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Fiitjee All India Test Series: JEE (Advanced) - 2019

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FIITJEE

ALL INDIA TEST SERIES


FULL TEST – VIII

JEE (Advanced)-2019
PAPER – 2
Time Allotted: 3 Hours Maximum Marks: 180

General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

 Each Part is further divided into Two Sections: Section-A & Section-D.

1. Section-A (01 – 06, 19 – 24, 37 – 42) contains 18 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for all correct answer.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.

Section-A (07 – 10, 25 – 28, 43 – 46) contains 12 questions. Each question has TWO (02)
matching lists: LIST‐I and LIST‐II. FOUR options are given representing matching of elements
from LIST‐I and LIST‐II. ONLY ONE of these four options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
Each question has only one correct answer and carries +3 marks for correct answer and –1 mark
for wrong answer.
2. Section-D (11 – 18, 29 – 36, 47 – 54) contains 24 Numerical answer type questions with answer
XXXXX.XX and each question carries +3 marks for correct answer. There is no negative marking.

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Physics PART – I

SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MORE THAN ONE of these four options is(are) correct.

1. Two pendulums of same amplitude but time period 3s and 7s start oscillating
simultaneously from two opposite extreme positions. After how much time they will be in
phase?
21 21
(A) s (B) s
8 4
21 63
(C) s (D) s
2 8

2. A1 and B1 are two bubbles joined by a thin tube, similarly A2 and Soap Bubbles
B2 are rubber balloons filled with air joined by another thin tube
B1 A1
(Fig shows the situation) As time progress _____choose the
correct statement (A1 and A2 are smaller in volume, then B1 and Gas Bubbles
B2 respectively).
(A) A1 will shrink : B2 will shrink B2 A2
(B) A1 will shrink : A2 will expand
(C) A1 will expand : B2 will shrink
(D) A1 will expand : B2 will expand

3. A sound wave is traveling along positive x-direction. Y


Displacement (y) of particles from their mean
positions at any time t is shown in the figure.
(A) Particle located at S has zero velocity.
(B) Particle located at T has its velocity in the P Q R S T x
negative direction.
(C) Change in pressure at S is zero
(D) Particles located near R are under compression.

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4. A convex lens made of glass (g =3/2) has focal length f in air. The image of an object
placed in front of it is inverted real and magnified. Now the whole arrangement is
immersed in water (w=4/3) without changing the distance between object and lens.
Then
(A) the new focal length will become 4f
(B) the new focal length will become f / 4
(C) new image will be virtual and magnified
(D) new image will be real, inverted and smaller in size

5. If the potential difference of Coolidge tube producing X-ray is increased, then choose the
correct option(s).
(A) the interval between k and  k increases
(B) the interval between k and  0 increases
(C) the interval between  k and  0 increases
(D)  0 does not change
Here  0 is cutoff wavelength and k and kB are wavelength of k  and k B
characteristic X-rays.

6. Two identical circular coils M and N are arranged coaxially as M N


shown in the figure. Separation between the coils is large as
compared to their radii. The arrangement is viewed from left
along the common axis. The sign convention adopted is that
currents are taken to be positive when they appear to flow in
clockwise direction. Then
(A) if M carries a constant positive current and is moved towards N, a positive current is
induced in N
(B) if M carries a constant positive current and N is moved towards M, a negative current
is induced in N
(C) if a positive current in M is switched off, a positive current is momentarily induced
in N
(D) if both coils carry positive currents, they will attract each other

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(Matching List Type)


This section contains FOUR questions. Each question has TWO matching lists: LIST‐I and
LIST‐II. FOUR options are given representing matching of elements from LIST‐I and
LIST‐II. ONLY ONE of these four options corresponds to a correct matching.

7. Read the following and write the correct pairs. Q 2Q


Initially, the two plates (A and B) are given charges as shown.
Find the final charges on the plates after the key k is closed.
All plates are conducting, parallel and of infinite length and
breadth. k

A B C D

List-I List-II
(P) Final charge on plate A (1) Q/2
(Q) Final charge on plate B (2) Q
(R) Final charge on plate C (3) 0
(S) Final charge on plate D (4) 3Q/2
Codes:
(A) P–2, Q–1, R–4, S–3 (B) P–2, Q–4, R–1, S–3
(C) P–3, Q–1, R–4, S–2 (D) P–2, Q–3, R–2, S–4
8. The potential energy of a particle moving along U(x)
x-axis is show in figure. Where Eo is the total
mechanical energy of the particle. Eo

O X
x1 x2 x3

List-I List-II
(P) Force on the particle is towards (1) x1 < x < x2
+ve x-axis if
(Q) Particle can’t be found where (2) x2 < x < x3
(R) Force is towards the equilibrium (3) x < x1, x > x3
position if
(S) Force is towards the –ve x-axis if (4) x2 > x
(5) x1 < x < x3
Codes:
(A) P–2, Q–1, R–3,4, S–2,3 (B) P–1,4, Q–3, R–1,2 4,5, S–2
(C) P–2,3, Q–3, R–1,4, S–2,3 (D) P–2,3,4, Q–1, R–2, S–2,4

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9. Five batteries whose emf and internal resistance B A


are as shown in figure. Match the following 4 4V
5 6
5V 6V
D
C
3V 3 2V 2

List–I List–II
(P) Potential of point A (1) – 5V
(Q) Potential of point B (2) 1V
(R) Potential of point C (3) – 3V
(S) Potential of point D (4) 2.5V
(5) 1.5 V
Codes:
(A) P–3, Q–4, R–3, S–1 (B) P–2, Q–4, R–1, S–3
(C) P–3, Q–1, R–4, S–2 (D) P–2, Q–3, R–2, S–4

10. The speed (v) of a particle of mass 1 kg moving along a straight line, when it is at a
distance (x) from a fixed point on the line, is given by, v 2  144  9x 2 . Match the
following:
List–I List–II
Motion is simple harmonic with
(P) (1) 2 / 3 units
time period
Max. displacement from the fixed
(Q) (2) 27 units
point is
Magnitude of acceleration at a
(R) distance 3 units from the fixed point (3) 4 units
is
Potential energy at a distance x = 2
(S) (4) 2 units
unit from fixed point is
(5) 18 units
Codes:
(A) P–1, Q–4, R–2, S–3 (B) P–1, Q–3, R–5, S–2,5
(C) P–3, Q–1, R–2, S–5 (D) P–1, Q–3, R–2, S–5

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SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded‐off to the second decimal place; e.g. xxxxx.xx).

6
11. Gravitational acceleration on the surface of a planet is g , where g is the gravitational
11
2
acceleration on the surface of the earth. The average mass density of the planet is
3
times that of the earth. If the escape speed on the surface of the earth is taken to be 11
km s–1, the escape speed on the surface of the planet in kms-1 will be

12. A thin uniform bar lies on a frictionless surface and is


free to move in any way on the surface. Its mass is
0.16 kg and length 3 metres. Two particles each of 10 m/s
mass 0.08 kg are moving on the same surface and
0.5 m
towards the bar in a direction perpendicular to the bar,
one with a velocity 10 m/s and the other with 6 m/s as 3m
shown in Figure. The first particle strikes the bar at A 6 m/s 0.5 m
and the other at the point B. The points A and B are at
distances 0.5 m from centre of the bar. The particles
strike the bar at the same instant of time and stick to
the bar on collision. Calculate the loss of kinetic
energy of the system on the above collision process.

13. A light wooden rod fixed at one end is kept horizontal. A load of 0.4 kg tied to the free
end of the rod causes that end to be depressed by 2.8 cm. If this load is set into up and
down vibrations, with what frequency will it oscillate?

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14. A moving car encounters air resistance which is proportional to the square of the speed
2  Power required at 40 kmph
of the car. Find the value of
Power required at 80 kmph

15. The equivalent capacitance between points A and B 4C 4C


of the circuit will be (given: C = 1.3) 2C
A B
6C
4C 4C

16. The two ends A and B of a uniform rod of length VA = 20 m/s


 = 1m are moving with velocities VA and VB as
A= 53o B
shown. The velocity VB (m/s) is
A B= 37o
VB

17. A cylindrical uniform rod of mass 0.72 kg and radius 6 cm B


L
rests on two parallel rails, that are d = 50 cm apart. The
rod caries a current I = 48A (In the direction shown) and d
i
rolls along the rails without slipping. If it starts from rest, L
uniform magnetic field of magnitudes 0.25 T is directed
perpendicular to the rod and the rail, then find the friction
force(In N) between rod and rails

18. A 10 m wide spacecraft moves through the interstellar space at a speed 3 × 10 7 m/s.
A magnetic field B = 3 × 10–10 T exists in the space in a direction perpendicular to the
plane of motion. Treating the spacecraft as a conductor, calculate the emf induced
across its width. (in volt)
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Chemistry PART – II

SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MORE THAN ONE of these four options is(are) correct.

19. Which of the following substance(s) is/are more soluble than CaSO4 in water?
(A) BeSO4 (B) MgSO4
(C) SrSO4 (D) BaSO4

20. Which of the following compound(s) form(s) tribromo derivative(s) as the major product
when treated with bromine water?
OH OH
CH3
(A) (B)

OH
OH

(C) (D)

CH3
CH3

21. Which of the following is/are the anhydride(s) of boric acid(H3BO3)?


(A) B2O3 (B) HBO2
(C) H2B2O3 (D) H2B4O7

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22. The molecular formula of which of the following is/are C4H4O4?


(A) A cis-dibasic acid
(B) An ,  unsaturated dibasic acid which on heating gives a monobasic acid
(C) A cycic ester of dibasic acid
(D) An keto ester

 i CH3I excess 
  Pr oducts
23. N - CH3 ii Ag2O,H2O
iii 
Which of the following product(s) is/are formed in the above reaction?

(A) NH (B)

(C) (CH3)3N (D)

24. Which of the following statement(s) about aminoacids is/are correct?


(A) They are all high melting solids
(B) They are constituents of all proteins
(C) Glycine is the only naturally occurring amino acid which is optically inactive
(D) Most naturally occurring amino acids have D-configuration

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(Matching List Type)


This section contains FOUR questions. Each question has TWO matching lists: LIST‐I and
LIST‐II. FOUR options are given representing matching of elements from LIST‐I and
LIST‐II. ONLY ONE of these four options corresponds to a correct matching.

25. Match the compounds mentioned in List-I with their properties mentioned in List-II.
List – I List – II
(P) CH3 (1) Forms one monosubstituted product
in electrophilic substitution reactions.

CH3
(Q) CH3 (2) Forms more than one
monosubstituted product in
NC NO 2
electrophilic substitution reactions

(R) OH (3) More reactive than benzene towards


EAS reaction

OH
(S) Cl (4) Less reactive than benzene towards
EAS reaction

Cl
(5) The substituents exert –I as well as
+R effect
(A) P  1, 3; Q  1, 4; R  2, 4, 5; S  2, 4, 5
(B) P  3; Q  3, 5; R  1, 2 ; S  1, 3
(C) P  2; Q  4; R  1, 3; S  5
(D) P  4, 5; Q  2; R  5; S  1, 5
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26. Match the compounds mentioned in List – I with their properties mentioned in List – II.
List – I List – II
(P) OH (1) More reactive than toluene towards
common electrophilic bromination
reaction in water

(Q) ONa (2) Forms carbocation which is stabilized


through resonance

(R) Cl (3) Turns blue litmus to red

(S) CH2Cl (4) The substituted atom or group shows


+R effect

(5) The substituted atom or group shows


–I effect
(A) P  2, 3; Q  5; R  4; S  1
(B) P  4; Q  3; R  1, 2; S  1, 3
(C) P  1, 3, 4, 5; Q  1, 4, 5; R  4, 5; S  2, 5
(D) P  3; Q  1, 4; R  2, 3, 5; S  2, 4, 5

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27. Match the following:


List – I List – II
(P) (1)
D
T
BD3 ,THF
 
MeCO2 T

(Q) (2) D

BT3 ,THF

MeCO2D

(R) (3) T

BD3 ,THF

MeCO2H

(S) (4)
D
BH3 ,THF

MeCO2D

(5) T
D

(A) P  3, Q  1, R  4, S  5
(B) P  1; Q  5; R  2; S  4
(C) P  5, Q  4, R  3, S  2
(D) P  4, Q  2, R  5, S  1
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28. Match the substances mentioned in List-I with their properties mentioned in List-II.
List – I List – II
(P) CH3CH2CH2CHCl2 (1) Forms only terminal alkyne on
dehydrohalogenation reaction with NaNH2
followed by H2O
(Q) Cl (2) Forms only internal alkyne on
dehydrohalogenation reaction with NaNH2
CH3 - C - CH2CH3 followed by H2O
Cl
(R) CH3CHCHCH3 (3) Forms both internal and terminal alkyne
on dehydrohalogenation reaction with
Cl Cl NaNH2 followed by H2O
(S) ClCH2CH2CH2CH2Cl (4) Forms conjugated diene on
dehydrohalogenation reaction
(A) P  2, 3; Q  1, 2; R  4; S  1
(B) P  3; Q  4; R  1, 2; S  4
(C) P  4, Q  3, R  3, S  2
(D) P  1; Q  3; R  2, 4; S  4

SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded‐off to the second decimal place; e.g. xxxxx.xx).

Cl2
29. NaOH 
Cold
 P  NaOCl  H2O
Cl2
NaOH 
Hot
 P  NaClO3  H2O
What is the molar mass of ‘P’ in gram unit?

30. In how many kg water, should 50 moles of CaCl2 be dissolved in order to lower its
freezing point by 5oC? [Assume complete dissociation of CaCl2]
[Kf of water = 1.86 K kg mol–1]

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31. Percentage yield of 2-chlorobutane on photochlorination of n-butane is

32. The polymerization of the ethylene to linear polyethylene is represented by the reaction
n  CH2  CH2  
  CH2  CH2  n
Where n has a large integral value. Given that the average enthalpies of bond
dissociation for C = C and C – C at 298 K are +590 kJ/mol & +331 kJ/mol respectively.
Calculate the enthalpy of polymerization in kJ per mole of ethylene at 298 K?

33. For a certain chemical reaction, the variation of half-life(t½) with different initial
concentration(A0) of reactant has been represented in the following plot.

t1/2 (in s)

[A0] in mol L–1


What will be the half-life period of the reaction in ‘s’ unit if the rate constant is
15  10–3 s–1?

34. An orange colour solid(X) upon heating produces a green residue(Y) and evolves a
colourless and odourless gas(Z). When treated with aqueous NaOH, (X) produces NH3
gas and the solution turns yellow. What is the molar mass of ‘X’ in gram unit if the molar
mass of ‘Y’ is 152 g?

35. O

CH2  CH  CH2  C  CH2  CH  CH2


Above compound undergoes normal acidified permanganate(MnO4/H+) oxidation to form
compound(X), CO2 and H2O. (X) is a dicarboxylic acid which on heating forms(Y).
Reaction of three moles of (Y) with conc. H2SO4 forms compound(Z). What is the molar
mass of (Z) in gram unit?

36. 4 g of nitrate of a univalent metal(M) was heated with excess of previously ignited silica.
A loss of mass of 1.08 g takes place due to total expulsion of the nitrate part as N2O5. If
the mass percentage of nitrate group in the salt is X%, what is the value of ‘X’?
2MNO3  SiO2  M2SiO3  N2O5

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Mathematics PART – III

SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MORE THAN ONE of these four options is(are) correct.

37. Tangent drawn at point P(1, 3) of a parabola intersects its tangent at vertex at M(1, 5)
and cuts the axis of parabola at T. If R(5, 5) is a point on SP; where S is focus of the
parabola, then
(A) slope of axis is 3
5
(B) radius of circumcircle of SMP is units
2
(C) (ST)2  (SM)2  (PM)2
(D) tangent cuts the axis of parabola at T (3, 7)



38. If y = f(x) and y = g(x) are symmetrical about the line x = , then  f(x) g'(x)dx is equal
2 

to
 

(A)  f '(x) g(x)dx (B)  f '(x) g(x)dx


 
 
1 1
(C) (f(x) g'(x)  f '(x) g(x))dx (D) (f(x) g'(x)  f '(x) g(x))dx
2  2 

x
39. Suppose that f(x) is a differentiable invertible function, f(x)  0 and h(x)  1 f(t)dt. Given
that f(1)  f '(1)  1 and g(x) is inverse of f(x).,
Let G(x) = x2g(x) –xh(g(x)) x  R . Which of the following are correct:
(A) G’(1) = 2 (B) G’(1) = 3
(C) G”(1) = 2 (D) G”(1) = 3

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40. If the probability of choosing an integer ‘k’ out of 2m integers 1, 2, 3,……..2m is inversely
proportional to k 4 1  k  m  . If x1 is the probability that choosen number is odd and x 2
is the probability that chosen number is even, then
2 1
(A) x1  (B) x1 
3 2
2 1
(C) x1  (D) x 2 
3 2

41. Which of the following functions are twice differentiable at x = 0?


(A) f(x)  x | x | (B) g(x)  [x 2 ] tan1 x  {x2 } cot 1 x  [x 2 ] 
2

(C) h(x)  | sin2 x |


 4
 x cos
(D) h(x)  
1
x 
; x0
 0 ; x0

n
r 3  n3 n 1 3
r  n3
42. Let Sn  
r 1 n4
and Tn  
r 0 n4
for n  1,2,3,..... Then

5 5
(A) Sn  (B) Sn 
4 4
5 5
(C) Tn  (D) Tn 
4 4
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(Matching List Type)


This section contains FOUR questions. Each question has TWO matching lists: LIST‐I and
LIST‐II. FOUR options are given representing matching of elements from LIST‐I and
LIST‐II. ONLY ONE of these four options corresponds to a correct matching.

43. Match the list:


List - I List - II
(P) Radius of the largest circle which passes through the focus (1) 16
of the parabola y2 = 4x and is completely contained in it, is
(Q) If the shortest distance between the curves (2) 5
y2 = 4x and y2 = 2x  6 is d then d2 is
(R) Let AB be a focal chord of y2 = 12x with focus S. The (3) 6
harmonic mean of lengths of segments AS and BS is
(S) Tangents drawn from P meet the parabola y2 = 16x at A and (4) 4
B. If these two tangents are perpendicular then the least
value of AB is
(5) –1
(6) 0
The correct option is
(A) P → 4; Q → 2; R → 3; S → 5 (B) P → 4; Q → 2; R → 3; S → 4
(C) P → 4; Q → 2; R → 1; S → 6 (D) P → 4; Q → 3; R → 6; S → 5

44. The angles of a triangle are in the ratio 2 : 3 : 7


List  I List  II
(P) Smallest side = 2 (1) Largest side  3  1
(Q) Smallest side  2 (2) Largest side  6  2
(R) Semi-perimeter  3  3  2 (3) Largest side = 1
(S) Area of triangle  ( 3  1) / 4 (4) Largest side  2  2 3
(5) No such triangle is possible
(6) Angles are in AP
The correct option is
(A) P → 2; Q → 1; R → 4; S → 3 (B) P → 2; Q → 1; R → 3; S → 4
(C) P → 1; Q → 2; R → 4; S → 3 (D) P → 2; Q → 1; R → 5; S → 6
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AITS-FT-VIII-(Paper-2)-PCM-JEE(Advanced)/19 18

45. Each of 4 boys attends a school gathering with both of his parents. The number of ways
these 12 people can be divided into groups of three each group containing a boy, a male
parents, a female parent such that
List – I List – II
No boy is with both of his parents in his group is
(P) (1) 5
N then N is
Exactly two boy is with both their parents is N
(Q) (2) 453
then N is
Two particulars boys is with both of his parents
(R) (3) 3
is N then N is
(S) Every boy is with both his parents is N then N is (4) 18
(5) 1
(6) 283
The correct option is
(A) P → 6; Q → 4; R → 3; S → 5 (B) P → 2; Q → 1; R → 1; S → 5
(C) P → 6; Q → 2; R → 1; S → 5 (D) P → 2; Q → 4; R → 3; S → 5

46. A (–2, 0) and B (2, 0) are two fixed points and P is a point such that PA – PB = 2. Let S
be the circle x 2  y 2  r 2 . Then match the following.
List-I List-II
(P) If r  2, then the number of points P satisfying (1) 2
PA  PB  2 and lying on x 2  y 2  r 2 is
(Q) If r  1, then the number of points satisfying PA – PB = (2) 4
2 and lying on x 2  y 2  r 2 is
(R) For r  2 , then the number of common tangents is (3) 0
(S) 1 (4) 1
For r  , then the number of common tangents is
2
(5) 5
(6) 6
The correct option is
(A) P → 6; Q → 4; R → 3; S → 5
(B) P → 2; Q → 1; R → 1; S → 5
(C) P → 1; Q → 4; R → 3; S → 1
(D) P → 2; Q → 4; R → 3; S → 5

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SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded‐off to the second decimal place; e.g. xxxxx.xx).

(x – 3)2 (y – 4)2
47. Given the equation of the ellipse + = 1, a parabola is such that its vertex
16 49
is the lowest point of the ellipse and it passes through the ends of the minor axis of the
2
ellipse. The equation of the parabola is in the form 16y = A(x – H) – K. Determine the
A H K
value of   is equal to
7 3 16

48. A straight line cuts the x-axis at point A 1, 0  , and y-axis at point B, such that
 
OAB       . C is middle point of AB and B’ is a mirror image of point B with
 4
respect to line OC and C’ is a mirror image of point C with respect to line BB’, then the
ratio of the areas of triangles ABB’ and BB’C’ is equal to

49. The number of functions from f : A  B where A = {a1, a2, a3, a4, a5, a6}, B = {1, 2, 3, …,
9} such that f(ai+1) > f(ai)  i  N and f(ai)  i is

50. Let (x3 + px2 + 2x – 5)19 (x2 + qx – 41)8 (x4 – x3 + x – 7)6 = x97 + 391x96 + a95x95 + a94x94 +
.... a1x + a0 be an identity, where p, q, a95....a0 are integers. Compute the smallest
positive value of p.

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51. If number of points common between ||x| - |y|| = 1 and 2a |x| |y| + 1 = 2 |x| + a|y| are 8
then value of 3a (where a < 1) is ____.

52. Let f(x) = 30 – 2x – x3, then find the number of positive integral values of ‘x’ which
satisfies f(f(f(x))) > f(f(-x)).
   
53. a, b and c be three non – coplanar vectors, and d be a non zero vector, which is
         
   
perpendicular to a  b  c . Now if d  sin x a  b  cos y b  c  2 c  a , then   
2

minimum value of x 2  y 2 is equal to , where  is
4

(x  1)dx
54. If  (x  x  4 tan1[g(x)]  C , where C is an arbitrary constant of
x  x) x(x  1)
2
integration. Find g (1).

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