Metal Organic Frameworks
A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".
Deadline for manuscript submissions: closed (28 February 2010) | Viewed by 36864
Special Issue Editor
Interests: development of spectroscopic methods in order to achieve a detailed understanding of the physicochemical nature of a large variety of nanostructured high surface area materials, which find applications as heterogeneous catalysts in many processes; sustainability, strongly interconnected with energy efficiency and integration of (possibly renewable) resources in order to allow a sustainable growth of society
Special Issues, Collections and Topics in MDPI journals
Special Issue Information
Dear Colleagues,
In recent years several metallorganic frameworks (MOFs) have been deeply investigated for their properties and potential application in catalysis, gas storage, ion exchange, separation, and polymerization. The main properties of MOFs are ordered structures, the presence of channels or cavities with defined shapes and dimensions, a large surface area, and in some cases, a peculiar lattice flexibility. Due to these properties, MOFs are very attractive materials for their potential applications, as compared to "classic" porous materials, such as zeolites and active carbons. MOFs can be considered as three-dimensionally structured coordination metal complexes, in which the metal ions are connected to the ligands through covalent coordination bonds. The key to their success is the appropriate design of molecular building blocks (linkers, connectors, counter-ions, etc.), to obtain the desired structure and physico-chemical properties. For example, N-, O-, and S-donor ligands are suitable candidate building blocks for the obtainment of unique structural motifs, that can show not only a great aesthetic and conceptual appeal, but also attractive functional properties. The MOFs described in the recent literature can be divided into the following classes: i) porous materials containing solvents, or other neutral or ionic guest species,whose porous structure irreversibly collapses upon their removal (1st generation MOFs), ii) materials with a stable, rigid, and robust framework, that remain unchanged after the removal of the guests (2nd generation MOFs), and iii) flexible structures able to adapt themselves to a modification, or removal, of guest species or to external stimuli, by a reversible change of the shape and dimensions of pores, or, more generally, of the geometrical parameters of their crystal lattice (3rd generation MOFs).
Prof. Dr. Silvia Bordiga
Guest Editor
Keywords
- Metallorganic Frameworks
- Porous Coordination Polymers
- Hybrid Microporous Materials
- Design of Molecular Building Blocks
- Self-assembly Synthesis
- MOFs
- PCPs
- Synthesis of Linkers
- Synthesis of Connectors
- Characterization
- Modeling
Benefits of Publishing in a Special Issue
- Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
- Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
- Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
- External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
- e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.
Further information on MDPI's Special Issue policies can be found here.
