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CRD 717

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Ju Naid Malik

This document contains information about rate constants k1 and k2 for a chemical reaction at different temperatures. It provides the values of k1 and k2 calculated at temperatures ranging from 283K to 373K based on the Arrhenius equation. A graph is shown of how x(a) (extent of reaction) changes with temperature based on the calculated rate constants and rate equation.

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CRD 717

Uploaded by

Ju Naid Malik
56 views4 pages
This document contains information about rate constants k1 and k2 for a chemical reaction at different temperatures. It provides the values of k1 and k2 calculated at temperatures ranging from 283K to 373K based on the Arrhenius equation. A graph is shown of how x(a) (extent of reaction) changes with temperature based on the calculated rate constants and rate equation.

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CRD-717

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This document contains information about rate constants k1 and k2 for a chemical reaction at different temperatures. It provides the values of k1 and k2 calculated at temperatures ranging from 283K to 373K based on the Arrhenius equation. A graph is shown of how x(a) (extent of reaction) changes with temperature based on the calculated rate constants and rate equation.

Copyright:

© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
Download as xlsx, pdf, or txt
56 views4 pages

CRD 717

Uploaded by

Ju Naid Malik
This document contains information about rate constants k1 and k2 for a chemical reaction at different temperatures. It provides the values of k1 and k2 calculated at temperatures ranging from 283K to 373K based on the Arrhenius equation. A graph is shown of how x(a) (extent of reaction) changes with temperature based on the calculated rate constants and rate equation.

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© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
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Example 9.

3
Xa 0.581
T(c) 65
t(min) 1
R 8.314
k(1)t/Xae = -ln(1-Xa/Xae)
k(1) =Xae -ln(1-Xa/Xae)/t
at 65 k1 338
Xae 0.89
k1(338) 0.941513365387312
(𝑘1(338))/(𝑘1(298) )=
(𝐾10𝑒^(−𝐸1/𝑅(338)))/(𝐾10𝑒^(−𝐸1/𝑅(298)) )

(𝑘1(338))/(𝑘1(298))= 𝑒^(−𝐸1/𝑅(338) +□(64&𝐸1/(𝑅(298))))

1/R(338) 0.000355855169793
1/R(298) 0.000403620964396
(-1/R(338)+1/R(298) 4.77657946030517E-05

2.32522985469131 E1(-1/R338+1/R298)
E1 48679.8110240744
〖𝐾 1(338)=𝐾(10)𝑒 〗 ^(−𝐸1/𝑅(338))
(𝐾1(338))/(𝐾(10)) 〖 =
𝑒 〗 ^(−𝐸1/𝑅(338))
lnK1(338) - lnk(10) = -E1/R(338)
lnK1(338) + E1/R(338) = lnk(10)

lnk(10) 17.2626956823088
K(10) 31411847.3013586

k1 = K(10)exp(-E1/RT)

k1 = exp(17.34 - E1/RT)

K=k1/k2
K = exp(75300/RT - 24.7)
K2 = exp(17.34 - E1/RT)/exp(75300/RT - 24.7)
k2 = exp(42.04 - 124200/RT)
from rate equation
x(a) = k1Ca0 + r/k1+k2(ca0)
x(a) = k1+r/k1+k2
Xa 0.6
T(c) 25
t(min) 10

at 25 k1 298
Xae 0.993
k1(298) 0.0920432605
r T(c) T(K) k1 k2 x(a)
12.5 10 283 0.0351 0.0000215 356.92855082957
12.5 20 293 0.07111 0.00013036403 176.45320209067
12.5 30 303 0.13752 0.00070135203 91.427667769687
/(𝑅(298)))) 12.5 40 313 0.25498 0.00338859178 49.368115521374
12.5 50 323 0.45501 0.01485061207 27.571988836899
12.5 60 333 0.78422 0.05955625855 15.743788212332
12.5 70 343 1.30939 0.22026192787 9.0278159428453
12.5 80 353 2.12366 0.75643128253 5.0774994321063
12.5 90 363 3.35375 2.42704153856 2.742487805455
12.5 100 373 5.16816 7.31538302403 1.4153161624086

x(a)
400

350

300

250

200

150

100

50

0
283 293 303 313 323 333 343 353 363 373
363 373

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