Search Results (2,554)

Eucalyptus essential oil is widely valued for its therapeutic properties and extensive commercial applications, with its chemical composition significantly influenced by species variety, geographical origin, and environmental conditions. This study aims to develop a reliable method for identifying the geographical origin and variety of eucalyptus oil samples through the application of advanced analytical techniques combined with chemometric methods. Essential oils from Eucalyptus globulus and Eucalyptus camaldulensis were analyzed using Gas Chromatography–Flame Ionization Detection (GC–FID) and Fourier Transform Infrared (FTIR) Spectroscopy. Chemometric analyses, including Orthogonal Partial Least Squares-Discriminant Analysis (O2PLS-DA) and Hierarchical Cluster Analysis (HCA), were utilized to classify the oils based on their volatile compound profiles. Notably, O2PLS-DA was applied directly to the raw FTIR data without additional spectral processing, showcasing its robustness in handling unprocessed data. For geographical origin determination, the GC–FID model achieved a Correct Classification Rate (CCR) of 100%, with 100% specificity and 100% sensitivity for both calibration and validation sets. FTIR spectroscopy achieved a CCR of 100%, specificity of 100%, and sensitivity of 100% for the calibration set, while the validation set yielded a CCR of 95.83%, specificity of 99.02%, and sensitivity of 94.44%. In contrast, the analysis based on species variety demonstrated 100% accuracy across all metrics CCR, specificity, and sensitivity—for both calibration and validation using both techniques. These findings underscore the effectiveness of volatile and infrared spectroscopy profiling for quality control and authentication, providing robust tools for ensuring the consistency and reliability of eucalyptus essential oils in various industrial and therapeutic applications. Full article

Background: Simple surgical and clinical risk scores are useful in mortality prediction. Aims: The study’s aim was to validate three scores in real-world registry of percutaneous coronary intervention (PCI) for the left main coronary artery (LMCA). Methods: All data were obtained from the BIA-LM Registry. Discrimination and calibration of EuroSCORE II, ACEF, CHA₂DS₂-VASc, and CHA₂DS₂-VA were assessed with receiver operating characteristic (ROC) curves analysis and Hosmer–Lemeshow (HL) test. Results: The final cohort included 851 patients, median age was 71, and 156 patients had history of previous coronary artery bypass grafting (CABG). Median EuroSCORE II, ACEF, CHA₂DS₂-VASc, and CHA₂DS₂-VA were 3.1% (IQR 5.4%), 1.56 (IQR 0.9), 4 (IQR 2), and 4 (IQR 2), respectively. In the short- (30 days) and long-term (mean 4.1 years), there were 27 and 318 deaths. In short-term, EuroSCORE II showed the best discrimination in the overall population and subgroup with unprotected LMCA [area under the curve (AUC) 0.804, 95% CI 0.717–0.890 and AUC 0.826, 95% CI 0.737–0.913, respectively, p < 0.001 for comparisons with other models), with the best cut-off value at 7.1%. In long-term observation, EuroSCORE II and ACEF showed good predictive value (overall population: AUC 0.716, 95% CI 0.680–0.750 and AUC 0.725, 95% CI 0.690–760, respectively). In short- and long-term observation, EuroSCORE II and ACEF showed poor calibration (HL test p < 0.05) as compared to CHA₂DS₂-VASc (HL test p = 0.40 and 0.18). Conclusions: EuroSCORE II showed good mortality prediction in short-term observation; however, its predicted risk should be interpreted with caution due to poor calibration. ACEF and EuroSCORE II may be useful in long-term mortality prediction. Full article

Indonesian stingless bee honey (SBH) of Geniotrigona thoracica is popular and traded at an expensive price. Brown rice syrup (RS) is frequently used as a cheap adulterant for an economically motivated adulteration (EMA) in SBH. In this study, authentic Indonesian Geniotrigona thoracica SBH of Acacia mangium (n = 100), adulterated SBH (n = 120), fake SBH (n = 100), and RS (n = 200) were prepared. In short, 2 mL of each sample was dropped directly into an innovative sample holder without any sample preparation including no dilution. Fluorescence intensity was acquired using a fluorescence spectrometer. This portable instrument is equipped with a 365 nm LED lamp as the fixed excitation source. Principal component analysis (PCA) was calculated for the smoothed spectral data. The results showed that the authentic SBH and non-SBH (adulterated SBH, fake SBH, and RS) samples could be well separated using the smoothed spectral data. The cumulative percentage variance of the first two PCs, 98.4749% and 98.4425%, was obtained for calibration and validation, respectively. The highest prediction accuracy was 99.5% and was obtained using principal component analysis–linear discriminant analysis (PCA-LDA). The best partial least square (PLS) calibration was obtained using the combined interval with R²_cal = 0.898 and R²_val = 0.874 for calibration and validation, respectively. In the prediction, the developed model could predict the adulteration level in the adulterated honey samples with an acceptable ratio of prediction to deviation (RPD) = 2.282, and range error ratio (RER) = 6.612. Full article

Multi-baseline circular synthetic aperture radar (MB CSAR) can be applied to obtain a three-dimensional (3D) image of the observation scene. However, the phase error caused by radar platform motion or atmospheric propagation delay restricts its 3D imaging capabilities. The phase error calibration of MB CSAR data is an essential step in the 3D imaging procedure due to the limited accuracy of positioning sensors. Phase gradient autofocus (PGA) is widely utilized to estimate the phase errors but is subject to shifts in the direction perpendicular to the line of sight and long iteration time in some sub-apertures. In this paper, an improved PGA method for MB CSAR 3D imaging is proposed, which can suppress the shifts and reduce computation time. This method is based on phase gradient estimation, but the prominent units are selected with an energy criterion. Then, weighted phase gradient estimation is presented to suppress the influence of prominent units with poor quality. Finally, a contrast criterion is adopted to reach faster convergence. The experimental results based on the measured MB CSAR data (Gotcha dataset) demonstrate the validity and feasibility of the proposed phase error calibration method for MB CSAR 3D imaging. Full article

South Korea’s River Act mandates the maintenance of instream flow to support river ecosystems. This regulation has evolved from early river management practices to more advanced, systematic approaches, including the Instream Flow Incremental Methodology (IFIM). Despite these advancements, river management in South Korea, particularly in the Seomjin River Basin, continues to face numerous challenges. In this study, a three-dimensional numerical model was developed to simulate the hydrodynamic and salinity conditions of the Seomjin River Estuary. This study proposes optimal instream flows to support critical habitats for the Corbicula bivalve, which has seen a significant decline due to salinity intrusion by environmental changes. Using the Environmental Fluid Dynamics Code (EFDC), the model simulates salinity and river discharge with calibration and validation by incorporating historical data. Subsequently, this study evaluates how river discharge affects salinity in four major Corbicula habitats (Dugok, Shinbi, Mokdo, and Hwamok). Finally, we determine the minimum flow (instream flow) needed to sustain Corbicula habitats. In short, this study found that the minimum flow rates (instream flow) required to meet target salinities varied significantly across these sites and under different tidal conditions. These findings highlight the necessity of adapting river flow management practices to preserve the ecological health for Corbicula in the Seomjin River Estuary. Furthermore, this study suggests integrating an additional water supply to be used with local water management plans by suggesting short-term and long-term alternatives in order to sustain adapting river minimum flow (instream flow). Full article

The upcoming Landsat Next will provide more frequent land surface observations at higher spatial and spectral resolutions that will greatly benefit the agricultural sector. Early modeling of the upcoming Landsat Next products for soybean yield prediction is essential for long-term satellite monitoring strategies. In this context, this article evaluates the contribution of Landsat Next’s improved spectral resolution for soybean yield prediction under varying levels of water availability. Ground-based hyperspectral data collected over five cropping seasons at the Brazilian Agricultural Research Corporation were resampled to Landsat Next spectral resolution. The spectral dataset (n = 384) was divided into calibration and external validation datasets and investigated using three strategies for soybean yield prediction: (1) using the reflectance from each spectral band; (2) using existing and new vegetation indices developed based on three general equations: Normalized Difference Vegetation Index (NDVI-like), Band Ratio Vegetation Index (RVI-like), and Band Difference Vegetation Index (DVI-like), replacing the traditional spectral bands by all possible combinations between two bands for index calculation; and (3) using a partial least squares regression (PLSR) model composed of all Landsat Next spectral bands, in comparison to PLSR models using Landsat OLI and Sentienel-2 MSI bands. The results show the distribution of the new spectral bands over the most prominent changes in leaf reflectance due to water deficit, particularly in the visible and shortwave infrared spectrum. (1) Band 18 (centered at 1610 nm) had the highest correlation with yield (R² = 0.34). (2) A new vegetation index, called Normalized Difference Shortwave Vegetation Index (NDSWVI), is proposed and calculated from bands 19 and 20 (centered at 2028 and 2108 nm). NDSWVI showed the best performance (R² = 0.37) compared to traditional existing and new vegetation indices. (3) The PLSR model gave the best results (R² = 0.65), outperforming the Landsat OLI and Sentinel-2 MSI sensors. The improved spectral resolution of Landsat Next is expected to contribute to improved crop monitoring, especially for soybean crops in Brazil, increasing the sustainability of the production systems and strengthening food security in Brazil and globally. Full article

Timber–concrete composite (TCC) systems join the positive aspects of engineered wood products (good seismftaic behaviour, low thermal conductivity, environmental sustainability, good behaviour under fire if appropriately designed) with those of concrete (high thermal inertia, durability, excellent fire resistance). TCC facades are typically composed of an internal insulated timber-frame wall and an external concrete slab, separated by a ventilated air cavity. However, there is very limited knowledge concerning the performance of TCC facades, especially concerning their thermal behaviour. The present paper deals with the development and optimization of a 2D Computational Fluid Dynamic (CFD) model for the analysis of TCC ventilated façades’ thermal behaviour. The model is calibrated and validated against experimental data collected during the annual monitoring of a real TCC ventilated envelope in the north of Italy. Also, a new solver algorithm is developed to significantly speed up the simulation (i.e., 45 times faster simulation at an error below 3.5 °C compared to a typical CFD solver). The final model can be used for the time-efficient analysis (simulation time of approximately 23 min for a full day in real-time) and the optimization of the thermal performance of TCC ventilated facades, as well as other ventilated facades with external massive cladding. Our simulation strategy partially avoids the expensive and time-consuming construction of mock-ups, or the use of comparably slow (conventional) CFD solvers that are less suitable for optimization studies. Full article

Tree- and block-level prediction of mango yield is important for farm operations, but current manual methods are inefficient. Previous research has identified the accuracies of mango yield forecasting using very-high-resolution (VHR) satellite imagery and an ’18-tree’ stratified sampling method. However, this approach still requires infield sampling to calibrate canopy reflectance and the derived block-level algorithms are unable to translate to other orchards due to the influences of abiotic and biotic conditions. To better appreciate these influences, individual tree yields and corresponding canopy reflectance properties were collected from 2015 to 2021 for 1958 individual mango trees from 55 orchard blocks across 14 farms located in three mango growing regions of Australia. A linear regression analysis of the block-level data revealed the non-existence of a universal relationship between the 24 vegetation indices (VIs) derived from VHR satellite data and fruit count per tree, an outcome likely due to the influence of location, season, management and cultivar. The tree-level fruit count predicted using a random forest (RF) model trained on all calibration data produced a percentage root mean squared error (PRMSE) of 26.5% and a mean absolute error (MAE) of 48 fruits/tree. The lowest PRMSEs produced from RF-based models developed from location, season and cultivar subsets at the individual tree level ranged from 19.3% to 32.6%. At the block level, the PRMSE for the combined model was 10.1% and the lowest values for the location, seasonal and cultivar subset models varied between 7.2% and 10.0% upon validation. Generally, the block-level predictions outperformed the individual tree-level models. Maps were produced to provide mango growers with a visual representation of yield variability across orchards. This enables better identification and management of the influence of abiotic and biotic constraints on production. Future research could investigate the causes of spatial yield variability in mango orchards. Full article

Wind estimation is crucial for studying the atmospheric boundary layer. Traditional methods such as weather balloons offer limited in situ capabilities; besides an Air Data System (ADS) combined with inertial measurements and satellite positioning is required to estimate the wind on fixed-wing drones. As pressure probes are an important constituent of an ADS, they are susceptible to malfunctioning or failure due to blockages, thus affecting the capability of wind sensing and possibly the safety of the drone. This paper presents a novel approach, using low-fidelity aerodynamic models of drones to estimate wind synthetically. In our work, the aerodynamic model parameters are derived from post-processed flight data, in contrast to existing approaches that use expensive wind tunnel calibration for identifying the same. In sum, our method integrates aerodynamic force and moment models into a Vehicle Dynamic Model (VDM)-based navigation filter to yield a synthetic wind estimate without relying on an airspeed sensor. We validate our approach using two geometrically distinct drones, each characterized by a unique aerodynamic model and different quality of inertial sensors, altogether tested across several flights. Experimental results demonstrate that the proposed cross-platform method provides a synthetic wind velocity estimate, thus offering a practical backup to traditional techniques. Full article

Background: Head and neck carcinosarcoma (HNCS) is a rare and highly aggressive malignancy with limited research, resulting in an incomplete understanding of disease progression and a lack of reliable prognostic tools. This study aimed to retrospectively analyze the clinical characteristics and outcomes of HNCS patients using data from the Surveillance, Epidemiology, and End Results (SEER) database and to develop a nomogram to predict overall survival (OS) and cancer-specific survival (CSS). Methods: Patients diagnosed with HNCS from 1975 to 2020 were identified in the SEER database. Univariate and multivariate Cox regression analyses were conducted to identify independent prognostic indicators, with the optimal model selected using the minimal Akaike Information Criterion (AIC). The identified prognostic factors were incorporated into nomograms to predict OS and CSS. Model performance was assessed using the concordance index (C-index), area under the curve (AUC), calibration curves, and decision curve analysis (DCA). Survival curves were generated using Kaplan–Meier analysis and compared via the log-rank test. Results: A total of 152 HNCS patients were included, with 108 assigned to the training cohort and 44 to the validation cohort in a 7:3 ratio. Prognostic factors including age, primary tumor site, marital status, radiotherapy, chemotherapy, tumor size, pathological grade, and tumor stage were incorporated into the nomogram models. The models demonstrated strong predictive performance, with C-index values for OS and CSS of 0.757 and 0.779 in the training group, and 0.777 and 0.776 in the validation group, respectively. AUC values for predicting 3-, 5-, and 10-year OS were 0.662, 0.713, and 0.761, and for CSS the values were 0.726, 0.703, and 0.693. Kaplan–Meier analysis indicated significantly improved survival for patients with lower risk scores. The 3-, 5-, and 10-year OS rates for the entire cohort were 54.1%, 45.6%, and 35.1%, respectively, and the CSS rates were 62.9%, 57.5%, and 52.2%, respectively. Conclusions: This study provides validated nomograms for predicting OS and CSS in HNCS patients, offering a reliable tool to support clinical decision-making for this challenging malignancy. These nomograms enhance the ability to predict patient prognosis and personalize treatment strategies. Full article

Forest fuels are the core element of fire management; each fuel component plays an important role in fire behavior. Therefore, accurate determination of their characteristics and spatial distribution is crucial. This paper introduces a novel method for mapping the spatial distribution of litter and duff fuel loads using data collected by unmanned aerial vehicles. The approach leverages a very high-resolution multispectral data analysis within a machine learning framework to achieve precise and detailed results. A set of vegetation indices and texture metrics derived from the multispectral data, optimized by a “Variable Selection Using Random Forests” (VSURF) algorithm, were used to train random forest (RF) models, enabling the modeling of high-resolution maps of litter and duff fuel loads. A field campaign to measure fuel loads was conducted in the mixed forest of the natural protected area of “Sierra de Quila”, Jalisco, Mexico, to measure fuel loads and obtain field reference data for calibration and validation purposes. The results revealed moderate determination coefficients between observed and predicted fuel loads with R² = 0.32, RMSE = 0.53 Mg/ha for litter and R² = 0.38, RMSE = 13.14 Mg/ha for duff fuel loads, both with significant p-values of 0.018 and 0.015 for litter and duff fuel loads, respectively. Moreover, the relative root mean squared errors were 33.75% for litter and 27.71% for duff fuel loads, with a relative bias of less than 5% for litter and less than 20% for duff fuel loads. The spatial distribution of the litter and duff fuel loads was coherent with the structure of the vegetation, despite the high complexity of the study area. Our modeling approach allows us to estimate the continuous high-resolution spatial distribution of litter and duff fuel loads, aligned with their ecological context, which dictates their dynamics and spatial variability. The method achieved acceptable accuracy in monitoring litter and duff fuel loads, providing researchers and forest managers with timely data to expedite decision-making in fire and forest fuel management. Full article

Underwater natural gas pipelines constitute critical infrastructure for energy transportation. Any damage or leakage in these pipelines poses serious security risks, directly threatening marine and lake ecosystems, and potentially causing operational issues and economic losses in the energy supply chain. However, current methods for detecting deterioration and regularly inspecting these submerged pipelines remain limited, as they rely heavily on divers, which is both costly and inefficient. Due to these challenges, the use of unmanned underwater vehicles (UUVs) becomes crucial in this field, offering a more effective and reliable solution for pipeline monitoring and maintenance. In this study, we conducted an underwater pipeline tracking and damage detection experiment using a remote-controlled unmanned underwater vehicle (UUV) with autonomous features. The primary objective of this research is to demonstrate that UUV systems provide a more cost-effective, efficient, and practical alternative to traditional, more expensive methods for inspecting submerged natural gas pipelines. The experimental method included vehicle (UUV) setup, pre-test calibration, pipeline tracking mechanism, 3D navigation control, damage detection, data processing, and analysis. During the tracking of the underwater pipeline, damages were identified, and their locations were determined. The navigation information of the underwater vehicle, including orientation in the x, y, and z axes (roll, pitch, yaw) from a gyroscope integrated with a magnetic compass, speed and position information in three axes from an accelerometer, and the distance to the water surface from a pressure sensor, was integrated into the vehicle. Pre-tests determined the necessary pulse width modulation values for the vehicle’s thrusters, enabling autonomous operation by providing these values as input to the thruster motors. In this study, 3D movement was achieved by activating the vehicle’s vertical thruster to maintain a specific depth and applying equal force to the right and left thrusters for forward movement, while differential force was used to induce deviation angles. In pool experiments, the unmanned underwater vehicle autonomously tracked the pipeline as intended, identifying damages on the pipeline using images captured by the vehicle’s camera. The images for damage assessment were processed using a convolutional neural network (CNN) algorithm, a deep learning method. The position of the damage relative to the vehicle was estimated from the pixel dimensions of the identified damage. The location of the damage relative to its starting point was obtained by combining these two positional pieces of information from the vehicle’s navigation system. The damages in the underwater pipeline were successfully detected using the CNN algorithm. The training accuracy and validation accuracy of the CNN algorithm in detecting underwater pipeline damages were 94.4% and 92.87%, respectively. The autonomous underwater vehicle also followed the designated underwater pipeline route with high precision. The experiments showed that the underwater vehicle followed the pipeline path with an error of 0.072 m on the x-axis and 0.037 m on the y-axis. Object recognition and the automation of the unmanned underwater vehicle were implemented in the Python environment. Full article

Given the recent proliferation of Unmanned Aerial Systems (UASs) and the consequent importance of counter-UASs, this project aims to perform the detection and tracking of small non-cooperative UASs using Electro-optical (EO) and Infrared (IR) sensors. Two data integration techniques, at the decision and pixel levels, are compared with the use of each sensor independently to evaluate the system robustness in different operational conditions. The data are submitted to a YOLOv7 detector merged with a ByteTrack tracker. For training and validation, additional efforts are made towards creating datasets of spatially and temporally aligned EO and IR annotated Unmanned Aerial Vehicle (UAV) frames and videos. These consist of the acquisition of real data captured from a workstation on the ground, followed by image calibration, image alignment, the application of bias-removal techniques, and data augmentation methods to artificially create images. The performance of the detector across datasets shows an average precision of 88.4%, recall of 85.4%, and [email protected] of 88.5%. Tests conducted on the decision-level fusion architecture demonstrate notable gains in recall and precision, although at the expense of lower frame rates. Precision, recall, and frame rate are not improved by the pixel-level fusion design. Full article

Sindh is in the lower reaches of the Indus River; it is most vulnerable to a variety of upstream water development challenges. The aim of this research was to determine aquifer characteristics in the command area of Tando Allahyar-II distributary within the culmination of underground water potential. The hydraulic properties of the aquifer as well as the susceptibility of the formation to tedious extraction and saltwater upcoming were recognized. Three pumping tests were performed at head, middle, and tail reaches along the selected distributary. The drawdowns were measured at head reach (5.1667 h), at middle reach (6.0 h), and at tail reach (19.667 h) of the selected distributary by performing the pumping tests. Groundwater levels were lower at the tail reach compared to those at the head and middle reaches, likely due to a higher concentration of tubewells in the lower reach. The head and middle reaches showed higher groundwater levels, possibly due to constant head conditions promoting infiltration and recharge. The pumping test versus drawdown analysis revealed that the tubewells should be run with 7-h (on) and 4-h (off) operation. Further, the tubewells at all reaches (head, middle, and tail) should be closed for a minimum of 4 h between operations. This strategy would allow safe groundwater extraction, maintain water quality, and prevent water table depletion in the study area. The hydrodynamic and hydro-salinity behaviors were scrutinized in PWMIN 5.3 (version) by means of the MODFLOW mode. The results were estimated to compare the calibration and validation simulation outcomes using measured data. The model was successfully calibrated, and the root mean square (RMS) value of the head tubewell varied between 0.024 and 0.108, whereas it speckled between 0.0166 and 0.0349 for the middle tubewell and between 0.0659 and 0.0069 for the tail tubewell. The RMS values for hydrodynamic behavior for the head, middle, and tail reaches were less than 10%. These values represent a suitable match between the observed and simulated heads when a water table depletion of 1 to 2 m was observed due to extreme pumping. However, the average relative error values, for all validated procedures, were less than 10%. Full article

Validation of groundwater models is relatively challenging due to the need to reserve scarce water level data for calibration targets. In addition, traditional statistical validation metrics are unintuitive for non-technical audiences and do not directly identify model behaviors that require further refinement. We developed a novel model validation method that analyzes rate change events at pump-and-treat wells and statistically compares the water level responses at nearby monitoring wells between the data and model. The method takes advantage of events that occur alongside ambient pumping, unlike parameter estimation techniques that require independent drawdown or recovery events. The ability of the model to match well connections that are evident (or not evident) in the observations is characterized statistically, leading to four decision scenarios: model matches the observed connection (1) or lack thereof (2), model exhibits a connection that is not observed (3), or model over- or understates the observed connection (4). The method is applied to an FEHM-based groundwater flow and transport model that is shown to match 84.5% of the well connections analyzed. The method provides novel perspectives on the influence of calibration targets on the flow field and suggests that although the overall effect of drawdown targets was to improve the model, the choice of target well pairs creates flow pathways that may be inconsequential during normal operational conditions. The model adequately matches the flow over short spatial scales (<800 m) and over-represents the flow over greater distances (300–1200 m), suggesting the need for “null” drawdown targets in subsequent rounds of calibration. Full article