Revision Date: 24/06/2011

SDS No.

10093

SAFETY DATA SHEET Stirling Lloyd Solvent No. 1

According to Regulation (EC) No 1907/2006 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier
Product Name REACH Registration Number CAS-No. EU Index No. EC No. Stirling Lloyd Solvent No. 1 01-2119471330-49-XXXX 67-64-1 606-001-00-8 200-662-2

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Uses Advised Against Solvent Must not be handled in confined space without sufficient ventilation.

1.3. Details of the supplier of the safety data sheet

Supplier: STIRLING LLOYD POLYCHEM LTD. UNION BANK, KING STREET, KNUTSFORD, CHESHIRE, WA16 6EF. T : +44(0)1565 633111 (Technical/Commercial enquiries) F : +44(0)1565 633555 sdsadministrator@stirlinglloyd.com

1.4. Emergency telephone number

For chemical emergencies please contact the National Chemical Emergency Centre on :+44 (0)870 190 6777

SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture

Classification (EC 1272/2008) Physical and Chemical Hazards Flam. Liq. 2 - H225 Human health EUH066;Eye Irrit. 2 - H319;STOT Single 3 - H336 Environment Not classified. Xi;R36. F;R11. R66, R67.

Classification (1999/45/EEC)

2.2. Label elements

EC No. Contains: 200-662-2 ACETONE

Label In Accordance With (EC) No. 1272/2008

Signal Word Hazard Statements

Danger H225 H319 H336 Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. 1/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

Precautionary Statements P210 P243 P305+351+338 P403+235 P405 Supplementary Precautionary Statements P233 P240 P241a P242 P261e P264a P271 P280 P303+361+353 P304+340 P312 P337 P370 P378a P501a Supplemental Label Information (EU) EUH066 Repeated exposure may cause skin dryness or cracking. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store in a well-ventilated place. Keep cool. Store locked up. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical equipment. Use only non-sparking tools. Avoid breathing vapours. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: In case of fire: Use alcohol-resistant foam, carbon dioxide or dry powder for extinction. Dispose of contents/container in accordance with local regulations.

2.3. Other hazards

This product does not contain any PBT or vPvB Substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures

ACETONE CAS-No.: 67-64-1 EC No.: 200-662-2 60-100%

Classification (EC 1272/2008) Flam. Liq. 2 - H225 EUH066 Eye Irrit. 2 - H319 STOT Single 3 - H336 REACH Registration Number CAS-No. EU Index No. EC No. 01-2119471330-49-XXXX 67-64-1 606-001-00-8 200-662-2

Classification (67/548/EEC) F;R11 Xi;R36 R66 R67

The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16

SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures

General Information NOTE! Keep affected person away from heat, sparks and flames! Inhalation. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Perform artificial respiration if breathing has stopped. Keep the affected person warm and at rest. Get prompt medical attention.

2/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! DO NOT INDUCE VOMITING! Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Get medical attention immediately! Skin Contact Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention if any discomfort continues. Eye Contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General Information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation. Vapours may cause headache, fatigue, dizziness and nausea. Ingestion May cause nausea, headache, dizziness and intoxication. Burning sensation in mouth. May cause stomach pain or vomiting. Skin Contact Prolonged or repeated contact with skin may cause redness, itching, irritation and eczema/chapping. Eye Contact Irritation, burning, lachrymation, blurred vision after liquid splash.

4.3. Indication of any immediate medical attention and special treatment needed
No specific first aid measures noted.

SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media

Extinguishing Media Use: Foam. Carbon dioxide (CO2). Water spray, fog or mist. Dry chemicals, sand, dolomite etc. Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Hazardous Combustion Products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards Forms explosive mixtures with air. May explode in a fire. May travel considerable distance to source of ignition and flash back. Vapours are heavier than air and may spread near ground to sources of ignition.

5.3. Advice for firefighters

Special Fire Fighting Procedures Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Use water spray to reduce vapours. Water spray may be used to flush spills away from exposures and dilute spills to non-flammable mixtures. Protective Measures In Fire Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.

6.2. Environmental precautions

Do not allow to enter drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up

Stop leak if possible without risk. Provide ventilation and confine spill. Do not allow runoff to sewer. Collect for reclamation or absorb in vermiculite, dry sand or similar material. Containers with collected spillage must be properly labelled with correct contents and hazard symbol.

6.4. Reference to other sections

For personal protection, see section 8. See section 11 for additional information on health hazards.

3/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Static electricity and formation of sparks must be prevented. Use explosion proof electric equipment.

7.2. Conditions for safe storage, including any incompatibilities

Flammable/combustible - Keep away from oxidisers, heat and flames. May attack some plastics, rubber and coatings. Store in tightly closed original container in a dry, cool and well-ventilated place. Ground container and transfer equipment to eliminate static electric sparks. Storage Class Flammable liquid storage.

7.3. Specific end use(s)

Usage Description Solvent

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters

Name ACETONE WEL = Workplace Exposure Limit. DNEL DNEL DNEL DNEL DNEL DNEL PNEC PNEC PNEC PNEC PNEC PNEC Industry Industry Industry Consumer Consumer Consumer Freshwater Marinewater Sediment Sediment Soil STP Dermal Inhalation. Inhalation. Oral Dermal Inhalation. 10.6 1.06 30.4 3.04 29.5 29.5 Long Term Short Term Long Term Long Term Long Term Long Term mg/l mg/l mg/kg mg/kg mg/kg mg/l 186 mg/kg/day 2420 mg/m3 1210 mg/m3 62 mg/kg/day 62 mg/kg/day 200 mg/m3 STD WEL TWA - 8 Hrs 500 ppm 1210 mg/m3 STEL - 15 Min 1500 ppm 3620 mg/m3 Notes

8.2. Exposure controls

Protective Equipment

Engineering Measures Explosion-proof general and local exhaust ventilation. Respiratory Equipment Gas mask with organic vapour canister (chin-style). Hand Protection Use protective gloves made of: Butyl rubber. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye Protection Wear approved safety goggles. Other Protection Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station. Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear air-supplied mask in confined areas.

4/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

Hygiene Measures DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet. Use appropriate hand lotion to prevent defatting and cracking of skin.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties
Appearance Colour Odour Solubility Initial Boiling Point and Boiling Range: Melting Point (C) Relative Density Vapour Density (Air=1) Vapour Pressure Evaporation Rate Evaporation Factor Viscosity Solubility Value (G/100G H2O@20C) Odour Threshold, Lower Flash Point (C) Auto Ignition Temperature (C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Liquid Clear Colourless Pleasant, agreeable. Characteristic Acetone, ketone. Miscible with water Miscible with: Alcohol Ether. ~ 56C @ 760 mm Hg ~ -95 0.79 @ 20 C 2 182.00 hPa @ 20 C 2 (EtEt=1) 1.40 0.32 mPas @ 20 C 100.00 100.00 ~ -18C CC (Closed cup). 465C 2.15% 13.30% -0.24

9.2. Other information

Refractive Index Mol. Weight Volatile By Vol. (%) 1.358-1.359 58.08 100%

SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity

Will react violently with: Strong oxidising substances. Reacts with alkalis and amines generating excessive heat.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions

Hazardous Polymerisation Will not polymerise.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.

10.5. Incompatible materials

Materials To Avoid Strong oxidising substances.

10.6. Hazardous decomposition products

During fire, toxic gases (CO, CO2) are formed.

SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects

Toxic Dose 1 - LD 50 5800 mg/kg (oral rat) 5/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

Other Health Effects IARC Not Listed. NTP Not Listed. Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Skin Corrosion/Irritation - Animal Data Serious Eye Damage/Irritation Respiratory Sensitisation Guinea Pig There is no evidence that the material can lead to respiratory hypersensitivity. Skin Sensitisation Mouse Not Sensitising. Germ Cell Mutagenicity (In Vitro) Gene Mutation: Negative. Carcinogenicity Inhalation Vapours may cause drowsiness and dizziness. Skin Contact Repeated exposure may cause skin dryness or cracking. Eye Contact Irritating to eyes. Health Warnings Gas or vapour is harmful on prolonged exposure or in high concentrations. Gas or vapour is harmful on prolonged exposure or in high concentrations. Irritant of eyes and mucous membranes. Narcotic effect. CNS depressant. Prolonged or repeated contact leads to drying of skin. Repeated exposure may cause chronic eye irritation. Route of entry Inhalation. Skin absorption. Ingestion. Skin and/or eye contact. Target Organs Central nervous system Eyes Gastro-intestinal tract Respiratory system, lungs Skin Medical Symptoms Irritation of eyes and mucous membranes. Upper respiratory irritation. Skin irritation. NOAEL 79 mg/kg Dermal Rat 5800 mg/kg Rat 20000 mg/kg Rabbit 76 mg/l (vapours) Rat 4 hours Rabbit Draize test: Slightly irritating. Draize test: Irritating to eyes.

SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity

Acute Fish Toxicity Not considered toxic to fish. Acute Toxicity - Fish Acute Toxicity - Aquatic Invertebrates Acute Toxicity - Aquatic Plants Chronic Toxicity - Aquatic Invertebrates Phototransformation Stability (Hydrolysis) No significant reaction in water. Biodegradation Water 84 Degradation (%): 5 days The substance is readily biodegradable. LC50 96 hours 5540 mg/l Onchorhynchus mykiss (Rainbow trout) EC50 48 hours 8800 mg/l Daphnia magna EC50 96 hours 7000 mg/l Selenastrum capricornutum NOEC 28 days 2212 mg/l Daphnia magna

12.2. Persistence and degradability

Air. DT50 ~ 15 days

12.3. Bioaccumulative potential

Bioaccumulative Potential: The product is not bioaccumulating. Bioaccumulation Factor BCF 3 6/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

Partition Coefficient log Pow -0.24

12.4. Mobility in soil

Mobility: Highly volatile. The product is miscible with water. May spread in water systems. Henry's Law Constant 2.303 Pa m3/mol Surface Tension 23.3 mN/m

12.5. Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

None known.

SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION 14.1. UN number

UN No. (ADR/RID/ADN) UN No. (IMDG) UN No. (ICAO) 1090 1090 1090

14.2 UN Proper shipping name

Proper Shipping Name ACETONE

14.3 Transport hazard class(es)

ADR/RID/ADN Class ADR/RID/ADN Class ADR Label No. IMDG Class ICAO Class/Division Transport Labels 3 Class 3: Flammable liquids. 3 3 3

14.4. Packing group

ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group II II II

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

EMS Emergency Action Code Hazard No. (ADR) Tunnel Restriction Code F-E, S-D 2YE 33 (D/E)

7/ 8

SDS No.

10093

Stirling Lloyd Solvent No. 1

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable. No information required.

SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. National Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 ("CDG 2009"), SI 2009 No 1348 Health And Environmental Listings Regulation EC 2037/2000 on substances that deplete the ozone layer. Regulation EC 850/2004 on persistent organic pollutants. Regulation EC 689/2008 concerning the export and import of dangerous chemicals. None of the ingredients are listed. Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006) No specific restrictions of use are noted for this product. Water Hazard Classification WGK 1

15.2. Chemical Safety Assessment

A chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

General Information This product is intended for use for the application set out in the technical data sheet only. The Risk Phrases shown below relate to the individual components in Section 3 and NOT to the Product. The Risk Phrases for the Product are shown in Section 2. . Revision Date 24/06/2011 Risk Phrases In Full R11 Highly flammable. , R36 Irritating to eyes. , R66 Repeated exposure may cause skin dryness or cracking. , R67 Vapours may cause drowsiness and dizziness. Hazard Statements In Full EUH066 Repeated exposure may cause skin dryness or cracking. , H225 Highly flammable liquid and vapour. , H319 Causes serious eye irritation. , H336 May cause drowsiness or dizziness.

Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8/ 8