Syllabus: Cambridge O Level Chemistry 5070
Syllabus: Cambridge O Level Chemistry 5070
Syllabus: Cambridge O Level Chemistry 5070
Cambridge O Level
Chemistry 5070
Use this syllabus for exams in 2022.
Exams are available in the June and November series.
Version 1
Please check the syllabus page at www.cambridgeinternational.org/olevel
to see if this syllabus is available in your administrative zone.
Changes to the syllabus for 2022
The latest syllabus is version 1, published September 2019.
There are no significant changes which affect teaching.
Any textbooks endorsed to support the syllabus for examination from 2017 are still suitable for
use with this syllabus.
1. Introduction...................................................................................................................... 2
1.1 Why choose Cambridge International?
1.2 Why choose Cambridge O Level?
1.3 Why choose Cambridge O Level Chemistry?
1.4 How can I find out more?
2. Teacher support............................................................................................................... 5
2.1 Support materials
2.2 Endorsed resources
2.3 Training
3. Assessment at a glance................................................................................................... 6
5. Syllabus content............................................................................................................. 11
6. Practical assessment..................................................................................................... 26
6.1 Paper 3: Practical Test
6.2 Paper 4: Alternative to Practical
6.3 Practical techniques
6.4 Apparatus
6.5 Reagents list
6.6 Guidance for the preparation of reagents
7. Appendix........................................................................................................................ 31
7.1 Qualitative Analysis Notes
7.2 The Periodic Table of Elements
7.3 Glossary of terms used in science papers
8. Other information........................................................................................................... 35
Introduction
1. Introduction
Our Cambridge Pathway gives students a clear path for educational success from age 5 to 19. Schools can
shape the curriculum around how they want students to learn – with a wide range of subjects and flexible
ways to offer them. It helps students discover new abilities and a wider world, and gives them the skills
they need for life, so they can achieve at school, university and work.
Our programmes and qualifications set the global standard for international education. They are created
by subject experts, rooted in academic rigour and reflect the latest educational research. They provide a
strong platform for students to progress from one stage to the next, and are well supported by teaching and
learning resources.
Every year, nearly a million Cambridge learners from 10 000 schools in 160 countries prepare for their future
with the Cambridge Pathway.
Cambridge learners
Our mission is to provide educational benefit through provision of international programmes and
qualifications for school education and to be the world leader in this field. Together with schools, we
develop Cambridge learners who are:
• confident in working with information and ideas – their own and those of others
• responsible for themselves, responsive to and respectful of others
• reflective as learners, developing their ability to learn
• innovative and equipped for new and future challenges
• engaged intellectually and socially, ready to make a difference.
Recognition
Our expertise in curriculum, teaching and learning, and assessment is the basis for the recognition of our
programmes and qualifications around the world.
Cambridge Assessment International Education is an education organisation and politically neutral. The
content of this syllabus, examination papers and associated materials do not endorse any political view.
We endeavour to treat all aspects of the exam process neutrally.
Quality management
Cambridge International is committed to providing exceptional quality. In line with this commitment, our
quality management system for the provision of international qualifications and education programmes
for students aged 5 to 19 is independently certified as meeting the internationally recognised standard,
ISO 9001:2015. Learn more at www.cambridgeinternational.org/ISO9001
Our aim is to balance knowledge, understanding and skills in our programmes and qualifications to enable
students to become effective learners and to provide a solid foundation for their continuing educational
journey.
Through our professional development courses and our support materials for Cambridge O Levels, we
provide the tools to enable teachers to prepare students to the best of their ability and work with us in the
pursuit of excellence in education.
Cambridge O Levels are considered to be an excellent preparation for Cambridge International AS & A Levels,
the Cambridge AICE (Advanced International Certificate of Education) Diploma, Cambridge Pre-U, and other
education programmes, such as the US Advanced Placement program and the International Baccalaureate
Diploma programme. Learn more about Cambridge O Levels at www.cambridgeinternational.org/olevel
Cambridge O Level Chemistry is recognised by universities and employers throughout the world as proof
of knowledge and understanding. Successful Cambridge O Level Chemistry candidates gain lifelong skills,
including:
• a better understanding of the technological world in which they live, and take an informed interest in
science and scientific developments
• knowledge of the basic principles of chemistry through a mix of theoretical and practical studies
• an understanding of the scientific skills essential for further study at Cambridge International
AS and A Level, and skills which are useful in everyday life
• how science is studied and practised, and an awareness that the results of scientific research can have
both good and bad effects on individuals, communities and the environment.
Candidates may also study for a Cambridge O Level in a number of other science subjects including physics
and biology. In addition to Cambridge O Levels, Cambridge also offers Cambridge IGCSE and Cambridge
International AS and A Levels for further study in both chemistry as well as other science subjects. See
www.cambridgeinternational.org for a full list of the qualifications you can take.
Prior learning
We recommend that candidates who are beginning this course should have previously studied a science
curriculum such as that of the Cambridge Lower Secondary Programme or equivalent national educational
frameworks. Candidates should also have adequate mathematical skills for the content contained in this
syllabus.
Progression
Cambridge O Levels are general qualifications that enable candidates to progress either directly to
employment, or to proceed to further qualifications.
Candidates who are awarded grades C to A* in Cambridge O Level Chemistry are well prepared to follow
courses leading to Cambridge International AS & A Level Chemistry, or the equivalent.
2. Teacher support
For teachers at registered Cambridge schools a range of additional support materials for specific syllabuses
is available online from the School Support Hub. Go to www.cambridgeinternational.org/support
(username and password required). If you do not have access, speak to the School Support coordinator at
your school.
We have resource lists which can be filtered to show all resources, or just those which are endorsed by
Cambridge International. The resource lists include further suggestions for resources to support teaching.
See www.cambridgeinternational.org/i-want-to/resource-centre for further information.
2.3 Training
We offer a range of support activities for teachers to ensure they have the relevant knowledge and skills to
deliver our qualifications. See www.cambridgeinternational.org/events for further information.
3. Assessment at a glance
For Cambridge O Level Chemistry, candidates take three components: Paper 1 and Paper 2 and either
Paper 3 or Paper 4. Candidates will be eligible for grades A* to E.
40 compulsory multiple-choice questions. A copy of the Periodic Table is provided as part of this
paper (see Appendix).
40 marks
Details of the syllabus and requirements for this A written paper of compulsory short-answer
paper are given in section 6. and structured questions designed to test
Candidates may not refer to notebooks, familiarity with laboratory practical procedures.
textbooks or any other information during the Further details are given in section 6.
practical examination.
Qualitative Analysis Notes are provided. Qualitative Analysis Notes are not provided.
40 marks scaled to a mark out of 30 60 marks scaled to a mark out of 30
Availability
This syllabus is examined in the June and November examination series.
This syllabus is available to private candidates. However, it is expected that private candidates learn in an
environment where practical work is an integral part of the course. Candidates will not be able to perform
well in this assessment or progress successfully to further study without this necessary and important
aspect of science education.
All Cambridge schools are allocated to one of six administrative zones. Each zone has a specific timetable.
Please note that Cambridge O Level, Cambridge IGCSE and Cambridge IGCSE (9–1) syllabuses are at the
same level.
Syllabus content defines the factual material that candidates may be required to recall and explain.
Questions testing these objectives will often begin with one of the following words: define, state, describe,
explain or outline (see the glossary of terms in section 7.3).
These assessment objectives cannot be precisely specified in the syllabus content because questions
testing such skills may be based on information that is unfamiliar to the candidate. In answering such
questions, candidates are required to use principles and concepts that are within the syllabus and apply
them in a logical, deductive or reasoned manner to a new situation. Questions testing these skills will often
begin with one of the following words: predict, suggest, calculate or determine (see the glossary of terms in
section 7.3).
The apparatus and techniques that candidates should be familiar with are given in part 1 of the syllabus
content and in the section on practical assessment. See also Appendix.
To avoid difficulties arising out of the use of L as the symbol for litre, use of dm3 in place of L or litre will be
made.
In accordance with current ASE convention, decimal markers in examination papers will be a single dot on
the line. Candidates are expected to follow this convention in their answers.
Candidates should give all answers to an appropriate number of significant figures and quantities should
have an appropriate unit. Marks will be awarded for these skills.
5. Syllabus content
It is expected that any course in chemistry will be based on experimental work. Teachers are encouraged
to develop appropriate practical work for candidates to facilitate a greater understanding of the subject.
Candidates should be aware of the hazards and the appropriate safety precautions to follow when handling
equipment and reagents in experimental work.
Teachers are reminded that, in the written papers, some of the marks are allocated to the higher ‘thinking’
skills of AO2. In almost every section of the syllabus, candidates should be given practice at dealing with
unfamiliar situations so that these higher thinking skills can be developed.
1 Experimental chemistry
Content
1.1 Experimental design
1.2 Methods of purification and analysis
1.3 Identification of ions and gases
It is expected that any course in chemistry will be based on experimental work. Teachers are encouraged
to develop appropriate practical work for candidates to facilitate a greater understanding of the subject.
Candidates should be aware of the hazards and appropriate safety precautions to follow when handling the
reagents mentioned in this section.
Learning outcomes
Candidates should be able to:
1.1 Experimental design
(a) name appropriate apparatus for the measurement of time, temperature, mass and volume, including
burettes, pipettes, measuring cylinders and gas syringes
(b) suggest suitable apparatus, given relevant information, for a variety of simple experiments, including
collection of gases and measurement of rates of reaction
1.2 Methods of purification and analysis
(a) describe methods of purification by the use of a suitable solvent, filtration and crystallisation,
distillation and fractional distillation, with particular references to the fractional distillation of crude oil,
liquid air and mixtures of liquids
(b) suggest suitable methods of purification, given information about the substances involved
(c) describe paper chromatography and interpret chromatograms including comparison with ‘known’
samples and the use of Rf values
(d) explain the need to use locating agents in the chromatography of colourless compounds
(e) deduce from given melting point and boiling point information, the identities of substances and their
purity
(f) explain that the measurement of purity in substances used in everyday life, e.g. foodstuffs and
drugs, is important
1.3 Identification of ions and gases
(a) describe the use of aqueous sodium hydroxide and aqueous ammonia to identify the following
aqueous cations: aluminium, ammonium, calcium, chromium( III ), copper( II ), iron( II ), iron( III ) and
zinc (formulae of complex ions are not required)
(b) describe tests to identify the following anions: carbonate (by the addition of dilute acid and
subsequent use of limewater); chloride (by reaction of an aqueous solution with nitric acid and
aqueous silver nitrate); iodide (by reaction of an aqueous solution with nitric acid and aqueous
silver nitrate); nitrate (by reduction with aluminium and aqueous sodium hydroxide to ammonia and
subsequent use of litmus paper), sulfate (by reaction of an aqueous solution with nitric acid and
aqueous barium nitrate), and sulfite (by warming with dilute acid)
(c) describe tests to identify the following gases: ammonia (using damp red litmus paper); carbon
dioxide (using limewater); chlorine (using damp litmus paper); hydrogen (using a burning splint);
oxygen (using a glowing splint) and sulfur dioxide (using acidified potassium manganate( VII ))
(d) describe a chemical test for water
Learning outcomes
Candidates should be able to:
2.1 Kinetic particle theory
(a) describe the solid, liquid and gaseous states of matter and explain their interconversion in terms of
the kinetic particle theory and of the energy changes involved
(b) describe and explain evidence for the movement of particles in liquids and gases (the treatment of
Brownian motion is not required)
(c) explain everyday effects of diffusion in terms of particles, e.g. the spread of perfumes and cooking
aromas; tea and coffee grains in water
(d) state qualitatively the effect of molecular mass on the rate of diffusion and explain the dependence
of rate of diffusion on temperature
(e) state qualitatively and explain the effects of temperature and pressure on the volumes of gases
2.2 Atomic structure
(a) state the relative charges and approximate relative masses of a proton, a neutron and an electron
(b) describe, with the aid of diagrams, the structure of an atom as containing protons and neutrons
(nucleons) in the nucleus and electrons arranged in shells (energy levels) (no knowledge of s, p, d
and f classification will be expected; a copy of the Periodic Table will be available in Papers 1 and 2)
(c) define proton number and nucleon number
12
(d) interpret and use symbols such as 6 C
(e) define the term isotopes
(f) deduce the numbers of protons, neutrons and electrons in atoms and ions from proton and nucleon
numbers
2.3 Structure and properties of materials
(a) describe the differences between elements, compounds and mixtures
(b) compare the structure of simple molecular substances, e.g. methane, iodine, with those of giant
covalent substances, e.g. sand (silicon dioxide), diamond, graphite in order to deduce their properties
(c) compare the bonding and structures of diamond and graphite in order to deduce properties such
as electrical conductivity, lubricating or cutting action (candidates will not be required to draw the
structures)
(d) deduce the physical and chemical properties of substances from their structures and bonding and
vice versa
4 Electrolysis
Candidates should be able to:
(a) describe electrolysis as the conduction of electricity by an ionic compound (an electrolyte), when molten
or dissolved in water, leading to the decomposition of the electrolyte
(b) describe electrolysis as evidence for the existence of ions which are held in a lattice when solid but
which are free to move when molten or in solution
(c) describe, in terms of the mobility of ions present and the electrode products, the electrolysis of molten
lead bromide, using inert electrodes
(d) predict the likely products of the electrolysis of a molten compound
(e) apply the idea of selective discharge (linked to the reactivity series for cations, see 9.2) to deduce the
electrolysis products of aqueous solutions; describe the electrolysis of concentrated aqueous sodium
chloride, aqueous copper( II ) sulfate and dilute sulfuric acid using inert electrodes
(f) predict the likely products of the electrolysis of an aqueous electrolyte, given relevant information
(g) construct equations for the reactions occurring at each electrode (anode and cathode) during electrolysis
(h) describe the electrolysis of purified aluminium oxide dissolved in molten cryolite as the method of
extraction of aluminium (see 9.5(a))
(i) describe the electrolysis of aqueous copper(II) sulfate with copper electrodes as a means of purifying copper
(j) describe the electroplating of metals, including copper plating, and recall one use of electroplating
(k) describe the production of electrical energy from simple cells (i.e. two electrodes in an electrolyte) linked
to the reactivity series (see 9.2)
6 Chemical reactions
Content
6.1 Rate of reaction
6.2 Redox
6.3 Reversible reactions
Learning outcomes
Candidates should be able to:
6.1 Rate of reaction
(a) describe the effect of concentration, pressure, particle size and temperature on the rates of reactions
and explain these effects in terms of collisions between reacting particles
(b) define the term catalyst and describe the effect of catalysts (including enzymes) on the rates of
reactions
(c) explain how pathways with lower activation energies account for the increase in rates of reactions
(d) state that transition elements and their compounds act as catalysts (see 8.3) in a range of industrial
processes and that enzymes are biological catalysts
(e) suggest a suitable method for investigating the effect of a given variable on the rate of a reaction
(f) interpret data obtained from experiments concerned with rate of reaction
6.2 Redox
(a) define oxidation and reduction (redox) in terms of oxygen/hydrogen gain/loss
(b) define redox in terms of electron transfer
(c) identify redox reactions in terms of oxygen/hydrogen, and/or electron, gain/loss (calculation of
oxidation numbers is not required)
(d) describe the use of aqueous potassium iodide in testing for oxidising agents and acidified potassium
manganate( VII ) in testing for reducing agents from the resulting colour changes
6.3 Reversible reactions
(a) describe the idea that some chemical reactions can be reversed by changing the reaction conditions
(b) describe the idea that some reversible reactions can reach dynamic equilibrium and predict and
explain the effect of changing the conditions (see 7.3(b) and 7.3(c))
Learning outcomes
Candidates should be able to:
7.1 The characteristic properties of acids and bases
(a) describe the meanings of the terms acid and alkali in terms of the ions they contain or produce in
aqueous solution and their effects on Universal Indicator paper
(b) describe how to test hydrogen ion concentration and hence relative acidity using Universal Indicator
paper and the pH scale
(c) describe the characteristic properties of acids as in reactions with metals, bases and carbonates
(d) describe qualitatively the difference between strong and weak acids in terms of the extent of
dissociation
(e) describe neutralisation as a reaction between hydrogen ions and hydroxide ions to produce
water, H+ + OH – → H2O
(f) describe the importance of controlling the pH in soils and how excess acidity can be treated using
calcium hydroxide
(g) describe the characteristic properties of bases in reactions with acids and with ammonium salts
(h) classify oxides as acidic, basic or amphoteric, based on metallic/non-metallic character
7.2 Preparation of salts
(a) describe the techniques used in the preparation, separation and purification of salts as examples of
some of the techniques specified in Section 1.2(a)
(methods for preparation should include precipitation and titration together with reactions of acids
with metals, insoluble bases and insoluble carbonates)
(b) describe the general rules of solubility for common salts to include nitrates, chlorides (including silver
and lead), sulfates (including barium, calcium and lead), carbonates, hydroxides, Group I cations and
ammonium salts
(c) suggest a method of preparing a given salt from suitable starting materials, given appropriate
information
(d) describe the meanings of the terms hydrated, anhydrous and water of crystallisation
7.3 Properties and uses of ammonia
(a) describe the use of nitrogen, from air, and hydrogen, from cracking hydrocarbons, in the manufacture
of ammonia
(b) state that some chemical reactions are reversible (e.g. manufacture of ammonia)
(c) describe and explain the essential conditions for the manufacture of ammonia by the Haber process
(d) describe the use of nitrogenous fertilisers in promoting plant growth and crop yield
(e) compare nitrogen content of salts used for fertilisers by calculating percentage masses
(f) describe eutrophication and water pollution problems caused by nitrates leaching from farm land and
explain why the high solubility of nitrates increases these problems
(g) describe the displacement of ammonia from its salts and explain why adding calcium hydroxide to
soil can cause the loss of nitrogen from added nitrogenous fertiliser
Learning outcomes
Candidates should be able to:
8.1 Periodic trends
(a) describe the Periodic Table as an arrangement of the elements in the order of increasing proton
(atomic) number
(b) describe how the position of an element in the Periodic Table is related to proton number and
electronic configuration
(c) describe the relationship between group number and the ionic charge of an element
(d) explain the similarities between the elements in the same group of the Periodic Table in terms of
their electronic configuration
(e) describe the change from metallic to non-metallic character from left to right across a period of the
Periodic Table
(f) describe the relationship between group number, number of valence electrons and metallic/
non‑metallic character
(g) predict the properties of elements in Group I, VII and the transition elements using the Periodic Table
8.2 Group properties
(a) describe lithium, sodium and potassium in Group I (the alkali metals) as a collection of relatively soft,
low-density metals showing a trend in melting point and in their reaction with water
(b) describe chlorine, bromine and iodine in Group VII (the halogens) as a collection of diatomic
non‑metals showing a trend in colour, state and their displacement reactions with solutions of other
halide ions
(c) describe the elements in Group VIII (the noble gases, also known as Group 0) as a collection of
monatomic elements that are chemically unreactive and hence important in providing an inert
atmosphere, e.g. argon and neon in light bulbs; helium in balloons; argon in the manufacture of steel
(d) describe the lack of reactivity of the noble gases in terms of their electronic configuration
8.3 Transition elements
(a) describe the central block of elements (transition metals) as metals having high melting points, high
density, variable oxidation state and forming coloured compounds
(b) state the use of these elements and/or their compounds as catalysts, e.g. iron in the Haber process;
vanadium(V) oxide in the contact process; nickel in the hydrogenation of alkenes, and how catalysts
are used in industry to lower energy demands and hence are economically advantageous and help
conserve energy sources
9 Metals
Content
9.1 Properties of metals
9.2 Reactivity series
9.3 Extraction of metals
9.4 Iron
9.5 Aluminium
Learning outcomes
Candidates should be able to:
9.1 Properties of metals
(a) describe the general physical properties of metals (as solids having high melting and boiling points;
malleable; good conductors of heat and electricity) in terms of their structure
(b) describe an alloy as a mixture of a metal with another element, e.g. brass; stainless steel
(c) identify representations of metals and alloys from diagrams of structures
(d) explain why alloys have different physical properties from their constituent elements
9.2 Reactivity series
(a) place in order of reactivity: aluminium (see also 9.5(b)), calcium, copper, (hydrogen), iron, lead,
magnesium, potassium, silver, sodium and zinc by reference to
(i) the reactions, if any, of the metals with water, oxygen, steam and dilute hydrochloric acid,
(ii) the reduction, if any, of their oxides by carbon and/or by hydrogen
(b) d
escribe the reactivity series as related to the tendency of a metal to form its positive ion, illustrated
by its reaction with
(i) the aqueous ions of the other listed metals
(ii) the oxides of the other listed metals
(c) deduce the order of reactivity from a given set of experimental results
(d)
describe the action of heat on the carbonates of the listed metals and relate thermal stability to the
reactivity series
9.3 Extraction of metals
(a) describe the ease of obtaining metals from their ores by relating the elements to their positions in
the reactivity series
(b) describe metal ores as a finite resource and hence the need to recycle metals
(c) discuss the social, economic and environmental advantages and disadvantages of recycling metals,
e.g. aluminium and copper
9.4 Iron
(a) describe and explain the essential reactions in the extraction of iron using haematite, limestone and
coke in the blast furnace
(b) describe steels as alloys which are a mixture of iron with carbon and often other metals and how
controlled use of these additives changes the properties of the iron, e.g. high carbon steels are
strong but brittle whereas low carbon steels are softer and more easily shaped
(c) state the uses of mild steel (e.g. car bodies; machinery) and stainless steel (e.g. chemical plant;
cutlery; surgical instruments)
(d) describe the essential conditions for the corrosion (rusting) of iron as the presence of oxygen and
water; prevention of rusting can be achieved by placing a barrier around the metal (e.g. painting;
greasing; plastic coating; galvanising)
(e) describe the sacrificial protection of iron by a more reactive metal in terms of the reactivity series
where the more reactive metal corrodes preferentially (e.g. underwater pipes have a piece of
magnesium attached to them)
9.5 Aluminium
(a) outline the manufacture of aluminium from pure aluminium oxide dissolved in cryolite (starting
materials and essential conditions, including identity of electrodes should be given together with
equations for the electrode reactions but no technical details or diagrams are required)
(b) explain the apparent lack of reactivity of aluminium
(c) state the uses of aluminium and relate the uses to the properties of this metal and its alloys, e.g. the
manufacture of aircraft; food containers; electrical cables
Learning outcomes
Candidates should be able to:
10.1 Air
(a) d
escribe the volume composition of gases present in dry air as 78% nitrogen, 21% oxygen and the
remainder being noble gases (with argon as the main constituent) and carbon dioxide
(b) describe the separation of oxygen, nitrogen and the noble gases from liquid air by fractional
distillation
(c) state the uses of oxygen (e.g. in making steel; oxygen tents in hospitals; in welding)
(d) n
ame some common atmospheric pollutants (e.g. carbon monoxide; methane; nitrogen oxides
(NO and NO2); ozone; sulfur dioxide; unburned hydrocarbons)
(e) state the sources of these pollutants as
(i) carbon monoxide from incomplete combustion of carbon-containing substances
(ii) methane from bacterial decay of vegetable matter
(iii) nitrogen oxides from lightning activity and internal combustion engines
(iv) ozone from photochemical reactions responsible for the formation of photochemical smog
(v) sulfur dioxide from volcanoes and combustion of fossil fuels
(vi) unburned hydrocarbons from internal combustion engines
(f) d
escribe the reactions used in possible solutions to the problems arising from some of the pollutants
named in (d)
(i) the redox reactions in catalytic converters to remove combustion pollutants
(ii) the use of calcium carbonate to reduce the effect of ‘acid rain’ and in flue gas desulfurisation
(g) discuss some of the effects of these pollutants on health and on the environment
(i) the poisonous nature of carbon monoxide
(ii) the role of nitrogen dioxide and sulfur dioxide in the formation of ‘acid rain’ and its effects on
organisms and buildings
(h) discuss the importance of the ozone layer and the problems involved with the depletion of ozone by
reaction with chlorine-containing compounds, chlorofluorocarbons (CFCs)
(i) describe the carbon cycle in simple terms, to include
(i) the processes of combustion, respiration and photosynthesis
(ii) how the carbon cycle regulates the amount of carbon dioxide in the atmosphere
(j) state that carbon dioxide and methane are greenhouse gases and may contribute to global warming,
give the sources of these gases and discuss the possible consequences of an increase in global
warming
10.2 Water
(a) state that water from natural sources contains a variety of dissolved substances
(i) naturally occurring (mineral salts; oxygen; organic matter)
(ii) pollutant (metal compounds; sewage; nitrates from fertilisers; phosphates from fertilisers and
detergents; harmful microbes)
(b) discuss the environmental effects of the dissolved substances named in (a)
(i) beneficial, e.g. oxygen and mineral salts for aquatic life
(ii) pollutant, e.g. hazards to health; eutrophication
(c) outline the purification of the water supply in terms of
(i) filtration to remove solids
(ii) use of carbon to remove tastes and odours
(iii) chlorination to disinfect the water
(d) describe how sea water can be converted into drinkable water by desalination
11 Organic chemistry
Content
11.1 Alkanes
11.2 Alkenes
11.3 Alcohols
11.4 Carboxylic acids
11.5 Polymers
*The use of molecular models is recommended to enable students to appreciate the three-dimensional
structures of molecules.
Learning outcomes
Candidates should be able to:
(a) state that the naphtha fraction from petroleum (crude oil) is the main source of hydrocarbons used as the
feedstock for the production of a wide range of organic compounds
(b) describe the issues relating to the competing uses of oil as an energy source and as a chemical
feedstock
11.1 Alkanes
(a) describe a homologous series as a group of compounds with a general formula, similar chemical
properties and showing a gradation in physical properties as a result of increase in the size and mass
of the molecules, e.g. melting and boiling points; viscosity
(b) describe the alkanes as a homologous series of saturated hydrocarbons with the general
formula CnH2n + 2
(c) draw the structures of branched and unbranched alkanes, C1 to C4, and name the unbranched
alkanes, methane to butane
(d) define isomerism and identify isomers
(e) describe the properties of alkanes (exemplified by methane) as being generally unreactive except in
terms of burning and substitution by chlorine
11.2 Alkenes
(a) describe the alkenes as a homologous series of unsaturated hydrocarbons with the general
formula CnH2n and containing the C=C functional group
(b) draw the structures of branched and unbranched alkenes, C2 to C4, and name the unbranched
alkenes, ethene to butene
(c) describe the manufacture of alkenes and hydrogen by cracking hydrocarbons and recognise that
cracking is essential to match the demand for fractions containing smaller molecules from the
fractional distillation of petroleum (crude oil)
(d) describe the difference between saturated and unsaturated hydrocarbons in terms of their structures
and in their reaction with aqueous bromine
(e) describe the properties of alkenes in terms of combustion, polymerisation and their addition
reactions with bromine, steam and hydrogen
(f) state the meaning of polyunsaturated when applied to food products
(g) describe the manufacture of margarine by the addition of hydrogen to unsaturated vegetable oils to
form a solid product
11.3 Alcohols
(a) describe the alcohols as a homologous series containing the –OH functional group
(b) draw the structures of alcohols, C1 to C4, and name the unbranched alcohols, methanol to butanol
(c) describe the properties of alcohols in terms of combustion and oxidation to carboxylic acids
(d) describe the formation of ethanol by the catalysed addition of steam to ethene and by fermentation
of glucose
(e) state some uses of ethanol, e.g. as a solvent; as a renewable fuel; in the production of vinegar
11.4 Carboxylic acids
(a) describe the carboxylic acids as a homologous series containing the –CO2H functional group
(b) draw the structures of carboxylic acids, methanoic acid to butanoic acid, and name the unbranched
acids, methanoic to butanoic acids
(c) describe the carboxylic acids as weak acids, reacting with carbonates, bases and some metals
(d) describe the formation of ethanoic acid by the oxidation of ethanol by acidified potassium
manganate( VII ) and the formation of vinegar by bacterial oxidation
(e) describe the reaction of carboxylic acids from C1 to C4 with alcohols from C1 to C4 to form esters
(f) draw the structures of and name the esters formed from carboxylic acids (see 11.4 (b)) and alcohols
(see 11.3 (b))
(g) state some commercial uses of esters, e.g. perfumes; flavourings; solvents
11.5 Polymers
(a) describe polymers as large molecules made from many small units called monomers, different
polymers having different repeat units and/or different linkages
(b) describe the formation of poly(ethene) as an example of addition polymerisation of ethene as the
monomer
(c) state some uses of poly(ethene) as a typical plastic, e.g. plastic bags; clingfilm
(d) describe nylon, a polyamide, and Terylene, a polyester, as condensation polymers, the partial
structure of nylon being represented as
O O O O
H H H H
and the partial structure of Terylene as
O O O O
(e) state some typical uses of synthetic fibres such as nylon and Terylene, e.g. clothing; curtain
materials; fishing line; parachutes; sleeping bags
(f) deduce the partial structure of the polymer product from a given monomer and vice versa
(g) describe the pollution problems caused by the disposal of non-biodegradable plastics
(h) identify proteins and complex carbohydrates (polysaccharides, e.g. starch) as natural polymers
(i) describe proteins as polymers possessing the same amide linkages as nylon but formed from
different monomers
(j) describe fats as molecules possessing the same ester linkages as Terylene
(k) describe the hydrolysis of proteins to amino acids and complex carbohydrates (polysaccharides, e.g.
starch) to simple sugars
6. Practical assessment
Scientific subjects are, by their nature, experimental. So it is important that an assessment of a candidate’s
knowledge and understanding of chemistry should contain a component relating to practical work and
experimental skills. Two alternative means of assessment are provided:
• Paper 3 – Practical Test
• Paper 4 – Alternative to Practical (written paper).
Systematic analysis will not be required but it will be assumed that candidates will be familiar with the
reactions of the following cations with aqueous sodium hydroxide and aqueous ammonia (aluminium,
ammonium, calcium, chromium( III ), copper( II ), iron( II ), iron( III ) and zinc), and with the tests for the anions
(carbonate, chloride, iodide, nitrate and sulfate) and gases (ammonia, carbon dioxide, chlorine, hydrogen and
oxygen) as detailed in the Qualitative Analysis Notes, which will be included with the question paper and are
reproduced in this syllabus document.
Exercises involving organic substances and ions not on the list above may be set but candidates will only be
required to record observations and to draw general conclusions.
Candidates may also be required to carry out simple calculations as detailed in the theory syllabus.
Candidates are not allowed to refer to note books, text books or any other information in the Practical Test.
Supervisors are reminded of their responsibilities for supplying the examiners with the information specified
in the instructions. Failure to supply such information may cause candidates to be unavoidably penalised.
Please refer to the section on science syllabuses in the Cambridge Handbook, which includes information
about arrangements for practical examinations.
6.4 Apparatus
This list given below has been drawn up in order to give guidance to schools concerning the apparatus that
is expected to be generally available for examination purposes. The list is not intended to be exhaustive, in
particular, items (such as Bunsen burners, tripods) that are commonly regarded as standard equipment in a
chemical laboratory are not included. The rate of allocation is ‘per candidate’.
• one burette, 50 cm3
• one pipette, 25 cm3
• a pipette filler
• two conical flasks within the range 150 cm3 to 250 cm3
• measuring cylinders, 25 cm3 and 10 cm3
• a filter funnel
• a beaker, squat form with lip: 250 cm3
• a thermometer, –10 °C to +110 °C at 1 °C intervals
• a polystyrene, or other plastic beaker of approximate capacity 150 cm3
• clocks (or wall-clock) to measure to an accuracy of 1 s (where clocks are specified candidates may use
their own wrist-watch if they prefer)
• wash bottle
• test-tubes (some of which should be Pyrex or hard glass), approximately 125 mm × 16 mm
• boiling tubes, approximately 150 mm × 25 mm
• stirring rod
• teat/dropping pipettes
• spatula
• test-tube holder (to hold test-tubes or boiling tubes)
Detailed guidance on preparing standard bench reagents and indicators will not be given in the Confidential
Instructions. The Confidential Instructions will refer Supervisors to the guidance notes in section 6.6 of this
syllabus document.
The following hazard codes are used where relevant and are in accordance with information provided by
CLEAPSS* at the time of publication of this syllabus. Centres should be aware that the United Nations
Global Harmonised System for hazard classification and compatible labelling (2015) is in the process of being
implemented and therefore Centres are advised to make full use of the ‘Safety Data Sheets’ supplied with
chemicals for current hazard information. The attention of Centres is also drawn to any local regulations
relating to safety, first-aid and disposal of chemicals.
C = corrosive
MH = moderate hazard
HH = health hazard
T = acutely toxic
F = flammable
O = oxidising
N = hazardous to the aquatic environment
* An advisory service providing support in practical science and technology for schools and colleges,
www.cleapss.org.uk
7. Appendix
Group
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)
Appendix
17. Sketch, when applied to graph work, implies that the shape and/or position of the curve need only
be qualitatively correct, but candidates should be aware that, depending on the context, some
quantitative aspects may be looked for, e.g. passing through the origin, having an intercept, asymptote or
discontinuity at a particular value.
In diagrams, sketch implies that a simple, freehand drawing is acceptable: nevertheless, care should be
taken over proportions and the clear exposition of important details.
18. Construct is often used in relation to chemical equations where a candidate is expected to write a
balanced equation, not by factual recall but by analogy or by using information in the question.
8. Other information
The standard assessment arrangements may present unnecessary barriers for candidates with disabilities
or learning difficulties. Arrangements can be put in place for these candidates to enable them to access the
assessments and receive recognition of their attainment. Access arrangements will not be agreed if they
give candidates an unfair advantage over others or if they compromise the standards being assessed.
Candidates who are unable to access the assessment of any component may be eligible to receive an award
based on the parts of the assessment they have taken.
Language
This syllabus and the associated assessment materials are available in English only.
Making entries
Exams officers are responsible for submitting entries to Cambridge International. We encourage them to
work closely with you to make sure they enter the right number of candidates for the right combination of
syllabus components. Entry option codes and instructions for submitting entries are in the Cambridge Guide
to Making Entries. Your exams officer has a copy of this guide.
Exam administration
To keep our exams secure, we produce question papers for different areas of the world, known as
‘administrative zones’. We allocate all Cambridge schools to one administrative zone determined by their
location. Each zone has a specific timetable. Some of our syllabuses offer candidates different assessment
options. An entry option code is used to identify the components the candidate will take relevant to the
administrative zone and the available assessment options.
Retakes
Candidates can retake the whole qualification as many times as they want to. This is a linear qualification so
candidates cannot re-sit individual components.