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Search Results (98)

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9 pages, 1346 KiB  
Proceeding Paper
From Grinding to Green Energy: Pursuit of Net-Zero Emissions in Cement Production
by Md. Shahariar Ahmed, Anica Tasnim and Golam Kabir
Eng. Proc. 2024, 76(1), 8; https://doi.org/10.3390/engproc2024076008 - 15 Oct 2024
Viewed by 207
Abstract
In an age of heightened environmental awareness and the pressing need for net-zero emissions, concerns over rising energy consumption in cement production, responsible for 5–8% of global CO2 emissions, have intensified. This paper proposes a novel pioneering framework that integrates Shannon’s entropy [...] Read more.
In an age of heightened environmental awareness and the pressing need for net-zero emissions, concerns over rising energy consumption in cement production, responsible for 5–8% of global CO2 emissions, have intensified. This paper proposes a novel pioneering framework that integrates Shannon’s entropy and Multi-Criteria Decision Making (MCDM) methods to steer the cement industry towards sustainability and net-zero emissions. Utilizing Shannon’s entropy, the research impartially determines the significance of multiple criteria, reducing biases in decision-making for energy efficiency in cement production. Four MCDM methods (TOPSIS, VIKOR, ELECTRE, WSM) are applied to rank energy efficiency alternatives, providing a nuanced analysis of options for the cement industry. The study integrates sensitivity analysis to evaluate the robustness of MCDM methods under varying conditions, assessing the impact of changes in criteria weights on the ranking of energy efficiency alternatives and showcasing the adaptability of the proposed framework. Examining six diverse scenarios reveals the framework’s adaptability and the versatility of the Horizontal Roller Mill (HRM), with the Vertical Roller Mill (VRM) emerging as a cost-effective emission reduction alternative. This interdisciplinary approach, integrating information theory, decision science, and environmental engineering, extends beyond industry relevance, providing valuable insights aligned with global sustainability goals. Harmonizing economic viability with ecological responsibility, this report offers an instructive guide, propelling the cement industry toward a more sustainable future. Full article
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<p>Flow diagram of energy-intensive cement [<a href="#B2-engproc-76-00008" class="html-bibr">2</a>,<a href="#B4-engproc-76-00008" class="html-bibr">4</a>] production (wet process).</p>
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<p>Electricity consumption in various cement-making processes [<a href="#B3-engproc-76-00008" class="html-bibr">3</a>]. Distribution of energy among equipment used in cement manufacturing [<a href="#B4-engproc-76-00008" class="html-bibr">4</a>].</p>
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<p>Study framework.</p>
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<p>Ranking comparison with the method of paper.</p>
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15 pages, 853 KiB  
Article
Towards a Synthetic Positive Energy District (PED) in İstanbul: Balancing Cost, Mobility, and Environmental Impact
by Mine Sertsöz
Buildings 2024, 14(10), 3153; https://doi.org/10.3390/buildings14103153 - 3 Oct 2024
Viewed by 722
Abstract
The influence of mobility modes within Positive Energy Districts (PEDs) has gained limited attention, despite their crucial role in reducing energy consumption and greenhouse gas emissions. Buildings in the European Union (EU) account for 40% of energy consumption and 36% of greenhouse gas [...] Read more.
The influence of mobility modes within Positive Energy Districts (PEDs) has gained limited attention, despite their crucial role in reducing energy consumption and greenhouse gas emissions. Buildings in the European Union (EU) account for 40% of energy consumption and 36% of greenhouse gas emissions. In comparison, transport contributes 28% of energy use and 25% of emissions, with road transport responsible for 72% of these emissions. This study aims to design and optimize a synthetic PED in Istanbul that integrates renewable energy sources and public mobility systems to address these challenges. The renewable energy sources integrated into the synthetic PED model include solar energy, hydrogen energy, and regenerative braking energy from a tram system. Solar panels provided a substantial portion of the energy, while hydrogen energy contributed to additional electricity generation. Regenerative braking energy from the tram system was also utilized to further optimize energy production within the district. This system powers a middle school, 10 houses, a supermarket, and the tram itself. Optimization techniques, including Linear Programming (LP) for economic purposes and the Weighted Sum Method (WSM) for environmental goals, were applied to balance cost and CO2 emissions. The LP method identified that the PED model can achieve cost competitiveness with conventional energy grids when hydrogen costs are below $93.16/MWh. Meanwhile, the WSM approach demonstrated that achieving a minimal CO2 emission level of 5.74 tons requires hydrogen costs to be $32.55/MWh or lower. Compared to a conventional grid producing 97 tons of CO2 annually, the PED model achieved reductions of up to 91.26 tons. This study contributes to the ongoing discourse on sustainable urban energy systems by addressing key research gaps related to the integration of mobility modes within PEDs and offering insights into the optimization of renewable energy sources for reducing emissions and energy consumption. Full article
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<p>General view of the synthetic PED model.</p>
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<p>A comparison between different scenarios for cost (<span>$</span>) and CO<sub>2</sub> emission.</p>
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19 pages, 714 KiB  
Article
Combining Semantic Matching, Word Embeddings, Transformers, and LLMs for Enhanced Document Ranking: Application in Systematic Reviews
by Goran Mitrov, Boris Stanoev, Sonja Gievska, Georgina Mirceva and Eftim Zdravevski
Big Data Cogn. Comput. 2024, 8(9), 110; https://doi.org/10.3390/bdcc8090110 - 4 Sep 2024
Viewed by 1015
Abstract
The rapid increase in scientific publications has made it challenging to keep up with the latest advancements. Conducting systematic reviews using traditional methods is both time-consuming and difficult. To address this, new review formats like rapid and scoping reviews have been introduced, reflecting [...] Read more.
The rapid increase in scientific publications has made it challenging to keep up with the latest advancements. Conducting systematic reviews using traditional methods is both time-consuming and difficult. To address this, new review formats like rapid and scoping reviews have been introduced, reflecting an urgent need for efficient information retrieval. This challenge extends beyond academia to many organizations where numerous documents must be reviewed in relation to specific user queries. This paper focuses on improving document ranking to enhance the retrieval of relevant articles, thereby reducing the time and effort required by researchers. By applying a range of natural language processing (NLP) techniques, including rule-based matching, statistical text analysis, word embeddings, and transformer- and LLM-based approaches like Mistral LLM, we assess the article’s similarities to user-specific inputs and prioritize them according to relevance. We propose a novel methodology, Weighted Semantic Matching (WSM) + MiniLM, combining the strengths of the different methodologies. For validation, we employ global metrics such as precision at K, recall at K, average rank, median rank, and pairwise comparison metrics, including higher rank count, average rank difference, and median rank difference. Our proposed algorithm achieves optimal performance, with an average recall at 1000 of 95% and an average median rank of 185 for selected articles across the five datasets evaluated. These findings give promising results in pinpointing the relevant articles and reducing the manual work. Full article
(This article belongs to the Special Issue Advances in Natural Language Processing and Text Mining)
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<p>Overview of the process of user-driven dataset generation.</p>
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<p>Box plot representing rank distribution for selected papers across multiple datasets.</p>
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<p>Median rank of selected papers across review papers.</p>
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18 pages, 9930 KiB  
Article
A Comparative Study of Cloud Microphysics Schemes in Simulating a Quasi-Linear Convective Thunderstorm Case
by Juan Huo, Yongheng Bi, Hui Wang, Zhan Zhang, Qingping Song, Minzheng Duan and Congzheng Han
Remote Sens. 2024, 16(17), 3259; https://doi.org/10.3390/rs16173259 - 2 Sep 2024
Viewed by 595
Abstract
An investigation is undertaken to explore a sudden quasi-linear precipitation and gale event that transpired in the afternoon of 30 May 2024 over Beijing. It was situated at the southwestern periphery of a double-center low-vortex system, where a moisture-rich belt efficiently channeled abundant [...] Read more.
An investigation is undertaken to explore a sudden quasi-linear precipitation and gale event that transpired in the afternoon of 30 May 2024 over Beijing. It was situated at the southwestern periphery of a double-center low-vortex system, where a moisture-rich belt efficiently channeled abundant warm, humid air northward from the south. The interplay between dynamical lifting, convergent airflow-induced uplift, and the amplifying effects of the northern mountainous terrain’s topography creates favorable conditions that support the development and persistence of quasi-linear convective precipitation, accompanied by gale-force winds at the surface. The study also analyzes the impacts of five microphysics schemes (Lin, WSM6, Goddard, Morrison, and WDM6) employed in a weather research and forecasting (WRF) numerical model, with which the simulated rainfall and radar reflectivity are compared against ground-based rain gauge network and weather radar observations, respectively. Simulations with the five microphysics schemes demonstrate commendable skills in replicating the macroscopic quasi-linear pattern of the event. Among the schemes assessed, the WSM6 scheme exhibits its superior agreement with radar observations. The Morrison scheme demonstrates superior performance in predicting cumulative rainfall. Nevertheless, five microphysics schemes exhibit limitations in predicting the rainfall amount, the rainfall duration, and the rainfall area, with a discernible lag of approximately 30 min in predicting precipitation onset, indicating a tendency to forecast peak rainfall events slightly posterior to their true occurrence. Furthermore, substantial disparities emerge in the simulation of the vertical distribution of hydrometeors, underscoring the intricacies of microphysical processes. Full article
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<p>Satellite images of the weather event observed by Himawari-8, obtained from observations at three visible bands (blue: 0.47 micron; green: 0.51 micron; red: 0.64 micron): (<b>a</b>–<b>i</b>) 1 h intervals from local time 10:00 to 18:00. The red dots represent the location of the Beijing urban area.</p>
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<p>Sites of all automatic weather stations and the measured rainfalls and wind speeds in Beijing. (<b>a</b>) Distribution of all AWS sites, the five selected representative sites are presented by green, black, blue, red and purple solid dots. (<b>b</b>) Variations of rainfall observed every minute from 14:00 to 15:00 at the five sites, the value 0 at the <span class="html-italic">X</span>-axis means 14:00 and 120 means 15:01. (<b>c</b>) Distribution of rainfall observed at the time of 14:55; (<b>d</b>) Variations of the wind speed observed every minute from 14:00 to 15:00 at the five sites. Unit of rainfall is mm and unit of the wind speed is ms<sup>−1</sup>.</p>
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<p>Distribution of 500 hPa (<b>a</b>–<b>c</b>), 750 hPa (<b>d</b>–<b>f</b>), and 950 hPa (<b>g</b>–<b>i</b>) geopotential heights (contours, unit in dagpm), positive vorticity (filled color, unit in 10<sup>−5</sup> s<sup>−1</sup>), and winds during the event. Left column: at 09:00; middle column: at 12:00; right column: at 15:00. The two red areas in (<b>e</b>) denote the low-vortex centers.</p>
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<p>Distribution of relative humidity (filled color, unit: %), and wind (blue arrows; unit: ms<sup>−1</sup>) at 500 hPa (<b>a</b>–<b>c</b>), 750 hPa (<b>d</b>–<b>f</b>), and 950 hPa (<b>g</b>–<b>i</b>) at different moments. Left column: 09:00; middle column: 12:00; right column: 15:00. Blue circle denotes water vapor transport path at 750 hPa.</p>
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<p>Topographic map with the red solid dots marking the location of Beijing.</p>
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<p>Comparisons of radar reflectivity observed at 14:30 on 30 May 2024 simulated with five cloud microphysics schemes. (<b>a</b>) Observed, (<b>b</b>) Lin scheme, (<b>c</b>) WSM6 scheme, (<b>d</b>) Goddard scheme, (<b>e</b>) Morrison scheme, and (<b>f</b>) WDM6 scheme. Unit: dBZ.</p>
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<p>Rainfall accumulation of the event on 30 May 2024 (accumulated 13:00~16:00, unit mm) observed by AWS and simulated by model. (<b>a</b>) Observed, (<b>b</b>) Lin scheme, (<b>c</b>) WSM6 scheme, (<b>d</b>) Goddard scheme, (<b>e</b>) Morrison scheme, and (<b>f</b>) WDM6 scheme.</p>
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<p>Quantitative contrast of the rainfall accumulation between simulations and observations: (<b>a</b>) MAE is the mean absolute error; (<b>b</b>) CSI is the critical success index.</p>
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<p>The vertical distribution of mixing ratios of the cloud droplet, rain, ice, snow and graupel at different stages simulated with five cloud microphysics schemes. Left column: at 14:00, middle column: 14:30, and right column: 15:00. (<b>a</b>–<b>c</b>) Lin scheme, (<b>d</b>–<b>f</b>) WSM6 scheme, (<b>g</b>–<b>i</b>) Goddard scheme, (<b>j</b>–<b>l</b>) Morrison scheme, (<b>m</b>–<b>o</b>) WDM6 scheme. Unit of the mixing ratio in g kg<sup>−1</sup>.</p>
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22 pages, 2629 KiB  
Article
Materials and Products Development Based on a Novelty Approach to Quality and Life Cycle Assessment (QLCA)
by Dominika Siwiec and Andrzej Pacana
Materials 2024, 17(15), 3859; https://doi.org/10.3390/ma17153859 - 4 Aug 2024
Viewed by 709
Abstract
The development of materials and the products made from them should respond to new challenges posed by market changes and also by climate change. Therefore, the objective of this investigation was to develop a method that supports the sustainable development of materials and [...] Read more.
The development of materials and the products made from them should respond to new challenges posed by market changes and also by climate change. Therefore, the objective of this investigation was to develop a method that supports the sustainable development of materials and the products made from them based on an aggregated indicator of quality and environmental load in the life cycle (QLCA). The testing and illustration of the QLCA method included a passenger car tyre and nine prototypes. These prototypes were described using eight quality criteria: season, class, size of the load index, speed index, rolling, adhesion, and external noise. Then, customer expectations regarding the importance of the criteria and satisfaction with the indicators in the current and modified states were obtained. Based on the customer assessment, the quality indicators of the prototypes were assessed. This assessment was supported by the weighted sum model (WSM) and the entropy method. Then, life cycle assessment for the reference tyre was performed using the Ecoinvent database in the OpenLCA program. LCA indicators were modelled for other prototypes, taking into account quality changes. As a result of the verification of the method, an aggregated QLCA indicator was estimated, based on which it was possible to select the most favourable (qualitatively and environmentally) prototype out of nine. This was the P4 prototype (QLCA = 0.57). The next position in the ranking was taken by P7 (QLCA = 0.43). The QLCA method can be used to determine the direction of development of materials and products in terms of their sustainable development. Full article
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<p>Decision making method based on prospective aggregation of the quality and life cycle assessment (LCA) metrics for material and product development. Own study.</p>
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<p>System boundaries of the passenger car tyre.</p>
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<p>The main contributions to the results of the carbon footprint impact throughout the life cycle of a passenger car tyre.</p>
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<p>Quality indicator of planned passenger car tyre prototypes.</p>
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<p>Modelled changes in the value of the carbon footprint emission factor in the life cycle of passenger car tyre prototypes.</p>
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<p>Results of QLCA assessment for passenger car tyre prototypes.</p>
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13 pages, 71992 KiB  
Article
The Impact of Spoofing Attacks in Connected Autonomous Vehicles under Traffic Congestion Conditions
by Zisis-Rafail Tzoannos, Dimitrios Kosmanos, Apostolos Xenakis and Costas Chaikalis
Telecom 2024, 5(3), 747-759; https://doi.org/10.3390/telecom5030037 - 2 Aug 2024
Viewed by 1284
Abstract
In recent years, the Internet of Things (IoT) and the Internet of Vehicles (IoV) represent rapidly developing technologies. The majority of car manufacturing companies invest large amounts of money in the field of connected autonomous vehicles. Applications of connected and autonomous vehicles (CAVs) [...] Read more.
In recent years, the Internet of Things (IoT) and the Internet of Vehicles (IoV) represent rapidly developing technologies. The majority of car manufacturing companies invest large amounts of money in the field of connected autonomous vehicles. Applications of connected and autonomous vehicles (CAVs) relate to smart transport services and offer benefits to both society and the environment. However, the development of autonomous vehicles may create vulnerabilities in security systems, through which attacks could harm both vehicles and their drivers. To this end, CAV development in vehicular ad hoc networks (VANETs) requires secure wireless communication. However, this kind of communication is vulnerable to a variety of cyber-attacks, such as spoofing. In essence, this paper presents an in-depth analysis of spoofing attack impacts under realistic road conditions, which may cause some traffic congestion. The novelty of this work has to do with simulation scenarios that take into consideration a set of cross-layer parameters, such as packet delivery ratio (PDR), acceleration, and speed. These parameters can determine the integrity of the exchanged wave short messages (WSMs) and are aggregated in a central trusted authority (CTA) for further analysis. Finally, a statistical metric, coefficient of variation (CoV), which measures the consequences of a cyber-attack in a future crash, is estimated, showing a significant increase (12.1%) in a spoofing attack scenario. Full article
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<p>Vehicle route, highlighting its start and end points.</p>
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<p>(<b>a</b>) The platoon of vehicles under normal conditions; (<b>b</b>) the platoon of vehicles under spoofing attack.</p>
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<p>Vehicles create a queue of vehicles with almost zero speed due to spoofing attack while the Node 0 (Spoofer) continues its route normally.</p>
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<p>At the next crossroads, the vehicles from the node “Node 2” (in blue) and below are dynamically separated from the influence of the Victim node “Node 1” (in red) and continue their course on an alternative route. The green shows the notification of nodes in serial mode for “Change Route()”.</p>
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<p>Speed of platoon of vehicles in normal scenario.</p>
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<p>Speed of platoon of vehicles in spoofing attack scenario with a density of 10 vehicles/km.</p>
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<p>Acceleration of platoon of vehicles in normal scenario.</p>
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<p>Acceleration of platoon of vehicles in spoofing attack scenario with a density of 10 vehicles/km.</p>
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<p>Speed of platoon of vehicles with 25 vehicles/km in normal scenario.</p>
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<p>Speed of platoon of vehicles in spoofing attack scenario with a density of 25 vehicles/km.</p>
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<p>Acceleration of platoon of vehicles with 25 vehicles/km in normal scenario.</p>
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<p>Acceleration of platoon of vehicles in spoofing attack scenario with a density of 25 vehicles/km.</p>
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<p>Mean value of PDR and average total distance for different vehicle density values.</p>
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<p>Bar graphs for average total traveled distance for all nodes within a range of vehicle density.</p>
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13 pages, 2910 KiB  
Article
Deterministic Multi-Objective Optimization of Analog Circuits
by Zihan Xu, Zhenxin Zhao and Jun Liu
Electronics 2024, 13(13), 2510; https://doi.org/10.3390/electronics13132510 - 26 Jun 2024
Viewed by 1099
Abstract
Stochastic optimization approaches benefit from random variance to produce a solution in a reasonable time frame that is good enough for solving the problem. Compared with them, deterministic optimization methods feature faster convergence rates and better reproducibility but may get stuck at a [...] Read more.
Stochastic optimization approaches benefit from random variance to produce a solution in a reasonable time frame that is good enough for solving the problem. Compared with them, deterministic optimization methods feature faster convergence rates and better reproducibility but may get stuck at a local optimum that is insufficient to solve the problem. In this paper, we propose a group-based deterministic optimization method, which can efficiently achieve comparable performance to heuristic optimization algorithms, such as particle swarm optimization. Moreover, the weighted sum method (WSM) is employed to further improve our deterministic optimization method to be multi-objective optimization, making it able to seek a balance among multiple conflicting circuit performance metrics. With a case study of three common analog circuits tested for our optimization methodology, the experimental results demonstrate that our proposed method can more efficiently reach a better estimation of the Pareto front compared to NSGA-II, a well-known multi-objective optimization approach. Full article
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<p>Illustration of hypervolume with two objectives.</p>
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<p>Schematic of the two-stage Op-Amp.</p>
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<p>Pareto fronts generated by our method and the NSGA-II for the two-stage Op-Amp.</p>
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<p>Schematic of the folded-Cascode Op-Amp.</p>
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<p>Pareto front generated by our method and NSGA-II for the folded-Cascode Op-Amp.</p>
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<p>Schematic of the three-stage Op-Amp.</p>
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<p>Pareto front generated by our method and NSGA-II for the three-stage Op-Amp.</p>
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18 pages, 289 KiB  
Article
Combining the Fuzzy Analytic Hierarchy Process Method with the Weighted Aggregated Sum Product Assessment Method to Address Internet Platform Selection Problems in an Environment with Incomplete Information
by Kuei-Hu Chang, Hsin-Hung Lai and Bo-Jiun Hung
Appl. Sci. 2024, 14(11), 4390; https://doi.org/10.3390/app14114390 - 22 May 2024
Viewed by 710
Abstract
With the advancement of information technology, the Internet is pivotal in today’s society, serving as a global connectivity platform. Leveraging Internet technology within an enterprise can improve operational efficiency and curtail costs. However, traditional Internet platform selection methods cannot simultaneously handle quantitative and [...] Read more.
With the advancement of information technology, the Internet is pivotal in today’s society, serving as a global connectivity platform. Leveraging Internet technology within an enterprise can improve operational efficiency and curtail costs. However, traditional Internet platform selection methods cannot simultaneously handle quantitative and qualitative information, fuzzy semantics, and incomplete expert-provided information. To address these limitations, this study integrated the fuzzy analytic hierarchy process (FAHP) and the weighted aggregated sum product assessment (WASPAS) approaches to tackle Internet platform selection problems within an incomplete information environment. To demonstrate the validity of this research approach, this study utilized a construction industry Internet platform selection case to confirm the efficacy of the proposed novel fuzzy analytic hierarchy process-based method. Comparative analysis against the weighted sum model (WSM), weighted product model (WPM), FAHP, and typical WASPAS approaches was conducted with numerical verification, revealing that the proposed method in this study effectively manages comprehensive information and yields more rational outcomes for construction industry Internet platforms. Full article
(This article belongs to the Special Issue Applications of Fuzzy Systems and Fuzzy Decision Making)
33 pages, 20526 KiB  
Article
Genesis of Rare Metal Granites in the Nubian Shield: Tectonic Control and Magmatic and Metasomatic Processes
by Mohamed Zaki Khedr, Saif M. Abo Khashaba, Eiichi Takazawa, Safaa M. Hassan, Mokhles K. Azer, N. H. El-Shibiny, Kamal Abdelrahman and Yuji Ichiyama
Minerals 2024, 14(5), 522; https://doi.org/10.3390/min14050522 - 17 May 2024
Cited by 3 | Viewed by 1121
Abstract
The Igla Ahmr region in the Central Eastern Desert (CED) of Egypt comprises mainly syenogranites and alkali feldspar granites, with a few tonalite xenoliths. The mineral potential maps were presented in order to convert the concentrations of total rare earth elements (REEs) and [...] Read more.
The Igla Ahmr region in the Central Eastern Desert (CED) of Egypt comprises mainly syenogranites and alkali feldspar granites, with a few tonalite xenoliths. The mineral potential maps were presented in order to convert the concentrations of total rare earth elements (REEs) and associated elements such as Zr, Nb, Ga, Y, Sc, Ta, Mo, U, and Th into mappable exploration criteria based on the line density, five alteration indices, random forest (RF) machine learning, and the weighted sum model (WSM). According to petrography and geochemical analysis, random forest (RF) gives the best result and represents new locations for rare metal mineralization compared with the WSM. The studied tonalites resemble I-type granites and were crystallized from mantle-derived magmas that were contaminated by crustal materials via assimilation, while the alkali feldspar granites and syenogranites are peraluminous A-type granites. The tonalites are the old phase and are considered a transitional stage from I-type to A-type, whereas the A-type granites have evolved from the I-type ones. Their calculated zircon saturation temperature TZr ranges from 717 °C to 820 °C at pressure < 4 kbar and depth < 14 km in relatively oxidized conditions. The A-type granites have high SiO2 (71.46–77.22 wt.%), high total alkali (up to 9 wt.%), Zr (up to 482 ppm), FeOt/(FeOt + MgO) ratios > 0.86, A/CNK ratios > 1, Al2O3 + CaO < 15 wt.%, and high ΣREEs (230 ppm), but low CaO and MgO and negative Eu anomalies (Eu/Eu* = 0.24–0.43). These chemical features resemble those of post-collisional rare metal A-type granites in the Arabian-Nubian Shield (ANS). The parent magma of these A-type granites was possibly derived from the partial melting of the I-type tonalitic protolith during lithospheric delamination, followed by severe fractional crystallization in the upper crust in the post-collisional setting. Their rare metal-bearing minerals, including zircon, apatite, titanite, and rutile, are of magmatic origin, while allanite, xenotime, parisite, and betafite are hydrothermal in origin. The rare metal mineralization in the Igla Ahmr granites is possibly attributed to: (1) essential components of both parental peraluminous melts and magmatic-emanated fluids that have caused metasomatism, leading to rare metal enrichment in the Igla Ahmr granites during the interaction between rocks and fluids, and (2) structural control of rare metals by the major NW–SE structures (Najd trend) and conjugate N–S and NE–SW faults, which all are channels for hydrothermal fluids that in turn have led to hydrothermal alteration. This explains why rare metal mineralization in granites is affected by hydrothermal alteration, including silicification, phyllic alteration, sericitization, kaolinitization, and chloritization. Full article
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<p>(<b>a</b>) Geological map of the Eastern Desert of Egypt showing the distribution of rare meta-bearing granites [<a href="#B29-minerals-14-00522" class="html-bibr">29</a>]. (<b>b</b>) The geological map of the Igla Ahmr area produced from the combination of remote sensing images, field study, petrography, and geological maps modified after the Egyptian Geologic Survey and Mining Authority [<a href="#B8-minerals-14-00522" class="html-bibr">8</a>,<a href="#B30-minerals-14-00522" class="html-bibr">30</a>]. The structure and tectonic fabric trends in panel (<b>a</b>) are compiled from Greiling et al. [<a href="#B26-minerals-14-00522" class="html-bibr">26</a>], Fritz et al. [<a href="#B27-minerals-14-00522" class="html-bibr">27</a>], and Abd El-Wahed [<a href="#B28-minerals-14-00522" class="html-bibr">28</a>].</p>
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<p>Weighted sum model showing the distribution of rare earth elements in the Igla Ahmr area. Ab. 31, TW. 26, TW. 29, and TW. 81 are granite sample numbers enriched with REEs.</p>
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<p>Random forest model showing the distribution of rare earth elements in the Igla Ahmr area.</p>
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<p>Field photographs of the Igla Ahmr granites. (<b>a</b>) Tonalites intruded by mafic dykes. (<b>b</b>) The intrusive sharp contact between weathered tonalites and mafic metavolcanics. (<b>c</b>) The sharp intrusive contact between syenogranites and metavolcanics. (<b>d</b>) Kaolinite alteration in syenogranites. (<b>e</b>) Close-up view of the contact between fresh and weathered alkali feldspar granites. (<b>f</b>) High silicification and formation of quartz vein cutting alkali feldspar granites.</p>
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<p>Photomicrographs images of the Igla Ahmr granites. (<b>a</b>) Plagioclase (Pg) crystal exhibiting normal zoning in the tonalites. (<b>b</b>) Coarse subhedral crystals of plagioclase (Pg) altered to sericite and associated with anhedral crystals of amphibole (Amp) in tonalites. (<b>c</b>) Chlorite flaky after biotite crystals filling interstitial spaces between primary silicates in syenogranite. (<b>d</b>) Small subhedral crystals of K-feldspar (Kfs) associated with large crystals of biotite flakes (Bt) in syenogranites. (<b>e</b>) Kaolinite and chlorite (Chl) alterations due to metasomatism, syenogranites. (<b>f</b>) Biotite (Bt) flaky existence as clots in interstitial between quartz (Qz) and feldspar in syenogranites. (<b>g</b>) Highly altered K-feldspar (Kfs) and plagioclase (Pg) in alkali feldspar granites. (<b>h</b>) Micrographic texture of intergrowth between fine-grained quartz and alkali feldspar in alkali feldspar granites. (<b>i</b>) Sericite alteration in the core of plagioclase (Pg) grains associated with chlorite (Chl) in alkali feldspar granites.</p>
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<p>SEM images with EDS spectrum analyses of accessory minerals in the Igla Ahmr granites. (<b>a</b>) Coarse subhedral Fe-oxide crystals in alkali feldspar granites. (<b>b</b>) Tiny ilmenite crystals in plagioclase associated with zircon (Zr) in alkali feldspar granites. (<b>c</b>) Subhedral apatite crystals (Ap) accompanied with zircon (Zr) and Fe-oxide in alkali feldspar granites. (<b>d</b>) Small disseminated grains of titanite (Tnt) in alkali feldspar granites.</p>
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<p>SEM images with EDS spectrum analyses of rare metal-bearing minerals in the Igla Ahmr alkali feldspar granites and stream sediments. (<b>a</b>) Subhedral zircon crystals associated with apatite, titanite, and chlorite in the silicate matrix. (<b>b</b>) Subhedral to euhedral rutile crystals. (<b>c</b>) Small anhedral grains of xenotime at the rim of Fe-oxide. (<b>d</b>) Titanite intergrowth with allanite as a composite grain at edge of iron oxide. (<b>e</b>) Betafite grains in stream sediments.</p>
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<p>Mineral chemistry of the Igla Ahmr granites. (<b>a</b>,<b>b</b>) Feldspar compositions plotted on an albite (Ab)-anorthite (An)-orthoclase (Or) ternary diagram [<a href="#B34-minerals-14-00522" class="html-bibr">34</a>]. (<b>c</b>) 10 * TiO<sub>2</sub>-(FeO<sup>t</sup> + MnO)-MgO ternary diagram for classification of biotite [<a href="#B35-minerals-14-00522" class="html-bibr">35</a>]. (<b>d</b>) Mg versus Al discrimination diagram of analyzed biotites [<a href="#B36-minerals-14-00522" class="html-bibr">36</a>]. (<b>e</b>) Si versus Mg# discrimination diagram of amphibole [<a href="#B37-minerals-14-00522" class="html-bibr">37</a>]. (<b>f</b>) Si versus (Fe<sup>+2</sup> + Fe<sup>+3</sup>) binary diagram for classification of chlorites [<a href="#B38-minerals-14-00522" class="html-bibr">38</a>].</p>
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<p>In situ analyses of albite, K-feldspar, and chlorite for REEs and trace elements in alkali feldspar granites. (<b>a</b>) Chondrite (CI)-normalized REE patterns of albite. (<b>b</b>) Primitive mantle (PM)-normalized trace element patterns of albite. (<b>c</b>) The CI-normalized REE patterns of K-feldspar. (<b>d</b>) The PM-normalized trace element patterns of K-feldspar. (<b>e</b>) The CI-normalized REE patterns of chlorite. (<b>f</b>) The PM-normalized trace element patterns of chlorite. REE and trace elements are normalized to CI and PM values, respectively, after Sun and McDonough [<a href="#B39-minerals-14-00522" class="html-bibr">39</a>].</p>
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<p>R1–R2 classification diagram [<a href="#B41-minerals-14-00522" class="html-bibr">41</a>] of the Igla Ahmr granites. All samples are mainly syenogranites and alkali feldspar granites except one sample of tonalites. The field of A-type mineralized granites in the ANS collected from the Umm Naggat, Homrit Waggat, and El-Inegi areas is modeled after Sami et al. [<a href="#B4-minerals-14-00522" class="html-bibr">4</a>] and Khedr et al. [<a href="#B7-minerals-14-00522" class="html-bibr">7</a>].</p>
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<p>Chondrite (CI)-normalized REE patterns of the Igla Ahmr granites. (<b>a</b>) The CI-normalized REE patterns of granites. (<b>b</b>) Primitive mantle (PM)-normalized trace element patterns of syenogranites and alkali feldspar granites. The field of ANS A-type granites is used for comparison [<a href="#B4-minerals-14-00522" class="html-bibr">4</a>,<a href="#B6-minerals-14-00522" class="html-bibr">6</a>,<a href="#B7-minerals-14-00522" class="html-bibr">7</a>]. REE and trace elements of granites are normalized to CI and PM values, respectively, after Sun and McDonough [<a href="#B39-minerals-14-00522" class="html-bibr">39</a>].</p>
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<p>Magma type of the Igla Ahmr granites. (<b>a</b>) Discrimination diagram using 100((MgO + FeO<sup>t</sup> + TiO<sub>2</sub>)/SiO<sub>2</sub> vs. molar (Al<sub>2</sub>O<sub>3</sub> + CaO)/(FeO + Na<sub>2</sub>O + K<sub>2</sub>O) to differentiate between calc-alkaline, highly-fractionated calc-alkaline, and alkaline granites [<a href="#B50-minerals-14-00522" class="html-bibr">50</a>]. (<b>b</b>) Chemical classification diagrams using SiO<sub>2</sub> vs. (FeOt/(FeO<sup>t</sup> + MgO) of Frost [<a href="#B51-minerals-14-00522" class="html-bibr">51</a>]. (<b>c</b>) Chemical classification diagram using SiO<sub>2</sub> vs. (Na<sub>2</sub>O + K<sub>2</sub>O)-CaO [<a href="#B51-minerals-14-00522" class="html-bibr">51</a>]. The A-type granite field is modeled after Whalen et al. [<a href="#B17-minerals-14-00522" class="html-bibr">17</a>]. (<b>d</b>) Molar Al<sub>2</sub>O<sub>3</sub>/(Na<sub>2</sub>O + K<sub>2</sub>O) vs. Al<sub>2</sub>O<sub>3</sub>/(CaO +Na<sub>2</sub>O + K<sub>2</sub>O) for the studied granites [<a href="#B54-minerals-14-00522" class="html-bibr">54</a>]. (<b>e</b>) 10<sup>4</sup> × Ga/Al against Zr for distinguishing between I, S, M and A-type granites [<a href="#B54-minerals-14-00522" class="html-bibr">54</a>]. (<b>f</b>) The discrimination diagram of Nb-Y-Ga/3 showing subdivision of A-type granites into A<sub>1</sub> and A<sub>2</sub> sub-types, where A<sub>1</sub> and A<sub>2</sub> have element ratios similar to those observed for oceanic-island basalts and continental crust, respectively [<a href="#B52-minerals-14-00522" class="html-bibr">52</a>]. The field of A-type mineralized granites in the ANS collected from Umm Naggat, Homrit Waggat, El-Inegi, Abu Dabbab, Nuweiba, Mueilha, and Abu Diab areas is modeled after Sami et al. [<a href="#B4-minerals-14-00522" class="html-bibr">4</a>]; Azer et al. [<a href="#B5-minerals-14-00522" class="html-bibr">5</a>]; Seddik et al. [<a href="#B11-minerals-14-00522" class="html-bibr">11</a>]; Moussa et al. [<a href="#B55-minerals-14-00522" class="html-bibr">55</a>]; Khedr et al. [<a href="#B7-minerals-14-00522" class="html-bibr">7</a>]; and Abuamarah et al. [<a href="#B56-minerals-14-00522" class="html-bibr">56</a>].</p>
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<p>Tectonic setting of the Igla Ahmr granites. (<b>a</b>) Y + Nb vs. Rb tectonic discrimination diagram [<a href="#B2-minerals-14-00522" class="html-bibr">2</a>]. Post-collisional granites are after Pearce [<a href="#B57-minerals-14-00522" class="html-bibr">57</a>]. (<b>b</b>) SiO<sub>2</sub> versus FeO<sup>t</sup>/(FeO<sup>t</sup> + MgO) tectonic discrimination of Maniar and Piccoli [<a href="#B54-minerals-14-00522" class="html-bibr">54</a>]. (<b>c</b>) R<sub>1</sub>-R<sub>2</sub> multi-cationic diagram [<a href="#B58-minerals-14-00522" class="html-bibr">58</a>]. (<b>d</b>) Na<sub>2</sub>O-K<sub>2</sub>O-CaO ternary diagram of Egyptian granitoids [<a href="#B4-minerals-14-00522" class="html-bibr">4</a>,<a href="#B6-minerals-14-00522" class="html-bibr">6</a>,<a href="#B7-minerals-14-00522" class="html-bibr">7</a>,<a href="#B59-minerals-14-00522" class="html-bibr">59</a>]. Field of trondhjemites and calc-alkaline are after Barker and Arth [<a href="#B60-minerals-14-00522" class="html-bibr">60</a>], while the field of A-type mineralized granites in the ANS as in <a href="#minerals-14-00522-f012" class="html-fig">Figure 12</a>.</p>
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<p>Whole-rock compositions of the Igla Ahmr granites showing their origin and thermometry. (<b>a</b>) Zr vs. Th/Nb variation diagrams displaying fractional crystallization (FC), assimilation–fractional crystallization (AFC), and bulk assimilation (BA) trends [<a href="#B70-minerals-14-00522" class="html-bibr">70</a>]. (<b>b</b>) The Rb vs. K/Rb diagram for assimilation–crystal fractionation [<a href="#B64-minerals-14-00522" class="html-bibr">64</a>]. (<b>c</b>) Petrogenetic discrimination of Al<sub>2</sub>O<sub>3</sub>/(FeO<sup>t</sup> + MgO)-3CaO-5(K<sub>2</sub>O/Na<sub>2</sub>O) ternary diagram for the studied A-type granites [<a href="#B62-minerals-14-00522" class="html-bibr">62</a>]. The fields of A-type and I-type granites in the ANS are adopted from Robinson et al. [<a href="#B72-minerals-14-00522" class="html-bibr">72</a>]. (<b>d</b>) Compositions of the Igla Ahmr A-type granites compared to melts produced by experiment of the dehydrated melts of various lithologies [<a href="#B71-minerals-14-00522" class="html-bibr">71</a>]. (<b>e</b>) TiO<sub>2</sub> versus Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> (wt.%) diagram of the Igla Ahmr granitoids, showing a curvilinear trend of magmatic differentiation (<b>f</b>) Qz–Ab–Or normative compositions for granite thermometry. Dashed lines display quartz-alkali feldspar cotectic limit and trace of water saturated minimum melt compositions at range of pressure from 0.5 to 10 kbar [<a href="#B73-minerals-14-00522" class="html-bibr">73</a>]. The trace of minimum melt compositions at 1 kbar with excess H<sub>2</sub>O and increasing fluorine (F, up to 4 wt. %) delineated by solid lines [<a href="#B48-minerals-14-00522" class="html-bibr">48</a>].</p>
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<p>The tectono-magmatic evolution of the Igla Ahmr granites. (<b>a</b>) Syn-collision I-type and (<b>b</b>) post-collision A-type granites, showing lithospheric delamination, partial melting of lower crust and formation of A-type granites in the upper crust [<a href="#B5-minerals-14-00522" class="html-bibr">5</a>,<a href="#B7-minerals-14-00522" class="html-bibr">7</a>,<a href="#B11-minerals-14-00522" class="html-bibr">11</a>,<a href="#B74-minerals-14-00522" class="html-bibr">74</a>]. Crust and mantle thicknesses are not to scale.</p>
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15 pages, 1680 KiB  
Article
Metabolic Blockade-Based Genome Mining of Sea Anemone-Associated Streptomyces sp. S1502 Identifies Atypical Angucyclines WS-5995 A–E: Isolation, Identification, Biosynthetic Investigation, and Bioactivities
by Yuyang Wang, Le Zhou, Xiaoting Pan, Zhangjun Liao, Nanshan Qi, Mingfei Sun, Hua Zhang, Jianhua Ju and Junying Ma
Mar. Drugs 2024, 22(5), 195; https://doi.org/10.3390/md22050195 - 25 Apr 2024
Viewed by 1481
Abstract
Marine symbiotic and epiphyte microorganisms are sources of bioactive or structurally novel natural products. Metabolic blockade-based genome mining has been proven to be an effective strategy to accelerate the discovery of natural products from both terrestrial and marine microorganisms. Here, the metabolic blockade-based [...] Read more.
Marine symbiotic and epiphyte microorganisms are sources of bioactive or structurally novel natural products. Metabolic blockade-based genome mining has been proven to be an effective strategy to accelerate the discovery of natural products from both terrestrial and marine microorganisms. Here, the metabolic blockade-based genome mining strategy was applied to the discovery of other metabolites in a sea anemone-associated Streptomyces sp. S1502. We constructed a mutant Streptomyces sp. S1502/Δstp1 that switched to producing the atypical angucyclines WS-5995 A–E, among which WS-5995 E is a new compound. A biosynthetic gene cluster (wsm) of the angucyclines was identified through gene knock-out and heterologous expression studies. The biosynthetic pathways of WS-5995 A–E were proposed, the roles of some tailoring and regulatory genes were investigated, and the biological activities of WS-5995 A–E were evaluated. WS-5995 A has significant anti-Eimeria tenell activity with an IC50 value of 2.21 μM. The production of antibacterial streptopyrroles and anticoccidial WS-5995 A–E may play a protective role in the mutual relationship between Streptomyces sp. S1502 and its host. Full article
(This article belongs to the Special Issue Marine Omics for Drug Discovery and Development)
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Graphical abstract
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<p>Representative structures of atypical angucyclines.</p>
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<p>Streptopyrroles from <span class="html-italic">Streptomyces</span> sp. S1502 and their biosynthesis. (<b>A</b>) Images of the sea anemone host, <span class="html-italic">Streptomyces</span> sp. S1502, and the anti-MRSA bioactivity of extract of <span class="html-italic">Streptomyces</span> sp. S1502 fermented in RA medium. (<b>B</b>) HPLC analysis of extract of <span class="html-italic">Streptomyces</span> sp. S1502; peaks marked with * are streptopyrroles. (<b>C</b>) The biosynthetic gene cluster <span class="html-italic">stp</span> responsible for streptopyrroles biosynthesis; <span class="html-italic">stp1</span> for in-frame deletion is located in the middle of the cluster. (<b>D</b>) Proposed biosynthetic pathway of streptopyrroles.</p>
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<p>WS-5995 A–E from Δ<span class="html-italic">stp1</span> mutant of <span class="html-italic">Streptomyces</span> sp. S1502. (<b>A</b>) HPLC analysis of extract of <span class="html-italic">Streptomyces</span> sp. S1502 and Δ<span class="html-italic">stp1</span> mutant. (<b>B</b>) Structures of compounds <b>1</b>–<b>5</b>. (<b>C</b>) COSY and HMBC correlations of compound <b>1</b>.</p>
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<p>Proposed biosynthesis of WS-5995 A–E. (<b>A</b>) Comparison of <span class="html-italic">wsm</span> and <span class="html-italic">wsd</span> gene clusters and their gene organization. (<b>B</b>) Confirmation of <span class="html-italic">wsm</span> gene cluster by HPLC analysis. (<b>C</b>) Proposed biosynthetic pathway of WS-5995 A–E.</p>
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<p>HPLC analysis of mutants derived from <span class="html-italic">Streptomyces</span> sp. S1502/Δ<span class="html-italic">stp1.</span> <b>1</b>–<b>5</b> stand for compounds mentioned in the manuscript.</p>
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15 pages, 3636 KiB  
Article
Charge Critical Phenomena in a Field Heterostructure with Two-Dimensional Crystal
by Alexander L. Danilyuk, Denis A. Podryabinkin, Victor L. Shaposhnikov and Serghej L. Prischepa
Solids 2024, 5(2), 193-207; https://doi.org/10.3390/solids5020013 - 6 Apr 2024
Viewed by 955
Abstract
The charge properties and regularities of mutual influence of the electro-physical parameters in a metal (M)/insulator (I)/two-dimensional crystal heterostructure were studied. In one case, the transition metal dichalcogenide (TMD) MoS2 was considered as a two-dimensional crystal, and in another the Weyl semi-metal [...] Read more.
The charge properties and regularities of mutual influence of the electro-physical parameters in a metal (M)/insulator (I)/two-dimensional crystal heterostructure were studied. In one case, the transition metal dichalcogenide (TMD) MoS2 was considered as a two-dimensional crystal, and in another the Weyl semi-metal (WSM) ZrTe5, representative of a quasi-two-dimensional crystal was chosen for this purpose. By self-consistently solving the electrostatic equations of the heterostructures under consideration and the Fermi–Dirac distribution, the relationship between such parameters as the concentration of charge carriers, chemical potential, and quantum capacitance of the TMD (WSM), as well as the capacitance of the I layer and the interface capacitance I–TMD (WSM), and their dependence on the field electrode potential, have been derived. The conditions for the emergence of charge instability and the critical phenomena caused by it are also determined. Full article
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Figure 1
<p>Chemical potential <span class="html-italic">χ</span> of MoS<sub>2</sub> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different energy levels <span class="html-italic">E<sub>t</sub></span> of monoenergetic traps. Inset: DOS of the atomic monolayer MoS<sub>2</sub>.</p>
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<p>(<b>a</b>) Density of conduction electrons <span class="html-italic">n<sub>e</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different energy levels <span class="html-italic">E<sub>t</sub></span> of monoenergetic traps; (<b>b</b>) electron charge on traps <span class="html-italic">Q<sub>t</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different energy levels of <span class="html-italic">E<sub>t</sub></span> of monoenergetic traps.</p>
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<p>Quantum capacitance <span class="html-italic">C<sub>Q</sub></span>, capacitance of the I–TMD interface <span class="html-italic">C<sub>it</sub></span>, field electrode–TMD capacitance <span class="html-italic">C<sub>G</sub></span> and TMD capacitance <span class="html-italic">C<sub>CH</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at (<b>a</b>) <span class="html-italic">E<sub>t</sub></span> = 1.5 eV and (<b>b</b>) <span class="html-italic">E<sub>t</sub></span> = 1.6 eV.</p>
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<p>Chemical potential <span class="html-italic">χ</span> of MoS<sub>2</sub> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different dispersion <span class="html-italic">σ<sub>t</sub></span> of Gauss distribution of traps energy.</p>
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<p>Density of conduction electrons ne (solid lines) and density of electrons localized in traps n<sub>t</sub> (dashed lines) versus UG of FHS MIS at different dispersion σt of Gauss distribution of traps energy.</p>
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<p>(<b>a</b>,<b>b</b>) Quantum capacitance <span class="html-italic">C<sub>Q</sub></span>, capacitance of the I–TMD interface <span class="html-italic">C<sub>it</sub></span>, field electrode–TMD capacitance <span class="html-italic">C<sub>G,</sub></span> and TMD capacitance <span class="html-italic">C<sub>CH</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS in the case of Gauss distribution of traps energy at two slightly different sets of model parameters. For details, see the text. Inset to (<b>b</b>): Density of conduction electrons <span class="html-italic">n<sub>e</sub> </span>versus chemical potential <span class="html-italic">χ</span> for MoS<sub>2</sub>.</p>
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<p>Density of states DOS of ZrTe<sub>2</sub> at two energy gap values. Inset: The first derivative of DOS versus energy for ZrTe<sub>5</sub> at ∆ = 3 meV.</p>
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<p>Density of conduction electrons <span class="html-italic">n<sub>e</sub> </span>versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different values of the capacitance of the I–WSM interface <span class="html-italic">C<sub>it</sub></span>. Inset: Chemical potential of ZrTe<sub>5</sub> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS at different values of the capacitance of the I–WSM interface <span class="html-italic">C<sub>it</sub></span>.</p>
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<p>Quantum capacitance <span class="html-italic">C<sub>Q</sub></span> of ZrTe<sub>5</sub> and field electrode–WSM capacitance <span class="html-italic">C<sub>G</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS. <span class="html-italic">T</span> = 0.2 K.</p>
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<p>Quantum capacitance <span class="html-italic">C<sub>Q</sub></span> of ZrTe<sub>5</sub>, field electrode–WSM capacitance <span class="html-italic">C<sub>G</sub></span> and WSM capacitance <span class="html-italic">C<sub>CH</sub></span> versus <span class="html-italic">U<sub>G</sub></span> of FHS MIS. <span class="html-italic">T</span> = 0.8 K.</p>
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17 pages, 3069 KiB  
Article
The WRF Simulation Influence of Assimilating GNSS Water Vapor and Parameterization Schemes on Typhoon Rumbia
by Li Li, Yixiang Ma, Kai Li, Jianping Pan and Mingsong Zhang
Atmosphere 2024, 15(3), 255; https://doi.org/10.3390/atmos15030255 - 21 Feb 2024
Viewed by 1114
Abstract
The Weather Research and Forecasting (WRF) model was used to simulate Typhoon Rumbia in this paper. The sensitivity experiments were conducted with 16 different parameterization combination schemes, including four microphysics (WSM6, WSM5, Lin, and Thompson), two boundary layers (YSU and MYJ), and two [...] Read more.
The Weather Research and Forecasting (WRF) model was used to simulate Typhoon Rumbia in this paper. The sensitivity experiments were conducted with 16 different parameterization combination schemes, including four microphysics (WSM6, WSM5, Lin, and Thompson), two boundary layers (YSU and MYJ), and two cumulus convection (Kain–Fritsch and Grell–Freitas) schemes. The impacts of 16 parameterization combination schemes and the data assimilation (DA) of Global Navigation Satellite System (GNSS) water vapor were evaluated by the simulation accuracy of typhoon track and intensity. The results show that the typhoon track and intensity are significantly influenced by parameterization schemes of cumulus and boundary layers rather than microphysics. The averaged track error of Lin_KF_Y is 104.73 km in the entire 72-h simulation period. The track errors of all the other combination schemes are higher than Lin_KF_Y. During the entire 72-h, the averaged intensity error of Thompson_GF_M is 1.36 hPa. It is the lowest among all the combination schemes. As for data assimilation, the simulation accuracy of typhoon tracks can be significantly improved by adding the GNSS water vapor. Thompson_GF_M-DA combination scheme has the lowest average track error of 45.05 km in the initial 24 h. The Lin_KF_Y-DA combination scheme exhibits an average track error of 32.17 km on the second day, 28.03 km on the third day, and 35.33 km during 72-h. The study shows that the combination of parameterization schemes and the GNSS water vapor data assimilation significantly improve the initial conditions and the accuracy of typhoon predictions. The study results contribute to the selection of appropriate combinations of physical parameterization schemes for the WRF-ARW model in the mid-latitude region of the western Pacific coast. Full article
(This article belongs to the Special Issue GNSS Remote Sensing in Atmosphere and Environment)
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<p>The simulation region “d01” and “d02” of Typhoon Rumbia, where the shading is the terrain altitude (m).</p>
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<p>The flowchart of data assimilation and parameterization schemes in the WRF model.</p>
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<p>The comparison of typhoon track from different parameterization combination schemes with the observed track of Typhoon Rumbia for the KF_Y (<b>a</b>), the KF_M (<b>b</b>), the GF_Y (<b>c</b>), and GF_M (<b>d</b>).</p>
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<p>The comparison of typhoon track from different parameterization combination schemes with the observed track of Typhoon Rumbia for the KF_Y (<b>a</b>), the KF_M (<b>b</b>), the GF_Y (<b>c</b>), and GF_M (<b>d</b>).</p>
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<p>The comparison of typhoon intensity from different parameterization combination schemes with the observed intensity of Typhoon Rumbia for the KF_Y (<b>a</b>), the KF_M (<b>b</b>), the GF_Y (<b>c</b>), and GF_M (<b>d</b>) combination schemes.</p>
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<p>The comparison of typhoon intensity from different parameterization combination schemes with the observed intensity of Typhoon Rumbia for the KF_Y (<b>a</b>), the KF_M (<b>b</b>), the GF_Y (<b>c</b>), and GF_M (<b>d</b>) combination schemes.</p>
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<p>Comparison of simulated typhoon tracks (<b>a</b>) and track errors (<b>b</b>) after data assimilation for the selected parameterization combination schemes.</p>
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<p>Comparison of simulated typhoon intensity (<b>a</b>) and intensity error (<b>b</b>) after GNSS water vapor data assimilation for the selected parameterization combination schemes (hPa).</p>
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25 pages, 10775 KiB  
Article
Hydrostructural Phenomena in a Wastewater Screening Channel with an Ascendable Sub-Screen Using the Arbitrary Lagrangian–Eulerian Approach
by Shehnaz Akhtar, Safi Ahmed Memon, Hyeon-Bae Chae, Du-Whan Choi and Cheol-Woo Park
Appl. Sci. 2024, 14(1), 76; https://doi.org/10.3390/app14010076 - 21 Dec 2023
Cited by 1 | Viewed by 1034
Abstract
Wastewater invariably accumulates soluble and insoluble waste and requires treatment at a wastewater treatment plant (WTP) to become reusable. The preliminary screening of insoluble waste occurs through a wastewater screening mechanism (WSM) before entering the WTP. The present study computationally investigates the impact [...] Read more.
Wastewater invariably accumulates soluble and insoluble waste and requires treatment at a wastewater treatment plant (WTP) to become reusable. The preliminary screening of insoluble waste occurs through a wastewater screening mechanism (WSM) before entering the WTP. The present study computationally investigates the impact of a WSM, comprising a main screen, sliding sub-screen, and rake, on channel flow distribution, deformation, and stresses. Various sub-screen configurations, fully and partially lowered, are examined. The fluid–structure interaction between sewage water and the WSM was solved using the arbitrary Lagrangian–Eulerian approach. Unlike similar studies in the past which have been conducted in 2D, the present study considers the 3D design and thus captures a greater complexity of the WSM assembly. The velocity distribution inside the channel, structural deformation, and von Mises stresses of WSM components were analyzed for a range of inlet velocities at different stages of the screening process. The results reveal that a fully lowered sub-screen with an inactive rake ensures a uniform flow through the WSM, while a partially lowered sub-screen induces persistent flow separation. Structural analysis reveals significant deformation in the upper mid-region of the sub-screen and fluctuating deformations in the rake, accompanied by elevated von Mises stresses. The study serves as a design guideline for manufacturing and operating a WSM, ensuring the prevention of unfavorable stress and deformation in the WSM and the WTP. Full article
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<p>A 3D representation of the WSM.</p>
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<p>Geometric representation of the WSM with the sub-screen lifted at the vertical displacement of ε<sub>ss</sub> from the channel floor and the rake oriented at the angular displacement of <span class="html-italic">φ</span><sub>r</sub> from the vertical cross-sectional plane; A represents the location of the WSM in the channel cross-section. C represents the cross-sectional plane at c = 0.5 m upstream of the WSM, and D represents the cross-sectional plane at d = 0.5 m downstream of the WSM.</p>
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<p>Mesh configuration: (<b>a</b>) for the entire WSM channel, (<b>b</b>) rake, (<b>c</b>) sub-screen, and (<b>d</b>) the main screen.</p>
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<p>Mesh independence test at a flow velocity of 0.2 m/s for (<b>a</b>) upstream region (location C) and (<b>b</b>) downstream region (location D).</p>
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<p>Comparison of present technique with the study of Ali et al. [<a href="#B7-applsci-14-00076" class="html-bibr">7</a>]: (<b>a</b>) upstream region (location C) and (<b>b</b>) downstream region (location D).</p>
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<p>Normalized velocity contour plot around the WSM at <span class="html-italic">y</span> = 0.1 m for the inlet velocity of 0.2 m/s when the sub-screen is (<b>a</b>) fully lowered and (<b>b</b>) partially lowered; the arrows represent the velocity magnitude at the trailing points.</p>
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<p>Velocity profile along the x-direction for the inlet velocity of 0.2 m/s when the sub-screen is (<b>a</b>) fully lowered and (<b>b</b>) partially lowered; the arrows represent the horizontal component of the velocity at the trailing points.</p>
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<p>Velocity profile along the x-direction for the inlet velocity of 0.2 m/s when the sub-screen is (<b>a</b>) fully lowered and (<b>b</b>) partially lowered; the arrows represent the horizontal component of the velocity at the trailing points.</p>
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<p>Effects of different inlet velocities and sub-screen positions: upstream velocity (at location C) when the sub-screen is (<b>a</b>) fully lowered and (<b>b</b>) partially lowered; downstream velocity (at location D) when the sub-screen is (<b>c</b>) fully lowered and (<b>d</b>) partially lowered.</p>
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<p>Variation in flow average cross-sectional velocity along the flow direction at 0.2 m/s.</p>
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<p>Normalized velocity contour plots at <span class="html-italic">y</span> = 0.1 m for an inlet velocity of 0.2 m/s when the rake is operational and (<b>a</b>) <span class="html-italic">φ</span><sub>r</sub> = −75°; (<b>b</b>) <span class="html-italic">φ</span><sub>r</sub> = 0°; the view of the rake has been magnified, and the arrows represent the velocity magnitude at the trailing points.</p>
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<p>Normalized velocity contour plots at <span class="html-italic">y</span> = 0.1 m for an inlet velocity of 0.2 m/s when the rake is operational and (<b>a</b>) <span class="html-italic">φ</span><sub>r</sub> = −75°; (<b>b</b>) <span class="html-italic">φ</span><sub>r</sub> = 0°; the view of the rake has been magnified, and the arrows represent the velocity magnitude at the trailing points.</p>
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<p>Velocity profile along the x-direction for the inlet velocity of 0.2 m/s when the rake is operational and (<b>a</b>) φ<sub>r</sub> = −75°; (<b>b</b>) φ<sub>r</sub> = 0°; the arrows represent the horizontal component of the velocity at the trailing points.</p>
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<p>Effects of rake on the velocity magnitude at posterior position (φ<sub>r</sub> = −75°) and vertical position (φ<sub>r</sub> = 0°) in the (<b>a</b>) upstream region (location C) and (<b>b</b>) downstream region (location D).</p>
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<p>Normalized deformation contour plots of the main screen and sub-screen when the sub-screen is fully lowered for (<b>a</b>) U = 0.1 m/s and (<b>b</b>) U = 0.3 m/s and partially lowered for (<b>c</b>) U = 0.1 m/s and (<b>d</b>) U = 0.3 m/s.</p>
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<p>Deformation of the sub-screen bars when the sub-screen is fully lowered for (<b>a</b>) U = 0.1 m/s (<b>b</b>) U = 0.3 m/s and partially lowered for (<b>c</b>) U = 0.1 m/s and (<b>d</b>) U = 0.3 m/s.</p>
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<p>Normalized deformation contour plots of the rake at U = 0.2 m/s for (<b>a</b>) φ<sub>r</sub> = −75° and (<b>b</b>) φ<sub>r</sub> = 0°.</p>
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<p>Deformation of the different rake pins at U = 0.2 m/s for (<b>a</b>) φ<sub>r</sub> = −75° and (<b>b</b>) φ<sub>r</sub> = 0°.</p>
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<p>von Mises stress profile on the sub-screen bars when the sub-screen is fully lowered at (<b>a</b>) U = 0.1 m/s and (<b>b</b>) U = 0.3 m/s and for partially lowered at (<b>c</b>) U = 0.1 m/s and (<b>d</b>) U = 0.3 m/s.</p>
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<p>von Mises stress profile on the rake pins at U = 0.2 m/s for (<b>a</b>) φ<sub>r</sub> = −75° and (<b>b</b>) φ<sub>r</sub> = 0°.</p>
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19 pages, 21619 KiB  
Article
Discrete Element Modelling of a Bulk Cohesive Material Discharging from a Conveyor Belt onto an Impact Plate
by Otto C. Scheffler and Corné J. Coetzee
Minerals 2023, 13(12), 1501; https://doi.org/10.3390/min13121501 - 29 Nov 2023
Cited by 1 | Viewed by 1311
Abstract
The discrete element method (DEM) has become the numerical method of choice for analysing and predicting the behaviour of granular materials in bulk handling systems. Wet-and-sticky materials (WSM) are especially problematic, resulting in build-up and blockages. Furthermore, due to the large number of [...] Read more.
The discrete element method (DEM) has become the numerical method of choice for analysing and predicting the behaviour of granular materials in bulk handling systems. Wet-and-sticky materials (WSM) are especially problematic, resulting in build-up and blockages. Furthermore, due to the large number of particles in industrial-scale applications, it is essential to decrease the number of particles in the model by increasing their size (upscaling or coarse graining). In this study, the accuracy with which upscaled DEM particles can model the discharge of a cohesive material from a belt conveyor onto an inclined impact plate was investigated. Experimentally, three sand grades (particle size distributions, PSDs) were used, each in a dry (non-cohesive) state and with three levels of moisture-induced cohesion. The effects of the modelled PSDs on the material flow, build-up on the plate, the peak impact force and the residual weight were investigated. Although a linear cohesion contact model was mostly used, the results were also compared to that of the Johnson–Kendall–Roberts (JKR) and simplified JKR (SJKR) models. It was found that the general profile of the pile (build-up) could be accurately modelled, but using a more accurate (but still upscaled) PSD improved the results. The impact force and the residual weight on the plate could be accurately modelled (error <15%) if the particle size was not excessively scaled. The maximum acceptable scaling factor was found to be a geometric factor of the bulk measure of interest, and not a factor of the physical particle size. Furthermore, with an increase in cohesion, the bulk measures such as the thickness of the discharge stream and the height of the material build-up increased, which meant that the maximum acceptable scale factor also increased. The results are valuable for future accurate and efficient modelling of large industrial scale applications of WSMs. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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<p>Sand grades showing (<b>a</b>) the coarse grade, (<b>b</b>) the medium grade and (<b>c</b>) the fine grade. Reproduced with permission from [<a href="#B45-minerals-13-01501" class="html-bibr">45</a>]; published by Elsevier, 2023.</p>
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<p>The experimental conveyor system.</p>
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<p>Material flow from the conveyor head pulley onto the impact plate.</p>
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<p>Loading of test material on the conveyor.</p>
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<p>Three of the ten clumps generated based on the coarse-grade sand. Reproduced with permission from [<a href="#B44-minerals-13-01501" class="html-bibr">44</a>]; published by Elsevier, 2023.</p>
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<p>Experimental results of the three sand grades with varying saturation levels, <span class="html-italic">S</span>.</p>
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<p>Experimental pile of the fine sand at four saturation states, <span class="html-italic">S</span>.</p>
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<p>Modelled pile of fine sand at four saturation states, modelled with a clump scale of F21.4.</p>
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<p>Comparison of the impact force–time response of the medium sand, showing the experimental results and the DEM results for six clump scale factors for each of the four saturation levels.</p>
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<p>DEM prediction of the peak force of the coarse sand as a function of the clump scale and four saturation levels. The experimental mean (<math display="inline"><semantics> <mrow> <mo>±</mo> <mn>15</mn> <mo>%</mo> </mrow> </semantics></math>) is indicated for each saturation level.</p>
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<p>DEM prediction of the peak force of the fine sand as a function of the clump scale and four saturation levels. The experimental mean (<math display="inline"><semantics> <mrow> <mo>±</mo> <mn>15</mn> <mo>%</mo> </mrow> </semantics></math>) is indicated for each saturation level.</p>
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<p>Comparison of the fine sand’s dry and wet discharging stream thickness.</p>
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<p>DEM prediction of the residual weight of the coarse sand as a function of the clump scale and four saturation levels. The experimental mean (<math display="inline"><semantics> <mrow> <mo>±</mo> <mn>15</mn> <mo>%</mo> </mrow> </semantics></math>) is indicated for each saturation level.</p>
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<p>DEM prediction of the residual weight of the fine sand as a function of the clump scale and four saturation levels. The experimental mean (<math display="inline"><semantics> <mrow> <mo>±</mo> <mn>15</mn> <mo>%</mo> </mrow> </semantics></math>) is indicated for each saturation level.</p>
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<p>Modelled pile of fine sand at four saturation states, modelled with a clump scale of F24.7.</p>
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<p>Modelled pile of fine sand (F24.7) using the JKR (<b>left</b>) and SJKR-A (<b>right</b>) models.</p>
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<p>Modelled pile of the fine sand for three saturation states and a clump scale of F24.7 with the newly generated PSD based on fine sand.</p>
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25 pages, 6551 KiB  
Article
Effect of Single and Double Moment Microphysics Schemes and Change in Cloud Condensation Nuclei, Latent Heating Rate Structure Associated with Severe Convective System over Korean Peninsula
by A. Madhulatha, Jimy Dudhia, Rae-Seol Park, Subhash Chander Bhan and Mrutyunjay Mohapatra
Atmosphere 2023, 14(11), 1680; https://doi.org/10.3390/atmos14111680 - 13 Nov 2023
Cited by 2 | Viewed by 1885
Abstract
To investigate the impact of advanced microphysics schemes using single and double moment (WSM6/WDM6) schemes, numerical simulations are conducted using Weather Research and Forecasting (WRF) model for a severe mesoscale convective system (MCS) formed over the Korean Peninsula. Spatial rainfall distribution and pattern [...] Read more.
To investigate the impact of advanced microphysics schemes using single and double moment (WSM6/WDM6) schemes, numerical simulations are conducted using Weather Research and Forecasting (WRF) model for a severe mesoscale convective system (MCS) formed over the Korean Peninsula. Spatial rainfall distribution and pattern correlation linked with the convective system are improved in the WDM6 simulation. During the developing stage of the system, the distribution of total hydrometeors is larger in WDM6 compared to WSM6. Along with the mixing ratio of hydrometeors (cloud, rain, graupel, snow, and ice), the number concentration of cloud and rainwater are also predictable in WDM6. To understand the differences in the vertical representation of cloud hydrometeors between the schemes, rain number concentration (Nr) from WSM6 is also computed using particle density to compare with the Nr readily available in WDM6. Varied vertical distribution and large differences in rain number concentration and rain particle mass is evident between the schemes. Inclusion of the number concentration of rain and cloud, CCN, along with the mixing ratio of different hydrometers has improved the storm morphology in WDM6. Furthermore, the latent heating (LH) profiles of six major phase transformation processes (condensation, evaporation, freezing, melting, deposition, and sublimation) are also computed from microphysical production terms to deeply study the storm vertical structure. The main differences in condensation and evaporation terms are evident between the simulations due to the varied treatment of warm rain processes and the inclusion of CCN activation in WDM6. To investigate cloud–aerosol interactions, numerical simulation is conducted by increasing the CCN (aerosol) concentration in WDM6, which simulated comparatively improved pattern correlation for rainfall simulation along with intense hydrometer distribution. It can be inferred that the change in aerosol increased the LH of evaporation and freezing and affected the warming and cooling processes, cloud vertical distribution, and subsequent rainfall. Relatively, the WDM6 simulated latent heating profile distribution is more consistent with the ERA5 computed moisture source and sink terms due to the improved formulation of warm rain processes. Full article
(This article belongs to the Section Meteorology)
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<p>48-h accumulated rainfall in mm (00 UTC 15 July 2017–00 UTC 17 July 2017) using (<b>a</b>) TRMM Multisatellite Precipitation Analysis (TMPA) observations, (<b>b</b>) time series of three hourly accumulated rainfall (mm) over the precipitation core (126–130° E, 36–38° N, solid red box in (<b>a</b>)) and precipitation band (116–132° E, 32–39° N, solid grey box in (<b>a</b>)). (<b>c</b>) Radar image of rainfall rate and (<b>d</b>) satellite image (KMA) at 20 UTC of 15 July 2017. Black open circle in (<b>a</b>) represents the Cheongju region.</p>
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<p>(<b>a</b>) Nested domain model configuration along with orography shaded (m), (<b>b</b>) Zoomed innermost domain.</p>
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<p>Spatial distribution of 48 h accumulated precipitation in mm (00 UTC 15 July 2017–00 UTC 17 July 2017) using (<b>a</b>) AWS, (<b>b</b>) Tropical Rainfall Measuring Mission (TRMM), (<b>c</b>) WRF model numerical simulation (WSM6), (<b>d</b>) WDM6, and (<b>e</b>) temporal distribution of rainfall between the TRMM and WRF model simulations over the precipitation core region.</p>
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<p>Time height distribution of the total hydrometeor distribution over the precipitation core region. (<b>a</b>) WDM6, (<b>b</b>) WSM6, and (<b>c</b>) difference between the schemes.</p>
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<p>The vertical distribution of different hydrometeors averaged over the developing and dissipating stages of the severe convective system (solid line (dotted solid line) corresponds to the WDM6 (WSM6) schemes).</p>
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<p>Time height distribution of the (<b>a</b>,<b>b</b>) rainwater mixing ratio, (<b>c</b>,<b>d</b>) rain number concentration, and (<b>e</b>,<b>f</b>) rain particle mass (×10<sup>6</sup>) over the precipitation core region in the WSM6 (<b>left</b> panel) and WDM6 (<b>right</b> panel) schemes.</p>
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<p>Time height distribution of the (<b>a</b>,<b>b</b>) cloud water mixing ratio over the precipitation core region from the WSM6 (<b>left</b> panel) and WDM6 (<b>right</b> panel) schemes and the (<b>c</b>) cloud number concentration and (<b>d</b>) cloud particle mass from WDM6.</p>
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<p>Net latent heating rate computed based on microphysical transformation terms using both (<b>a</b>) WSM6 and (<b>b</b>) WDM6.</p>
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<p>Latent heating rate terms of major transformation process (<b>a</b>,<b>g</b>) Condensation, (<b>b</b>,<b>h</b>) Freezing, (<b>c</b>,<b>i</b>) Deposition, (<b>d</b>,<b>j</b>) Evaporation, (<b>e</b>,<b>k</b>) Melting, and (<b>f</b>,<b>l</b>) Sublimation using WSM6 (left panel), WDM6 (right panel) schemes.</p>
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<p>Mean latent heating profiles of the major transformation process during the developing (<b>a</b>,<b>c</b>) and dissipating stages (<b>b</b>,<b>d</b>) of MCS in WDM6 (<b>top</b> panel) and WSM6 (<b>bottom</b> panel).</p>
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<p>The 48-h accumulated rainfall in mm (00 UTC 15 July 2017–00 UTC 17 July 2017) (<b>a</b>) TRMM, (<b>b</b>) WDM6, (<b>c</b>) WDM6 (CCN1000), and (<b>d</b>) WSM6.</p>
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<p>Vertical Distribution of (<b>a</b>,<b>f</b>) Total hydrometeors, (<b>b</b>,<b>g</b>) net latent heating rate, LH due to (<b>c</b>,<b>h</b>) freezing, (<b>d</b>,<b>i</b>) rain evaporation, and (<b>e</b>,<b>j</b>) reflectivity in the WDM6 (left panel) and WDM6 with CCN_1000 (right panel).</p>
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<p>Contribution of different microphysical processes from different WRF simulations during the developing phase of the system (warming processes: (<b>a</b>,<b>c</b>,<b>e</b>) and cooling processes: (<b>b</b>,<b>d</b>,<b>f</b>)).</p>
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<p>Time height cross section of the simulated net latent heating rate (Kh<sup>−1</sup>) from the WRF simulations: (<b>a</b>) WSM6, (<b>b</b>) WDM6, (<b>c</b>) WDM_CCN1000, and ERA5 reanalysis. (<b>d</b>) Heat Source (Q1) and (<b>e</b>) moisture sink (Q2) terms.</p>
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