the fourth ionisation energy for six elements is shown in the table.

Plot a graph of these data.


(3)
 
(Total for question = 11 marks)
 
Mark Scheme

Q1.
 
 

Q2.
 
 

Q3.
 
 

Q4.
 
 

Q5.
 

Q6.
 
 

Q7.
 

Q8.
 
 
Q9.
 

Q10.
 
 

Q11.
 
 

You might also like