The document contains a single choice question with 14 questions about stereochemistry and identifying the R and S configurations of different organic molecules. It also includes matching, multiple choice and integer type questions related to stereochemistry. The answer key and detailed solutions are provided at the end.
The document contains a single choice question with 14 questions about stereochemistry and identifying the R and S configurations of different organic molecules. It also includes matching, multiple choice and integer type questions related to stereochemistry. The answer key and detailed solutions are provided at the end.
The document contains a single choice question with 14 questions about stereochemistry and identifying the R and S configurations of different organic molecules. It also includes matching, multiple choice and integer type questions related to stereochemistry. The answer key and detailed solutions are provided at the end.
The document contains a single choice question with 14 questions about stereochemistry and identifying the R and S configurations of different organic molecules. It also includes matching, multiple choice and integer type questions related to stereochemistry. The answer key and detailed solutions are provided at the end.
10. The Cahn-Ingold-Prelog stereochemical designations used for the following substance are :
(A) 2R, 4S (B) 2S, 4R (C) 2R, 4R (D) 2S, 4S
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 2 11. Which of these is not a correct Fischer projection formula of the (S) form of 3-bromo-1,1-dichloro-2-propanol?
CHCl2 CH2Br H OH H OH HO H Cl2HC CH2Br H CHCl2 CH2Br CHCl2 OH CH2Br (I) (II) (III) (IV)
(A) I (B) II (C) III (D) IV
One or more than one Type Question
12. Indicate figure/s having S configuration.
CH2–CH3 CH2–CH3 SR CH2–CH3 H3C OPh H3C I (A) (B) H NR2 (C) (D) CH3 Et CH2–CH2–CH3
13. Match the column-I with column-II, where column-I indicates a compound and column-II indicates its configuration. Note that column-I may have more than one matching options in column-II. Column-I Column-II
(A) (P) 2R 3S
(B) (Q) S
(C) (R) R
(D) (S) 2S 3R
(A) A-Q ; B-R ; C-P ; D - S
(B) A-S ; B-R ; C-P ; D - S (C) A-R ; B-Q ; C-P ; D - S (D) A-S ; B-P ; C-R ; D - Q
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 3 Integer Type Question
14. How many compounds having R configuraiton in the following given compounds.
(1) (2) (3) (4)
(5) (6) (7)
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 4 Answer Key + Solution
Single Choice Question
1. A 2. B 3. D 4. C 5. C 6. D 7. B 8. A 9. D 10. C 11. D
One or more than one Type Question
12. BCD 13. C
Integer Type Question
14. 4
Solution
1. A
2 CH=CH2 4 C 3 SR H CH3 1COOH
2. B
3. D
Cl H Cl H 2 4 1 3 5
4. C
4 H 3 1 H3C Cl 2 CH CH3 2 (R-2-Chlorobutane)
5. C
4 4 3 H H CH3 1 1 3 1 4 3 (I) H3C OH (III) HO CH3 (IV) HO H 2 2 2 CH2CH3 CH2CH3 CH2CH3 R-2-butanol S-2-butanol R-2-butanol
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 5 6. D 2 2 3 F F CH3 1 4 4 1 4 1 Cl H H Cl H Cl
3 CH3 3 CH3 2F (I) = S (II) = R (III) = S
7. B 2 2 3 F F CH3 1 4 4 1 4 1 Cl H H Cl H Cl
3 CH3 3 CH3 2F (I) = S (II) = R (III) = S
8. A 3 CH3 4 1 H Br S 2 CH2CH3
9. D
5 6 CH2CH3 3 4 4 1 H 1 Cl =S 2 4 3 3 (2S, 3R, 4S)-2,4-dichloro-3-methylhexane H CH3 = R 2 1 2 4 Cl H =S 3 1 CH3
10. C 4 H 3 3 1 Cl Cl 4 3 2 4 =R R= 1 2 H (2R, 4R) 5 1 2 Cl Cl
11. D 1 OH 4 3 H CHCl2 1 CH2Br (R)
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 6 12. BCD 1 SR 4 2 (B) H NR2 =S 3 Et
3 CH2–CH3 4 1 (C) H3C I =S 2 CH2–CH2–CH3
3 CH2–CH3 4 1 (D) H3C OPh =S 2
13. C A-R ; B-Q ; C-P ; D - S 3
1 4 Sol. (A) NH2 CH = NH =R 2 CH2OH
4 5 1
1 1 (B) 3 6 =S 1 2 1
4 CH3 3 H Cl = S (C) = 2R–3S 2 H Br = R
1CH3
1 COOH 2 HO H =S (D) = 2S–3S 3 H OH = R CH3 4
14. 4 Sol. (1) S (2) R (3) R (4) R (5) no chiral centre (6) S (7) R
Join with code "SKSIRLIVE" for 10% discount on your unacademy subscription. Page # 7
