MID -2 EXAMINATIONS
COMMON TO CSE&EEE
SUBJECT: CHEMISTRY Dt: /12/19 AN
Write any two of the following questions
1) Explain the dry corrosion with mechanism?
2) Explain the conformational analysis of n-butane with energy level diagram?
3) What are called substitution reactions? And explain SN 1 reaction with mechanism?
4) Explain NMR Spectroscopy in detail?
OBJECTIVE PAPER
1) A chiral carbon is ( )
3 2 2
A) SP B) SP C) SP D) dsp
2) In the presence of LiAlH4 an aldehyde is converted to ( )
A) Acid B) Primary alcohol C) Secondary alcohol D) tertiary alcohol
3) The reaction that involves the removal of two atoms or groups from the same molecule called
( )
A) Elimination reaction B) Substitution reaction C) hydrolysis D) addition
4) The isomers which are non-super imposable mirror images are
A) Diasteriomers B) Enantiomers C) Structural isomers D) Conformers ( )
5) If the curved arrow follows clock-wise direction, the configuration is ( )
A) R B) S C) Both D) NONE
6) An atom or group that contain an unshared pair of electrons for reaction is called ( )
A) Elecctophile B) Carbocation C) nucleophile D) free radical
7) The number of NMR signals given by CH 3-CH2- CH2-Cl ( )
A) 2 B) 3 C) 4 D) 1
8) The reference used in NMR Spectroscopy is ( )
A) Tetramethyl silane B) Trimethyl silicon
C)Trimethylsiloxane D) tetramethyl siloxane
9) The NMR Splitting of CH3-CHBr2 is as follows ( )
A) doublet, quartet B) doublet, triplet C) triplet, quartet D) Singlet, doublet
10) T he spectra that due to transitions between magnetic energy levels under influence of
magnetic field ( )
A) IR B) UV C) NMR D) NONE
11) A molecule with no plane of symmetry can be -------------------------
12) SN2 mechanism is ------------------------- step mechanism
13) The isomer which rotates the plane polarized light to right is called ---------------------------
14) The reaction between acetaldehyde and Grignard reagent gives ------------------------------
15) Hydroboration of olefin gives---------------------------------
16) The solid –wedge is used to represent a bond projecting --------------------------
17) The number of NMR signals tell us how many different kinds of ---------------- are there in a
molecule
18) --------------------- deals with the study of electromagnetic radiation with matter
19) IR spectroscopy is mainly used to detect ----------------------------
20) MRI stands for--------------------------------