PRIMEASIA UNIVERSITY
LAB REPORT
Course Code: TXE-308
Course Name: Wet Processing Technology-2 (Lab)
Experiment number : 3
Name of the experiment: Dying of Cotton fabric with Azoic Dye.
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Name: Md. Redwan Ibn Mahbub ID No: 191-060-041
Department: Textile Engineering Section: A
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Submitted to :
Mohammad Billal Hossain
Assistant Professor
Department of Textile Engineering
Primeasia University
Experiment number : 3
Name of the experiment: Dying of Cotton fabric with Azoic Dye.
Introduction:
The dyes containing insoluble azo group (‐N=N‐) are known as azoic dyes. These dyes are
not found in readymade form. Azoic dyes are produced by a reaction between two
components.
The components are:
Coupling Compound ( Naphthol)
Di‐azo–compound or diazobase or diazosalt.
The colored substance formed from this colorless compound is insoluble in water and
washing fastness of this shade is excellent.
Object:
To dye a material practically.
To observe the practical advantages and disadvantages of this dye.
To compare the theoretical idea with practical experiment.
Chemistry of dyeing:
Dyeing process of azoic dyes includes three main stages. They are-
1. Naphtholation
Naphthols are insoluble in water and converted into soluble form by treating
with alkali. The fabric is in pregnated with ß-naphthol and NaOH solution and
converted into ß-Naphthol Na-ß-Naphtholate.
2. Diazotisation
A base containing amino group reacts with sodium nitrite to a solution of the
hydro chloride of the base in the presence of excess of HCl at 0°-5°C.
3. Coupling
The impregnated material is treated in a bath containing diazonium solution to
carry out coupling and azoic colour is produced.
Process Sequence For dyeing with Azoic dyes:
Textile material is prepared
↓
Textile material is treated with Naphthol
Soln
↓
Preparation of base salt solution
↓
Naphthol treated fabric is treated with
↓
Diazosolution
↓
Colour developed
Recipe for Naptholation:
• ß-Napthol= 10% owf
• NaOH= 5 gm/l
• NaCl= 20gm/l
• Wetting agent= 1gm/l
• M:L = 1:30
• Temperature= 30°-40° C
• Time= 20 minute
Calculation:
Given fabric= 5gm
Total liquor= 5×30=150ml
ß-Napthol= 5×(10/100)= .5
gm NaOH= (150×5)/1000= .75
gm NaCl=(150×20)/1000= 3
gm
Wetting agent= (150×1×100)/(1000×5)=3 ml
Additional water=150-3=147 ml
Recipe for Diazotisation:
Base color=10%
HCl= 2cc/l
NaNO2=3gm/l
CH3COOH=.25cc/l
CH3-COONa= .3gm/l
Calculation:
Base color=(150×10×100)/(1000×2)= 75cc
HCl= (150×2×100)/(1000×5)= 6 cc NaNO2=
(150×3×100)/(1000×5)=9 cc
CH3COOH= (150×.25×100)/(1000×5)= .75 cc
CH3-COONa= (150×.3×100)/(1000×5)= .9 cc
Additional water= 150-(75+6+9+0.75+.9) cc
=150-91.65= 58.35 cc cold water
Working Procedur:
Naphthol preparation:
At first, according to calculation, sufficient amount of distilled water was taken in dye bath.
Then required amount of naptholin, alkali, wetting agent, and common salt was
taken in the dye bath and stirred to make soluble.
Then then sample fabric was immersed in the solution for 20 minutes.
Base colour preparation:
At first, ice water was taken in dye bath.
The required amount of base colour, HCl, acetic acid, sodium acetate,Sodium
nitrate are added in a bath.
Development:
Then the squeezed fabrics are mixed in the bath of base colour and the magic
colour Red is obtained.
After treatment:
After dyeing operation is completed the dye material is put into a bath
containing hot wash.
The material is treated with a 1g/L soap solution, which removes the unfixed
dye from fabric surface, and makes the surface clean.
Then material is treated with a cold-water bath.
Finally the material is dried in a drier.
Process Curve:
Naptholation
Diazotisation
Conclusion:
After completing all of the process, finally the fabric acquire the desired red colour and
shade was even
