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Appl. Sci., Volume 9, Issue 5 (March-1 2019) – 222 articles

Cover Story (view full-size image): The main character of this cover story is the human A3 Adenosine receptor, represented here in the active state, on the left, and inactive state, on the right. The EM correlation coefficient, by which they were selected among other possible competitors, is shown between them. When A3 thinks about a selective agonist, it remembers to wake up, the sun rises and the day starts, it is active! Whereas, when it thinks about a selective antagonist, it goes to sleep, the moon is already in the sky and it is inactive. View this paper.
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15 pages, 5858 KiB  
Article
PRGF-Modified Collagen Membranes for Guided Bone Regeneration: Spectroscopic, Microscopic and Nano-Mechanical Investigations
by Cristian Ratiu, Marcel Brocks, Traian Costea, Liviu Moldovan and Simona Cavalu
Appl. Sci. 2019, 9(5), 1035; https://doi.org/10.3390/app9051035 - 12 Mar 2019
Cited by 26 | Viewed by 4412
Abstract
The aim of our study was to evaluate the properties of different commercially available resorbable collagen membranes for guided bone regeneration, upon addition of plasma rich in growth factors (PRGF). The structural and morphological details, mechanical properties, and enzymatic degradation were investigated in [...] Read more.
The aim of our study was to evaluate the properties of different commercially available resorbable collagen membranes for guided bone regeneration, upon addition of plasma rich in growth factors (PRGF). The structural and morphological details, mechanical properties, and enzymatic degradation were investigated in a new approach, providing clinicians with new data in order to help them in a successful comparison and better selection of membranes with respect to their placement and working condition. Particular characteristics such as porosity, fiber density, and surface topography may influence the mechanical behavior and performances of the membranes, as revealed by SEM/AFM and nanoindentation measurements. The mechanical properties and enzymatic degradation of the membranes were analyzed in a comparative manner, before and after PRGF-modification. The changes in Young modulus values are correlated with the ultrastructural properties of each membrane type. The enzymatic (trypsin) degradation test also emphasized that PRGF-modified membranes exhibit a slower degradation compared to the native ones. Full article
(This article belongs to the Special Issue Development of Membranes for Oral and Maxillofacial Application)
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<p>Whole blood separation upon centrifugation at 580 G for 8 minutes at room temperature (<b>a</b>) and subsequent platelets rich in growth factor (PRGF) separation by pipetting (<b>b</b>); membrane immersion in PRGF (<b>c</b>).</p>
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<p>ATR FTIR (Attenuated Total Reflection Fourier Transform Infrared) spectra of commercial collagen membranes for bone-guided regeneration before and after PRGF treatment. Legend: Biocollagen<sup>®</sup> = MCP; Cova<sup>TM</sup>Max = MPP; Jason<sup>®</sup> = MC.</p>
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<p>Cross-sectional scanning electron microscopy (SEM) images of different commercial collagen membranes before (<b>a</b>,<b>d</b>,<b>g</b>) and after (<b>b</b>,<b>e</b>,<b>h</b>) PRGF treatment; AFM 3D topography of the membrane surface after PRGF treatment (<b>c</b>,<b>f</b>,<b>i</b>) showing the details of collagen fibers. The images correspond to Biocollagen<sup>®</sup> (<b>a</b>–<b>c</b>), Cova<sup>TM</sup> Max (<b>d</b>–<b>f</b>), and Jason<sup>®</sup> (<b>g</b>–<b>i</b>).</p>
Full article ">Figure 3 Cont.
<p>Cross-sectional scanning electron microscopy (SEM) images of different commercial collagen membranes before (<b>a</b>,<b>d</b>,<b>g</b>) and after (<b>b</b>,<b>e</b>,<b>h</b>) PRGF treatment; AFM 3D topography of the membrane surface after PRGF treatment (<b>c</b>,<b>f</b>,<b>i</b>) showing the details of collagen fibers. The images correspond to Biocollagen<sup>®</sup> (<b>a</b>–<b>c</b>), Cova<sup>TM</sup> Max (<b>d</b>–<b>f</b>), and Jason<sup>®</sup> (<b>g</b>–<b>i</b>).</p>
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<p>Nanoindentation measurements: load–displacement curves recorded for each membrane before (<b>a</b>,<b>c</b>,<b>e</b>) and after (<b>b</b>,<b>d</b>,<b>f</b>) PRGF treatment. The images correspond to Jason<sup>®</sup> (<b>a</b>,<b>b</b>), Biocollagen<sup>®</sup> (<b>c</b>,<b>d</b>), and Cova<sup>TM</sup> Max (<b>e</b>,<b>f</b>). Legend: MC1/MC2 = Jason<sup>®</sup> membrane before/after PRGF treatment; MCP1/MCP2 = Biocollagen<sup>®</sup> membrane before/after PRGF treatment; MPP1/MPP2 = Cova<sup>TM</sup> Max membrane before/after PRGF treatment.</p>
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<p>Young modulus calculations with respect to the three collagen membranes before (<b>a</b>) and after PRGF treatment (<b>b</b>). Legend: MPP1/MPP2 = Cova<sup>TM</sup>Max membrane before/after PRGF treatment; MC1/MC2 = Jason<sup>®</sup> membrane before/after PRGF treatment; MCP1/MCP2 = Biocollagen<sup>®</sup> membrane before/after PRGF treatment.</p>
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<p>Results of enzymatic degradation test of native (unmodified) and PRGF-modified collagen membranes. Legend: <span class="html-fig-inline" id="applsci-09-01035-i001"> <img alt="Applsci 09 01035 i001" src="/applsci/applsci-09-01035/article_deploy/html/images/applsci-09-01035-i001.png"/></span> Cova<sup>TM</sup>Max; <span class="html-fig-inline" id="applsci-09-01035-i002"> <img alt="Applsci 09 01035 i002" src="/applsci/applsci-09-01035/article_deploy/html/images/applsci-09-01035-i002.png"/></span> Jason<sup>®</sup>; <span class="html-fig-inline" id="applsci-09-01035-i003"> <img alt="Applsci 09 01035 i003" src="/applsci/applsci-09-01035/article_deploy/html/images/applsci-09-01035-i003.png"/></span> Biocollagen<sup>®</sup>.</p>
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17 pages, 3571 KiB  
Article
Biologically-Inspired Learning and Adaptation of Self-Evolving Control for Networked Mobile Robots
by Sendren Sheng-Dong Xu, Hsu-Chih Huang, Tai-Chun Chiu and Shao-Kang Lin
Appl. Sci. 2019, 9(5), 1034; https://doi.org/10.3390/app9051034 - 12 Mar 2019
Cited by 8 | Viewed by 2933 | Correction
Abstract
This paper presents a biologically-inspired learning and adaptation method for self-evolving control of networked mobile robots. A Kalman filter (KF) algorithm is employed to develop a self-learning RBFNN (Radial Basis Function Neural Network), called the KF-RBFNN. The structure of the KF-RBFNN is optimally [...] Read more.
This paper presents a biologically-inspired learning and adaptation method for self-evolving control of networked mobile robots. A Kalman filter (KF) algorithm is employed to develop a self-learning RBFNN (Radial Basis Function Neural Network), called the KF-RBFNN. The structure of the KF-RBFNN is optimally initialized by means of a modified genetic algorithm (GA) in which a Lévy flight strategy is applied. By using the derived mathematical kinematic model of the mobile robots, the proposed GA-KF-RBFNN is utilized to design a self-evolving motion control law. The control parameters of the mobile robots are self-learned and adapted via the proposed GA-KF-RBFNN. This approach is extended to address the formation control problem of networked mobile robots by using a broadcast leader-follower control strategy. The proposed pragmatic approach circumvents the communication delay problem found in traditional networked mobile robot systems where consensus graph theory and directed topology are applied. The simulation results and numerical analysis are provided to demonstrate the merits and effectiveness of the developed GA-KF-RBFNN to achieve self-evolving formation control of networked mobile robots. Full article
(This article belongs to the Special Issue Advanced Mobile Robotics)
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<p>Structure of the classical Kalman filter.</p>
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<p>Structure of the classical RBFNN (Radial Basis Function Neural Network).</p>
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<p>Block diagram of the RBFNN control scheme.</p>
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<p>Block diagram of the KF-RBFNN control scheme.</p>
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<p>Flowchart of evolutionary GA.</p>
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<p>Geometry of the omnidirectional mobile robot with four Swedish wheels.</p>
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<p>Block diagram of the GA-KF-RBFNN redundant control scheme for mobile robot.</p>
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<p>Leader-follower formation control with three mobile robots.</p>
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<p>Simulation result of circular formation control.</p>
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<p>Tracking error of the leader mobile robot for circular formation control.</p>
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<p>Formation error of follower robot #1 for circular formation control.</p>
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<p>Formation error of follower mobile robot #2 for circular formation control.</p>
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<p>Simulation result for the daisy curve formation control.</p>
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<p>Tracking error of the leader mobile robot for daisy curve formation control.</p>
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<p>Formation error of follower robot #1 for daisy curve formation control.</p>
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<p>Formation error of follower robot #2 for daisy curve formation control.</p>
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25 pages, 6110 KiB  
Review
Generation of Orbital Angular Momentum Modes Using Fiber Systems
by Hongwei Zhang, Baiwei Mao, Ya Han, Zhi Wang, Yang Yue and Yange Liu
Appl. Sci. 2019, 9(5), 1033; https://doi.org/10.3390/app9051033 - 12 Mar 2019
Cited by 43 | Viewed by 8396
Abstract
Orbital angular momentum (OAM) beams, characterized by the helical phase wavefront, have received significant interest in various areas of study. There are many methods to generate OAM beams, which can be roughly divided into two types: spatial methods and fiber methods. As a [...] Read more.
Orbital angular momentum (OAM) beams, characterized by the helical phase wavefront, have received significant interest in various areas of study. There are many methods to generate OAM beams, which can be roughly divided into two types: spatial methods and fiber methods. As a natural shaper of OAM beams, the fibers exhibit unique merits, namely, miniaturization and a low insertion loss. In this paper, we review the recent advances in fiber OAM mode generation systems, in both the interior and exterior of the beams. We introduce the basic concepts of fiber modes and the generation and detection theories of OAM modes. In addition, fiber systems based on different nuclear devices are introduced, including the long-period fiber grating, the mode-selective coupler, microstructural optical fiber, and the photonic lantern. Finally, the key challenges and prospects for fiber OAM mode systems are discussed. Full article
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<p>A summary of typical OAM generation techniques based on spatial components (spiral phase plate [<a href="#B18-applsci-09-01033" class="html-bibr">18</a>], spatial light modulator [<a href="#B16-applsci-09-01033" class="html-bibr">16</a>], metamaterial [<a href="#B24-applsci-09-01033" class="html-bibr">24</a>], micro-ring resonator [<a href="#B30-applsci-09-01033" class="html-bibr">30</a>], and computer-generated holograms [<a href="#B22-applsci-09-01033" class="html-bibr">22</a>]) [<a href="#B16-applsci-09-01033" class="html-bibr">16</a>,<a href="#B17-applsci-09-01033" class="html-bibr">17</a>,<a href="#B18-applsci-09-01033" class="html-bibr">18</a>,<a href="#B19-applsci-09-01033" class="html-bibr">19</a>,<a href="#B20-applsci-09-01033" class="html-bibr">20</a>,<a href="#B21-applsci-09-01033" class="html-bibr">21</a>,<a href="#B22-applsci-09-01033" class="html-bibr">22</a>,<a href="#B23-applsci-09-01033" class="html-bibr">23</a>,<a href="#B24-applsci-09-01033" class="html-bibr">24</a>,<a href="#B25-applsci-09-01033" class="html-bibr">25</a>,<a href="#B26-applsci-09-01033" class="html-bibr">26</a>,<a href="#B27-applsci-09-01033" class="html-bibr">27</a>,<a href="#B28-applsci-09-01033" class="html-bibr">28</a>,<a href="#B29-applsci-09-01033" class="html-bibr">29</a>,<a href="#B30-applsci-09-01033" class="html-bibr">30</a>]. Reprinted with permission from [<a href="#B18-applsci-09-01033" class="html-bibr">18</a>], copyright 2010 Springer Nature; [<a href="#B16-applsci-09-01033" class="html-bibr">16</a>], copyright 2004 The Optical Society; [<a href="#B24-applsci-09-01033" class="html-bibr">24</a>], copyright 2011 AAAS; [<a href="#B30-applsci-09-01033" class="html-bibr">30</a>], copyright 2012 AAAS; [<a href="#B22-applsci-09-01033" class="html-bibr">22</a>], copyright 2011AAAS.</p>
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<p>The propagation properties during half a period and the integer-period time average patterns of two typical CV modes, (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>T</mi> <msub> <mi>E</mi> <mrow> <mn>01</mn> </mrow> </msub> </mrow> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>T</mi> <msub> <mi>M</mi> <mrow> <mn>01</mn> </mrow> </msub> </mrow> </semantics></math>; and two typical LP modes, (<b>c</b>) <math display="inline"><semantics> <mrow> <mover accent="true"> <mi>x</mi> <mo stretchy="false">^</mo> </mover> <mi>L</mi> <msubsup> <mi>P</mi> <mrow> <mn>11</mn> </mrow> <mrow> <mi>e</mi> <mi>v</mi> <mi>e</mi> <mi>n</mi> </mrow> </msubsup> </mrow> </semantics></math> and (<b>d</b>) <math display="inline"><semantics> <mrow> <mover accent="true"> <mi>x</mi> <mo stretchy="false">^</mo> </mover> <mi>L</mi> <msubsup> <mi>P</mi> <mrow> <mn>11</mn> </mrow> <mrow> <mi>o</mi> <mi>d</mi> <mi>d</mi> </mrow> </msubsup> </mrow> </semantics></math>; and two typical OAM modes, (<b>e</b>) <math display="inline"><semantics> <mrow> <msup> <mover accent="true"> <mi>σ</mi> <mo stretchy="false">^</mo> </mover> <mo>−</mo> </msup> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>+</mo> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math> and (<b>f</b>) <math display="inline"><semantics> <mrow> <mover accent="true"> <mi>x</mi> <mo stretchy="false">^</mo> </mover> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>+</mo> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math>.</p>
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<p>Sketch of the four-dimension complex space model and the transformation among CV mode, LP mode, and OAM mode bases of <span class="html-italic">l</span>th azimuthal order modes.</p>
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<p>Sketch of fiber OAM modes generation system. Reprinted with permission from [<a href="#B54-applsci-09-01033" class="html-bibr">54</a>], copyright 2018 De Gruyter.</p>
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<p>The interference patterns of <math display="inline"><semantics> <mrow> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>+</mo> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>+</mo> <mn>2</mn> </mrow> </msub> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>+</mo> <mn>3</mn> </mrow> </msub> </mrow> </semantics></math> when <math display="inline"><semantics> <mrow> <msub> <mi>k</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>k</mi> <mi>f</mi> </msub> <mo>&gt;</mo> <mn>0</mn> <mo>,</mo> <mo> </mo> <msub> <mi>k</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>k</mi> <mi>f</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>k</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>k</mi> <mi>f</mi> </msub> <mo>&lt;</mo> <mn>0</mn> </mrow> </semantics></math> and (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϕ</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>ϕ</mi> <mi>f</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϕ</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>ϕ</mi> <mi>f</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>.</p>
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<p>(<b>a</b>) Interference patterns with different TCs, wave vectors and tilted degrees. The interference patterns of OAM beams (<math display="inline"><semantics> <mrow> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msub> <mo>,</mo> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>−</mo> <mn>2</mn> </mrow> </msub> <mo>,</mo> <mi>O</mi> <mi>A</mi> <msub> <mi>M</mi> <mrow> <mo>−</mo> <mn>3</mn> </mrow> </msub> </mrow> </semantics></math>) with (<b>b</b>) the tilted plane light wave; (<b>c</b>) itself with a translation when the initial phase interference <math display="inline"><semantics> <mrow> <msub> <mi>ϕ</mi> <mi>s</mi> </msub> <mo>−</mo> <msub> <mi>ϕ</mi> <mi>f</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math> or <math display="inline"><semantics> <mi>π</mi> </semantics></math>.</p>
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<p>Experimental setup of (<b>a</b>) mechanical micro-bending and (<b>b</b>) CO2 laser irradiation method to fabricate LPFGs; (<b>c</b>) transmission spectrum of the LPFGs. Reprinted with permission from [<a href="#B65-applsci-09-01033" class="html-bibr">65</a>], copyright 2000 The Optical Society; [<a href="#B60-applsci-09-01033" class="html-bibr">60</a>], copyright 2018 The Optical Society; [<a href="#B43-applsci-09-01033" class="html-bibr">43</a>], copyright 2018.</p>
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<p>(<b>a</b>) and (<b>b</b>) Operating principle of OAM generation based on LPFGs system; (<b>c</b>)-(<b>e</b>) mode pattern of corresponding generated OAM modes in (<b>c</b>) [<a href="#B43-applsci-09-01033" class="html-bibr">43</a>], (<b>d</b>) [<a href="#B34-applsci-09-01033" class="html-bibr">34</a>], and (<b>e</b>) [<a href="#B32-applsci-09-01033" class="html-bibr">32</a>], respectively. Reprinted with permission from [<a href="#B35-applsci-09-01033" class="html-bibr">35</a>], copyright 2015 The Optical Society; [<a href="#B32-applsci-09-01033" class="html-bibr">32</a>], copyright 2018 The Optical society; [<a href="#B34-applsci-09-01033" class="html-bibr">34</a>], copyright 2016 The Optical Society; [<a href="#B43-applsci-09-01033" class="html-bibr">43</a>], copyright 2018 De Gruyter.</p>
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<p>The mode pattern of generated OAM mode based on the (<b>a</b>) LCFG and (<b>b</b>) RCFG respectively; RCP: right circularly-polarized; LCP: left circularly-polarized. Reprinted with permission from [<a href="#B44-applsci-09-01033" class="html-bibr">44</a>], copyright 2019 The Optical Society.</p>
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<p>Schematics of the MSCs, composed of the SMF and the FMF. SMF: single-mode fiber; FMF: four-mode fiber.</p>
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<p>(<b>a</b>) A typical experimental setup based on MSC to generate OAM modes; (<b>b</b>–<b>c</b>) mode pattern of generated (<b>b</b>) LP-OAM, and (<b>c</b>) two orthogonal CP-OAM mode, respectively.</p>
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<p>Schematic of proposed micro-structured optical fiber to generate OAM mode in [<a href="#B49-applsci-09-01033" class="html-bibr">49</a>]. Reprinted with permission from [<a href="#B49-applsci-09-01033" class="html-bibr">49</a>], copyright 2015 The Optical Society.</p>
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<p>Schematic of operating principle of OAM generating based on the MSPL. Reprinted with permission from [<a href="#B52-applsci-09-01033" class="html-bibr">52</a>], copyright 2018 The Optical Society.</p>
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<p>Mode pattern of generated OAM modes and the multiplexing of OAM modes using the MSPL. Reprinted with permission from [<a href="#B53-applsci-09-01033" class="html-bibr">53</a>], copyright 2018 The Optical Society.</p>
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17 pages, 3656 KiB  
Article
Effect of Carbon Nanotubes on Chloride Penetration in Cement Mortars
by Panagiota T. Dalla, Ilias K. Tragazikis, Dimitrios A. Exarchos, Konstantinos G. Dassios, Nektaria M. Barkoula and Theodore E. Matikas
Appl. Sci. 2019, 9(5), 1032; https://doi.org/10.3390/app9051032 - 12 Mar 2019
Cited by 25 | Viewed by 3909
Abstract
The study investigates the effect of carbon nanotubes on chloride penetration in nano-modified mortars and reports on the physical, electrical, and mechanical performance of the material. Mortars were artificially corroded and their surface electrical surface conductivity as well as flexural and compressive strength [...] Read more.
The study investigates the effect of carbon nanotubes on chloride penetration in nano-modified mortars and reports on the physical, electrical, and mechanical performance of the material. Mortars were artificially corroded and their surface electrical surface conductivity as well as flexural and compressive strength were measured. The influence of variable nanotube concentration in accelerated corrosion damage was evaluated. Nanotube concentration was found to significantly affect the permeability of the mortars; improvements in flexural and compressive response of mortars exposed to salt spray fog, compared to virgin specimens, were rationalized upon decreases in the apparent porosity of the materials due to filling of the pores with sodium chloride. Electrical resistivity was found to increase up to two orders of magnitude with respect to the surface value; above the percolation threshold, the property impressively increased up to five orders of magnitude. Full article
(This article belongs to the Special Issue Multi-Walled Carbon Nanotubes)
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<p>Experimental set up for the rapid chloride permeability test method.</p>
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<p>(<b>a</b>) Salt spray chamber and (<b>b</b>) sealed specimens inside the chamber.</p>
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<p>Testing cores drilled off from mortars exposed to accelerated corrosion.</p>
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<p>Change of flowability and air content across nano-modified mortars with different concentrations of carbon nanotubes.</p>
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<p>Current passing through nano-modified mortars with different amount of carbon nanotubes (CNTs).</p>
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<p>Total charge passed through specimens with different CNT loadings.</p>
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<p>Chloride profile of the nano-modified mortars at different depths.</p>
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<p>Chloride diffusion coefficient for each nano-modified mortar.</p>
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<p>Pore size distributions of nano-modified mortars.</p>
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<p>Chloride diffusion coefficient a function of mortar porosity.</p>
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<p>Surface electrical resistivity with respect to the depth below the exposed surface for all the nano-modified cement mortar.</p>
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<p>Mechanical properties of the nano-modified mortars before and after the exposure to the salt spray chamber.</p>
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18 pages, 13806 KiB  
Article
MAG Welding Tests of Modern High Strength Steels with Minimum Yield Strength of 700 MPa
by Teemu Lahtinen, Pedro Vilaça, Pasi Peura and Saara Mehtonen
Appl. Sci. 2019, 9(5), 1031; https://doi.org/10.3390/app9051031 - 12 Mar 2019
Cited by 33 | Viewed by 5770
Abstract
The modern high strength steel plates have an excellent combination of strength and toughness based on micro-alloying and complex microstructure. Retaining this combination of properties in the weld zone is a major challenge for applications in high-demanding structural construction. This work investigates the [...] Read more.
The modern high strength steel plates have an excellent combination of strength and toughness based on micro-alloying and complex microstructure. Retaining this combination of properties in the weld zone is a major challenge for applications in high-demanding structural construction. This work investigates the weldability of three different modern high strength steel plates, with a thickness of 8 mm. Two of the test materials were produced by a thermo-mechanically controlled process (TMCP) and one by a quenching and tempering method (Q&T). Two-passes MAG (metal active gas) welding was used with four different heat inputs. The tests implemented on all the materials included tensile, hardness profiles (HV5), Charpy-V impact toughness tests, and microstructure analysis using scanning electron microscope (SEM). For one of the TMCP steels, some extended tests were conducted to define how the tensile properties change along the weld line. These tests included tensile tests with digital image correlation (DIC), and 3-point bending tests. The most notable differences in mechanical properties of the welds between the materials were observed in Charpy-V impact toughness tests, mostly at the vicinity of the fusion line, with the Q&T steel more prone to embrittlement of the heat affected zone (HAZ) than the TMCP steels. Microstructural analysis revealed carbide concentration combined with coarse bainitic structures in HAZ of Q&T steel, explaining the more severe embrittlement. During the tensile tests, the DIC measurements have shown a strain localization in the softest region of the HAZ. Increasing the heat input resulted in earlier localization of the strain and less maximum strength. The tensile properties along the weld line were investigated in all welding conditions, and the results emphasize relevant and systematic differences of the yield strength at the transient zones near the start and end of the weld compared with the intermediate stationary domain. Full article
(This article belongs to the Special Issue Welding of Steels)
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Figure 1

Figure 1
<p>Optical (above) and SEM (below) micrographs of microstructures of the three base materials. The microstructures of TMCP (MC) steels are fairly similar between each other, consisting of fine ferritic grains with small amount of second phase constituents at the grain boundaries. Deformation from the rolling can be seen as elongated grains. Base material of Q&amp;T steel consists mainly of tempered martensite.</p>
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<p>Schematic presentation of the weld joint: (<b>a</b>) joint design; (<b>b</b>) welding sequence. All dimensions in [mm].</p>
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<p>Locations of the specimens for tensile tests testing the difference in strength along the weld axis.</p>
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<p>Charpy-V impact test specimens: (<b>a</b>) dimension; (<b>b</b>) notch locations with red vertical lines representing the locations: WM (weld metal), FL (fusion line) + 1 mm, FL + 3 mm and FL + 5 mm.</p>
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<p>Elongations of the welds: (<b>a</b>) machined specimens; (<b>b</b>) specimens with reinforcements.</p>
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<p>Yield and ultimate tensile strength of the welds: (<b>a</b>) machined specimens; (<b>b</b>) specimens with reinforcements.</p>
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<p>The effect of the distance from the start of the weld on tensile test properties in the S700MC-1. The distance is measured to the center of the tensile specimen.</p>
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<p>Results of DIC-measurements in specimens extracted from the steady-state domain from the welds of S700MC-1.</p>
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<p>Average displacement-load/width curves for each heat input: (<b>a</b>) face side bending; (<b>b</b>) root side bending; (<b>c</b>) formation of the gap during testing induces the change in slope of the curve.</p>
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<p>Charpy-V impact toughness results for the base materials. The error bars illustrate the standard deviation of the three individual tests.</p>
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<p>Charpy-V impact toughness results for all the welds. Specimens having the notch at FL + 1 mm were tested at −20, −40 and −60 °C. Specimens having the notch at WM, FL + 3 mm and FL + 5 mm were tested only at −40 and −60 °C.</p>
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<p>Hardness profiles of the welds of different materials with four different heat inputs.</p>
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<p>Locations of the SEM images in the cross section of weld specimens: (<b>a</b>) low heat input, t<sub>8/5</sub> = 5 s; (<b>b</b>) high heat input, t<sub>8/5</sub> = 20 s.</p>
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<p>SEM images from low heat input (t<sub>8/5</sub> = 5 s) weld HAZ for steel S700MC-1. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>SEM images from high heat input (t<sub>8/5</sub> = 20 s) weld HAZ for steel S700MC-1. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>SEM images from low heat input weld (t<sub>8/5</sub> = 5 s) HAZ for steel S700MC-2. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>SEM images from high heat input weld (t<sub>8/5</sub> = 20 s) HAZ for steel S700MC-2. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>SEM images from low heat input weld (t<sub>8/5</sub> = 5 s) HAZ for steel S690QL. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>SEM images from high heat input weld (t<sub>8/5</sub> = 20 s) HAZ for steel S690QL. (<b>A</b>–<b>D</b>) are locations established in <a href="#applsci-09-01031-f013" class="html-fig">Figure 13</a>.</p>
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<p>Carbide concentrations in detail from location D of the HAZ of S690QL produced with the high heat input weld (t<sub>8/5</sub> = 20 s).</p>
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22 pages, 4703 KiB  
Review
Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
by Gene Yang, Wonsang Jung, Sung-Jin Ahn and Dongkyu Lee
Appl. Sci. 2019, 9(5), 1030; https://doi.org/10.3390/app9051030 - 12 Mar 2019
Cited by 33 | Viewed by 6788
Abstract
Achieving the fast oxygen reduction reaction (ORR) kinetics at the cathode of solid oxide fuel cells (SOFCs) is indispensable to enhance the efficiency of SOFCs at intermediate temperatures. Mixed ionic and electronic conducting (MIEC) oxides such as ABO3 perovskites and Ruddlesden-Popper (RP) [...] Read more.
Achieving the fast oxygen reduction reaction (ORR) kinetics at the cathode of solid oxide fuel cells (SOFCs) is indispensable to enhance the efficiency of SOFCs at intermediate temperatures. Mixed ionic and electronic conducting (MIEC) oxides such as ABO3 perovskites and Ruddlesden-Popper (RP) oxides (A2BO4) have been widely used as promising cathode materials owing to their attractive physicochemical properties. In particular, oxides in forms of thin films and heterostructures have enabled significant enhancement in the ORR activity. Therefore, we aim to give a comprehensive overview on the recent development of thin film cathodes of SOFCs. We discuss important advances in ABO3 and RP oxide thin film cathodes for SOFCs. Our attention is also paid to the influence of oxide heterostructure interfaces on the ORR activity of SOFC cathodes. Full article
(This article belongs to the Special Issue Progress in Solid-Oxide Fuel Cell Technology)
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Figure 1

Figure 1
<p>Schematic of possible elementary reaction steps during oxygen reduction reaction (ORR) and possible pathways for two different classes of cathode materials; (<b>a</b>) pure electronic conductor and (<b>b</b>) mixed ionic and electronic conducting (MIEC) cathodes.</p>
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<p>Schematic crystal structure of ABO<sub>3</sub> perovskite oxides, where A and B are a rare earth and transition metal atom.</p>
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<p>Arrhenius plots of surface exchange coefficients (<span class="html-italic">k</span>*) for epitaxial La<sub>1−x</sub>Sr<sub>x</sub>CoO<sub>3−δ</sub> thin films. (<b>a</b>) Effect of thickness difference on <span class="html-italic">k</span>* for La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3−δ</sub> [<a href="#B96-applsci-09-01030" class="html-bibr">96</a>] and of substrate difference (STO and LAO) on <span class="html-italic">k</span>* for La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3−δ</sub> [<a href="#B64-applsci-09-01030" class="html-bibr">64</a>] thin films and La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3−δ</sub> [<a href="#B9-applsci-09-01030" class="html-bibr">9</a>] polycrystalline samples. (<b>b</b>) Effect of Sr substitution on <span class="html-italic">k</span>* for La<sub>1−x</sub>Sr<sub>x</sub>CoO<sub>3−δ</sub> (x = 0, 0.2 and 0.4, [<a href="#B64-applsci-09-01030" class="html-bibr">64</a>,<a href="#B95-applsci-09-01030" class="html-bibr">95</a>,<a href="#B96-applsci-09-01030" class="html-bibr">96</a>]) thin films and La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3−δ</sub> [<a href="#B9-applsci-09-01030" class="html-bibr">9</a>] polycrystalline oxides.</p>
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<p>(<b>a</b>) Schematic electronic structure plots to illustrate the correlation of the ORR energetics vs. the O p-band center based on the rigid band model. Reprinted from [<a href="#B100-applsci-09-01030" class="html-bibr">100</a>] with permission of The Royal Society of Chemistry. (<b>b</b>) DFT calculations for the oxygen 2p-band center with respect to the Fermi level as a function of strain in LSCO films. The calculated oxygen 2p-band centers are averaged over LSCO films with five different Sr orderings. Reprinted from [<a href="#B96-applsci-09-01030" class="html-bibr">96</a>] with permission of The American Chemical Society.</p>
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<p>Arrhenius plots of surface exchange coefficients (<span class="html-italic">k</span>*) for La<sub>1−x</sub>Sr<sub>x</sub>Co<sub>1−y</sub>Fe<sub>y</sub>O<sub>3−δ</sub> thin films. (<b>a</b>) Effect of strain on <span class="html-italic">k</span>* for La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub> [<a href="#B117-applsci-09-01030" class="html-bibr">117</a>] and La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub> [<a href="#B118-applsci-09-01030" class="html-bibr">118</a>] films and La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub> (Ref. [<a href="#B119-applsci-09-01030" class="html-bibr">119</a>]) polycrystalline samples. (<b>b</b>) Effect of Sr substitution on <span class="html-italic">k</span>* for La<sub>1−x</sub>Sr<sub>x</sub>Co<sub>1−y</sub>Fe<sub>y</sub>O<sub>3−δ</sub> (red [<a href="#B117-applsci-09-01030" class="html-bibr">117</a>], black [<a href="#B47-applsci-09-01030" class="html-bibr">47</a>] and blue [<a href="#B114-applsci-09-01030" class="html-bibr">114</a>]) films and La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub> [<a href="#B119-applsci-09-01030" class="html-bibr">119</a>] polycrystalline oxides.</p>
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<p>Schematic crystal structure of RP oxides, where A and B are a rare earth and transition metal atom.</p>
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<p>Arrhenius plots of surface exchange coefficients (<span class="html-italic">k</span>*) for A<sub>2</sub>NiO<sub>4+δ</sub> (A = La and Nd): (<b>a</b>) Tensile (Tens.) and compressive (Comp.) strained (001)-oriented La<sub>2</sub>NiO<sub>4+δ</sub> films [<a href="#B61-applsci-09-01030" class="html-bibr">61</a>] and tensile, zero, and compressive strained (100)-oriented Nd<sub>2</sub>NiO<sub>4+δ</sub> thin films [<a href="#B135-applsci-09-01030" class="html-bibr">135</a>]; (<b>b</b>) (001)- and (100)-oriented La<sub>2</sub>NiO<sub>4+δ</sub> [<a href="#B61-applsci-09-01030" class="html-bibr">61</a>,<a href="#B63-applsci-09-01030" class="html-bibr">63</a>] thin films with various thickness and substrates.</p>
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<p>Oxygen surface exchange coefficients (<span class="html-italic">k</span>*) of La<sub>2</sub>CuO<sub>4</sub> (light blue), LaSrCoO<sub>4</sub> (green), La<sub>1.85</sub>Sr<sub>0.15</sub>CuO<sub>4</sub> (blue), La<sub>1.6</sub>Sr<sub>0.4</sub>CuO<sub>4</sub> (deep blue), and LaSrNiO<sub>4</sub> (red) films with (001) orientations measured at 550 °C versus the computed DFT bulk O 2p-band centers (relative to the Fermi level, E<sub>Fermi</sub>). The gray dashed lines represent the correlation between experimental oxygen surface-exchange coefficients and the computed bulk O 2p-band centers for a series of SOFC perovskites. Reprinted from [<a href="#B126-applsci-09-01030" class="html-bibr">126</a>] with permission of The American Chemical Society.</p>
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<p>Arrhenius plots of surface exchange coefficients (<span class="html-italic">k</span>*) for different RP oxides: (<b>a</b>) <span class="html-italic">k</span>* along c-direction in La<sub>2-<span class="html-italic">x</span></sub>Sr<span class="html-italic"><sub>x</sub></span>MO<sub>4</sub> (M = Cu, Co, Ni, [<a href="#B126-applsci-09-01030" class="html-bibr">126</a>,<a href="#B133-applsci-09-01030" class="html-bibr">133</a>,<a href="#B135-applsci-09-01030" class="html-bibr">135</a>,<a href="#B144-applsci-09-01030" class="html-bibr">144</a>]); and (<b>b</b>) <span class="html-italic">k</span>* along a-b plane in A<sub>2-<span class="html-italic">x</span></sub>Sr<span class="html-italic"><sub>x</sub></span>MO<sub>4</sub> (A = Sr, La, Nd and M = Co, Ni, [<a href="#B61-applsci-09-01030" class="html-bibr">61</a>,<a href="#B65-applsci-09-01030" class="html-bibr">65</a>,<a href="#B128-applsci-09-01030" class="html-bibr">128</a>,<a href="#B133-applsci-09-01030" class="html-bibr">133</a>,<a href="#B135-applsci-09-01030" class="html-bibr">135</a>,<a href="#B144-applsci-09-01030" class="html-bibr">144</a>]) thin films.</p>
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<p>(<b>a</b>) The calculated Sr/La substitution energies in the bulk LSC<sub>214</sub>, LSC<sub>113</sub>, and LSCF<sub>113</sub> (all relative to that of LSC<sub>113</sub>, which is set to 0). (<b>b</b>) The heterostructured interface model used in the DFT simulations and the results of Sr/La substitution energies. The elements are represented as: La/Sr (dark blue), Fe/Co (light blue, center of the octahedra), and O (red). Reprinted from [<a href="#B86-applsci-09-01030" class="html-bibr">86</a>] with permission of The Royal Society of Chemistry.</p>
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<p>Arrhenius plots of surface exchange coefficients (<span class="html-italic">k</span>*) for various heterostructure oxide thin films. Effect of heterostructure interfaces on <span class="html-italic">k</span>* for La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3−δ</sub>/(LaSr)<sub>2</sub>CoO<sub>4±δ</sub> [<a href="#B150-applsci-09-01030" class="html-bibr">150</a>], La<sub>0.625</sub>Sr<sub>0.375</sub>Fe<sub>0.75</sub>Co<sub>0.25</sub>O<sub>3−δ</sub>/(LaSr)<sub>2</sub>CoO<sub>4±δ</sub> [<a href="#B86-applsci-09-01030" class="html-bibr">86</a>], La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3−δ</sub>/La<sub>0.8</sub>Sr<sub>0.2</sub>MnO<sub>3−δ</sub> [<a href="#B76-applsci-09-01030" class="html-bibr">76</a>], La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3−δ</sub>/(LaSr)<sub>2</sub>CoO<sub>4±δ</sub> [<a href="#B148-applsci-09-01030" class="html-bibr">148</a>] and La<sub>0.6</sub>Sr<sub>0.4</sub>Fe<sub>0.8</sub>Co<sub>0.2</sub>O<sub>3−δ</sub>/La<sub>0.4</sub>Sr<sub>0.6</sub>CoO<sub>3−δ</sub>:(LaSr)<sub>2</sub>CoO<sub>4±δ</sub> [<a href="#B66-applsci-09-01030" class="html-bibr">66</a>].</p>
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13 pages, 3483 KiB  
Article
Research on the Influence of Backlash on Mesh Stiffness and the Nonlinear Dynamics of Spur Gears
by Yangshou Xiong, Kang Huang, Fengwei Xu, Yong Yi, Meng Sang and Hua Zhai
Appl. Sci. 2019, 9(5), 1029; https://doi.org/10.3390/app9051029 - 12 Mar 2019
Cited by 24 | Viewed by 3893
Abstract
In light of ignoring the effect of backlash on mesh stiffness in existing gear dynamic theory, a precise profile equation was established based on the generating processing principle. An improved potential energy method was proposed to calculate the mesh stiffness. The calculation result [...] Read more.
In light of ignoring the effect of backlash on mesh stiffness in existing gear dynamic theory, a precise profile equation was established based on the generating processing principle. An improved potential energy method was proposed to calculate the mesh stiffness. The calculation result showed that when compared with the case of ignoring backlash, the mesh stiffness with backlash had an obvious decrease in a mesh cycle and the rate of decline had a trend of decreasing first and then increasing, so a stiffness coefficient was introduced to observe the effect of backlash. The Fourier series expansion was employed to fit the mesh stiffness rather than time-varying mesh stiffness, and the stiffness coefficient was fitted with the same method. The time-varying mesh stiffness was presented in terms of the piecewise function. The single degree of freedom model was employed, and the fourth order Runge–Kutta method was utilized to investigate the effect of backlash on the nonlinear dynamic characteristics with reference to the time history chart, phase diagram, Poincare map, and Fast Fourier Transformation (FFT) spectrogram. The numerical results revealed that the gear system primarily performs a non-harmonic-single-periodic motion. The partially enlarged views indicate that the system also exhibits small-amplitude and low-frequency motion. For different cases of backlash, the low-frequency motion sometimes shows excellent periodicity and stability and sometimes shows chaos. It is of practical guiding significance to know the mechanisms of some unusual noises as well as the design and manufacture of gear backlash. Full article
(This article belongs to the Special Issue Optical High-speed Information Technology)
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Figure 1

Figure 1
<p>The principle of the generating method: (<b>a</b>) involute; (<b>b</b>) transition curve.</p>
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<p>The geometric model of the gear profile.</p>
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<p>The single-tooth-pair mesh stiffness.</p>
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<p>The time-varying mesh stiffness.</p>
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<p><math display="inline"><semantics> <mi>η</mi> </semantics></math> for the different values of backlash.</p>
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<p>The single-tooth-pair mesh stiffness: (<b>a</b>) Comparison of calculated stiffness and fitted stiffness. (<b>b</b>) Relative error curve.</p>
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<p>A snapshot of the contact pattern (at <span class="html-italic">t</span> = 0) of a spur gear pair.</p>
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<p>The non-linear dynamic model.</p>
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<p>The system response in terms of the dynamic transmission error for <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>.</p>
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<p>The system response in terms of the dynamic transmission error of various backlash. (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>1.25</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>1.5</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>c</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>1.75</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>d</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>2</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>e</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>2.25</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>f</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>2.5</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>;(<b>g</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>2.75</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>; (<b>h</b>) <math display="inline"><semantics> <mrow> <mi>b</mi> <mo>=</mo> <mn>3</mn> <msub> <mi>b</mi> <mrow> <mi>m</mi> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math>.</p>
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18 pages, 5645 KiB  
Article
Numerical and Experimental Investigation of Guided Wave Propagation in a Multi-Wire Cable
by Pengfei Zhang, Zhifeng Tang, Fuzai Lv and Keji Yang
Appl. Sci. 2019, 9(5), 1028; https://doi.org/10.3390/app9051028 - 12 Mar 2019
Cited by 16 | Viewed by 5505
Abstract
Ultrasonic guided waves (UGWs) have attracted attention in the nondestructive testing and structural health monitoring (SHM) of multi-wire cables. They offer such advantages as a single measurement, wide coverage of the acoustic field, and long-range propagation ability. However, the mechanical coupling of multi-wire [...] Read more.
Ultrasonic guided waves (UGWs) have attracted attention in the nondestructive testing and structural health monitoring (SHM) of multi-wire cables. They offer such advantages as a single measurement, wide coverage of the acoustic field, and long-range propagation ability. However, the mechanical coupling of multi-wire structures complicates the propagation behaviors of guided waves and signal interpretation. In this paper, UGW propagation in these waveguides is investigated theoretically, numerically, and experimentally from the perspective of dispersion and wave structure, contact acoustic nonlinearity (CAN), and wave energy transfer. Although the performance of all possible propagating wave modes in a multi-wire cable at different frequencies could be obtained by dispersion analysis, it is ineffective to analyze the frequency behaviors of the wave signals of a certain mode, which could be analyzed using the CAN effect. The CAN phenomenon of two mechanically coupled wires in contact was observed, which was demonstrated by numerical guided wave simulation and experiments. Additionally, the measured guided wave energy of wires located in different layers of an aluminum conductor steel-reinforced cable accords with the theoretical prediction. The model of wave energy distribution in different layers of a cable also could be used to optimize the excitation power of transducers and determine the effective monitoring range of SHM. Full article
(This article belongs to the Special Issue Ultrasonic Guided Waves)
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Figure 1

Figure 1
<p>Phase and group velocity dispersion curves for (<b>a</b>) a single 7-mm-diameter steel wire and (<b>b</b>) a single steel and aluminum wire with a diameter of 2.5 mm and 3.2 mm, respectively.</p>
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<p>The vibration displacement distribution of (<b>a</b>) longitudinal, (<b>b</b>) torsional, and (<b>c</b>) flexural waves in a 7-mm-diameter steel wire. Wave structure of the (<b>d</b>) L(0,1) and (<b>e</b>) F(1,1) modes at different frequencies.</p>
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<p>A schematic drawing of contact acoustic nonlinearity (CAN) at the rough contact interface of a pair of coupled cylindrical waveguides.</p>
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<p>A model of the wave energy transfer between two adjacent wires. The results of the active wire are plotted by a red line, and the results of the passive wire are plotted by a blue line. The transient finite element (FE) simulation data of the two wires obtained in <a href="#sec3dot2-applsci-09-01028" class="html-sec">Section 3.2</a>. are marked by asterisks.</p>
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<p>The excitation signal and fast Fourier transform (FFT) spectrum: the triangular pulse with a broadband of 500 kHz in the (<b>a</b>) time domain and (<b>b</b>) frequency domain; the Hann-windowed, five-cycle, 60 kHz sinusoidal tone burst in the (<b>c</b>) time domain signal and (<b>d</b>) frequency domain.</p>
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<p>Guided waves in a single wire were excited using three loading methods: (<b>a</b>) an oblique triangular pulse with three equal components along the <span class="html-italic">x</span>, <span class="html-italic">y</span>, and <span class="html-italic">z</span> directions, (<b>b</b>) a perpendicular triangular pulse along the <span class="html-italic">z</span>-direction, and (<b>c</b>) a perpendicular sinusoidal tone burst along the <span class="html-italic">z</span>-direction.</p>
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<p>The phase velocity dispersion spectra obtained from nodal accelerations with different excitation methods: (<b>a</b>) an oblique triangular pulse signal with three equal components, and (<b>b</b>) a perpendicular triangular pulse signal with a <span class="html-italic">z</span>-axial component. The theoretical phase velocity dispersion curves obtained in <a href="#applsci-09-01028-f001" class="html-fig">Figure 1</a>a are represented by the black dotted lines.</p>
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<p>The phase velocity dispersion spectrum from nodal accelerations with a Hann-windowed, five-cycle, 60 kHz sinusoidal tone burst along the <span class="html-italic">z</span>-direction. The theoretical phase velocity dispersion curve of the L(0,1) mode obtained in <a href="#applsci-09-01028-f001" class="html-fig">Figure 1</a>a is represented by a black dotted line.</p>
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<p>The phase velocity dispersion spectra of two wires from nodal accelerations with an equal components triangular pulse force along the <span class="html-italic">x</span>, <span class="html-italic">y</span>, and <span class="html-italic">z</span> directions: (<b>a</b>) the active wire and (<b>b</b>) the passive wire. The theoretical phase velocity dispersion curves obtained in <a href="#applsci-09-01028-f001" class="html-fig">Figure 1</a>a are represented by the black dotted lines.</p>
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<p>The phase velocity dispersion spectra of wires from nodal accelerations with a Hann-windowed, five-cycle, 60 kHz sinusoidal tone burst along the <span class="html-italic">z</span>-axial direction: (<b>a</b>) the active wire and (<b>b</b>) the passive wire. The theoretical dispersion curve of L(0,1) obtained in <a href="#applsci-09-01028-f001" class="html-fig">Figure 1</a>a is represented by white dotted lines. (<b>c</b>) The FFT spectra of a representative received signal of the active wire and (<b>d</b>) part of the representative acceleration time-domain-received signals in the active wire.</p>
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<p>The experimental setup for guided wave excitation and reception in three types of samples. (<b>a</b>) The schematic of the experiment. Photos of (<b>b</b>) the piezoelectric (PZT) transducer, (<b>c</b>) the single wire experiment case, and (<b>d</b>) the two contact wires.</p>
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<p>The time-frequency analysis spectrum using a continuous wavelet transform (CWT) for a single 7-mm-diameter steel wire at a 60-kHz frequency: (<b>a</b>) horizontal excitation and horizontal reception, (<b>b</b>) horizontal excitation but lateral reception, (<b>c</b>) lateral excitation but horizontal reception, and (<b>d</b>) lateral excitation and lateral reception. The theoretical group velocity dispersion curves obtained in <a href="#applsci-09-01028-f001" class="html-fig">Figure 1</a>a are represented by the dotted line.</p>
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<p>The wave signals and FFT spectrum for the two contact wires with an exciting center frequency of 60 kHz: (<b>a</b>) the time domain signal of the active wire, (<b>b</b>) the FFT spectrum of the active wire, (<b>c</b>) the time domain signal of the passive wire, and (<b>d</b>) the FFT spectrum of the passive wire.</p>
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<p>Guided wave propagation experiments on the aluminum conductor steel-reinforced (ACSR) cable: (<b>a</b>) a photo of the exciting and receiving transducers installation, (<b>b</b>) the received time domain signals of each layer, and (<b>c</b>) the simulated and measured time average wave energy distribution in each layer.</p>
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15 pages, 3752 KiB  
Article
Selection of Optimal Hyperspectral Wavebands for Detection of Discolored, Diseased Rice Seeds
by Insuck Baek, Moon S. Kim, Byoung-Kwan Cho, Changyeun Mo, Jinyoung Y. Barnaby, Anna M. McClung and Mirae Oh
Appl. Sci. 2019, 9(5), 1027; https://doi.org/10.3390/app9051027 - 12 Mar 2019
Cited by 37 | Viewed by 4670
Abstract
The inspection of rice grain that may be infected by seedborne disease is important for ensuring uniform plant stands in production fields as well as preventing proliferation of some seedborne diseases. The goal of this study was to use a hyperspectral imaging (HSI) [...] Read more.
The inspection of rice grain that may be infected by seedborne disease is important for ensuring uniform plant stands in production fields as well as preventing proliferation of some seedborne diseases. The goal of this study was to use a hyperspectral imaging (HSI) technique to find optimal wavelengths and develop a model for detecting discolored, diseased rice seed infected by bacterial panicle blight (Burkholderia glumae), a seedborne pathogen. For this purpose, the HSI data spanning the visible/near-infrared wavelength region between 400 and 1000 nm were collected for 500 sound and discolored rice seeds. For selecting optimal wavelengths to use for detecting diseased seed, a sequential forward selection (SFS) method combined with various spectral pretreatments was employed. To evaluate performance based on optimal wavelengths, support vector machine (SVM) and linear and quadratic discriminant analysis (LDA and QDA) models were developed for detection of discolored seeds. As a result, the violet and red regions of the visible spectrum were selected as key wavelengths reflecting the characteristics of the discolored rice seeds. When using only two or only three selected wavelengths, all of the classification methods achieved high classification accuracies over 90% for both the calibration and validation sample sets. The results of the study showed that only two to three wavelengths are needed to differentiate between discolored, diseased and sound rice, instead of using the entire HSI wavelength regions. This demonstrates the feasibility of developing a low cost multispectral imaging technology based on these selected wavelengths for non-destructive and high-throughput screening of diseased rice seed. Full article
(This article belongs to the Special Issue Applications of Hyperspectral Imaging for Food and Agriculture II)
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<p>Schematic of the hyperspectral imaging system.</p>
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<p>Key procedure steps used for the discrimination of diseased rice seed.</p>
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<p>Mean spectra of diseased and sound (non-diseased) rice seeds and standard deviation bars after preprocessing with the standard normal variate (SNV) method.</p>
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<p>Performance comparison of SFS using the classifiers of (<b>a</b>) linear discriminant analysis (LDA); (<b>b</b>) quadratic discriminant analysis (QDA); (<b>c</b>) support vector machine (SVM) and (<b>d</b>) SVM with radial basis function (RBF) kernel, with different data preprocessing methods for two-class classification.</p>
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<p>The decision boundaries are visualized by using two wavelengths. (<b>a</b>,<b>b</b>) show LDA with range normalization and QDA with range normalization. (<b>c</b>,<b>d</b>) show SVM with raw data and RBF SVM with raw data. (<b>e</b>,<b>f</b>) show RBF SVM with range normalization and QDA with SNV.</p>
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<p>The decision boundaries are visualized in raw data for classification between sound and diseased rice samples by using (<b>a</b>) SVM and (<b>b</b>) RBF SVM classification methods with three features.</p>
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<p>Visualization of classification image with smoothing pretreatment by using (<b>a</b>) two and (<b>b</b>) three wavelengths.</p>
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23 pages, 636 KiB  
Review
A Systematic Review of Oxygen Therapy for the Management of Medication-Related Osteonecrosis of the Jaw (MRONJ)
by Roberto Sacco, Racheal Leeson, Joseph Nissan, Sergio Olate, Carlos Henrique Bettoni Cruz de Castro, Alessandro Acocella and Anand Lalli
Appl. Sci. 2019, 9(5), 1026; https://doi.org/10.3390/app9051026 - 12 Mar 2019
Cited by 8 | Viewed by 4562
Abstract
Background: Medication-related osteonecrosis of the jaw (MRONJ) can be a life changing iatrogenic complication of antiresorptive and antiangiogenic drug therapy. It is most often associated with high doses of these medications that are used to prevent skeletal-related events in patients with cancer and [...] Read more.
Background: Medication-related osteonecrosis of the jaw (MRONJ) can be a life changing iatrogenic complication of antiresorptive and antiangiogenic drug therapy. It is most often associated with high doses of these medications that are used to prevent skeletal-related events in patients with cancer and bone pathologies. Unfortunately, managing MRONJ lesions has proven difficult and remains a major challenge for clinicians. Due to the lack of efficacy in treating MRONJ by surgical modalities (local debridement and free flap reconstruction), the nonsurgical management of MRONJ is still advocated to aid healing or avoid disease progression. The aim of this systematic review is to identify, analyse and understand the published evidence related to the success of oxygen therapies such as ozone (OT) and hyperbaric oxygen (HBO) in treating MRONJ. Material and methods: A multi-database (PubMed, MEDLINE, EMBASE, CINAHL and Cochrane CENTRAL) systematic search was performed by three authors. The identified articles were independently assessed for their risk of bias. Any type of study evaluating humans treated with antiresorptive and antiangiogenic drugs were considered. The aim is primarily to evaluate the success of OT and HBO in resolving MRONJ and secondarily to identify any improvements in quality of life (QoL), rate of complications, time-to-event and severity of side effects related to these treatments. Results: In total, just 13 studies were eligible for analysis. A pooled total of 313 patients (HBO group n = 82; OT group n = 231) described in these studies have shown good tolerance for oxygen therapies. Complete resolution of MRONJ was reported in 44.58% of OT patients but only 5.17% of the HBO group. Progression of MRONJ was reported only in the HBO studies in 10.34% of cases (6 patients). The quality of evidence was low or very low in all studies. This was due to limitations in how the studies were designed, run and reported. Conclusions: Based on the limited data available, it is difficult to suggest OT is better or worse than HBO or whether it is better than a placebo. As the level of evidence available is low, this necessitates larger well-designed trials to justify these interventions for patients affected by MRONJ. Full article
(This article belongs to the Section Applied Biosciences and Bioengineering)
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<p>Study flow diagram.</p>
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15 pages, 684 KiB  
Article
A Multi-Period Approach for the Optimal Energy Retrofit Planning of Street Lighting Systems
by Raffaele Carli, Mariagrazia Dotoli and Roberta Pellegrino
Appl. Sci. 2019, 9(5), 1025; https://doi.org/10.3390/app9051025 - 12 Mar 2019
Cited by 11 | Viewed by 3170
Abstract
Investing in the optimal measures for improving the energy efficiency of urban street lighting systems has become strategic for the economic, technological and social development of cities. The decision-making process for the selection of the optimal set of interventions is not so straightforward. [...] Read more.
Investing in the optimal measures for improving the energy efficiency of urban street lighting systems has become strategic for the economic, technological and social development of cities. The decision-making process for the selection of the optimal set of interventions is not so straightforward. Several criticalities-such as difficulties getting access to credit for companies involved in street lighting systems refurbishment, budget constraints of municipalities, and unawareness of the actual energy and economic performance after a retrofitting intervention-require a decision-making approach that supports the city energy manager in selecting the optimal street lighting energy efficiency retrofitting solution while looking not only based on the available budget, but also based on the future savings in energy expenditures. In this context, the purpose of our research is to develop an effective decision-making model supporting the optimal multi-period planning of the street lighting energy efficiency retrofitting, which proves to be more effective and beneficial than the classical single-period approach and has never before been applied to the considered public lighting system context. The proposed methodology is applied to a real street lighting system in the city of Bari, Italy, showing the energy savings and financial benefit obtained through the proposed method. Numerical experiments are used to investigate and quantify the effects of using a multi-period planning approach instead of a single-period approach. Full article
(This article belongs to the Special Issue Smart Urban Lighting Systems)
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<p>The cumulative energy savings over time intervals achieved by single- (<b>a</b>) and multi-period (<b>b</b>) retrofit planning for an initial investment budget <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 30,000.00.</p>
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<p>The cumulative energy savings over time intervals achieved by single- and multi-period retrofit planning for different initial investment budgets: (<b>a</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 10,000.00, (<b>b</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 30,000.00, and (<b>c</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 50,000.00.</p>
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<p>The NPVs over time intervals achieved by single- and multi-period retrofit planning for different initial investment budgets: (<b>a</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 10,000.00, (<b>b</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 30,000.00, and (<b>c</b>) <math display="inline"><semantics> <mi>b</mi> </semantics></math> = € 50,000.00.</p>
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14 pages, 2431 KiB  
Article
The Influence of Capacitance and Inductance Changes on Frequency Response of Transformer Windings
by Szymon Banaszak, Konstanty M. Gawrylczyk, Katarzyna Trela and Patryk Bohatyrewicz
Appl. Sci. 2019, 9(5), 1024; https://doi.org/10.3390/app9051024 - 12 Mar 2019
Cited by 8 | Viewed by 3509
Abstract
Frequency Response Analysis (FRA) is a test method used for assessment of mechanical condition of transformer active parts. Its biggest problem is the interpretation of test results, namely the relationship between scale of differences between compared curves and the decision for further operation [...] Read more.
Frequency Response Analysis (FRA) is a test method used for assessment of mechanical condition of transformer active parts. Its biggest problem is the interpretation of test results, namely the relationship between scale of differences between compared curves and the decision for further operation of the given transformer. Very often visible differences between two FRA curves do not mean that there is a deformation in the winding. The cause of the curve shift may come from other elements of the transformer that influence inductive or capacitive parameters. This paper takes under consideration the influence of both capacitance and inductance changes on transformer frequency response (FR). The analysis is performed with the computer model of a transformer and also some experimental results are presented, showing the influence of capacitance and inductance changes on the FR of real transformers. The results of research showed that this influence may lead to misleading effects on the shape of FR characteristics. The paper presents an analysis that can be used in the assessment of FRA measurement, especially in the case of uncertain data comparison results. Full article
(This article belongs to the Special Issue Power System Reliability)
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<p>End-to-end open test setup configuration on the example of a Dyn transformer: (<b>a</b>) delta winding, (<b>b</b>) star winding.</p>
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<p>Example of frequency response amplitude curves of a three-phase transformer, measured in end-to-end open test setup, presented in a logarithmic scale. Three frequency ranges are marked.</p>
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<p>2D FEM model of 450 turn LV winding.</p>
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<p>Network used for calculations of FRA characteristics. The circuit in the bottom relates to the bushing.</p>
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<p>Complex permeability of the core material (<span class="html-italic">μ</span><sub>r</sub> = 560, <span class="html-italic">γ</span> = 2·10<sup>6</sup> S/m, 2<span class="html-italic">D</span> = 0.23 mm) as a function of frequency.</p>
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<p>FR modeling for the three positions of the tap changer (405, 450, and 495 turns).</p>
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<p>FR modeling for two positions of the tap changer for 405 and 450 turns, and for 405 turns with bushing capacitance change.</p>
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<p>FR modeling for two positions of the tap changer for 405 and 495 turns, and for 495 turns with bushing capacitance change.</p>
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<p>FR of HV phase A of a 250 MVA, 400/110/30 kV autotransformer with additional capacitances installed on HV phase B.</p>
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<p>FR of LV phase a of 250 MVA, 400/110/30 kV autotransformer with additional capacitances installed on HV phase B.</p>
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<p>FR of phase A of 160 MVA, 220/110/15 kV autotransformer for three positions of OLTC.</p>
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<p>FR of phase A of 31.5 MVA, 110/30 kV transformer for three positions of OLTC.</p>
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<p>FR of distribution transformer with different core magnetization.</p>
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13 pages, 1972 KiB  
Article
Rheological Characteristics Evaluation of Bitumen Composites Containing Rock Asphalt and Diatomite
by Wentong Huang, Duanyi Wang, Peiyong He, Xiang Long, Bing Tong, Jun Tian and Peng Yu
Appl. Sci. 2019, 9(5), 1023; https://doi.org/10.3390/app9051023 - 12 Mar 2019
Cited by 25 | Viewed by 3450
Abstract
Previous studies have showed that rock asphalt (RA) or diatomite were used to modify the petroleum bitumen. This paper presents the findings from a study conducted to evaluate the potential impact of RA and diatomite on the rheological characteristics of bitumen composites. RA [...] Read more.
Previous studies have showed that rock asphalt (RA) or diatomite were used to modify the petroleum bitumen. This paper presents the findings from a study conducted to evaluate the potential impact of RA and diatomite on the rheological characteristics of bitumen composites. RA and diatomite with three different dosages were added into the petroleum bitumen: 18% RA, 13% RA+7% diatomite, and 16% RA+9% diatomite by weight. The rheological characteristics of the RA and diatomite modified bitumens were evaluated in this study. The tests conducted included temperature sweep and frequency sweep tests with a dynamic shear rheometer (DSR), a Brookfield rotation viscosity test, and a scanning electron microscope test. The research showed that the addition of RA and diatomite to petroleum bitumen considerably increased the apparent viscosity, dynamic shear modulus, and rutting resistance in bitumen specimens. However, the DSR test indicated a slight reduction in the fatigue performance of composites made of RA and diatomite modified bitumens. Overall, RA and diatomite are good modifiers for petroleum bitumen for a performance improvement. Full article
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<p>A SEM image of rock asphalt (RA).</p>
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<p>A SEM image of diatomite.</p>
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<p>The temperature sweep results: (<b>a</b>) dynamic shear modulus; (<b>b</b>) rutting index; (<b>c</b>) phase angle; (<b>d</b>) loss tangent; and (<b>e</b>) fatigue index.</p>
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<p>The frequency sweep results: (<b>a</b>) dynamic shear modulus; (<b>b</b>) rutting index; (<b>c</b>) phase angle; (<b>d</b>) loss tangent; and (<b>e</b>) fatigue index.</p>
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<p>The frequency sweep results: (<b>a</b>) dynamic shear modulus; (<b>b</b>) rutting index; (<b>c</b>) phase angle; (<b>d</b>) loss tangent; and (<b>e</b>) fatigue index.</p>
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<p>The BBR test results: (<b>a</b>) creep stiffness and (<b>b</b>) m-value.</p>
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22 pages, 4001 KiB  
Article
Optimal Design of Hybrid PV-Battery System in Residential Buildings: End-User Economics, and PV Penetration
by Imane Worighi, Thomas Geury, Mohamed El Baghdadi, Joeri Van Mierlo, Omar Hegazy and Abdelilah Maach
Appl. Sci. 2019, 9(5), 1022; https://doi.org/10.3390/app9051022 - 12 Mar 2019
Cited by 23 | Viewed by 4456
Abstract
This paper proposes an optimal design for hybrid grid-connected Photovoltaic (PV) Battery Energy Storage Systems (BESSs). A smart grid consisting of PV generation units, stationary Energy Storage Systems (ESSs), and domestic loads develops a multi-objective optimization algorithm. The optimization aims at minimizing the [...] Read more.
This paper proposes an optimal design for hybrid grid-connected Photovoltaic (PV) Battery Energy Storage Systems (BESSs). A smart grid consisting of PV generation units, stationary Energy Storage Systems (ESSs), and domestic loads develops a multi-objective optimization algorithm. The optimization aims at minimizing the Total Cost of Ownership (TCO) and the Voltage Deviation (VD) while considering the direct and indirect costs for the prosumer, and the system stability with regard to intermittent PV generation. The optimal solution for the optimization of the PV-battery system sizing with regard to economic viability and the stability of operation is found while using the Genetic Algorithm (GA) with the Pareto front. In addition, a fuzzy logic-based controller is developed to schedule the charging and discharging of batteries while considering the technical and economic aspects, such as battery State of Charge (SoC), voltage profile, and on/off-peak times to shave the consumption peaks. Thus, a hybrid approach that combines a Fuzzy Logic Controller (FLC) and the GA is developed for the optimal sizing of the combined Renewable Energy Sources (RESs) and ESSs, resulting in reductions of approximately 4% and 17% for the TCO and the VD, respectively. Furthermore, a sensitivity cost-effectiveness analysis of the complete system is conducted to highlight and assess the profitability and the high dependency of the optimal system configuration on battery prices. Full article
(This article belongs to the Special Issue Intelligent Energy Management of Electrical Power Systems)
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<p>Grid structure.</p>
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<p>Time sequence characteristic curve of the total load.</p>
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<p>Hourly solar radiation throughout the year received on a horizontal surface in Brussels, Belgium.</p>
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<p>Flow chart of battery-Photovoltaic Genetic Algorithm (PV GA) optimization.</p>
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<p>Flow chart of the implemented controller and GA.</p>
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<p>Input membership function State of Charge (SoC).</p>
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<p>Input membership function Voltage.</p>
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<p>Input membership function On/Off peak hours.</p>
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<p>Output membership function Charge and Discharge rate.</p>
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<p>Fuzzy Logical Controller structure.</p>
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<p>Fuzzy Logical Controller rules.</p>
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<p>Voltage deviation before and after implementation of the optimally sized Distributed Generator (DG) and battery.</p>
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<p>Voltage profile of the load.</p>
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<p>Simulation and optimization results.</p>
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<p>Evaluation of Total Cost of Ownership (TCO) over Number of Evaluation Function (NFE) in optimization process.</p>
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<p>Total yearly cost with/without PV-battery system.</p>
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13 pages, 2088 KiB  
Article
Analysis of Life Cycle Environmental Impact of Recycled Aggregate
by Won-Jun Park, Taehyoung Kim, Seungjun Roh and Rakhyun Kim
Appl. Sci. 2019, 9(5), 1021; https://doi.org/10.3390/app9051021 - 12 Mar 2019
Cited by 43 | Viewed by 6220
Abstract
This study assessed the influence of matter discharged during the production (dry/wet) of recycled aggregate on global warming potential (GWP) and acidification potential (AP), eutrophication potential (EP), ozone depletion potential (ODP), biotic resource depletion potential (ADP), photochemical ozone creation potential (POCP) using the [...] Read more.
This study assessed the influence of matter discharged during the production (dry/wet) of recycled aggregate on global warming potential (GWP) and acidification potential (AP), eutrophication potential (EP), ozone depletion potential (ODP), biotic resource depletion potential (ADP), photochemical ozone creation potential (POCP) using the ISO 14044 (LCA) standard. The LCIA of dry recycled aggregate was 2.94 × 10−2 kg-CO2eq/kg, 2.93 × 10−5 kg-SO2eq/kg, 5.44 × 10−6 kg-PO43eq/kg, 4.70 × 10−10 kg-CFC11eq/kg, 1.25 × 10−5 kg-C2H4eq/kg, and 1.60 × 10−5 kg-Antimonyeq/kg, respectively. The environmental impact of recycled aggregate (wet) was up to 16~40% higher compared with recycled aggregate (dry); the amount of energy used by impact crushers while producing wet recycled aggregate was the main cause for this result. The environmental impact of using recycled aggregate was found to be up to twice as high as that of using natural aggregate, largely due to the greater simplicity of production of natural aggregate requiring less energy. However, ADP was approximately 20 times higher in the use of natural aggregate because doing so depletes natural resources, whereas recycled aggregate is recycled from existing construction waste. Among the life cycle impacts assessment of recycled aggregate, GWP was lower than for artificial light-weight aggregate but greater than for slag aggregate. Full article
(This article belongs to the Special Issue New Trends in Recycled Aggregate Concrete)
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<p>Dry production method.</p>
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<p>Wet production method process.</p>
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<p>Environmental impact comparison by aggregate. (<b>a</b>) GWP: Global Warming Potential; (<b>b</b>) POCP: Photochemical Ozone Creation Potential; (<b>c</b>) AP: Acidification Potential; (<b>d</b>) EP: Eutrophication Potential; (<b>e</b>) ODP: Ozone Depletion Potential; (<b>f</b>) ADP: Abiotic Depletion Potential</p>
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<p>Environmental impact comparison by aggregate. (<b>a</b>) GWP: Global Warming Potential; (<b>b</b>) POCP: Photochemical Ozone Creation Potential; (<b>c</b>) AP: Acidification Potential; (<b>d</b>) EP: Eutrophication Potential; (<b>e</b>) ODP: Ozone Depletion Potential; (<b>f</b>) ADP: Abiotic Depletion Potential</p>
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<p>Comparison of environmental impact by recycled aggregate mixing ratio. (<b>a</b>) GWP: Global Warming Potential; (<b>b</b>) ADP: Abiotic Depletion Potential</p>
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11 pages, 1919 KiB  
Article
Large-Scale Whale-Call Classification by Transfer Learning on Multi-Scale Waveforms and Time-Frequency Features
by Lilun Zhang, Dezhi Wang, Changchun Bao, Yongxian Wang and Kele Xu
Appl. Sci. 2019, 9(5), 1020; https://doi.org/10.3390/app9051020 - 12 Mar 2019
Cited by 19 | Viewed by 4121
Abstract
Whale vocal calls contain valuable information and abundant characteristics that are important for classification of whale sub-populations and related biological research. In this study, an effective data-driven approach based on pre-trained Convolutional Neural Networks (CNN) using multi-scale waveforms and time-frequency feature representations is [...] Read more.
Whale vocal calls contain valuable information and abundant characteristics that are important for classification of whale sub-populations and related biological research. In this study, an effective data-driven approach based on pre-trained Convolutional Neural Networks (CNN) using multi-scale waveforms and time-frequency feature representations is developed in order to perform the classification of whale calls from a large open-source dataset recorded by sensors carried by whales. Specifically, the classification is carried out through a transfer learning approach by using pre-trained state-of-the-art CNN models in the field of computer vision. 1D raw waveforms and 2D log-mel features of the whale-call data are respectively used as the input of CNN models. For raw waveform input, windows are applied to capture multiple sketches of a whale-call clip at different time scales and stack the features from different sketches for classification. When using the log-mel features, the delta and delta-delta features are also calculated to produce a 3-channel feature representation for analysis. In the training, a 4-fold cross-validation technique is employed to reduce the overfitting effect, while the Mix-up technique is also applied to implement data augmentation in order to further improve the system performance. The results show that the proposed method can improve the accuracies by more than 20% in percentage for the classification into 16 whale pods compared with the baseline method using groups of 2D shape descriptors of spectrograms and the Fisher discriminant scores on the same dataset. Moreover, it is shown that classifications based on log-mel features have higher accuracies than those based directly on raw waveforms. The phylogeny graph is also produced to significantly illustrate the relationships among the whale sub-populations. Full article
(This article belongs to the Section Acoustics and Vibrations)
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<p>Illustration of the proposed architecture.</p>
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<p>The evolution of accuracies and losses in the training based on the ResN-logm and ResN-wav models (color online).</p>
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<p>The similarity matrix based on the Softmax ‘likelihood’ vectors (color online).</p>
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<p>The phylogeny created for whale sub-populations.</p>
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17 pages, 3310 KiB  
Review
The Growth Methods and Field Emission Studies of Low-Dimensional Boron-Based Nanostructures
by Haibo Gan, Tong Zhang, Zekun Guo, Haojian Lin, Zijuan Li, Huanjun Chen, Jun Chen and Fei Liu
Appl. Sci. 2019, 9(5), 1019; https://doi.org/10.3390/app9051019 - 12 Mar 2019
Cited by 10 | Viewed by 3462
Abstract
Based on the morphology characteristics, low-dimensional (LD) nanostructures with high aspect ratio can be usually divided into nanowire, nanocone, nanotube, nanorod, nanoribbon, nanobelt and so on. Among numerous LD nanostructures, boron-based nanostructures attracted much interest in recent years because they have high melting-point, [...] Read more.
Based on the morphology characteristics, low-dimensional (LD) nanostructures with high aspect ratio can be usually divided into nanowire, nanocone, nanotube, nanorod, nanoribbon, nanobelt and so on. Among numerous LD nanostructures, boron-based nanostructures attracted much interest in recent years because they have high melting-point, large electric and thermal conductivity, and low work function. Compared to traditional thermal emission, field emission (FE) has notable advantages, such as lower power dissipation, longer working life, room-temperature operation, higher brightness and faster switching speed. Most studies reveal they have lower turn-on and threshold fields as well as high current density, which are believed as ideal cold cathode nanomaterials. In this review, we will firstly introduce the growth methods of LD boron-based nanostructures (boron monoelement and rare-earth metal hexaboride). Then, we will discuss their FE properties and applications. At last, the conclusions and outlook will be summarized based on the above studies. Full article
(This article belongs to the Special Issue Field Emission from Graphene and other Nanostructures)
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<p>Schematic diagram of a typical CVD system.</p>
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<p>Typical morphologies of boron NWs (<b>a</b>) [<a href="#B80-applsci-09-01019" class="html-bibr">80</a>] (Copyright 2014 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim), boron NTs (<b>b</b>) [<a href="#B24-applsci-09-01019" class="html-bibr">24</a>] (Copyright 2010 The Royal Society of Chemistry), LaB<sub>6</sub> NWs (<b>c</b>) [<a href="#B32-applsci-09-01019" class="html-bibr">32</a>] (Copyright 2013 Nature Publishing Group), NdB<sub>6</sub>, SmB<sub>6</sub> and CeB<sub>6</sub> NWs (<b>d</b>,<b>f</b>) [<a href="#B51-applsci-09-01019" class="html-bibr">51</a>] (Copyright 2011 American Chemical Society).</p>
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<p>(<b>a</b>) Typical SEM images of boron NBs grown by laser ablation [<a href="#B55-applsci-09-01019" class="html-bibr">55</a>]. Copyright 2002 Elsevier Science B.V. (<b>b</b>,<b>c</b>) Representative SEM images of boron NWs grown by magnetron sputtering way [<a href="#B61-applsci-09-01019" class="html-bibr">61</a>]. Copyright 2002 American Institute of Physics. (<b>d</b>) SmB<sub>6</sub> NWs fabricated by novel solid-state reaction method [<a href="#B64-applsci-09-01019" class="html-bibr">64</a>]. Copyright 2016. The Royal Society of Chemistry. (<b>e</b>) LaB<sub>6</sub> FE arrays by etching single crystal [<a href="#B34-applsci-09-01019" class="html-bibr">34</a>]. Copyright 2009 IOP Publishing Ltd. (<b>f</b>) LaB<sub>6</sub> FE microtriodes by micro-fabrication technology [<a href="#B33-applsci-09-01019" class="html-bibr">33</a>]. Copyright 2009 SPIE.</p>
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<p>(<b>a</b>) Typical SEM image during in-situ microprobe measurements of individual nanostructure [<a href="#B28-applsci-09-01019" class="html-bibr">28</a>]. Copyright 2017 The Royal Society of Chemistry. (<b>b</b>) I-E curves of a single boron NW [<a href="#B23-applsci-09-01019" class="html-bibr">23</a>]. Copyright 2008 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim. (<b>c</b>) I-E curves of a single boron NT [<a href="#B24-applsci-09-01019" class="html-bibr">24</a>]. Copyright 2010 The Royal Society of Chemistry. (<b>d</b>) FE properties of individual LaB<sub>6</sub> NW [<a href="#B28-applsci-09-01019" class="html-bibr">28</a>]. Copyright 2017 The Royal Society of Chemistry.</p>
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<p>(<b>a</b>,<b>b</b>) FIM patterns obtained from the clean surface of the &lt;001&gt; and &lt;012&gt; oriented LaB<sub>6</sub> NWs, respectively [<a href="#B40-applsci-09-01019" class="html-bibr">40</a>]. Copyright 2010 American Chemical Society.</p>
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<p>(<b>a</b>) FE curves of boron nanocones (NCs) [<a href="#B30-applsci-09-01019" class="html-bibr">30</a>]. Copyright 2011 Chinese Physical Society and IOP Publishing Ltd. (<b>b</b>) FE curves of CeB<sub>6</sub> NWs [<a href="#B36-applsci-09-01019" class="html-bibr">36</a>]. Copyright 2010 The Chinese Society of Rare Earths. Published by Elsevier B.V. (<b>c</b>) FE curves of SmB<sub>6</sub> nanostructures [<a href="#B39-applsci-09-01019" class="html-bibr">39</a>]. Copyright 2017 Chinese Physical Society and IOP Publishing Ltd. (<b>d</b>) FE curves of LaB<sub>6</sub> FE microtriode [<a href="#B33-applsci-09-01019" class="html-bibr">33</a>]. Copyright 2009 SPIE. (<b>d</b>) FE and FE stability curves of LaB<sub>6</sub> NWs [<a href="#B28-applsci-09-01019" class="html-bibr">28</a>]. Copyright 2017 The Royal Society of Chemistry.</p>
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<p>(<b>a</b>,<b>b</b>) Temperature-dependent FE curves of the PrB<sub>6</sub> NWs by Y. M. Zhao et al. [<a href="#B37-applsci-09-01019" class="html-bibr">37</a>]. Copyright 2009 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim. (<b>c</b>,<b>d</b>) Temperature-dependent FE curves of the LaB<sub>6</sub> NWs from J. Q. Xu et al. [<a href="#B32-applsci-09-01019" class="html-bibr">32</a>]. Copyright 2013 Nature Publishing Group. (<b>e</b>,<b>f</b>) Temperature-dependent FE curves of the LaB<sub>6</sub> NWs from F. Liu et al. [<a href="#B28-applsci-09-01019" class="html-bibr">28</a>]. Copyright 2017 The Royal Society of Chemistry.</p>
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<p>Individual LaB<sub>6</sub> NW as a FE electron gun in a modified SEM system [<a href="#B97-applsci-09-01019" class="html-bibr">97</a>]. Copyright 2015 Springer Nature. (<b>a</b>–<b>c</b>) Schematic diagram, SEM picture and FE images of a single LaB<sub>6</sub> NW fixed on the top of W needle. (<b>d</b>) Typical 100,000 times magnification image captured by SEM with individual LaB<sub>6</sub> NW cathode at 5.0 kV extraction voltage. (<b>e</b>) EDS mapping result. The inset is the spectrum of the mapping area. (<b>f</b>) The dependence of normalized angular current density on extraction voltage. The corresponding FN plots are shown in the inset. (<b>g</b>) Electron energy distribution from a LaB<sub>6</sub> NW and a W(310) tip.</p>
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11 pages, 2479 KiB  
Article
Influence of Initial Phase Modulation on the Sensitivity of the Optical Fiber Sagnac Acoustic Emission Sensor
by Zhuming Cheng, Jie Zeng, Dakai Liang, Chen Chang and Bing Wang
Appl. Sci. 2019, 9(5), 1018; https://doi.org/10.3390/app9051018 - 12 Mar 2019
Cited by 4 | Viewed by 3032
Abstract
Improving the phase sensitivity of the optical fiber Sagnac sensor is very important for accurately detecting weak signals of acoustic emission. Theoretical analysis shows that the initial phase of the sensor is π under ideal conditions, and the maximum phase sensitivity is obtained [...] Read more.
Improving the phase sensitivity of the optical fiber Sagnac sensor is very important for accurately detecting weak signals of acoustic emission. Theoretical analysis shows that the initial phase of the sensor is π under ideal conditions, and the maximum phase sensitivity is obtained when the bias phase is π/2. In this work, an experimental system was built with an aluminum alloy plate as the experimental object. The initial phase of the sensor was modulated by a Y-branch waveguide, and the fitting curve of the experimental data was in good agreement with the curve of the numerical simulation. Moreover, our experiments show there was a single value for the bias phase of π/2, which significantly deviated from the theoretical value. The results show that the greatest phase sensitivity of the sensor not only could be increased by nearly nine times through modulating the initial phase, but also could suppress the harmonic interferences in the sensing system. This study can provide a useful reference for improving the phase sensitivity of the optical fiber Sagnac AE sensor in practical applications. Full article
(This article belongs to the Special Issue Recent Progress in Fiber Optic Sensors: Bringing Light to Measurement)
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<p>Principle of the optical fiber Sagnac acoustic emission (AE) sensor.</p>
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<p>Ooutput voltage signal without phase modulation in the numerical simulation. (<b>a</b>) Output voltage waveform; (<b>b</b>) corresponding frequency spectrum.</p>
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<p>Output voltage with a phase modulation of <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ϕ</mi> <mo>=</mo> <mi mathvariant="sans-serif">π</mi> <mo>/</mo> <mn>2</mn> </mrow> </semantics></math> in the numerical simulation. (<b>a</b>) Output voltage waveform; (<b>b</b>) corresponding frequency spectrum.</p>
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<p>Relationship between the amplitude of the output fundamental voltage and <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ϕ</mi> </mrow> </semantics></math>. The red scatter points represent the simulative values, and the blue curve is the corresponding fitting curve.</p>
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<p>Experimental system of the optical fiber Sagnac AE sensor.</p>
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<p>Output voltage of the sensor without phase modulation in the experiments. (<b>a</b>) Output voltage waveform; (<b>b</b>) Corresponding frequency spectrum.</p>
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<p>Output voltage of the sensor with a phase modulation of <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ϕ</mi> <mo>=</mo> <mi mathvariant="sans-serif">π</mi> <mo>/</mo> <mn>2</mn> </mrow> </semantics></math> in the experiments. (<b>a</b>) Output voltage waveform; (<b>b</b>) Corresponding frequency spectrum.</p>
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<p>Result of experimental fitting. The horizontal axis represents the amplitude of the modulation voltage, and the longitudinal axis represents the amplitude of the fundamental voltage.</p>
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22 pages, 5929 KiB  
Article
Cracking Behavior of RC Beams Strengthened with Different Amounts and Layouts of CFRP
by Muhammad Umair Saleem, Hisham Jahangir Qureshi, Muhammad Nasir Amin, Kaffayatullah Khan and Hassan Khurshid
Appl. Sci. 2019, 9(5), 1017; https://doi.org/10.3390/app9051017 - 12 Mar 2019
Cited by 17 | Viewed by 4901
Abstract
The bending and shear behavior of RC beams strengthened with Carbon Fiber-Reinforced Polymers (CFRP) is the primary objective of this paper, which is focused on the failure mechanisms and on the moment-curvature response prior-to, and post, strengthening with different amounts and layouts of [...] Read more.
The bending and shear behavior of RC beams strengthened with Carbon Fiber-Reinforced Polymers (CFRP) is the primary objective of this paper, which is focused on the failure mechanisms and on the moment-curvature response prior-to, and post, strengthening with different amounts and layouts of the CFRP reinforcement. Seven reinforced concrete beams were tested in 4-point bending, one without any CFRP reinforcement (control beam, Specimen C1), four with the same amount of CFRP in flexure but with different layouts of the reinforcement for shear (Specimens B1–B4), and two with extra reinforcement in bending, with and without reinforcement in shear (Specimens B6 and B5, respectively). During each test, the load and the mid-span deflection were monitored, as well as the crack pattern. The experimental results indicate that: (a) increasing the CFRP reinforcement above certain levels does not necessarily increase the bearing capacity; (b) the structural performance can be optimized through an appropriate combination of CFRP flexural and shear reinforcement; and (c) bond properties at the concrete–CFRP interface play a vital role, as the failure is very often triggered by the debonding of the CFRP strips. The experimental values were also verified analytically and a close agreement between the analytical and experimental values was achieved. Full article
(This article belongs to the Special Issue Fatigue and Fracture of Non-metallic Materials and Structures)
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<p>Details of beam specimens (<b>a</b>) Control specimen, (<b>b</b>) CFRP-B1, (<b>c</b>) CFRP-B2, (<b>d</b>) CFRP-B3, (<b>e</b>) CFRP-B4, (<b>f</b>) CFRP-B5, and (<b>g</b>) CFRP-B6.</p>
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<p>Lateral views of the beams strengthened with CFRP layers and strips.</p>
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<p>Test setup (<b>a</b>) and test layout for Beam CFRP-B1 (<b>b</b>).</p>
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<p>Moment-curvature relation for control specimen C1, CFRP-B1, CFRP-B2, CFRP-B3, and CFRP-B4.</p>
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<p>Moment-curvature relation for control specimen C1, CFRP-B5, and CFRP-B6.</p>
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<p>Moment-curvature relation for control specimen C1, CFRP-B3, and CFRP-B5.</p>
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<p>Stain, stress, and force distribution diagram of CFRP strengthened RC beam.</p>
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<p>Dimensional variables used in shear-strengthening calculations.</p>
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<p>Failure pattern of control specimen C1 at different load levels.</p>
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<p>Failure pattern of control specimen C1 at different load levels.</p>
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<p>Failure Pattern of CFRP-B1 at different load levels.</p>
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<p>Failure pattern of CFRP-B2 at different load levels.</p>
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<p>Failure pattern of CFRP-B3 at different load levels.</p>
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<p>Failure pattern of CFRP-B4 at different load levels.</p>
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<p>Failure pattern of CFRP-B4 at different load levels.</p>
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<p>Failure pattern of CFRP-B5 at different load levels.</p>
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<p>Failure pattern of CFRP-B5 at different load levels.</p>
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<p>Failure pattern of CFRP-B6 at different load levels.</p>
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<p>Failure pattern of CFRP-B6 at different load levels.</p>
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11 pages, 2198 KiB  
Article
Cut-Price Fabrication of Free-standing Porous Carbon Nanofibers Film Electrode for Lithium-ion Batteries
by Pengfei Zhao, Wei Li, Shiqing Fang, Ji Yu, Zhenyu Yang and Jianxin Cai
Appl. Sci. 2019, 9(5), 1016; https://doi.org/10.3390/app9051016 - 12 Mar 2019
Cited by 3 | Viewed by 3632
Abstract
Freestanding thin film electrodes are competitive candidate materials for high-performance energy stockpile equipment due to their self-supporting structure and because they lack any polymer binder or conductive additive. In our work, a porous carbon nanofiber film (PCNF) electrode has been synthesized via a [...] Read more.
Freestanding thin film electrodes are competitive candidate materials for high-performance energy stockpile equipment due to their self-supporting structure and because they lack any polymer binder or conductive additive. In our work, a porous carbon nanofiber film (PCNF) electrode has been synthesized via a convenient and low-cost electrospinning approach and the following carbonization and air etching process. The obtained PCNF electrode sample shows a high reversible capacity (1138 mAh g−1 at 0.1 C), remarkable rate capacity (101.2 mAh g−1 at 15 C), and superior cycling stability with a lower capacity decay rate of ~0.013% each cycle upon 1000 cycles (278 mAh g−1 at 5 C). The prominent electrochemical performance of PCNF can be put down to the stable self-supporting conductive structure and the porous feature in each carbon nanofiber, which will significantly promote the transfer tempo of Li-ion and electron and relieve the large volume change during inserting lithium ion. More interestingly, this work exhibits a low-cost and primitive strategy to fabricate thin film anode for lithium-ion batteries. Full article
(This article belongs to the Section Nanotechnology and Applied Nanosciences)
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<p>(<b>a</b>) Diagrammatization of synthesis process of the polyporous carbon nanofibers films; (<b>b</b>) Photographic images of the PVP fiber, pretreated PVP fiber, CNF and PCNF.</p>
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<p>The XRD and Raman images of CNF (black) and PCNF (red) samples: (<b>a</b>) XRD pattern; (<b>b</b>) Raman pattern.</p>
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<p>SEM and TEM measurements (images) of PVP, CNF and PCNF nanofibers: (<b>a</b>,<b>d</b>,<b>g</b>) PVP nanofibers; (<b>b</b>,<b>e</b>,<b>h</b>) CNF nanofibers; (<b>c</b>,<b>f</b>,<b>i</b>) PCNF nanofibers.</p>
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<p>(<b>a</b>) N<sub>2</sub> adsorption-desorption isotherms of the CNF; (<b>b</b>) pore diameter distribution of the CNF; (<b>c</b>) N<sub>2</sub> adsorption-desorption isotherms of the PCNF; (<b>d</b>) pore diameter distributions of the PCNF.</p>
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<p>Electrochemical measurements of CNF and PCNF samples. (<b>a</b>) First discharge-charge images at 0.1 C; (<b>b</b>) rate capability; (<b>c</b>) Long cycling capability at 5 C; (<b>d</b>) electrochemical impedance spectra.</p>
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16 pages, 3462 KiB  
Article
Study on Low-Speed Steering Resistance Torque of Vehicles Considering Friction between Tire and Pavement
by Dong Cao, Bin Tang, Haobin Jiang, Chenhui Yin, Di Zhang and Yingqiu Huang
Appl. Sci. 2019, 9(5), 1015; https://doi.org/10.3390/app9051015 - 12 Mar 2019
Cited by 12 | Viewed by 6966
Abstract
Electric power steering (EPS) systems under existing vehicle power systems cannot provide enough power for heavy-duty commercial vehicles under pivot or low-speed steering conditions. To solve this problem, the paper proposes an EPS system that is based on the hybrid power system constituted [...] Read more.
Electric power steering (EPS) systems under existing vehicle power systems cannot provide enough power for heavy-duty commercial vehicles under pivot or low-speed steering conditions. To solve this problem, the paper proposes an EPS system that is based on the hybrid power system constituted by the vehicle power system and the supercapacitor in parallel. In order to provide a theoretical basis for the intervention and withdrawal mechanisms of a super-capacitor in the new EPS, the law of steering resistance torque at a low or extremely low vehicle speed should be explored. Firstly, the finite element model of tire/pavement was established to conduct the simulation and calculation of the low-speed steering friction force between the tire and pavement, and to obtain the fitting expression of the equivalent steering friction coefficient with the running speed of the tire. Secondly, the expression of the steering friction torque was deduced based on the calculus theory and mathematical model of the low-speed steering resistance torque, including the steering friction torque and aligning torques, established to conduct the simulation of the equivalent resistance torque applied on a steering column under low-speed condition. Subsequently, the real vehicle experiments were carried out and comparisons of the experimental results and simulation results was performed. The consistency indicated that the model of low-speed steering resistance torque had a high accuracy. Finally, the law of low-speed steering resistance torque with a vehicle speed and steering wheel angle were analyzed according to the 3D surface plot drawn from the simulation results. Full article
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<p>Structure of the SC-EPS system.</p>
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<p>Finite element models of the tire and pavement.</p>
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<p>Simulation results of low-speed steering friction force: (<b>a</b>) Curves of steering friction force; and (<b>b</b>) fitting curve of the equivalent friction coefficient with the running speed of the tire.</p>
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<p>Diagram of contact between the tire and pavement.</p>
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<p>Steering model of the steered wheel: (<b>a</b>) Schematic diagram of the kingpin axis and kingpin offset; (<b>b</b>) geometric model of the low-speed steering friction torque; and (<b>c</b>) longitudinal pressure distribution of the tire.</p>
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<p>Solution procedure of the aligning torques caused by the kingpin caster and pneumatic trail.</p>
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<p>The relation curves obtained by ‘Magic Formula’: (<b>a</b>) The lateral force with the side-slip angle of tire; and (<b>b</b>) the aligning torque with the side-slip angle of tire.</p>
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<p>Simulation model of the low-speed steering resistance torque.</p>
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<p>The experimental scene.</p>
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<p>Simulation and experimental results of the steering wheel torque at different speeds.</p>
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<p>3D surface plot of the low-speed steering resistance torque.</p>
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10 pages, 3471 KiB  
Article
Enhancement of the Oil Absorption Capacity of Poly(Lactic Acid) Nano Porous Fibrous Membranes Derived via a Facile Electrospinning Method
by Jun-Wei Liang, Gajula Prasad, Shi-Cai Wang, Jia-Lin Wu and Sheng-Guo Lu
Appl. Sci. 2019, 9(5), 1014; https://doi.org/10.3390/app9051014 - 12 Mar 2019
Cited by 32 | Viewed by 4837
Abstract
Oil spilling has been a serious problem in the world for a long time, which can bring toxic substances to marine life. A large number of researchers around the world have introduced many measures to address this problem. One of the effective methods [...] Read more.
Oil spilling has been a serious problem in the world for a long time, which can bring toxic substances to marine life. A large number of researchers around the world have introduced many measures to address this problem. One of the effective methods to remove oil from the oil/water mixture is to absorb oil from the mixture. Here, we prepared porous poly(lactic acid) (PLA) membranes using the electrospinning approach with different sized syringe needles, and used these membranes to absorb oil from the top of the water. It was found that the diameter of the needle has a big impact on the size and structure of the pores on the PLA fibers. The oil absorption capacity of membranes increases with a decreasing needle diameter due to the increased pore volume and specific surface area. The highest absorption capacity reached was 42.38 g/g for vacuum pump oil, 28.17 g/g for peanut oil, and 6.74 g/g for diesel oil. Full article
(This article belongs to the Special Issue Electrospinning Technology: Control of Morphology for Nanostructure)
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Graphical abstract

Graphical abstract
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<p>SEM (scanning electron microscope) images of different PLA porous fibers prepared using different needle diameters: (<b>a</b>) 14 G, (<b>b</b>) 16 G, (<b>c</b>) 18 G, (<b>d</b>) 19 G and (<b>e</b>) 21 G. (All images are ×10.0 k).</p>
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<p>Average fiber diameters (black line) and relative pore volumes (red line) of porous fibers obtained using different needle diameters.</p>
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<p>A schematic diagram of droplet stretching from the needle tip to the collection board in a high electric field.</p>
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<p>A schematic diagram of pores formed in fibers.</p>
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<p>The wettability of fibers is presented: (<b>a</b>) the WCA of fibers prepared by the 21 G needle, (<b>b</b>) the OCA of fibers prepared by 21 G the needle, (<b>c</b>) the WCAs and OCAs of the fiber membranes for samples obtained using different needle diameters.</p>
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<p>The absorption time of an oil drop on the different porous fibers.</p>
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<p>The ATR-FTIR spectra of samples prepared by 14 G, 16 G, 18 G, 19 G, 21 G needles and the raw PLA.</p>
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<p>Maximum oil absorption capacity of porous membranes with different diameters for different kinds of oil.</p>
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<p>The absorption test was carried out in 60 s. (<b>a</b>) Ten grams of pump oil dyed in green were suspended on the top of 80 mL water. (<b>b</b>) Fiber membranes of 0.5 g in weight were fixed to adsorb the oils in the suspension. The images were taken after 30 s. (<b>c</b>) After 60 s, the oil absorption was almost complete, and the adsorbed fiber films were moved to another beaker.</p>
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14 pages, 2692 KiB  
Review
Nano-Structured Demineralized Human Dentin Matrix to Enhance Bone and Dental Repair and Regeneration
by Xianling Gao, Wei Qin, Ping Wang, Lin Wang, Michael D. Weir, Mark A. Reynolds, Liang Zhao, Zhengmei Lin and Hockin H. K. Xu
Appl. Sci. 2019, 9(5), 1013; https://doi.org/10.3390/app9051013 - 12 Mar 2019
Cited by 26 | Viewed by 5780
Abstract
Demineralized dentin matrix (DDM), derived from human teeth, is an excellent scaffold material with exciting bioactive properties to enhance bone and dental tissue engineering efficacy. In this article, first the nano-structure and bioactive components of the dentin matrix were reviewed. Then the preparation [...] Read more.
Demineralized dentin matrix (DDM), derived from human teeth, is an excellent scaffold material with exciting bioactive properties to enhance bone and dental tissue engineering efficacy. In this article, first the nano-structure and bioactive components of the dentin matrix were reviewed. Then the preparation methods of DDM and the resulting properties were discussed. Next, the efficacy of DDM as a bone substitute with in vitro and in vivo properties were analyzed. In addition, the applications of DDM in tooth regeneration with promising results were described, and the drawbacks and future research needs were also discussed. With the extraction of growth factors from DDM and the nano-structural properties of DDM, previous studies also broadened the use of DDM as a bioactive carrier for growth factor delivery. In addition, due to its excellent physical and biological properties, DDM was also investigated for incorporation into other biomaterials design and fabrication, yielding great enhancements in hard tissue regeneration efficacy. Full article
(This article belongs to the Special Issue Nanomaterials for Bone Tissue Engineering)
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<p>The nano-structure of dentin and DDM in scanning electron microscopy. (<b>A</b>) Dentin had micrometer-sized tubules. PTD was highly mineralized and collagen-free (black arrow). The mineral in ITD was embedded in collagen-rich matrix (white arrow). Scale bar = 1 μm (larger figure). Scale bar = 2 μm (inset). (<b>B</b>). Demineralization mainly dissolved the mineral in PTD, with opened and wider tubules, and a meshwork protruding towards the tubule lumen. Scale bar = 2 μm. (<b>C</b>) Higher magnification of demineralized dentin showing a complex network of filaments protruding from tubule walls. Scale bar = 2 μm. (From Berttasoni [<a href="#B37-applsci-09-01013" class="html-bibr">37</a>] in <span class="html-italic">Micron</span>, with permission.)</p>
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<p>The dentin matrix-induced bone formation depended on the degree of demineralization and particle size. (<b>A</b>) Micro-CT analysis. New bone formation was enhanced in all particle sizes in PDDM groups, more than in CDDM groups. The results of 1000 μm PDDM were especially noteworthy. In contrast, in UDD groups, much less new bone formed, and defects were occupied by dentin particles. (<b>B</b>) Newly formed bone (n-Bone%) were quantitatively evaluated. At 4 weeks, there is significant difference of n-Bone% between the PDDM and other groups in each particle size. At 8 weeks, there is a significant difference of the n-Bone% between the PDDM and the other groups in the 200 and 500 μm samples. (From Takamitsu [<a href="#B17-applsci-09-01013" class="html-bibr">17</a>] in <span class="html-italic">PLOS ONE</span>, with permission.)</p>
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<p>In vivo pulp-capping effects after pulp exposure. Dentin bridge formation was analyzed by Micro-CT. (From Chen [<a href="#B10-applsci-09-01013" class="html-bibr">10</a>] <span class="html-italic">J. Tissue Eng. Regen. Med.</span>, with permission.)</p>
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<p>Biochemical changes after implantation in DDM/rhBMP-2 group and DDM group. (<b>A</b>) Dry weight (mg/pellet). (<b>B</b>) ALP activity (IU/pellet). (<b>C</b>) Ca content (mg/pellet). (From Murata [<a href="#B62-applsci-09-01013" class="html-bibr">62</a>] <span class="html-italic">Journal of Biomedical Baterials Research</span> Part A, with permission.)</p>
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<p>The combination of APES/TDM and DPEM/TDM on odontoblastic differentiation of DPSCs. (<b>A</b>,<b>B</b>) The APES group up-regulated DSPP and DMP-1, two classic odontogenic markers. Meanwhile, the expression of vasculogenesis and angiogenesis marker VEGF was up-regulated, but early osteogenic/odontogenic markers ALP, BSP and RUNX-2, were down-regulated. (<b>C</b>,<b>D</b>) In DPEM group, the expression of ALP, BSP and RUNX-2 expression were inhibited. The expression of DMP-1 and VEGF did not change. (<b>E</b>,<b>F</b>) In TDM group, DMP-1 and DSPP were up-regulated, but ALP, BSP and VEGF were not. (<b>G</b>,<b>H</b>) In the group of DPEM/TDM or APES/TDM, the expression of DMP-1 and DSPP were up-regulated, while ALP and RUNX-2 were down-regulated. Interestingly, DPEM/TDM not only up-regulated BSP, but also kept the expression level of VEGF. * <span class="html-italic">p</span> &lt; 0.05, ** <span class="html-italic">p</span> &lt; 0.01, *** <span class="html-italic">p</span> &lt; 0.001, NS: no significance. (From Chen [<a href="#B69-applsci-09-01013" class="html-bibr">69</a>], <span class="html-italic">Biomaterials</span>, with permission.)</p>
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<p>Schematic description of the dentin bioink for 3D-bioprinting. The bioink was made of insoluble dentin proteins, soluble dentin molecules and alginate hydrogel. (From Athirasala [<a href="#B70-applsci-09-01013" class="html-bibr">70</a>] <span class="html-italic">Biofabrication</span>, with permission.)</p>
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9 pages, 2422 KiB  
Article
Using Computer Simulation to Investigate Which Joint Angle Changes Have the Most Effect on Ball Release Speed in Overarm Throwing
by Nurhidayah Omar, Maurice R. Yeadon and Mark A. King
Appl. Sci. 2019, 9(5), 999; https://doi.org/10.3390/app9050999 - 11 Mar 2019
Cited by 1 | Viewed by 3991
Abstract
Efficient throwing mechanics is predicated on a pitcher’s ability to perform a sequence of movements of body segments, which progresses from the legs, pelvis, and trunk to the smaller, distal arm segments. Each segment plays a vital role in achieving maximum ball velocity [...] Read more.
Efficient throwing mechanics is predicated on a pitcher’s ability to perform a sequence of movements of body segments, which progresses from the legs, pelvis, and trunk to the smaller, distal arm segments. Each segment plays a vital role in achieving maximum ball velocity at ball release. The perturbation of one joint angle has an effect on the ball release speed. An eight-segment angle-driven simulation model of the trunk, upper limbs and ball was developed to determine which joint angle changes have the most influence on ball release speed in overarm throwing for an experienced pitcher. Fifteen overarm throwing trials were recorded, and the joint angle time histories of each trial were input into the simulation model. Systematically replacing each joint angle time history with a constant value showed that overarm throwing was sensitive (≥5 m/s effect on ball release speed) to trunk extension/flexion and upper arm external/internal rotation, and very sensitive (≥10 m/s effect) to forearm extension/flexion. Computer simulation allows detailed analysis and complete control to investigate contributions to performance, and the key joint angle changes for overarm throwing were identified in this analysis. Full article
(This article belongs to the Special Issue Computer Science in Sport)
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<p>Schematic of experimental set-up; light grey arrows represent Vicon cameras and dark grey arrow represents video camera.</p>
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<p>Ball with reflective markers.</p>
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<p>Segments used within the angle-driven model.</p>
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<p>Joint angle time histories for the 15 recorded trials (ball release at time zero).</p>
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16 pages, 3896 KiB  
Article
Optimal Design of a Tower Type SCR-deNOx Facility for a 1000 MW Coal-Fired Power Plant Based on CFD Simulation and FMT Validation
by Haojun Zeng, Jingqi Yuan and Jingcheng Wang
Appl. Sci. 2019, 9(5), 1012; https://doi.org/10.3390/app9051012 - 11 Mar 2019
Cited by 8 | Viewed by 3572
Abstract
Selective catalytic reduction (SCR) is one of the most efficient methods to reduce NOx emissions from coal-fired power plants. This paper deals with an optimal design tower type SCR-deNOx facility for a 1000 MW coal-fired power plant. Combined with computational fluid [...] Read more.
Selective catalytic reduction (SCR) is one of the most efficient methods to reduce NOx emissions from coal-fired power plants. This paper deals with an optimal design tower type SCR-deNOx facility for a 1000 MW coal-fired power plant. Combined with computational fluid dynamics (CFD), the configuration of the baffles geometry was studied with spatial constraints. Flow field was regulated at the ammonia injection grid (AIG) with the dual aim of reducing difficulties in implementing the non-uniformed ammonia (NH3) injection strategy and achieving a more homogeneous distribution at the catalyst entrance. A flow model test (FMT) was carried out at a laboratory scale to verify the design results. The results of the flow model test are in good agreement with the computational fluid dynamics. It is indicated that small-sized baffles are recommended for installation at the upstream side of the facility as the optimal design and ability to regulate the flow field at the ammonia injection grid makes it an effective way to deal with spatial constraints. This paper provides a good reference for optimizing the tower type SCR-deNOx facilities with spatial constraints. Full article
(This article belongs to the Section Chemical and Molecular Sciences)
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<p>The schematic geometry of a tower type SCR-deNO<span class="html-italic"><sub>x</sub></span> facility for a 1000 MW coal-fired power plant. AIG: Ammonia Injection Grid.</p>
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<p>Meshing geometry of the representative area.</p>
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<p>The platform of flow model test (FMT) experiments.</p>
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<p>The sketch map of detection spots over the perforate plate.</p>
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<p>The baffles installation in the expansion duct for the optimal design (unit: mm).</p>
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<p>The sizes and locations of the baffles installation in the expansion duct: (<b>a</b>) Y-positive view; (<b>b</b>) X-negative view.</p>
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<p>The sizes and locations of the baffles installation in the expansion duct: (<b>a</b>) Y-positive view; (<b>b</b>) X-negative view.</p>
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<p>The crossed baffles installation at the upstream side of the ammonia injection grid (AIG) (unit: mm).</p>
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<p>The sizes and locations of the crossed baffles installation at the upstream side of the AIG: (<b>a</b>) Y-positive view; (<b>b</b>) X-negative view.</p>
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<p>Contours of gas velocity at the observation plane for the optimal design (unit: m/s).</p>
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<p>(<b>a</b>) The injection divisions of AIG (top view); (<b>b</b>) The corresponding non-uniformed NH<sub>3</sub> injection strategy (unit: m/s).</p>
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<p>Contours of NH<sub>3</sub> concentration at the observation plane for the optimal design (unit: kg/m<sup>3</sup>).</p>
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<p>The influence of the crossed baffles on gas velocities and NH<sub>3</sub> concentration.</p>
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23 pages, 17253 KiB  
Article
The Development of a Soft Robot Hand with Pin-Array Structure
by Hong Fu and Wenzeng Zhang
Appl. Sci. 2019, 9(5), 1011; https://doi.org/10.3390/app9051011 - 11 Mar 2019
Cited by 18 | Viewed by 3959
Abstract
This paper proposes a soft robot hand with pin-array structure and self-adaptive function, CTSA-II hand, where CTSA is the Cluster tube self-adaption. The CTSA-II hand is designed with a quite concise structure and consists of bases, a pin array, a spring array, and [...] Read more.
This paper proposes a soft robot hand with pin-array structure and self-adaptive function, CTSA-II hand, where CTSA is the Cluster tube self-adaption. The CTSA-II hand is designed with a quite concise structure and consists of bases, a pin array, a spring array, and a membrane. When the CTSA-II hand grasps an object, the pins will slide along the trajectory to conform to the profile of the object under the reaction force applied by the object, and thus the outer membrane will form a specific shape, and then the vacuum drives the CTSA-II hand to grasp the object. Theoretical analysis shows that the CTSA-II hand can generate enough grasping force and get good stability. Moreover, the optimization of its structure is achieved by studying the effects of specific parameters. The capture experimental results of the prototype show that the CTSA-II hand can realize self-adaptive grasping of different sizes and shapes with a high degree of fit and a high success rate. A series of research experiments show the influence of various factors on the grasping force, which verifies the results of the theoretical analysis with the CTSA-II hand. Compared to the traditional robot hand, the CTSA-II hand has good crawl performance, concise structure, small volume, and easy assembly. Full article
(This article belongs to the Special Issue Soft Robotics: New Design, Control, and Application)
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<p>The Omnigripper.</p>
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<p>The objects that omnigripper can or cannot crawl.</p>
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<p>The cluster tube self-adaptive (CTSA) grasping mode.</p>
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<p>The CTSA hand.</p>
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<p>The expected improved design of CTSA hand, including components: 1, base; 2, spring; 3, balloon membrane; 4, pins; 5, gas or fluid; 6, object.</p>
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<p>The design of the CTSA-II hand: (<b>a</b>) the explosion view, (<b>b</b>) the overall appearance.</p>
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<p>Grasping process of the robot hand: (<b>a</b>) before grasping, (<b>b</b>) self-adaptive step, (<b>c</b>) self-adaptive step hiding membrane, (<b>d</b>) gripping step, and (<b>e</b>) gripping step hiding membrane.</p>
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<p>The overall force situation: 1, base: 2, spring; 3, balloon membrane; 4, bendable sliding pins.</p>
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<p>Force analysis of single pin.</p>
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<p>Influences of <span class="html-italic">r<sub>p</sub></span>, <span class="html-italic">l</span>, and <span class="html-italic">N</span> on <span class="html-italic">F<sub>o</sub></span> (<span class="html-italic">r</span> = 0.02 m, <span class="html-italic">R<sub>o</sub></span> = 0.015 m, <span class="html-italic">x<sub>o</sub></span> = 0, <span class="html-italic">y<sub>o</sub></span> = 0.03 m, <span class="html-italic">E</span> = 5 × 10<sup>7</sup> Pa, <span class="html-italic">p<sub>o</sub></span> = 1.01 × 10<sup>5</sup> Pa, and <span class="html-italic">p<sub>i</sub></span> = 0.8 <span class="html-italic">p<sub>o</sub></span>).</p>
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<p>Influences of <span class="html-italic">x<sub>o</sub></span>, <span class="html-italic">y<sub>o</sub></span>, and <span class="html-italic">E</span> on <span class="html-italic">F<sub>o</sub></span> (<span class="html-italic">r</span> = 0.02 m, <span class="html-italic">R<sub>o</sub></span> = 0.01 m, <span class="html-italic">l</span> = 0.03 m, <span class="html-italic">r<sub>p</sub></span> = 0.003 m, <span class="html-italic">N</span> = 12, <span class="html-italic">p<sub>o</sub></span> = 1.01 × 10<sup>5</sup> Pa, and <span class="html-italic">p<sub>i</sub></span> = 0.8 <span class="html-italic">p<sub>o</sub></span>).</p>
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<p>The instability of pin.</p>
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<p>The composition of the pin.</p>
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<p>Three CTSA-II hands with different numbers of pin assemblies.</p>
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<p>The comparison of contraction state and initial state.</p>
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<p>The experiments with the verification of the crawl function.</p>
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<p>The experimental platform of exploring pressure.</p>
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<p>The experimental structure of exploring pressure.</p>
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<p>The characteristics of the vacuum generator used in the system of CTSA-II hand.</p>
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<p>The change of internal pressure when the CTSA-II hand grasps objects.</p>
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<p>The experiment of measuring the grasping force.</p>
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<p>The relationships between the internal pressure and the grasping force.</p>
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<p>The relationships between the cross-sectional dimensions of objects and the grasping force.</p>
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15 pages, 4097 KiB  
Article
An Automatic Modulation Recognition Method with Low Parameter Estimation Dependence Based on Spatial Transformer Networks
by Mingxuan Li, Ou Li, Guangyi Liu and Ce Zhang
Appl. Sci. 2019, 9(5), 1010; https://doi.org/10.3390/app9051010 - 11 Mar 2019
Cited by 12 | Viewed by 4672
Abstract
Recently, automatic modulation recognition has been an important research topic in wireless communication. Due to the application of deep learning, it is prospective of using convolution neural networks on raw in-phase and quadrature signals in developing automatic modulation recognition methods. However, the errors [...] Read more.
Recently, automatic modulation recognition has been an important research topic in wireless communication. Due to the application of deep learning, it is prospective of using convolution neural networks on raw in-phase and quadrature signals in developing automatic modulation recognition methods. However, the errors introduced during signal reception and processing will greatly deteriorate the classification performance, which affects the practical application of such methods. Therefore, we first analyze and quantify the errors introduced by signal detection and isolation in noncooperative communication through a baseline convolution neural network. In response to these errors, we then design a signal spatial transformer module based on the attention model to eliminate errors by a priori learning of signal structure. By cascading a signal spatial transformer module in front of the baseline classification network, we propose a method that can adaptively resample the signal capture to adjust time drift, symbol rate, and clock recovery. Besides, it can also automatically add a perturbation on the signal carrier to correct frequency offset. By applying this improved model to automatic modulation recognition, we obtain a significant improvement in classification performance compared with several existing methods. Our method significantly improves the prospect of the application of automatic modulation recognition based on deep learning under nonideal synchronization. Full article
(This article belongs to the Special Issue Advances in Deep Learning)
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<p>Recognition Signal Processing Flow.</p>
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<p>The framework of the proposed method with SSTM for directly using raw in-phase and quadrature (IQ) samples.</p>
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<p>The bi-directional long short-term memory (Bi-LSTM) structure in the signal parameterized estimation network.</p>
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<p>Overall classification accuracy of baseline classifier for various training scenarios vs. frequency offset and SNR. (<b>a</b>) CFO1; (<b>b</b>) CFO2.</p>
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<p>Overall classification accuracy of baseline classifier for various training scenarios vs. sample rate offsets and SNR. (<b>a</b>) SRO1; (<b>b</b>) SRO2.</p>
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<p>Overall classification accuracy for various offsets in Ideal, SRO1, SRO2, CFO1, CFO2, with SNR fixed at 20 dB (<b>a</b>) frequency offsets in Ideal, CFO1, CFO2; (<b>b</b>) sample rate offsets in Ideal, SRO1, SRO2.</p>
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<p>Overall classification accuracy of the classifier with SSTM for various training scenarios vs. frequency offset and SNR. (<b>a</b>) CFO1; (<b>b</b>) SRO1.</p>
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<p>Overall classification accuracy with various offsets in SRO1 and CFO1 scenarios with the aforementioned methods. (<b>a</b>) CFO1; (<b>b</b>) SRO1.</p>
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17 pages, 6026 KiB  
Article
Image Shadow Removal Using End-To-End Deep Convolutional Neural Networks
by Hui Fan, Meng Han and Jinjiang Li
Appl. Sci. 2019, 9(5), 1009; https://doi.org/10.3390/app9051009 - 11 Mar 2019
Cited by 23 | Viewed by 7195
Abstract
Image degradation caused by shadows is likely to cause technological issues in image segmentation and target recognition. In view of the existing shadow removal methods, there are problems such as small and trivial shadow processing, the scarcity of end-to-end automatic methods, the neglecting [...] Read more.
Image degradation caused by shadows is likely to cause technological issues in image segmentation and target recognition. In view of the existing shadow removal methods, there are problems such as small and trivial shadow processing, the scarcity of end-to-end automatic methods, the neglecting of light, and high-level semantic information such as materials. An end-to-end deep convolutional neural network is proposed to further improve the image shadow removal effect. The network mainly consists of two network models, an encoder–decoder network and a small refinement network. The former predicts the alpha shadow scale factor, and the latter refines to obtain sharper edge information. In addition, a new image database (remove shadow database, RSDB) is constructed; and qualitative and quantitative evaluations are made on databases such as UIUC, UCF and newly-created databases (RSDB) with various real images. Using the peak signal-to-noise ratio (PSNR) and the structural similarity (SSIM) for quantitative analysis, the algorithm has a big improvement on the PSNR and the SSIM as opposed to other methods. In terms of qualitative comparisons, the network shadow has a clearer and shadow-free image that is consistent with the original image color and texture, and the detail processing effect is much better. The experimental results show that the proposed algorithm is superior to other algorithms, and it is more robust in subjective vision and objective quantization. Full article
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<p>The architecture of the RSnet. RSnet consists of two cooperative sub-networks. The left side of the dotted line shows the encoding–decoding network, and the right side shows the refinement network.</p>
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<p>Illustration of several shadow and shadow-free image pairs in the RSDB database. The (<b>a1</b>, <b>b1</b>, <b>c1</b>) columns show the shadow images (inputs) in different scenes. The (<b>a2</b>, <b>b2</b>, <b>c2</b>) columns indicate true shadow-free images (targets) corresponding to the (<b>a1</b>, <b>b1</b>, <b>c1</b>) columns.</p>
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<p>Schematic diagram of shadow removal in simple scenes.</p>
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<p>Schematic diagram of shadow removal in complex scenes.</p>
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<p>Schematic diagram of shadow removal in special scenes.</p>
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13 pages, 5166 KiB  
Article
Efficient Demulsification of Acidic Oil-In-Water Emulsions with Silane-Coupled Modified TiO2 Pillared Montmorillonite
by Gaohong Zuo, Yingchao Du, Lianqi Wei, Bo Yu, Shufeng Ye, Xiaomeng Zhang and Hongshun Hao
Appl. Sci. 2019, 9(5), 1008; https://doi.org/10.3390/app9051008 - 11 Mar 2019
Cited by 8 | Viewed by 4043
Abstract
Emulsified pickling waste liquid, derived from cleaning oily hardware, cause serious environmental and ecological issues. In this work, a series of grafted (3-aminopropyl)triethoxysilane (APTES) TiO2 pillared montmorillonite (Mt), Ti-Mt-APTES, are prepared and characterized for their assessment in demulsification of acidic oil-in-water emulsion. [...] Read more.
Emulsified pickling waste liquid, derived from cleaning oily hardware, cause serious environmental and ecological issues. In this work, a series of grafted (3-aminopropyl)triethoxysilane (APTES) TiO2 pillared montmorillonite (Mt), Ti-Mt-APTES, are prepared and characterized for their assessment in demulsification of acidic oil-in-water emulsion. After titanium hydrate is introduced through ion exchange, montmorillonite is modified by hydrophobic groups coming from APTES. The Ti-Mt-APTES in acidic oil-in-water emulsion demulsification performance and mechanism are studied. Results show that the prepared Ti-Mt-APTES has favorable demulsification performance. The Ti-Mt-APTES demulsification efficiency (ED) increased to an upper limit value when the mass ratio of APTES to the prepared TiO2 pillared montmorillonite (Ti-Mt) (RA/M) was 0.10 g/g, and the 5 h is the optimal continuous stirring time for breaking the acidic oil-in-water emulsion by Ti-Mt-APTES. The ED increased to 94.8% when 2.5 g/L of Ti-Mt-APTES is added into the acidic oil-in-water emulsion after 5 h. An examination of the demulsification mechanism revealed that amphiphilicity and electrostatic interaction both played vital roles in oil-in-water separation. It is demonstrated that Ti-Mt-APTES is a promising, economical demulsifier for the efficient treatment of acidic oil-in-water emulsions. Full article
(This article belongs to the Special Issue New Materials and Techniques for Environmental Science)
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<p>Preparation of Ti-Mt-APTES. Mt. Mt, montmorillonite; APTES, (3-aminopropyl)triethoxysilane.</p>
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<p>XRD patterns of Na-Mt and Ti-Mt-APTES.</p>
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<p>FTIR spectra of Na-Mt and Ti-Mt-APTES.</p>
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<p>N<sub>2</sub> adsorption/desorption isotherms of Na-Mt and Ti-Mt-APTES.</p>
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<p>SEM image of Na-Mt (<b>a</b>), circle enlarged image (<b>b</b>), SEM image of Ti-Mt-APTES (<b>c</b>) and EDS results of Ti-Mt-APTES.</p>
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<p>Photographs of the acidic oil-in-water emulsion and after demulsification by Ti-Mt-APTES-0.10.</p>
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<p>(<b>a</b>) Demulsification performance of Na-Mt, Ti-Mt, Na-Mt-APTES-0.10, and Ti-Mt-APTES-0.10. (<b>b</b>) Effect of the Ti-Mt-APTES dosage on demulsification efficiency at various R<sub>A/M.</sub></p>
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<p>Demulsification performance of Ti-Mt-APTES-0.1 under various stirring times.</p>
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<p>Micrographs of the oil–water mixture before and after demulsification: (<b>a</b>) the oil-in-water emulsion; (<b>b</b>) the newly separated water phase; (<b>c</b>) the newly separated oil phase; (<b>d</b>) Ti-Mt-APTES in oil-in-water emulsion.</p>
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<p>FTIR spectra of Ti-Mt-APTES before and after demulsification.</p>
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<p>High resolution XPS spectra of Ti 2p (<b>a</b>), C 1s (<b>b</b>), N 1s (<b>c</b>), O 1s (<b>d</b>) in Ti-Mt-APTES before and after demulsification.</p>
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<p>Zeta potentials of Na-Mt and Ti-Mt-APTES at various pH levels.</p>
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<p>Schematic illustration of the demulsification mechanism.</p>
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21 pages, 4980 KiB  
Article
Application of Hybrid PCM Thermal Energy Storages with and without Al Foams in Solar Heating/Cooling and Ground Source Absorption Heat Pump Plant: An Energy and Economic Analysis
by Renato Lazzarin, Marco Noro, Giulia Righetti and Simone Mancin
Appl. Sci. 2019, 9(5), 1007; https://doi.org/10.3390/app9051007 - 11 Mar 2019
Cited by 18 | Viewed by 4670
Abstract
The use of phase change materials (PCM) can be considered an effective way to improve the energy storage capabilities of hybrid water thermal energy storage (TESs) in solar heating and cooling plants. However, due to a few shortcomings, their use is still limited. [...] Read more.
The use of phase change materials (PCM) can be considered an effective way to improve the energy storage capabilities of hybrid water thermal energy storage (TESs) in solar heating and cooling plants. However, due to a few shortcomings, their use is still limited. This paper aims to give a direct estimation of the considerable advantages achievable by means of these hybrid TESs by simulating the annual performance of an existing gymnasium building located in northern Italy. The solar heating/cooling and ground source absorption heat pump plant is simulated using Trnsys. A validated type allows for the simulation of the hybrid water TESs, and also includes the possibility to use aluminum foams to enhance the heat transfer capabilities of the paraffin waxes used as PCM. This paper presents an optimization of the plant design from both energy and economic points of view by considering different cases: all three tanks modeled as sensible (water) storage, or one of the tanks modeled as PCM storage, or as enhanced PCM with metal foam. Full article
(This article belongs to the Special Issue Advanced Applications of Phase Change Materials)
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<p>(<b>a</b>) Schematic of the simulated system (not in scale, in millimeters); (<b>b</b>) enthalpy–temperature curve for the paraffin used in the simulations for type validation.</p>
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<p>(<b>a</b>) Schematic of the experimental setup and (<b>b</b>) location of the temperature probes (in millimeters).</p>
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<p>Simulated vs. experimental temperature profiles along the top radial section (axial node 10 at the top of the tubes) with the water temperature kept at 50 °C during the loading process of the paraffin/Al-foam composite PCM and pure paraffin wax (simulated and experimental curves).</p>
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<p>Temperature profiles (axial node 10 at the top of the tubes) during the unloading process of paraffin/Al-foam composite PCM and pure paraffin wax (simulated and experimental curves). Water temperature was kept at 23 °C. Experimental temperature was measured in the centre of the section.</p>
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<p>The retrofitting intervention and definition of thermal zones for the ground floor (<b>a</b>) and first floor (<b>b</b>).</p>
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<p>The retrofitting intervention and definition of thermal zones for the second floor (<b>a</b>); building as is and post-intervention (<b>b</b>).</p>
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<p>Monthly energy needs in terms of heating, cooling, ventilation (hot and cold coils of air handling units (AHU)), and domestic hot water (DHW).</p>
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<p>Simplified functional diagram of the heating, ventilation, and air conditioning (HVAC) plant. The mass flows of the main circuits (ground, solar, tanks, hot and cold collectors) are shown (the part of the plant operating during heating season only is in grey).</p>
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<p>Schematic of the Trnsys project of the HVAC plant model.</p>
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<p>Enthalpy–temperature curves for the paraffin used in the simulations.</p>
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<p>Solar energy balance for the A3 alternative.</p>
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<p>Absorption HP/chiller energy balance for the A3 alternative.</p>
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<p>Energy balance for the DHW tank for the A3 alternative.</p>
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<p>Energy balance for the hot tank for the A3 alternative.</p>
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<p>Energy demand percentage covering of different energy sources and the primary energy ratio (PER) (alternative A3).</p>
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<p>PER and electricity consumption by the circulation pumps (PER*) for the different alternatives.</p>
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<p>Annual discounted differential cash flows between the A1–A5 alternatives and the traditional one (A0).</p>
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<p>No-renewable primary energy consumption and primary energy ratio for the different alternatives.</p>
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<p>Useful solar radiation from thermal collectors to ground, hot tank and DHW tank.</p>
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<p>Temperature and flow rate of water at the outlet of the DHW tank in the case of sensible (water), phase change materials (PCM), and the enhanced PCM DHW tank.</p>
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