Thermal expansion refers to a fractional
change in size of a material in response to a
    change in temperature.
     This includes…
    o     changes in length compared to original
      length (Δℓ/ℓ ) called linear expansion
                  0
    o     changes in area compared to original area
      (ΔA/A ) called areal expansion or superficial
           0
      expansion
    o     changes in volume compared to original
      volume (ΔV/V ) called volumetric
                      0
      expansion or cubical expansion
     For most materials, over small temperature
    ranges, these fractional changes…
    o     are directly proportional to temperature
      change (ΔT) and
    o     have the same sign (i.e., materials usually
      expand when heated and contract when
      cooled)
    o     are larger for liquids than solids
     A coefficient of thermal expansion…
    o     is the ratio of the fractional change in size
      of a material to its change in temperature
    o     is represented by the symbol α (alpha) for
      solids and β (beta) for liquids
    o     uses the SI unit inverse kelvin (K  or 1/K) or
                                            −1
      the equivalent acceptable non SI unitinverse
      degree Celsius (℃  or 1/℃).
                          −1
     Solids…
  o     tend to retain their shape when not
    constrained and so are best described by a
    linear coefficient of thermal
    expansion, α (alpha).
  o     have an areal expansion that is very nearly
    twice their linear expansion, 2α (since two
    perpendicular linear measurements describe
    an area)
  o     have a volumetric expansion that is very
    nearly three times their linear
    expansion, 3α(since three perpendicular linear
    measurements describe a volume)
   Liquids…
  o     tend to take on the shape of their container
    and so are best described by a volumetric
    coefficient of thermal expansion, β (beta).
   Gases…
  o     have a thermal expansion that is best
    described using the ideal gas law
    described laterin this book.
  equation solids
Δℓ  =  ℓ αΔT linear expansion
          0
 Δ A 2αΔ
    =    areal (or superficial) expansion
 A    0T
 Δ V 3αΔ
    =    volumetric (or cubical) expansion
 V    0T
equation    liquids
Δ V
   =  βΔT volumetric (or cubical) expansion
V   0
equation    gases
P           ideal gas law (We are not going to
   =  nRT
V           use this)
        Equations of thermal expansion