Product name: Loctite(R) Superflex(R) Blue RTV Silicone Item No. : 30560 / IDH No. 270642 Adhesive Sealant Product type: Silicone Region: United States Company address: Contact Information: Henkel Corporation Telephone: 860.571.5100 1001 Trout Brook Crossing Emergency telephone: 860.571.5100 Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Distillates( petroleum), hydrotreated 5-10 None None None middle 64742-46-7 3 3 3 Silica, amorphous (fumed) 5-10 6 mg/m TWA 10 mg/m TWA 3 mg/m TWA respirable dust 7631-86-9
Ethyltriacetoxysilane 1-5 None None None
17689-77-9
Methyltriacetoxysilane 1-5 None None None
4253-34-3
Non hazardous components
Silicone Resins 50-100 %
Exposure to moisture during cure will release 1-5% acetic acid. The above components are hazardous as defined in 29 CFR 1910.1200.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW HMIS: Physical state: Paste HEALTH: 1 Color: Blue FLAMMABILITY: 1 Odor: Acetic Acid PHYSICAL HAZARD: 0 Personal Protection: See Section 8 CAUTION: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Skin contact, Eye contact, Inhalation
Potential Health Effects
Inhalation: Acetic acid produced during cure may irrritate eyes, nose and throat. When heated to temperatures exceeding 300° F (150° C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limt. Skin contact: May cause skin irritation. Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation. Ingestion: Not expected to be harmful by ingestion.
Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
See Section 11 for additional toxicological information.
Item No. : 30560 / IDH No. 270642 Product name: Loctite(R) Superflex(R) Blue RTV Silicone Adhesive Sealant 1 of 4 4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If discomfort persists seek medical attention.
Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water.
Eye contact: Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist.
Ingestion: Do not induce vomiting. If a person feels unwell or symptoms of skin irritation appear, consult a physician.
Notes to physician: Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93ºC (200ºF) Tagliabue closed cup
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: None
Unusual fire or explosion hazards: None
Hazardous combustion products: Formaldehyde. Silica Mist. Acrid smoke and fumes.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Scrape up as much material as possible. Spilled material will solidify. Store in a closed container until ready for disposal. Maintain good ventilation for large spills.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Do not get in eyes. Do not get on skin or clothing. Do not wear contact lenses.
Storage: Store in a dry area below 90° F Keep container closed.
Incompatible products: Avoid contact with water. Acids. Oxidizing agents.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
Respiratory protection: No personal respiratory protective equipment normally required. Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Chemical resistant, impermeable gloves.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Item No. : 30560 / IDH No. 270642 Product name: Loctite(R) Superflex(R) Blue RTV Silicone Adhesive Sealant 2 of 4 Physical state: Paste Color: Blue Odor: Acetic Acid Vapor pressure: <10 mmHg @20°C (68° F) pH: Not applicable Boiling point/range: Not available Melting point/range: Not available Specific gravity: 1.04 at 20 deg. C Vapor density: Heavier than air Evaporation rate: Not available Solubility in water: Insoluble Polymerizes in presence of water Partition coefficient (n-octanol/water): Not available VOC content: 3.08%; 32 grams/liter
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Acetic acid is liberated slowly upon contact with moisture. Formaldehyde.
Distillates( petroleum), hydrotreated No No No middle 64742-46-7 Silica, amorphous (fumed) No No No 7631-86-9 Ethyltriacetoxysilane No No No 17689-77-9 Methyltriacetoxysilane No No No 4253-34-3
Literature Referenced Target Organ & Other Health Effects
Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this material; however, commonly available data on the material indicate that uncontrolled releases to soil, groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the quantity and concentration of such releases. Releases of volatile components to the atmosphere are not believed to entail significant ecological consequences provided such releases are within the exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which may occur should be contained and cleaned up immediately in accordance with Section 6.
Item No. : 30560 / IDH No. 270642 Product name: Loctite(R) Superflex(R) Blue RTV Silicone Adhesive Sealant 3 of 4 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose according to EPA and local governmental regulations. Cured rubber can be incinerated or landfilled following EPA and local regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None
WaterTransportation (IMO/IMDG): Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Marine pollutant: None known
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None.
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. WHMIS hazard class: D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.
Prepared by: Lou Fabrizio, Senior Health & Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
Item No. : 30560 / IDH No. 270642 Product name: Loctite(R) Superflex(R) Blue RTV Silicone Adhesive Sealant 4 of 4
