BHARATHIAR UNIVESITY COIMBATORE
Syllabus for
Post-Graduate Diploma in Nanotechnology
(With effect from 2008-2009)
BHARATHIAR UNIVESITY, COIMBATORE
POST-GRADUATE DIPLOMA IN NANOTECHNOLOGY
With effect from 2008-2009 Scheme of Examinations Semester I
Paper
Title of the Paper
Marks
Paper I Paper II
Fundamentals of Nanoscale Science Synthesis and Characterization of Nanomaterials
100 100
Paper III Paper IV Paper V
Nanoelectronics and Nanolithography Nanobiotechnology and Devices Nanotechnology Practicals
100 100 100
Semester II
Paper Paper VI
Title of the Paper Project & Viva-Voce
Marks 200
PAPER I -FUNDAMENTALS OF NANOSCALE SCIENCE Unit I Background to nanotechnology: scientific revolutions  types of nanotechnology and nano machines  atomic structure  molecules & phases  energy  molecular and atomic size  surfaces and dimensional space  top down and bottom up. Unit II Basic problems and limitations -opportunities at the nanoscale  time and length scale in structures  energy landscapes  basic intermolecular forces  interdynamic aspects of intermolecular forces. Evolution of Band structures and Fermi surface. Unit III Definition of a nano system -dimensionality and size dependent phenomena; Quantum dots, Nanowires and Nanotubes, 2D films; Nano & mesopores  size dependent variation in Magnetic, electronic transport, reactivity etc., Unit IV Forces between atoms and molecules, particles and grain boundaries, surfaces -strong intermolecular forces -Van der Waals and electrostatic forces between surfaces  similarities and differences between intermolecular and interparticle forces  covalent and coulomb interactions  interactions involving polar molecules and polarization  weak intermolecular forces and total intermolecular pair potentials  Forces between solvation, hydration; polymers at surfaces; adhesion  thermodynamics of self-assembly; micelles, bilayers, vesicles  bionanomachines  biological membranes. References: 1 2 3 4 5 6 7 Nanotechnology: basic science and emerging technologies  Mick Wilson, Kamali Kannangara, Geoff Smith, Michelle Simmons, Burkhard Raguse, Overseas Press (2005). Amorphous and Nanocrystalline Materials: Preparation , Properties, and Applications, A.Inoue, K.Hashimoto (Eds.,) (2000) Understanding Nanotechnology, Scientific American, editors at Scientific American, Warner Books (2002) Introduction to Nanotechnology by Charles P. Poole, Frank J. Owens, Wiley-Interscience (2003). www. nanonet.rice.edu/intronanosci/ www.acclab.helsinki.fi/~knordlun/nanotiede/ Nanotechnology: A Gentle Introduction to the Next Big Idea, Mark A. Ratner, Daniel Ratner, Mark Ratne, Prentice Hall PTR; 1st edition (2002)
PAPER II -SYNTHESIS AND CHARACTERIZATION OF NANOMATERIALS Unit I Introduction : various preparation techniques  basic concepts of nanostructured materials  nucleation  grain size distribution  nano particle transport in low density media  vapour nano phase thermodynamics  coagulation of nano particles  aggregate formation  mass fractal morphologies Unit II Synthesis Methods: Sol-gel processing  self assembly - ball milling - chemical vapour deposition method  catalytic route  plasma arcing  electro deposition  pyrolytic synthesis  thermal evaporation  Spray Pyrolysis, Flame Pyrolysis - molecular beam epitaxy  pulsed laser deposition  sputter deposition  chemical solution deposition  Langmuir Blodgelt films  different types of nanomaterials. Unit III
Characterization: X-ray diffraction  determination of grain size  Scherrer formula  dislocation density  micro strain - macro molecular crystallography using synchrotron radiation properties of light and nano technology  Magnetic characterization  micro hardness  nano indentation.
Unit IV
Scanning electron microscopy  transmission electron microscopy - atomic force microscopy  scanning tunneling microscopy - nano manipulator  nano tweezers  PL - XPS  ICP.
References: 1 2 3 4 5 www.eng.uc.edu/~gbeaucag/Classes/NanoPowder.html Nanoelectronics and information technology: Advanced electronic materials and novel nd devices (2 edition), Rainer Waser (Ed.), Wiley-VCH Verlag, Weiheim (2005). Recent Advances in the Liquid-phase syntheses if inorganic nanoparticles, Brain L.Cushing, Vladimir L.Kolesnichenko, Charles J. OConnor, Chem Rev. 104 (2004) 3893-3946. Nanocomposite science and technology, Pulickel M.Ajayan, Linda S.Schadler, Paul V.Braun, Wiley-VCH Verlag, Weiheim (2003). Amorphous and Nanocrystalline Materials: Preparation, Properties, and Applications, A.Inoue, K.Hashimoto (Eds.,) (2000).
PAPER III - NANOELECTRONICS AND NANOLITHOGRAPHY Unit I Basics of nano electronics - what will nano electronics do for us?  some physical fundamentals  basics of information theory- the birth of electronics  the tools for micro and nano fabricationBasics of Lithographic techniques for nanoelectronics. Unit II Quantum electronic devices : from classical to quantum physics - upcoming electronic devices  short channel MOS transistor  split gate transistor  electron wave transistor  electron spin transistor  quantum cellular automate  quantum dot array  principles of Single Electron Transistor (SET)  Nano electronics with tunneling devices  tunneling element technology RTD  Molecular electronics - elementary circuits  flux quantum devices  applications of super conducting devices.
Unit III Optical lithography  principle  nano designs for electronic circuits  Electron lithography  principle  Applications  Ion beam lithography  types of ion beam lithography - Applications. Unit IV E-beam nanolithography  principle and its application  Proximal probe nanolithography Principles of STM , AFM and dip pen nanolithography _ applications. References: 1. 2. 3. 4. 5. 6. Nanoelectronics and Nanosystems: From transistors to molecular devices. K.Goser, P. Glosekotter, J. Dienstuhl, Springer (2004) Nanoelectronics and information technology: Advanced electronic materials and novel devices (2nd edition), Rainer Waser (Ed.), Wiley-VCH Verlag, Weiheim (2005). Nanotechnology: basic science and emerging technologies  Mick Wilson, Kamali Kannangara, Geoff Smith, Michelle Simmons, Burkhard Raguse, Overseas Press (2005). C.Y. Chang and S.M.Sze, ULSI Technology, McGraw-Hill Companies Inc.,Singapore, 1996. John N. Helbert, Hand Book of VLSI Microlithography, Noyes Publication, USA, 2001. James R. Sheats and Bruce W. Amith, Microlithography Sciences and Technology, Marcel Dekker Inc., New York, 1998.
PAPER IV  NANOBIOTECHNOLOGY AND DEVICES Unit I Biology inspired concepts - biological networks  biological Neurons  the function of neuronal cell  biological neuronal cells on silicon modeling of neuronal cells by VLSI circuits bioelectronics  molecular Processor  DNA analyzer as biochip  molecular electronics Unit II Nano-biometrics - introduction  lipids as nano-bricks and mortar: self assembled nanolayers  the bits that do think  proteins  three dimensional structures using a 20 amino acid  biological computing  A Protein based 3D optical memory using DNA to build nano cubes and hinges DNA as smart glue  DNA as wire template  DNA computer. Unit III
Nanocarriers for Drug Delivery - Needs and Requirements  Nanoparticle Flow: Implications for Drug Delivery  Polymeric Nanoparticles as Drug Carriers and Controlled Release - Implant Devices  Genetic Vaccines: A Role for Liposomes  Polymer Micelles as Drug Carriers  Recent Advances in Microemulsions as Drug Delivery Vehicles  Lipoproteins as Pharmaceutical Carriers  Solid Lipid Nanoparticles as Drug Carriers  Magnetic Nanoparticles as Drug Carriers. Unit IV Nanoscale Magetic devices: Nanomagnetism  Spintronics  GMR  Inter layer exchange coupling - Fabrication techniques  Memory devices and sensors  Nano ferroelectrics - ferroelectric random access memories  introduction  calorimetric sensors  electrochemical cells  electronic noses.
References
1. 2. 3. 4. 5. 6. Nanoelectronics and Nanosystems: From transistors to molecular devices. K.Goser, P. Glosekotter, J. Dienstuhl, Springer (2004) Nanotechnology: basic science and emerging technologies  Mick Wilson, Kamali Kannangara, Geoff Smith, Michelle Simmons, Burkhard Raguse, Overseas Press (2005). Nanobiotechnology: Concepts, Applications and Perspectives, Christof M.Niemeyer, / Chad A.Mirkin, (eds.), Wiley-VCH, Weinheim, (2004) Bionanotechnology : Lessons from Nature, by: David S. Goodsell, Wiley-Liss (2004) Nano Medicines Edited by Dr.Parag Diwan and Ashish Bharadwaj, Pentagon Press(2006) ISBN 81-8274-139-4 Nanoparticulates as Drug Carriers Edited by Vladimir P.Torchilin, Imperial College Press, North Eastern University, USA (2006) ISBN 1-86094-630-5 Magnetic Microscopy of Nanostructures, Hans P.Oepen and H.Hopster, Springer (2004) ISBN 3540401865 Ultra thin Magnetic Structures III  Fundamentals of Nanomagnetism, JAC Bland and B. Heinrich, Springer (2004) ISBN 3540219536 Magnetic Materials : Fundamentals and Device Applications, Nicola Ann Spaldin, Cambridge University Press (2003) ISBN 0521016584
7. 8. 9.
PAPER V NANOTECHNOLOGY PRACTICALS 1. Preparation of nanoparticles by Co-precipitation Method 2. Preparation nanoparticles by Sol-Gel 3. Preparation nanoparticles by Ball-mill 4. Preparation of thin films by Chemical Path deposition 5. Preparation of thin film by sputtering 6. Preparation of nanocomposite 7. Structural Studies by using X-ray diffraction 8. Surface analysis using AFM 9. Optical band-gap calculation using transmission spectra 10. Emission Spectra of nanoparticles by PL 11. Simulation of bionanotubes 12. Interaction of diatomic molecules inside the bionanotube.
PAPER VI  PROJECT WORK & VIVA VOCE