This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.
This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.
This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.
This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.
9. Objective To introduce the laws of thermodynamics and their applications to chemical equilibrium conditions.
10. Details of the Course:
Sl. Contents Contact
No. Hours 1 Introduction to Thermodynamics: Basic concept and definitions- 2 concept of state, reversible and irreversible processes, path and state functions, extensive and intensive properties, thermodynamic equilibrium, zeroth law of thermodynamics 2 First Law of Thermodynamics: Internal energy, Enthalpy, Constant 5 volume and pressure process; Isothermal and adiabatic process. 3 Second Law of Thermodynamics: Criterion for equilibrium, Entropy 7 and disorder, Most probable microstate, Configutational entropy and thermal entropy; Auxiliary functions, Maxwells relations, Gibbs- Helmholtz equation. 4 Third Law of Thermodynamics: Variation of Gibbs energy with 8 temperature and pressure, Clausius-Clapeyron equation; Thermodynamic properties of mixtures of ideal and imperfect gasses; reaction in gas mixtures, reaction of pure condensed phases with gas mixture, Standard Gibbs energy of reactions, Ellingham diagrams. 5 Theory and Models of Metallic Solutions: Raoults and Henrys law, 8 activity of a component, Gibbs-Duhem equation, non-ideal solutions, regular solutions, quasi-chemical model of solutions, activity and alternative standard state; Reaction equilibrium in condensed systems, Gibbs phase rule; Derivation of binary phase diagrams, ternary phase diagrams 6 Relation Between Chemical and Electrical Driving Forces: Nernst 6 equation, concentration and formation cells, Pourbaix diagram, Thermodynamics of point defects, Thermodynamics of surfaces. 7 Metallurgical Kinetics: Heterogeneous reaction; Gas-solid, solid- 6
1 liquid, liquid-liquid and solid-solid systems. Empirical and Semi- empirical Kinetics, Concept of Johnson-Mehl equation, Thermal analysis. Total 42
