[go: up one dir, main page]

Next Issue
Volume 6, December
Previous Issue
Volume 6, June
 
 

Minerals, Volume 6, Issue 3 (September 2016) – 41 articles

  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list.
  • You may sign up for e-mail alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.
Order results
Result details
Section
Select all
Export citation of selected articles as:
6797 KiB  
Article
Synthesis of Novel Ether Thionocarbamates and Study on Their Flotation Performance for Chalcopyrite
by Gang Zhao, Jing Peng, Hong Zhong, Shuai Wang and Guangyi Liu
Minerals 2016, 6(3), 97; https://doi.org/10.3390/min6030097 - 21 Sep 2016
Cited by 19 | Viewed by 5666
Abstract
Novel ether thionocarbamates, O-butoxy isopropyl-N-ethoxycarbonyl thionocarbamate (BIPECTC) and O-(2-butoxy-1-methylethoxy) isopropyl-N-ethoxycarbonyl thionocarbamate (BMIPECTC), were synthesized in this study. Their collecting efficiencies in the flotation of chalcopyrite were investigated using flotation tests, adsorption measurements, ultraviolet spectra (UV) and Fourier transform-infrared spectroscopy (FT-IR) and density functional [...] Read more.
Novel ether thionocarbamates, O-butoxy isopropyl-N-ethoxycarbonyl thionocarbamate (BIPECTC) and O-(2-butoxy-1-methylethoxy) isopropyl-N-ethoxycarbonyl thionocarbamate (BMIPECTC), were synthesized in this study. Their collecting efficiencies in the flotation of chalcopyrite were investigated using flotation tests, adsorption measurements, ultraviolet spectra (UV) and Fourier transform-infrared spectroscopy (FT-IR) and density functional theory (DFT) calculations. The synthesized ether thionocarbamates showed better frothing properties than methyl-isobutyl-carbinol (MIBC) and stronger affinity to chalcopyrite compared with O-isopropyl-N-ethyl thionocarbamate (IPETC) and O-isobutyl-N-ethoxycarbonyl thionocarbamate (IBECTC). UV spectra analysis showed that the ether thionocarbamates react with Cu2+, with the exception of Fe2+, Ni2+, Zn2+ and Pb2+. Additionally, it was further confirmed by FTIR spectra that a chemical reaction occurs between copper ion and BIPECTC and BMIPECTC. The adsorption capacity measurements revealed that chalcopyrite exhibits good adsorption ability for ether thionocarbamates at an approximate pH of 8–10, which agrees with the flotation tests. The quantum chemistry calculation results indicated that the ether thionocarbamates exhibit stronger collecting ability for copper mineral in terms of frontier molecular orbital analysis, binding model simulation with copper ions and the molecular hydrophobicity compared with IPETC and IBECTC. The computational results are in very good agreement with the experimental results. Full article
Show Figures

Figure 1

Figure 1
<p>Diagrammatic sketch of the frothing property determined by the airflow method.</p>
Full article ">Figure 2
<p>The flow sheet of rougher flotation for chalcopyrite.</p>
Full article ">Figure 3
<p>Maximum foam height and half-life as a function of the frother concentrations in aqueous solution. (<b>a</b>) Foam height; (<b>b</b>) Foam half-life.</p>
Full article ">Figure 4
<p>Maximum foam height and half-life as a function of the collector concentrations in slurry. (<b>a</b>) Foam heigh; (<b>b</b>) Foam half-life.</p>
Full article ">Figure 5
<p>Relationship between the foam height and half-life.</p>
Full article ">Figure 6
<p>Effects of the pH and collector dosage on copper recoveries. (<b>a</b>) Slurry pH (collector dosage: 60 mg/L); (<b>b</b>) Collector dosage (pH = 10)</p>
Full article ">Figure 7
<p>Recovery response surface plots with both the slurry pH and collector dosage.</p>
Full article ">Figure 8
<p>Adsorption quantity function of pH.</p>
Full article ">Figure 9
<p>Adsorption quantity as a function of the collector concentration (pH = 9).</p>
Full article ">Figure 10
<p>UV spectra of collectors and their complexes with Cu<sup>2+</sup>, Fe<sup>2+</sup>, Ni<sup>2+</sup>, Zn<sup>2+</sup> or Pb<sup>2+</sup> ions: (<b>a</b>) BIPECTC; and (<b>b</b>) BMIPECTC.</p>
Full article ">Figure 11
<p>FTIR spectra of: (<b>a</b>) chalcopyrite; (<b>b</b>) chalcopyrite + BIPECTC; (<b>c</b>) chalcopyrite + BMIPECTC.</p>
Full article ">Figure 12
<p>Optimized geometries of IPETC, IBECTC, BIPECTC and BMIPECTC.</p>
Full article ">Figure 12 Cont.
<p>Optimized geometries of IPETC, IBECTC, BIPECTC and BMIPECTC.</p>
Full article ">Figure 13
<p>MEP maps for IPETC, IBECTC, BIPECTC and BMIPECTC.</p>
Full article ">Figure 14
<p>The binding model between copper ion and BIPECTC, BMIPECTC and IPETC.</p>
Full article ">Figure 15
<p>Atom numbers in the functional groups of IPETC, IBECTC, BIPECTC and BMIPECTC.</p>
Full article ">
2295 KiB  
Article
China’s Rare Earths Supply Forecast in 2025: A Dynamic Computable General Equilibrium Analysis
by Jianping Ge, Yalin Lei and Lianrong Zhao
Minerals 2016, 6(3), 95; https://doi.org/10.3390/min6030095 - 21 Sep 2016
Cited by 30 | Viewed by 7332
Abstract
The supply of rare earths in China has been the focus of significant attention in recent years. Due to changes in regulatory policies and the development of strategic emerging industries, it is critical to investigate the scenario of rare earth supplies in 2025. [...] Read more.
The supply of rare earths in China has been the focus of significant attention in recent years. Due to changes in regulatory policies and the development of strategic emerging industries, it is critical to investigate the scenario of rare earth supplies in 2025. To address this question, this paper constructed a dynamic computable equilibrium (DCGE) model to forecast the production, domestic supply, and export of China’s rare earths in 2025. Based on our analysis, production will increase by 10.8%–12.6% and achieve 116,335–118,260 tons of rare-earth oxide (REO) in 2025, based on recent extraction control during 2011–2016. Moreover, domestic supply and export will be 75,081–76,800 tons REO and 38,797–39,400 tons REO, respectively. The technological improvements on substitution and recycling will significantly decrease the supply and mining activities of rare earths. From a policy perspective, we found that the elimination of export regulations, including export quotas and export taxes, does have a negative impact on China’s future domestic supply of rare earths. The policy conflicts between the increase in investment in strategic emerging industries, and the increase in resource and environmental taxes on rare earths will also affect China’s rare earths supply in the future. Full article
Show Figures

Figure 1

Figure 1
<p>Structure of China’s DCGE model for forecasting rare earths (within a period).</p>
Full article ">Figure 2
<p>Production, domestic supply, and export variations from 2010 to 2025 (%).</p>
Full article ">Figure 3
<p>Rare earths consumption variation in relevant sectors from 2010 to 2025 (%).</p>
Full article ">Figure 4
<p>Rare earths prices variations from 2010 to 2025 (%).</p>
Full article ">Figure 5
<p>Differences among the variations in production, domestic supply and exports before and after the abolition of export regulations (%).</p>
Full article ">Figure 6
<p>Differences among the variations in rare earths supply in different sectors before and after the abolition of export regulations (%).</p>
Full article ">
3932 KiB  
Article
Pb-Isotopic Study of Galena by LA-Q-ICP-MS: Testing a New Methodology with Applications to Base-Metal Sulphide Deposits
by Christopher R. M. McFarlane, Azam Soltani Dehnavi and David R. Lentz
Minerals 2016, 6(3), 96; https://doi.org/10.3390/min6030096 - 15 Sep 2016
Cited by 12 | Viewed by 7730
Abstract
In situ laser ablation quadrupole inductively coupled plasma mass spectrometry was used to measure Pb isotopes in galena. Data acquisition was optimized by adjusting spot size, energy density, and ablation time to obtain near steady-state low relative standard deviation (%RSD) signals. Standard-sample bracketing [...] Read more.
In situ laser ablation quadrupole inductively coupled plasma mass spectrometry was used to measure Pb isotopes in galena. Data acquisition was optimized by adjusting spot size, energy density, and ablation time to obtain near steady-state low relative standard deviation (%RSD) signals. Standard-sample bracketing using in-house Broken Hill galena as external reference standard was used and offline data reduction was carried out using VizualAge for Iolite3. Using this methodology, galena grain in polished thin sections from selected massive sulphide deposits of the Bathurst Mining Camp, Canada, were tested and compared to previously published data. Absolute values and errors on the weighted mean of ~20 individual analyses from each sample compared favourably with whole-rock Pb-Pb isotope data. This approach provides a mean to obtain rapid, accurate, and moderately (0.1% 2σ) precise Pb isotope measurements in galena and is particularly well suited for exploratory or reconnaissance studies. Further refinement of this approach may be useful in exploration for volcanogenic massive sulphides deposits and might be a useful vectoring tool when complemented with other conventional exploration techniques. Full article
(This article belongs to the Special Issue Advances in Mineral Analytical Techniques)
Show Figures

Figure 1

Figure 1
<p>Simplified geological map of the Bathurst Mining Camp, northeastern New Brunswick, showing the location of massive sulphide deposits examined during this study (black circles) (modified from [<a href="#B26-minerals-06-00096" class="html-bibr">26</a>,<a href="#B29-minerals-06-00096" class="html-bibr">29</a>]).</p>
Full article ">Figure 2
<p>Photomicrographs (plane-polarized reflected light) of representative samples from massive sulphide deposits of the BMC. (<b>a</b>) A massive sulphide sample containing intergrowth of galena (Gn) with sphalerite (Sp). Sample is from drill hole 62-55-115 @ 35.2 m (Caribou deposit). (<b>b</b>) A bedded sulphide sample containing masses of sphalerite, showing intergrowth with pyrite (Py) and galena. Sample is from drill hole 94-DL-32 @ 402 m (Key Anacon East zone deposit).</p>
Full article ">Figure 3
<p>Plot of the error on weighted mean of Pb isotopic ratios vs. crater size (sample 62-55-115, Caribou deposit).</p>
Full article ">Figure 4
<p>Comparison of results of different ablation condition of galena: (<b>a</b>) 23 µm, 2.5 Hz, and 1 J·cm<sup>−2</sup>; and (<b>b</b>) 60 µm, 2 Hz, and 0.35 J·cm<sup>−2</sup>.</p>
Full article ">Figure 5
<p>Probability density plots of Pb isotope ratios of galena from the Caribou deposit. MSWD stands for Mean Square Weighted Deviations.</p>
Full article ">Figure 6
<p>Plot of <sup>206</sup>Pb/<sup>204</sup>Pb versus (<b>a</b>) <sup>207</sup>Pb/<sup>204</sup>Pb and (<b>b</b>) <sup>208</sup>Pb/<sup>204</sup>Pb of galena by LA-Q-ICP-MS from representative massive sulphide deposits of the BMC. The Pb isotopic ratios presented for BMC VMS (grey area) ([<a href="#B34-minerals-06-00096" class="html-bibr">34</a>,<a href="#B35-minerals-06-00096" class="html-bibr">35</a>,<a href="#B36-minerals-06-00096" class="html-bibr">36</a>] (R.I. Thorpe, unpublished data), [<a href="#B48-minerals-06-00096" class="html-bibr">48</a>]) and New Brunswick, Canada (NB pluton) [<a href="#B50-minerals-06-00096" class="html-bibr">50</a>]. The average Pb evolution curves for mantle (M), orogene (O), and upper crust (UC) are from [<a href="#B48-minerals-06-00096" class="html-bibr">48</a>]. Thick dashed lines present the ablation of galena under the 44 µm, 2 Hz, and 1 J·cm<sup>−2</sup> condition. Thick solid lines present the ablation of galena under the 60 µm, 2 Hz, and 0.35 J·cm<sup>−2</sup> condition. Dotted line presents the reference values of Pb isotopes of examined deposits for comparison ([<a href="#B34-minerals-06-00096" class="html-bibr">34</a>]).</p>
Full article ">
4477 KiB  
Article
Investigation of Platinum-Group Minerals (PGM) from Othrys Chromitites (Greece) Using Superpanning Concentrates
by Basilios Tsikouras, Elena Ifandi, Sofia Karipi, Tassos A. Grammatikopoulos and Konstantin Hatzipanagiotou
Minerals 2016, 6(3), 94; https://doi.org/10.3390/min6030094 - 12 Sep 2016
Cited by 12 | Viewed by 5658
Abstract
Platinum-group minerals were concentrated using superpanning from two composite chromitite samples, which were collected from two old mines within the Othrys ophiolite. This method allows for the recovery of a broad spectrum of these rare and fine-grained minerals, and helps to better identify [...] Read more.
Platinum-group minerals were concentrated using superpanning from two composite chromitite samples, which were collected from two old mines within the Othrys ophiolite. This method allows for the recovery of a broad spectrum of these rare and fine-grained minerals, and helps to better identify them and interpret their origin. Major differences between the east and west Othrys ophiolites were determined, probably as a result of their different origin and evolution. Primary Os-, Ir-, and Ru-bearing platinum-group minerals (IPGM)-alloys and the Rh-, Pt- and Pd-bearing platinum-group minerals (PPGM) occur only in the east Othrys chromitite, indicating an evolution from initially low fS2 conditions at shallower mantle levels with the subsequent implication of a S-saturated ascending fluid. In contrast, the absence of primary IPGM-alloys in west Othrys chromitite indicates that S saturation had been attained. The presence of erlichmanite suggests that sulphur fugacity eventually increased significantly in both suites. Substantial fluctuations of a fluid phase, likely related to serpentinising fluids, modified the platinum-group minerals (PGM) assemblage of west Othrys, and resulted in a large diversity of secondary PGM minerals. The limited number of secondary species developed in the east Othrys indicate that secondary processes were also different in the two suites. Full article
(This article belongs to the Special Issue Advanced Research on Accessory Minerals)
Show Figures

Figure 1

Figure 1
<p>Distribution of the two ophiolitic belts in Greece and west part of Turkey (modified after [<a href="#B26-minerals-06-00094" class="html-bibr">26</a>]).</p>
Full article ">Figure 2
<p>Simplified geological map of the Othrys ophiolite (modified after [<a href="#B23-minerals-06-00094" class="html-bibr">23</a>]).</p>
Full article ">Figure 3
<p>Plot of the statistical data of PGM distribution according to their number of grains and surface area from the: Agios Stefanos (<b>a</b>–<b>c</b>); and Tsangli (<b>d</b>,<b>e</b>) samples.</p>
Full article ">Figure 4
<p>Plot of the statistical data of PGM grain sizes (ECD) from the: Agios Stefanos (<b>a</b>–<b>c</b>); and Tsangli (<b>d</b>,<b>e</b>) samples. Number of grains are indicated on top of the bars.</p>
Full article ">Figure 5
<p>Backscattered electron images combined with their pseudocolourised images (insets) of PGM from the Agios Stefanos composite sample: (<b>a</b>–<b>f</b>) fine tip fraction (−400 mesh); and (<b>g</b>,<b>h</b>) coarse tip fraction (+400 mesh). Mineral abbreviations are: Cpr: cooperate; Erl: erlicmanite; Hlw: hollingworthite; Irs: irarsite; Lrt: laurite; Lrt-Erl: laurite-erlichmanite solid solution; Mln: malanite; and dS: desulphurised. For details, see text.</p>
Full article ">Figure 6
<p>Backscattered electron images combined with their pseudocolourised images (insets) of PGM from the Tsangli composite sample: (<b>a</b>) fine tip fraction (−400 mesh); and (<b>b</b>–<b>d</b>) chromite fraction (−400 mesh). Mineral abbreviations are: Erl: erlicmanite; Irs: irarsite; Lrt: laurite; Lrt-Erl: laurite-erlichmanite solid solution; Mrn: merenskyite; and Spr: speryllite. See text for details.</p>
Full article ">Figure 7
<p>Pie charts of the collective modal abundance of PGM groups (primary and secondary assemblages) in all fractions from Agios Stefanos and Tsangli.</p>
Full article ">
1994 KiB  
Article
The Effect of Ca2+ and Mg2+ on the Dispersion and Flocculation Behaviors of Muscovite Particles
by Jiayan Tang, Yimin Zhang and Shenxu Bao
Minerals 2016, 6(3), 93; https://doi.org/10.3390/min6030093 - 8 Sep 2016
Cited by 19 | Viewed by 6701
Abstract
The dispersion and flocculation behavior of muscovite suspensions in the presence of Ca2+ and Mg2+ are relevant for industrial processing of pre-concentrated muscovite from stone coal, a primary source of vanadium. In this study, the dispersion and flocculation behavior were investigated [...] Read more.
The dispersion and flocculation behavior of muscovite suspensions in the presence of Ca2+ and Mg2+ are relevant for industrial processing of pre-concentrated muscovite from stone coal, a primary source of vanadium. In this study, the dispersion and flocculation behavior were investigated by means of sedimentation, zeta potential, and ion absorption experiments, as well as the force between particles and ion speciation calculations. The results indicated that the dispersion and flocculation behavior of muscovite particles without excess ions were in qualitative agreement with the classical DLVO theory. The muscovite particles aggregated mainly due to basal surface-edge interactions in acidic suspensions but were dispersed in alkaline suspension by electrostatic repulsion of the total particle surface. In acidic suspensions, the ability of muscovite to form dispersions of muscovite was increased with the decrease in the electrostatic attraction between the basal surface and the edge caused by the compression of the electric double layers withCa2+ and Mg2+. In alkaline suspension, the main adsorption form of Ca2+ and Mg2+ on muscovite surface was the ion-hydroxy complexes. The flocculation behavior of muscovite was affected by the static bridge effect of the ion-hydroxy complexes. Full article
(This article belongs to the Special Issue Mineral Surface Science and Nanogeoscience)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Particle size of the sample.</p>
Full article ">Figure 2
<p>The effect of pH value on dispersion and flocculation of mineral with the presence of Ca<sup>2+</sup>.</p>
Full article ">Figure 3
<p>Effect of pH value on dispersion and flocculation of mineral with the presence of Mg<sup>2+</sup>.</p>
Full article ">Figure 4
<p>Zeta potentials of muscovite as a function of pH in deionized water with Ca<sup>2+</sup> and Mg<sup>2+</sup>.</p>
Full article ">Figure 5
<p>Total interaction energy of particles at different pH values without and with Ca<sup>2+</sup>, Mg<sup>2+</sup>.</p>
Full article ">Figure 6
<p>Total interaction energy of three kinds of form at different pH values.</p>
Full article ">Figure 7
<p>Calculated concentration of calcium species in solution with 1 × 10<sup>−3</sup> mol/L Ca<sup>2+</sup>.</p>
Full article ">Figure 8
<p>Calculated concentration of magnesium species in solution with 1 × 10<sup>−3</sup> mol/L Mg<sup>2+</sup>.</p>
Full article ">Figure 9
<p>Adsorption capacity of Ca<sup>2+</sup> and Mg<sup>2+</sup> at different pH levels.</p>
Full article ">Figure 10
<p>Bridging effect of hydroxy complex.</p>
Full article ">
2603 KiB  
Article
The Effect of Chloride Ions on the Activity of Cerussite Surfaces
by Qicheng Feng, Shuming Wen, Qinbo Cao, Jiushuai Deng and Wenjuan Zhao
Minerals 2016, 6(3), 92; https://doi.org/10.3390/min6030092 - 6 Sep 2016
Cited by 21 | Viewed by 4679
Abstract
Chloride ions were found to potentially increase activity of cerussite surfaces. Dissolution experiments, zeta potential measurements, X-ray photoelectron spectroscopy (XPS) studies, and density functional theory (DFT) computation were conducted in this study. Dissolution experiments showed that the lead ion concentrations in the NaCl [...] Read more.
Chloride ions were found to potentially increase activity of cerussite surfaces. Dissolution experiments, zeta potential measurements, X-ray photoelectron spectroscopy (XPS) studies, and density functional theory (DFT) computation were conducted in this study. Dissolution experiments showed that the lead ion concentrations in the NaCl solution system were lower than those in the deionized water system and that the lead ion concentrations in NaCl + Na2S aqueous systems decreased by approximately one order of magnitude compared with that in the Na2S system alone. Results of zeta potential measurements revealed that the pretreatment with chloride ions of cerussite caused a more positive zeta potential than that without chloride ions. XPS analysis results indicated that the number of lead ions on the mineral surface increased after cerussite was treated with chloride ions. Results of DFT computation implied that the number of lead atoms on the mineral surface increased and that the activity improved after PbCl+ was adsorbed onto the cerussite surface. The contribution of chloride ions to the activity on the mineral surface is attributed to the increase in the number of active sites and enhancement in the activity of these sites, resulting in improved sulfidization and flotation performance. Full article
(This article belongs to the Special Issue Mineral Surface Science and Nanogeoscience)
Show Figures

Figure 1

Figure 1
<p>Slab model of perfect cerussite (110) surface.</p>
Full article ">Figure 2
<p>Zeta potential of cerussite as a function of pH.</p>
Full article ">Figure 3
<p>C 1s spectra for the mineral surface treated with chloride ions: (<b>a</b>) before; (<b>b</b>) after.</p>
Full article ">Figure 4
<p>O 1s spectra for the mineral surface treated with chloride ions: (<b>a</b>) before; (<b>b</b>) after.</p>
Full article ">Figure 5
<p>Pb 4f spectra for the mineral surface treated with chloride ions: (<b>a</b>) before; (<b>b</b>) after.</p>
Full article ">Figure 6
<p>Adsorption configurations of PbCl<sup>+</sup> on perfect cerussite (110) surface.</p>
Full article ">Figure 7
<p>Density of state of atoms for cerussite surface after PbCl<sup>+</sup> adsorption.</p>
Full article ">Figure 8
<p>Density of state of Pb atoms for perfect cerussite surface: (<b>a</b>) before; (<b>b</b>) after PbCl<sup>+</sup> adsorption.</p>
Full article ">
14187 KiB  
Article
The Cedrolina Chromitite, Goiás State, Brazil: A Metamorphic Puzzle
by Yuri De Melo Portella, Federica Zaccarini, George L. Luvizotto, Giorgio Garuti, Ronald J. Bakker, Nelson Angeli and Oskar Thalhammer
Minerals 2016, 6(3), 91; https://doi.org/10.3390/min6030091 - 1 Sep 2016
Cited by 11 | Viewed by 6541
Abstract
The Cedrolina chromitite body (Goiás-Brazil) is concordantly emplaced within talc-chlorite schists that correspond to the poly-metamorphic product of ultramafic rocks inserted in the Pilar de Goiás Greenstone Belt (Central Brazil). The chromite ore displays a nodular structure consisting of rounded and ellipsoidal orbs [...] Read more.
The Cedrolina chromitite body (Goiás-Brazil) is concordantly emplaced within talc-chlorite schists that correspond to the poly-metamorphic product of ultramafic rocks inserted in the Pilar de Goiás Greenstone Belt (Central Brazil). The chromite ore displays a nodular structure consisting of rounded and ellipsoidal orbs (up to 1.5 cm in size), often strongly deformed and fractured, immersed in a matrix of silicates (mainly chlorite and talc). Chromite is characterized by high Cr# (0.80–0.86), high Fe2+# (0.70–0.94), and low TiO2 (av. = 0.18 wt %) consistent with variation trends of spinels from metamorphic rocks. The chromitite contains a large suite of accessory phases, but only irarsite and laurite are believed to be relicts of the original igneous assemblage, whereas most accessory minerals are thought to be related to hydrothermal fluids that emanated from a nearby felsic intrusion, metamorphism and weathering. Rutile is one of the most abundant accessory minerals described, showing an unusually high Cr2O3 content (up to 39,200 ppm of Cr) and commonly forming large anhedral grains (>100 µm) that fill fractures (within chromite nodules and in the matrix) or contain micro-inclusions of chromite. Using a trace element geothermometer, the rutile crystallization temperature is estimated at 550–600 °C (at 0.4–0.6 GPa), which is in agreement with P and T conditions proposed for the regional greenschist to low amphibolite facies metamorphic peak of the area. Textural, morphological, and compositional evidence confirm that rutile did not crystallize at high temperatures simultaneously with the host chromitite, but as a secondary metamorphic mineral. Rutile may have been formed as a metamorphic overgrowth product following deformation and regional metamorphic events, filling fractures and incorporating chromite fragments. High Cr contents in rutile very likely are due to Cr remobilization from Cr-spinel during metamorphism and suggest that Ti was remobilized to form rutile. This would imply that the magmatic composition of chromite had originally higher Ti content, pointing to a stratiform origin. Another possible interpretation is that the Ti-enrichment was caused by external metasomatic fluids which lead to crystallization of rutile. If this was the case, the Cedrolina chromitites could be classified as podiform, possibly representing a sliver of tectonically dismembered Paleoproterozoic upper mantle. However, the strong metamorphic overprint that affected the studied chromitites makes it extremely difficult to establish which of the above processes were active, if not both (and to what extent), and, therefore, the chromitite’s original geodynamic setting. Full article
(This article belongs to the Special Issue Advanced Research on Accessory Minerals)
Show Figures

Figure 1

Figure 1
<p>Geological sketch maps of Cedrolina chromitites (<b>A</b>,<b>B</b>)—Geographical location of the studied area; (<b>C</b>)—General geology of the central-northern Pilar de Goiás greenstone belt area simplified after [<a href="#B23-minerals-06-00091" class="html-bibr">23</a>]; (<b>D</b>)—Detailed geological map of a small portion of the Cedrolina Formation where the investigated chromitites occur [<a href="#B20-minerals-06-00091" class="html-bibr">20</a>].</p>
Full article ">Figure 2
<p>Simplified petrogenetic grid for metamorphosed mafic rocks modified after [<a href="#B28-minerals-06-00091" class="html-bibr">28</a>]. The red polygon represents the paragenesis hornblende, garnet, andesine, and magnetite (devoid of chlorite and clinopyroxene) described by [<a href="#B20-minerals-06-00091" class="html-bibr">20</a>] in amphibolites and amphibole schists of the Cedrolina Formation indicative of T &gt; 570 °C and Pressures of 0.4–0.6 GPa. Dashed blue lines represent temperatures calculated using the Zr-in-rutile geothermometer for crystals in samples 14, 100, 105, and 106 (for details about the temperature calculations and dataset please refer to the text). Notice that the pressure effect for the 0.2–1.0 GPa range is less than 35 °C. Mineral abbreviations (Ab = albite, Act = actinolite, An = anorthite, Ca-Ts = Ca-tschermakite, Chl = chlorite, Cpx = Ca-clinopyroxene, <span class="html-italic">E</span> = an epidote mineral: epidote, zoisite, or clinozoisite, <span class="html-italic">F</span> = aqueous fluid, Gln = glaucophane, Grt = garnet, Hbl = hornblende, Ky = kyanite, Lws = lawsonite, Mt = magnetite, Ol = olivine, Omp = omphacite, Opx = orthopyroxene, Pg = paragonite, Pl = plagioclase, Qtz = quartz).</p>
Full article ">Figure 3
<p>Hand specimens of the Cedrolina chromitite. (<b>A</b>) Slightly altered dark green chromitite (sample 106A); (<b>B</b>) Initial stage of weathering showing bluish green color of the matrix silicates (sample 100); (<b>C</b>) Moderate weathering exhibiting grayish color (sample 105C); (<b>D</b>) Spherical chromite nodules and minute chromite particles dispersed in the silicate matrix; (<b>E</b>) Intensely weathered rock with whitish-pinkish colored matrix (sample 47B); (<b>F</b>) Hand specimen of a mantle hosted ophiolitic chromitite from Troodos (Cyprus) evidencing nodular “leopard” chromite with coalescent contacts.</p>
Full article ">Figure 4
<p>Backscattered electron images (BSE) of the Cedrolina chromitite. (<b>A</b>) Massive chromite nodule; (<b>B</b>) Fractured chromite nodule; (<b>C</b>,<b>D</b>) Internal texture of the nodules characterized by the presence of euhedral crystals of chromite with very sharp/linear contacts amongst themselves. Fractures superimpose former sharp contacts, resembling a cumulus-type texture; (<b>E</b>) Single large crystal of chromite; (<b>F</b>) Various sizes of euhedral chromite crystals.</p>
Full article ">Figure 5
<p>Binary diagrams showing podiform (P) and stratiform (S) chromite fields where &gt;500 chromite analyses from Cedrolina were plotted (modified after [<a href="#B33-minerals-06-00091" class="html-bibr">33</a>,<a href="#B34-minerals-06-00091" class="html-bibr">34</a>]). (<b>A</b>) TiO<sub>2</sub> vs. Cr<sub>2</sub>O<sub>3</sub>; (<b>B</b>) Cr# vs. Mg#.</p>
Full article ">Figure 6
<p>Ternary Cr–Al–Fe<sup>3+</sup> diagrams exhibiting &gt;500 analyses of chromite from Cedrolina. (<b>A</b>) Modified after [<a href="#B11-minerals-06-00091" class="html-bibr">11</a>], with the fields of different metamorphic facies from [<a href="#B39-minerals-06-00091" class="html-bibr">39</a>,<a href="#B40-minerals-06-00091" class="html-bibr">40</a>,<a href="#B41-minerals-06-00091" class="html-bibr">41</a>]; (<b>B</b>) Stability limits of spinels defined for chromite and magnetite (calculated in equilibrium with Fo90 olivine). Modified after [<a href="#B42-minerals-06-00091" class="html-bibr">42</a>,<a href="#B43-minerals-06-00091" class="html-bibr">43</a>]. Both arrows (black and white) indicate the direction of metamorphic retrogression to greenschist facies.</p>
Full article ">Figure 7
<p>BSE images of different forms of occurrence of rutile in the Cedrolina chromitite (<b>A</b>) Plenty of prismatic micro inclusions (&lt;10 μm) of rutile and chlorite in chromite; (<b>B</b>) Large anhedral/irregular rutile crystal in the chromite/chlorite contact, also exhibiting an included chromite fragment; (<b>C</b>) Anhedral rutile crystal observed in the chromite/matrix interface; (<b>D</b>) Rutile porphyroblasts/prisms concordantly oriented with the metamorphic foliation (Fn is vertical in the photo) and often presenting inclusions of chromite fragments, situated near the edge of a large Cr-spinel aggregate. Area of red rectangle zoomed in (F); (<b>E</b>) Elongated and anomalously large rutile crystal (&gt;250 μm) that fills a fracture between two large chromite fragments; (<b>F</b>) Zoomed area of red rectangle in (D) displaying a rutile porphyroblast with abundant micro-inclusions of chromite fragments. Abbreviations: Chr = chromite; Chl = chlorite; Mtx = matrix; Rtl = rutile; Zrn = zircon.</p>
Full article ">Figure 8
<p>BSE images of zircon crystals in the matrix (sample 105C). (<b>A</b>) and (<b>B</b>) Apparently zoned crystals; (<b>C</b>) Mega-crystal associated with a Th-silicate. The dark gray mass around zircon is gibbsite with thin bands of magnetite (light gray); (<b>D</b>) Zircon crystals in close association with rutile in the matrix. Abbreviations: Chl = chlorite, Chr = chromite, Gbs = gibbsite, Mag = magnetite, Rt = rutile, ThSi = Th-silicate, Zrn = zircon.</p>
Full article ">Figure 9
<p>(<b>A</b>) Zircon BSE image; (<b>B</b>–<b>F</b>) Elemental distribution map.</p>
Full article ">Figure 10
<p>Trace element plots from accessory zircons found in the Cedrolina chromitite. Different source rock fields adapted from [<a href="#B19-minerals-06-00091" class="html-bibr">19</a>]. (<b>A</b>) Hf vs. Y; (<b>B</b>) Y vs. Th; (<b>C</b>) Y vs. U.</p>
Full article ">Figure 11
<p>BSE images of PGM, Au and Ag minerals. (<b>A</b>) Native gold at the chromite/matrix interface; (<b>B</b>) Irarsite included in chromite; (<b>C</b>) Unnamed gold and palladium alloy (Au<sub>3</sub>Pd) in the chromite/matrix interface; (<b>D</b>) Unnamed gold, copper and nickel alloy (Au<sub>3</sub>Cu<sub>3</sub>Ni) in the chromite/matrix interface; (<b>E</b>) Unidentified silver, copper, arsenic and antimony sulfide (possibly pearceite: [(Ag<sub>8</sub>CuS<sub>4</sub>)][(AgCu)<sub>6</sub>(As,Sb)<sub>2</sub>S<sub>7</sub>]) included in chromite; (<b>F</b>) Laurite and irarsite association in the matrix. Abbreviations: (Ag,Cu,As,Sb)S = unidentified sulfide, Au = gold, Au<sub>3</sub>Pd = unnamed PGE alloy, Au<sub>3</sub>Cu<sub>3</sub>Ni = unnamed gold alloy, Chr = chromite, Chl = chlorite, Dol = dolomite, Irs = irarsite, Lrt = laurite, Tlc= talc.</p>
Full article ">
3255 KiB  
Article
The Flotation of Kyanite and Sillimanite with Sodium Oleate as the Collector
by Junxun Jin, Huimin Gao, Zijie Ren and Zhijie Chen
Minerals 2016, 6(3), 90; https://doi.org/10.3390/min6030090 - 31 Aug 2016
Cited by 21 | Viewed by 7721
Abstract
Kyanite and sillimanite are two polymorphic minerals with the same formula of Al2SiO5, but different crystal structures. Despite their high economic values, selectively recovering them by flotation is a challenge. In this study, the flotation behaviors of the two [...] Read more.
Kyanite and sillimanite are two polymorphic minerals with the same formula of Al2SiO5, but different crystal structures. Despite their high economic values, selectively recovering them by flotation is a challenge. In this study, the flotation behaviors of the two minerals with sodium oleate as the collector were examined at different pH conditions. Zeta potential measurement, infrared spectroscopic measurement, chemical speciation and X-ray photoelectron spectroscopy measurement were conducted to identify the underpinning mechanisms. It is found that the flotation behavior of both minerals is different under the same flotation condition. The flotation recovery of sillimanite is much higher than that of kyanite in the presence of the collector sodium oleate. Sodium oleate adsorbs onto the surfaces of kyanite and sillimanite mainly through the chemical interaction of the ionic–molecular dimers with aluminum atoms at pH 8.0. The higher sillimanite flotation recovery between the two minerals is related to the higher electrostatic charge densities of the aluminum atoms in six-fold coordination, which leads to the higher collector adsorption. Full article
(This article belongs to the Special Issue Flotation in Mineral Processing)
Show Figures

Figure 1

Figure 1
<p>The unit cell model of kyanite (<b>a</b>) and sillimanite (<b>b</b>). Atom color: pink = Al, red = O, yellow = Si.</p>
Full article ">Figure 2
<p>Flotation recovery of kyanite and sillimanite as a function of sodium oleate concentration at pH 8.0. Error bars represent mean values of three tests ± standard deviation.</p>
Full article ">Figure 3
<p>Flotation recovery of kyanite and sillimanite as a function of slurry pH at a sodium oleate concentration of 8.0 × 10<sup>−4</sup> mol·L<sup>−1</sup>. Error bars represent mean values of three tests ± standard deviation.</p>
Full article ">Figure 4
<p>Logarithmic concentration of the hydrolysis species at an initial sodium oleate concentration of 8.0 × 10<sup>−4</sup> mol·L<sup>−1</sup>.</p>
Full article ">Figure 5
<p>The infrared spectra of sodium oleate.</p>
Full article ">Figure 6
<p>The infrared spectra of kyanite (<b>a</b>), kyanite treated with sodium oleate (<b>b</b>), sillimanite (<b>c</b>) and sillimanite treated with sodium oleate (<b>d</b>).</p>
Full article ">Figure 7
<p>The enlarged spectra of kyanite (<b>a</b>), kyanite treated with sodium oleate (<b>b</b>), sillimanite (<b>c</b>) and sillimanite treated with sodium oleate (<b>d</b>).</p>
Full article ">Figure 8
<p>Zeta potentials of kyanite and sillimanite as a function of pH. Error bars represent mean values of three tests ± standard deviation.</p>
Full article ">Figure 9
<p>XPS high-resolution spectra of C1s, Al2p, Si2p and O1s on kyanite in the absence and presence of sodium oleate (NaOL).</p>
Full article ">Figure 10
<p>XPS high-resolution spectra of C1s, Al2p, Si2p and O1s on sillimanite in the absence and presence of sodium oleate (NaOL).</p>
Full article ">
3369 KiB  
Article
The Influence of Impurity Monovalent Cations Adsorption on Reconstructed Chalcopyrite (001)-S Surface in Leaching Process
by Zhenlun Wei, Yubiao Li, Qing Xiao and Shaoxian Song
Minerals 2016, 6(3), 89; https://doi.org/10.3390/min6030089 - 29 Aug 2016
Cited by 13 | Viewed by 4305
Abstract
Hydrometallurgical processing of chalcopyrite is hindered predominantly due to the passivation layers formed on the chalcopyrite surface. However, the effects of impurity cations released from the gangue are not yet well understood. Density functional theory (DFT) calculations were carried out to investigate monovalent [...] Read more.
Hydrometallurgical processing of chalcopyrite is hindered predominantly due to the passivation layers formed on the chalcopyrite surface. However, the effects of impurity cations released from the gangue are not yet well understood. Density functional theory (DFT) calculations were carried out to investigate monovalent cations of Na+ and K+ on chalcopyrite (001)-S surface using Materials Studio. The results show that the 3d orbital of Fe and 3p orbital of S predominantly contribute to their activities during chalcopyrite oxidation and dissolution processes. In addition, SO42− is more likely to be adsorbed on one Fe site in the presence of Na+, while it is preferentially adsorbed on two Fe sites in the presence of K+. However, the adsorption of both Na2SO4 and K2SO4 on the chalcopyrite (001)-S surface contributes to the breakage of S–S bonds, indicating that the impurity cations of Na+ and K+ are beneficial to chalcopyrite leaching in a sulfuric environment. The adsorption energy and partial density of states (PDOS) analyses further indicate that the adsorption of Na2SO4 on chalcopyrite (001)-S surface is favored in both -BB (bidentate binuclear ) and -BM (bidentate mononuclear) modes, compared to the adsorption of K2SO4. Full article
(This article belongs to the Special Issue Mineral Surface Science and Nanogeoscience)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>The optimized unit of chalcopyrite.</p>
Full article ">Figure 2
<p>The chalcopyrite (001)-S surface: (<b>a</b>) unrelaxed and (<b>b</b>) relaxed. Distances in Angstroms.</p>
Full article ">Figure 3
<p>The electron density of chalcopyrite (001)-S surfaces: (<b>a</b>) unrelaxed and (<b>b</b>) relaxed.</p>
Full article ">Figure 4
<p>Density of states of chalcopyrite (001)-S surface.</p>
Full article ">Figure 5
<p>Partial density of states of chalcopyrite (001)-S surface.</p>
Full article ">Figure 6
<p>The adsorption sites of SO<sub>4</sub><sup>2−</sup> on the chalcopyrite (001)-S surface: (<b>a</b>) top view; (<b>b</b>) side view. Distances are in angstroms.</p>
Full article ">Figure 7
<p>The most stable configuration of Na<sub>2</sub>SO<sub>4</sub> adsorbed on the (001)-S chalcopyrite surface: (<b>a</b>) top view and (<b>b</b>) side view in -BB mode; (<b>c</b>) top view and (<b>d</b>) side view in -BM mode. Distances are in angstroms.</p>
Full article ">Figure 8
<p>The most stable configuration of K<sub>2</sub>SO<sub>4</sub> adsorbed on the chalcopyrite (001)-S surface: (<b>a</b>) top and (<b>b</b>) side view in -BB mode. Distances are in angstroms.</p>
Full article ">
19136 KiB  
Article
Marine Phosphorites as Potential Resources for Heavy Rare Earth Elements and Yttrium
by James R. Hein, Andrea Koschinsky, Mariah Mikesell, Kira Mizell, Craig R. Glenn and Ray Wood
Minerals 2016, 6(3), 88; https://doi.org/10.3390/min6030088 - 29 Aug 2016
Cited by 58 | Viewed by 10346
Abstract
Marine phosphorites are known to concentrate rare earth elements and yttrium (REY) during early diagenetic formation. Much of the REY data available are decades old and incomplete, and there has not been a systematic study of REY distributions in marine phosphorite deposits that [...] Read more.
Marine phosphorites are known to concentrate rare earth elements and yttrium (REY) during early diagenetic formation. Much of the REY data available are decades old and incomplete, and there has not been a systematic study of REY distributions in marine phosphorite deposits that formed over a range of oceanic environments. Consequently, we initiated this study to determine if marine phosphorite deposits found in the global ocean host REY concentrations of high enough grade to be of economic interest. This paper addresses continental-margin (CM) and open-ocean seamount phosphorites. All 75 samples analyzed are composed predominantly of carbonate fluorapatite and minor detrital and authigenic minerals. CM phosphorites have low total REY contents (mean 161 ppm) and high heavy REY (HREY) complements (mean 49%), while seamount phosphorites have 4–6 times higher individual REY contents (except for Ce, which is subequal; mean ΣREY 727 ppm), and very high HREY complements (mean 60%). The predominant causes of higher concentrations and larger HREY complements in seamount phosphorites compared to CM phosphorites are age, changes in seawater REY concentrations over time, water depth of formation, changes in pH and complexing ligands, and differences in organic carbon content in the depositional environments. Potential ore deposits with high HREY complements, like the marine phosphorites analyzed here, could help supply the HREY needed for high-tech and green-tech applications without creating an oversupply of the LREY. Full article
(This article belongs to the Special Issue Marine Minerals: From Genesis to Resources)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Location of samples used in this study. See <a href="#app1-minerals-06-00088" class="html-app">Table S1</a> for coordinates.</p>
Full article ">Figure 2
<p>Photographs of seamount phosphorites: (<b>A</b>) cement-supported breccia; cement from carbonate fluorapatite (CFA)-replaced pelagic foraminifera matrix. (<b>B</b>) Massive, layered (<b>A</b>–<b>D</b>), recrystallized phosphorite; protolith cannot be distinguished, low porosity. (<b>C</b>) Massive bed of CFA-replaced foraminifera, with nearly pristine microfossil structure; minor rim cement on foraminifera indurates the rock; very high porosity. (<b>D</b>) CFA-replaced carbonate sand that filled fractures in basalt. Note Fe-Mn crust on at least one surface of each sample.</p>
Full article ">Figure 3
<p>Scatter plot of phosphorus versus calcium for seamount and continental margin phosphorite deposits analyzed here. Arrows show deviations from the carbonate fluorapatite end member (most pure phosphorite) with increasing calcite and detrital/authigenic (Si, Al, and Fe) contents.</p>
Full article ">Figure 4
<p>Bar diagram of mean contents of individual rare earth elements and yttrium for the sample groups studied here; note that the order for each element follows the order in the key.</p>
Full article ">Figure 5
<p>Post Archean Australian Shale-normalized rare earth element plot for mean data of sample groups compared with patterns for Prime Crust Zone (PCZ) crusts, Clarion-Clipperton Zone (CCZ) nodules, and seawater (× 10<sup>9</sup>) at ~2000 m water depth [<a href="#B19-minerals-06-00088" class="html-bibr">19</a>].</p>
Full article ">Figure 6
<p>Bar diagram of ratio of mean REY data for seamount phosphorites and Pacific Prime Crust Zone ferromanganese crusts.</p>
Full article ">Figure 7
<p>Comparison of mean total HREY contents of ferromanganese deposits with seamount and continental margin phosphorites.</p>
Full article ">Figure 8
<p>Bar diagram of mean total REY data for ferromanganese crusts and nodules compared to mean data for seamount and continental margin phosphorites.</p>
Full article ">
2346 KiB  
Article
Restraining Na-Montmorillonite Delamination in Water by Adsorption of Sodium Dodecyl Sulfate or Octadecyl Trimethyl Ammonium Chloride on the Edges
by Hongliang Li, Yunliang Zhao, Tianxing Chen, Yuri Nahmad and Shaoxian Song
Minerals 2016, 6(3), 87; https://doi.org/10.3390/min6030087 - 23 Aug 2016
Cited by 3 | Viewed by 5395
Abstract
The delamination of montmorillonite in water leads to sliming in ore slurry, which is detrimental to mineral flotation and solid/water separation. In this work, the delamination of Na-montmorillonite (Na-MMT) has been restrained by sodium dodecyl sulfate (SDS) or octadecyl trimethyl ammonium chloride (1831) [...] Read more.
The delamination of montmorillonite in water leads to sliming in ore slurry, which is detrimental to mineral flotation and solid/water separation. In this work, the delamination of Na-montmorillonite (Na-MMT) has been restrained by sodium dodecyl sulfate (SDS) or octadecyl trimethyl ammonium chloride (1831) through the adsorption on the edge of the mineral. The experimental results have shown that the pretreatment by adding SDS and 1831 could greatly reduce the Stokes size percentage of −1.1 µm particles in the aqueous Na-MMT suspension. From the X-ray diffractometer (XRD) results, the interlayer spacing of the MMT pre-treated by SDS and 1831 is smaller than that of original MMT particles. Adsorption position of SDS and 1831 on MMT surfaces was analyzed by the measurements of adsorption capacity of SDS and 1831, inductively-coupled plasma spectra, and zeta potential before and after the plane surface of MMT was covered with tetraethylenepentaminecopper ([Cu(tetren)]2+). The results indicated that SDS and 1831 are adsorbed on the edge and the whole surface of Na-MMT, respectively. Delamination of MMT could be well restrained by the adsorption of SDS and 1831 on the edges of MMT. Full article
(This article belongs to the Special Issue Mineral Surface Science and Nanogeoscience)
Show Figures

Figure 1

Figure 1
<p>XRD pattern of MMT sample.</p>
Full article ">Figure 2
<p>Standard curve of SDS and 1831. (<b>a</b>) SDS; and (<b>b</b>) 1831.</p>
Full article ">Figure 3
<p>Stokes percentage of minus 1.1 μm particle in aqueous solutions pre-treated by of SDS and 1831.</p>
Full article ">Figure 4
<p>XRD pattern of MMT particles pre-treated by mechanical chemical adsorption of SDS and 1831.</p>
Full article ">Figure 5
<p>Zeta potential of MMT treated with [Cu(tetren)]<sup>2+</sup>.</p>
Full article ">Figure 6
<p>Adsorption capacity of SDS on the surface of original MMT sample and the MMT sample adsorbed with [Cu(tetren)]<sup>2+</sup>.</p>
Full article ">Figure 7
<p>Adsorption capacity of 1831 on the surface of the original MMT sample and the MMT sample adsorbed with [Cu(tetren)]<sup>2+</sup>.</p>
Full article ">Figure 8
<p>Content of Cu in MMT samples treated by different methods.</p>
Full article ">Figure 9
<p>Zeta potential of MMT samples immersed in different concentration of SDS solutions with various pH values.</p>
Full article ">Figure 10
<p>Zeta potential of MMT samples immersed in different concentrations of 1831 solutions with various pH values.</p>
Full article ">Figure 11
<p>Schematic representation of the adsorption position of SDS and 1831 on the surface of MMT particles. ( <span class="html-fig-inline" id="minerals-06-00087-i001"> <img alt="Minerals 06 00087 i001" src="/minerals/minerals-06-00087/article_deploy/html/images/minerals-06-00087-i001.png"/></span>: [Cu(tetren)]<sup>2+</sup>; <span class="html-fig-inline" id="minerals-06-00087-i002"> <img alt="Minerals 06 00087 i002" src="/minerals/minerals-06-00087/article_deploy/html/images/minerals-06-00087-i002.png"/></span>: SDS; <span class="html-fig-inline" id="minerals-06-00087-i003"> <img alt="Minerals 06 00087 i003" src="/minerals/minerals-06-00087/article_deploy/html/images/minerals-06-00087-i003.png"/></span>: 1831).</p>
Full article ">
3637 KiB  
Article
Selective Flocculation Enhanced Magnetic Separation of Ultrafine Disseminated Magnetite Ores
by Tao Su, Tiejun Chen, Yimin Zhang and Peiwei Hu
Minerals 2016, 6(3), 86; https://doi.org/10.3390/min6030086 - 23 Aug 2016
Cited by 15 | Viewed by 5787
Abstract
Simple magnetic separation for a certain magnetite mine with ultrafine disseminated lean ores has resulted in low performance, as the fine sizes and aggregation of ground mineral particles have caused inefficient recovery of the ultrafine minerals. In this study, we attempt to increase [...] Read more.
Simple magnetic separation for a certain magnetite mine with ultrafine disseminated lean ores has resulted in low performance, as the fine sizes and aggregation of ground mineral particles have caused inefficient recovery of the ultrafine minerals. In this study, we attempt to increase the apparent sizes of target mineral particles, and improve the separation indices, by using a multi-stage grinding-dispersion-selective flocculation-weak magnetic separation process. The results showed that under the conditions of 500 g/t sodium hexametaphospate (SHMP) as dispersant, 750 g/t carboxymethyl starch (CMS) as flocculant, agitating at 400 rpm for 10 min, with slurry pH 11, and final grinding fineness of 93.5% less than 0.03 mm, the obtained concentrate contained 62.82% iron, with recovery of 79.12% after multi-stage magnetic separation. Compared to simple magnetic separation, the concentrate’s iron grade increased by 1.26%, and a recovery rate by 5.08%. Fundamental analysis indicated that, in a dispersed state of dispersion, magnetite particles had weaker negative surface charges than quartz, allowing the adsorption of negative CMS ions via hydrogen bonding. Consequently, the aggregate size of the initial concentrate increased from 24.30 to 38.37 μm, accomplishing the goal of selective flocculation, and increasing the indices of separation. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Optical microscope images of simples.</p>
Full article ">Figure 2
<p>The flow-sheet of process.</p>
Full article ">Figure 3
<p>The quantity-quality flow-sheet of simple magnetic separation.</p>
Full article ">Figure 4
<p>Scanning Electronic Microscopy (SEM) and Electron Probe Microanalysis (EPMA) analysis on tailings II.</p>
Full article ">Figure 5
<p>The particle size distributions of products.</p>
Full article ">Figure 6
<p>The effect of dispersants and their amounts.</p>
Full article ">Figure 7
<p>Dispersion rate at different slurry pH.</p>
Full article ">Figure 8
<p>The zeta potential of magnetite and quartz particles.</p>
Full article ">Figure 9
<p>The effects of flocculant types and amounts on concentrate. (<b>a</b>) Iron recovery; (<b>b</b>) Iron grades.</p>
Full article ">Figure 10
<p>The effects of agitator speed on concentrate. (<b>a</b>) Iron recovery; (<b>b</b>) Iron grades.</p>
Full article ">Figure 11
<p>(<b>a</b>) The particle size distributions of rough concentrate before and after flocculation; (<b>b</b>) The particle size distributions of magnetite and quartz before and after flocculation.</p>
Full article ">Figure 12
<p>Infrared spectral analysis.</p>
Full article ">Figure 13
<p>C1 XPS of the flocculated initial concentrate.</p>
Full article ">Figure 14
<p>Fe 2p3/2 and XPS spectrum before and after flocculation. (<b>a</b>) Fe<sub>3</sub>O<sub>4</sub>; (<b>b</b>) SiO<sub>2</sub>.</p>
Full article ">
8715 KiB  
Article
Matrix-Matched Iron-Oxide Laser Ablation ICP-MS U–Pb Geochronology Using Mixed Solution Standards
by Liam Courtney-Davies, Zhiyong Zhu, Cristiana L. Ciobanu, Benjamin P. Wade, Nigel J. Cook, Kathy Ehrig, Alexandre R. Cabral and Allen Kennedy
Minerals 2016, 6(3), 85; https://doi.org/10.3390/min6030085 - 23 Aug 2016
Cited by 35 | Viewed by 7665
Abstract
U–Pb dating of the common iron-oxide hematite (α-Fe2O3), using laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICP-MS), provides unparalleled insight into the timing and processes of mineral deposit formation. Until now, the full potential of this method has been negatively impacted by the [...] Read more.
U–Pb dating of the common iron-oxide hematite (α-Fe2O3), using laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICP-MS), provides unparalleled insight into the timing and processes of mineral deposit formation. Until now, the full potential of this method has been negatively impacted by the lack of suitable matrix-matched standards. To achieve matrix-matching, we report an approach in which a U–Pb solution and ablated material from 99.99% synthetic hematite are simultaneously mixed in a nebulizer chamber and introduced to the ICP-MS. The standard solution contains fixed U- and Pb-isotope ratios, calibrated independently, and aspiration of the isotopically homogeneous solution negates the need for a matrix-matched, isotopically homogenous natural iron-oxide standard. An additional advantage of using the solution is that the individual U–Pb concentrations and isotope ratios can be adjusted to approximate that in the unknown, making the method efficient for dating hematite containing low (~10 ppm) to high (>1 wt %) U concentrations. The above-mentioned advantage to this solution method results in reliable datasets, with arguably-better accuracy in measuring U–Pb ratios than using GJ-1 Zircon as the primary standard, which cannot be employed for such low U concentrations. Statistical overlaps between 207Pb/206Pb weighted average ages (using GJ-1 Zircon) and U–Pb upper intercept ages (using the U–Pb mixed solution method) of two samples from iron-oxide copper-gold (IOCG) deposits in South Australia demonstrate that, although fractionation associated with a non-matrix matched standard does occur when using GJ-1 Zircon as the primary standard, it does not impact the 207Pb/206Pb or upper intercept age. Thus, GJ-1 Zircon can be considered reliable for dating hematite using LA-ICP-MS. Downhole fractionation of 206Pb/238U is observed to occur in spot analyses of hematite. The use of rasters in future studies will hopefully minimize this problem, allowing for matrix-matched data. Using the mixed-solution method in this study, we have validated a published hematite Pb–Pb age for Olympic Dam, and provide a new age (1604 ± 11 Ma) for a second deposit in the same province. These ages are further evidence that the IOCG mineralizing event is tied to large igneous province (LIP) magmatism in the region at ~1.6 Ga. Full article
(This article belongs to the Special Issue Advances in Mineral Analytical Techniques)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Schematic of the sample introduction system displaying the laser-ablation inductively-coupled plasma-mass spectrometry (LA-ICP-MS) system connected to the U–Pb solution and blank HNO<sub>3</sub> solutions.</p>
Full article ">Figure 2
<p>(<b>A</b>) Measured <sup>206</sup>Pb/<sup>238</sup>U ratios of solution standards with different concentrations; (<b>B</b>) <sup>206</sup>Pb/<sup>238</sup>U drifts of adjoining standards. The error bars represent 1 sigma standard error.</p>
Full article ">Figure 3
<p>Sketch map showing the location of the Olympic Cu-Au Province within South Australia, as well as exposed Gawler Range Volcanics and Hiltaba Suite intrusive rocks.</p>
Full article ">Figure 4
<p>Back scattered electron images of U-bearing zoned hematite. (<b>A</b>,<b>B</b>) Hematite (Hm) displaying oscillatory and sectorial zoning expressed as high-U from Olympic Dam (<b>A</b>) and a second sample from another IOCG deposit in the Olympic Cu-Au Province (<b>B</b>) note differences in size, and coarser zones for the latter. Additionally note association with sulphides, bornite (Bn) and chalcopyrite (Cp), respectively; (<b>C</b>,<b>D</b>) low-U hematite from Carajás (CUR-002) showing aggregates of hematite with zones containing U and W in the centers of the lamellae (brighter on BSE images).</p>
Full article ">Figure 5
<p>Conventional concordia plots displaying analyzed grains of high-U hematite from the Olympic Province. The first concordia displays sample OD10-4 analyzed through the U–Pb solution method. The second concordia overlays data from sample PH93 collected through the U–Pb solution method (a) and GJ-1 Zircon (b). Data are given in <a href="#minerals-06-00085-t002" class="html-table">Table 2</a>, <a href="#minerals-06-00085-t003" class="html-table">Table 3</a> and <a href="#minerals-06-00085-t004" class="html-table">Table 4</a>. Note, all U–Pb solution data plots on or above concordia, whereas all GJ-1 Zircon data plots on or below concordia.</p>
Full article ">Figure 6
<p>Conventional concordia plot (<b>a</b>) and Tera-Wasserburg diagram (<b>b</b>) for the low-U sample (CUR-002; Carajás, Brazil). The more robust data points marked in red are included in the age regression. Data given in <a href="#minerals-06-00085-t005" class="html-table">Table 5</a> as “included” are plotted in red, “excluded” as grey.</p>
Full article ">Figure 7
<p>Time-resolved spectra data produced using IOLITE from data obtained from hematite in Olympic Cu-Au Province samples. Note no downhole fractionation within the solution standard, but significant fractionation of the <sup>206</sup>Pb/<sup>238</sup>U ratio (red), which increases with time during the duration of the spot analysis. The <sup>207</sup>Pb/<sup>206</sup>Pb ratio (green) remains relatively constant throughout analysis, showing the robustness of the <sup>207</sup>Pb/<sup>206</sup>Pb ages. This represents a minor disadvantage of the method but may be overcome in the future through linear rastering rather than spot analysis, if the homogeneity of the analyzed grain allows this.</p>
Full article ">
6428 KiB  
Article
Phytomining for Artisanal Gold Mine Tailings Management
by Baiq Dewi Krisnayanti, Christopher W.N. Anderson, S. Sukartono, Yusrin Afandi, Herman Suheri and Ardiana Ekawanti
Minerals 2016, 6(3), 84; https://doi.org/10.3390/min6030084 - 15 Aug 2016
Cited by 22 | Viewed by 10594
Abstract
Mine tailings are generally disposed of by artisanal and small scale gold miners in poorly constructed containment areas and this leads to environmental risk. Gold phytomining could be a possible option for tailings management at artisanal and small-scale gold mining (ASGM) locations where [...] Read more.
Mine tailings are generally disposed of by artisanal and small scale gold miners in poorly constructed containment areas and this leads to environmental risk. Gold phytomining could be a possible option for tailings management at artisanal and small-scale gold mining (ASGM) locations where plants accumulate residual gold in their above ground biomass. The value of metal recovered from plants could offset some of the costs of environmental management. Getting gold into plants has been repeatedly demonstrated by many research groups; however, a simple working technology to get gold out of plants is less well described. A field experiment to assess the relevance of the technology to artisanal miners was conducted in Central Lombok, Indonesia between April and June 2015. Tobacco was planted in cyanidation tailings (1 mg/kg gold) and grown for 2.5 months before the entire plot area was irrigated with NaCN to induce metal uptake. Biomass was then harvested (100 kg), air dried, and ashed by miners in equipment currently used to ash activated carbon at the end of a cyanide leach circuit. Borax and silver as a collector metal were added to the tobacco ash and smelted at high temperature to extract metals from the ash. The mass of the final bullion (39 g) was greater than the mass of silver used as a collector (31 g), indicating recovery of metals from the biomass through the smelt process. The gold yield of this trial was low (1.2 mg/kg dry weight biomass concentration), indicating that considerable work must still be done to optimise valuable metal recovery by plants at the field scale. However, the described method to process the biomass was technically feasible, and represents a valid technique that artisanal and small-scale gold miners are willing to adopt if the economic case is good. Full article
(This article belongs to the Special Issue Biotechnologies and Mining)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Location of the phytomining demonstration trial in Pringgarata District, Central Lombok Regency, West Nusa Tenggara, Indonesia.</p>
Full article ">Figure 2
<p>Tobacco plants before (<b>a</b>) and after (<b>b</b>) irrigation of the tailings surface with NaCN.</p>
Full article ">Figure 3
<p>Loading the sun dried biomass into a steel drum (<b>a</b>) and burning the biomass to generate a plant ash (<b>b</b>).</p>
Full article ">Figure 4
<p>Mixture of plant ash and borax (<b>a</b>) and smelting the tobacco ash (<b>b</b>).</p>
Full article ">Figure 5
<p>Final extraction process using silver as a collector metal before (<b>a</b>) and during smelting (<b>b</b>).</p>
Full article ">
5533 KiB  
Article
Kinetics and Mechanisms of Chalcopyrite Dissolution at Controlled Redox Potential of 750 mV in Sulfuric Acid Solution
by Yubiao Li, Zhenlun Wei, Gujie Qian, Jun Li and Andrea R. Gerson
Minerals 2016, 6(3), 83; https://doi.org/10.3390/min6030083 - 10 Aug 2016
Cited by 25 | Viewed by 6060
Abstract
To better understand chalcopyrite leach mechanisms and kinetics, for improved Cu extraction during hydrometallurgical processing, chalcopyrite leaching has been conducted at solution redox potential 750 mV, 35–75 °C, and pH 1.0 with and without aqueous iron addition, and pH 1.5 and 2.0 without [...] Read more.
To better understand chalcopyrite leach mechanisms and kinetics, for improved Cu extraction during hydrometallurgical processing, chalcopyrite leaching has been conducted at solution redox potential 750 mV, 35–75 °C, and pH 1.0 with and without aqueous iron addition, and pH 1.5 and 2.0 without aqueous iron addition. The activation energy (Ea) values derived indicate chalcopyrite dissolution is initially surface chemical reaction controlled, which is associated with the activities of Fe3+ and H+ with reaction orders of 0.12 and −0.28, respectively. A surface diffusion controlled mechanism is proposed for the later leaching stage with correspondingly low Ea values. Surface analyses indicate surface products (predominantly Sn2− and S0) did not inhibit chalcopyrite dissolution, consistent with the increased surface area normalised leach rate during the later stage. The addition of aqueous iron plays an important role in accelerating Cu leaching rates, especially at lower temperature, primarily by reducing the length of time of the initial surface chemical reaction controlled stage. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Cu concentrations and % extraction versus time for leaching experiments at 750 mV at 35, 43, 50, 65 and 75 °C: (<b>a</b>) pH 1.0, no iron addition; (<b>b</b>) pH 1.0 with 4 mmol iron addition; (<b>c</b>) pH 1.5, no iron addition; (<b>d</b>) pH 2.0, no iron addition; (<b>e</b>) Fe concentration versus Cu concentration at 750 mV, 75 °C and pH 1.0–2.0.</p>
Full article ">Figure 2
<p>Comparison of the free Fe<sup>3+</sup>/Fe<sup>2+</sup> activity ratio calculated using the Nernst Equation (Equation (2)) and the PHREEQC solution speciation simulation software.</p>
Full article ">Figure 3
<p><math display="inline"> <semantics> <mrow> <msub> <mi>E</mi> <mi mathvariant="normal">a</mi> </msub> </mrow> </semantics> </math> (kJ·mol<sup>−1</sup>) calculation based on leaching with (<b>a</b>) &lt;10% Cu extraction; (<b>b</b>) 20%–80% Cu extraction.</p>
Full article ">Figure 4
<p>Predicted and measured log <span class="html-italic">r</span> for &lt;10% Cu extraction at 750 mV, 35–75 °C, pH 1.0 (with and without iron addition), 1.5 and 2.0 without iron addition.</p>
Full article ">Figure 5
<p>Relative surface area normalised leach rate and Cu extraction (%) against leach time for leaching at pH 1.0, 43 °C and 750 mV without iron addition. The large estimated errors for the last few data points are due to error propagation based on both experimental and fitting errors.</p>
Full article ">Figure 6
<p>High-resolution S 2<span class="html-italic">p</span> XP spectra collected from chalcopyrite leached for 1 h at 750 mV, 75 °C and pH 1.0 without iron addition.</p>
Full article ">Figure 7
<p>Fe 2<span class="html-italic">p</span> XP spectra collected from chalcopyrite leached at 750 mV, 75 °C and pH 1.0 for (<b>a</b>) 1 h and (<b>b</b>) 30 h both without iron addition and for (<b>c</b>) 1 h and (<b>d</b>) 30 h with iron addition.</p>
Full article ">Figure 8
<p>SEM images of final residues collected from leaches carried out at 750 mV, pH 1.0 without iron addition at: (<b>a</b>) 35 °C, (<b>b</b>) 43 °C, (<b>c</b>) 50 °C, (<b>d</b>) 65 °C, (<b>e</b>) 75 °C; pH 2.0 without iron addition at: (<b>f</b>) 35 °C, (<b>g</b>) 43 °C, (<b>h</b>) 50 °C, (<b>i</b>) 65 °C, (<b>j</b>) selected particle from (<b>i</b>), (<b>k</b>) 75 °C; (<b>l</b>) ED spectra from selected area shown in (<b>j</b>).</p>
Full article ">Figure 9
<p>SEM images collected from chalcopyrite leached with 4 mmol added iron at 750 mV and 75 °C for (<b>a</b>) 1 h, (<b>b</b>) 30 h, (<b>c</b>) 72 h; without iron addition for (<b>d</b>) 1 h, (<b>e</b>) 30 h, (<b>f</b>) 72 h.</p>
Full article ">
1589 KiB  
Article
Pre-Concentration of Vanadium from Stone Coal by Gravity Using Fine Mineral Spiral
by Xin Liu, Yimin Zhang, Tao Liu, Zhenlei Cai and Kun Sun
Minerals 2016, 6(3), 82; https://doi.org/10.3390/min6030082 - 4 Aug 2016
Cited by 21 | Viewed by 6299
Abstract
Due to the low grade of V2O5 in stone coal, the existing vanadium extraction technologies face challenges in terms of large handling capacity, high acid consumption and production cost. The pre-concentration of vanadium from stone coal before the extraction process [...] Read more.
Due to the low grade of V2O5 in stone coal, the existing vanadium extraction technologies face challenges in terms of large handling capacity, high acid consumption and production cost. The pre-concentration of vanadium from stone coal before the extraction process is an effective method to reduce cost. In this study, detailed mineral characterization of stone coal was investigated. It has been confirmed that the vanadium mainly occurs in muscovite and illite. A significant demand for an effective pre-concentration process with simple manipulation for discarding quartz and other gangue minerals is expected. Based on the mineralogical study, a new vanadium pre-concentration process using a fine mineral spiral was investigated. The experimental results showed that the separation process, which was comprised of a rougher and scavenger, could efficiently discard quartz, pyrite and apatite. A final concentrate with V2O5 grade of 1.02% and recovery of 89.6% could be obtained, with 26.9% of the raw ore being discarded as final tailings. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Schematic set-up of spiral (<b>a</b>), and a sectional view of spiral trough flow (<b>b</b>).</p>
Full article ">Figure 2
<p>X-ray diffraction (XRD) pattern of raw sample, the final concentrate (FC) and the final tailings (FT).</p>
Full article ">Figure 3
<p>V<sub>2</sub>O<sub>5</sub> grade and distribution rate of each size fraction of grinding product and the raw sample.</p>
Full article ">Figure 4
<p>Tailing V<sub>2</sub>O<sub>5</sub> grade vs. tailing mass rate of different wash water flow rate (WWFR: wash water flow rate).</p>
Full article ">Figure 5
<p>V<sub>2</sub>O<sub>5</sub> recovery in concentrate, middling and tailing of each size fraction.</p>
Full article ">Figure 6
<p>Flowsheet for the pre-concentration of vanadium from stone coal (GPD: ground pulp density, WWFR: wash water flow rate, FR: feed rate, FSSC: feed slurry solid concentration).</p>
Full article ">Figure 7
<p>Chemical compositions of FT and FC.</p>
Full article ">
7359 KiB  
Article
Modeling of Geometric Change Influence on Blast-Wave Propagation in Underground Airways Using a 2D-Transient Euler Scheme
by Liang Wang, Sisi Que, Jerry C. Tien and Nassib S. Aouad
Minerals 2016, 6(3), 81; https://doi.org/10.3390/min6030081 - 3 Aug 2016
Viewed by 4095
Abstract
The impact of methane explosions on mining operations can never be over-emphasized. The safety of miners could be threatened and local ventilation facilities are likely to be damaged by the flame and overpressure induced by a methane explosion event, making it essential to [...] Read more.
The impact of methane explosions on mining operations can never be over-emphasized. The safety of miners could be threatened and local ventilation facilities are likely to be damaged by the flame and overpressure induced by a methane explosion event, making it essential to understand the destructiveness and influence range of a specific explosion. In this paper, the attenuation effect of geometric changes, most commonly bends, obstacles, and branches, present in the way of blast-wave propagation and the capability of the selected numerical model were studied. Although some relevant experimental research has been provided, quantitative analysis is insufficient. This paper investigates the attenuation factors of seven bends, three obstacles, and two T-branch scenarios to ascertain a better insight of this potentially devastating event quantitatively. The results suggest that (1) the numerical model used is capable of predicting four of the seven validated scenarios with a relative error less than 12%; (2) the maximum peak overpressure is obtained when the angle equals 50° for bend cases; and (3) the selected numerical scheme would overestimate the obstacle cases by around 15%. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Schematic of the methane explosion experiment system (not to scale).</p>
Full article ">Figure 2
<p>Regions of the methane explosion process in a duct [<a href="#B15-minerals-06-00081" class="html-bibr">15</a>].</p>
Full article ">Figure 3
<p>Pressure sensor layout and high overpressure region.</p>
Full article ">Figure 4
<p>Overpressure gradient contours for a blast-wave propagating through a 30° bend after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000682 s and (<b>f</b>) 0.00137 s.</p>
Full article ">Figure 5
<p>Overpressure histories upstream and downstream of the 30° bend.</p>
Full article ">Figure 6
<p>Overpressure gradient contours for blast-wave propagating through a 40° bend at (<b>a</b>) 25 time steps, (<b>b</b>) 100 time steps, (<b>c</b>) 200 time steps, (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000691 s and (<b>f</b>) 0.00158 s.</p>
Full article ">Figure 7
<p>Overpressure gradient contours for blast-wave propagating through 50° bend at (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000595 s and (<b>f</b>) 0.00149 s.</p>
Full article ">Figure 8
<p>Overpressure gradient contours for blast-wave propagating through 90° bend after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.00136 s and (<b>f</b>) 0.00161 s.</p>
Full article ">Figure 8 Cont.
<p>Overpressure gradient contours for blast-wave propagating through 90° bend after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.00136 s and (<b>f</b>) 0.00161 s.</p>
Full article ">Figure 9
<p>Overpressure gradient contours for blast-wave propagating through 120° bend after (<b>a</b>) 25 time steps, (<b>b</b>) 100 time steps, (<b>c</b>) 200 time steps, (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000679 s and (<b>f</b>) 0.00158 s.</p>
Full article ">Figure 9 Cont.
<p>Overpressure gradient contours for blast-wave propagating through 120° bend after (<b>a</b>) 25 time steps, (<b>b</b>) 100 time steps, (<b>c</b>) 200 time steps, (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000679 s and (<b>f</b>) 0.00158 s.</p>
Full article ">Figure 10
<p>Overpressure gradient contours for blast-wave propagating through 140° bend after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000692 s and (<b>f</b>) 0.00164 s.</p>
Full article ">Figure 11
<p>Overpressure gradient contours for blast-wave propagating through 160° bend after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.000695 s and (<b>f</b>) 0.00159 s.</p>
Full article ">Figure 12
<p>Overpressure histories upstream and downstream of (<b>a</b>) 40°; (<b>b</b>) 50°; (<b>c</b>) 90°; (<b>d</b>) 120°; (<b>e</b>) 140°; and (<b>f</b>) 160° bends.</p>
Full article ">Figure 13
<p>Overpressure gradient contours for the blast-wave propagating through obstacles with a BR of 25% after (<b>a</b>) 25 time steps; (<b>b</b>) 100 time steps; (<b>c</b>) 200 time steps; (<b>d</b>) 300 time steps; and at (<b>e</b>) 0.00183 s and (<b>f</b>) 0.00215 s; (<b>g</b>) shows the location of the obstacle in experimental and numerical explosion ducts.</p>
Full article ">Figure 14
<p>Overpressure histories upstream and downstream of BR 25%.</p>
Full article ">Figure 15
<p>Overpressure histories upstream and downstream of (<b>a</b>) BR 50% and (<b>b</b>) BR 75%.</p>
Full article ">Figure 16
<p>Overpressure gradient contours for a blast-wave propagating through the T-branch (<b>a</b>) flow from the branch arm and (<b>b</b>) flow from the main arm when the downstream sensors reach maximum overpressures.</p>
Full article ">Figure 17
<p>Overpressure histories upstream and downstream of the T-branch flows from the (<b>a</b>) main arm and (<b>b</b>) branch arm.</p>
Full article ">Figure 18
<p>Comparison of simulation and experimental attenuation factors for the bends.</p>
Full article ">Figure 19
<p>Comparison of simulation and experimental attenuation factors for obstacles.</p>
Full article ">
15726 KiB  
Article
Microstructural Control on Perlite Expansibility and Geochemical Balance with a Novel Application of Isocon Analysis: An Example from Milos Island Perlite (Greece)
by Basilios Tsikouras, Kalliopi-Sofia Passa, Ioannis Iliopoulos and Christos Katagas
Minerals 2016, 6(3), 80; https://doi.org/10.3390/min6030080 - 2 Aug 2016
Cited by 10 | Viewed by 6259
Abstract
Representative perlite bulk rock samples from two areas of Milos Island, Greece were collected and the expansion properties of their industrial product were investigated. Coarse crude perlite from Tsigrado exhibits better expansibility, which is assigned to the presence of coarser crystallites in its [...] Read more.
Representative perlite bulk rock samples from two areas of Milos Island, Greece were collected and the expansion properties of their industrial product were investigated. Coarse crude perlite from Tsigrado exhibits better expansibility, which is assigned to the presence of coarser crystallites in its bulk parent rock. During thermal treatment, the finer crystallites of the coarse crude perlite from Trachilas are entrapped in the groundmass and lead to overheating, which inhibits expansion and eventually results in shrinkage. Geochemical modification of the expanded perlites relative to their crude precursors were investigated, using the isocon method. Volatilisation of crystalline water is the main factor controlling mass reduction of the expanded perlites. Other elements, during the adequate expansion of the Tsigrado perlite, can be classified into three categories. The elements that participate preferentially in crystals decrease in the expanded material at amounts higher than the total mass loss of the rock, due to their escape controlled mainly by the removal of the crystalline phases. The elements equally participating in crystals and the groundmass show losses equivalent to the total mass loss of the rocks, as they escaped in the crystalline phases and airborne particles from the groundmass during thermal treatment. Decrease of highly incompatible elements, which mostly participate in the groundmass, in the expanded products is less than the total mass loss, as they escaped mainly in the airborne particles. The inadequate expansion and burst of the Trachilas perlite did not allow for a similar categorisation, due to random and unpredictable escape of the elements. We propose the application of this method to an artificial system to predict unexpandable mineral phases in bulk perlite, as well as elements that are most likely to participate in the amorphous perlite phase, which cannot be determined from a regular industrial production line. This graphical method may also predict environmental pollution of the atmosphere from the release of volatile compounds and airborne particles during thermal treatment of perlite or other processes of mineral treatment. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>XRD patterns of two 1.18–2.5 mm crude perlite samples from Milos Island and their expanded counterparts: (<b>a</b>) Tsigrado area (sample TS1) and (<b>b</b>) Trachilas area (sample TR1). For clarity, patterns of the expanded samples have been shifted 400 counts along the <span class="html-italic">y</span>-axis. Qz: quartz; Pl: plagioclase; Kfs: K-feldspar; Mc: mica; Phg: phengite; Spl: spinel; Ilm: ilmenite; Zrn: zircon.</p>
Full article ">Figure 2
<p>Secondary electron images of 1.18–2.5 mm industrial size fraction of Tsigrado perlite sample: (<b>a</b>–<b>c</b>) crude perlite and (<b>d</b>–<b>f</b>) its expanded counterpart. 1: voids; 2: pumiceous microstructure; 3: elongated vesicles; 4: pockets of coalesced vesicles; 5: crystalline patches; 6: expanded perlite sherds; 7: open pores; 8: closed pores; 9: thin-walled bubbles; and 10: microspheres.</p>
Full article ">Figure 3
<p>Secondary electron images of 1.18–2.5 mm industrial size fraction of Trachilas perlite sample: (<b>a</b>–<b>c</b>) crude perlite; (<b>d</b>–<b>f</b>) its expanded counterpart. 1: voids; 2: perlitic microcracks; 3: pumiceous microstructure; 4: pipes; 5: crystalline patches; 6: expanded perlite sherds; 7: intact glassy groundmass; 8: crystalline inclusions; 9: compact microspheres and 10: cracks.</p>
Full article ">Figure 4
<p>Plot of isocon analysis for crude 1.18–2.5 mm perlite expansion from Tsigrado (<b>a</b>–<b>d</b>) and Trachilas (<b>e</b>) areas. Insets in diagrams show sample numbers. The abscissa and the ordinate represent original (CCP) and altered (expanded) elemental concentrations, respectively. Isocon lines are drawn on the basis of the calculated mass losses (<a href="#minerals-06-00080-t001" class="html-table">Table 1</a>). Major elements plotted as weight percent, trace and rare earth elements as ppm. Scaling factors are given in <a href="#app1-minerals-06-00080" class="html-app">Table S1</a> (see online <a href="#app1-minerals-06-00080" class="html-app">Supplementary Materials</a>).</p>
Full article ">Figure 4 Cont.
<p>Plot of isocon analysis for crude 1.18–2.5 mm perlite expansion from Tsigrado (<b>a</b>–<b>d</b>) and Trachilas (<b>e</b>) areas. Insets in diagrams show sample numbers. The abscissa and the ordinate represent original (CCP) and altered (expanded) elemental concentrations, respectively. Isocon lines are drawn on the basis of the calculated mass losses (<a href="#minerals-06-00080-t001" class="html-table">Table 1</a>). Major elements plotted as weight percent, trace and rare earth elements as ppm. Scaling factors are given in <a href="#app1-minerals-06-00080" class="html-app">Table S1</a> (see online <a href="#app1-minerals-06-00080" class="html-app">Supplementary Materials</a>).</p>
Full article ">
1585 KiB  
Article
Stability of Naturally Relevant Ternary Phases in the Cu–Sn–S System in Contact with an Aqueous Solution
by Andrea Giaccherini, Giordano Montegrossi and Francesco Di Benedetto
Minerals 2016, 6(3), 79; https://doi.org/10.3390/min6030079 - 26 Jul 2016
Cited by 12 | Viewed by 6137
Abstract
A relevant research effort is devoted to the synthesis and characterization of phases belonging to the ternary system Cu–Sn–S, mainly for their possible applications in semiconductor technology. Among all ternary phases, kuramite, Cu3SnS4, mohite, Cu2SnS3, [...] Read more.
A relevant research effort is devoted to the synthesis and characterization of phases belonging to the ternary system Cu–Sn–S, mainly for their possible applications in semiconductor technology. Among all ternary phases, kuramite, Cu3SnS4, mohite, Cu2SnS3, and Cu4Sn7S16 have attracted the highest interest. Numerous studies were carried out claiming for the description of new phases in the ternary compositional field. In this study, we revise the existing literature on this ternary system, with a special focus on the phases stable in a temperature range at 25 °C. The only two ternary phases observed in nature are mohite and kuramite. Their occurrence is described as very rare. A numerical modelling of the stable solid phases in contact with a water solution was underwent to define stability relationships of the relevant phases of the system. The numerical modelling of the Eh-pH diagrams was carried out through the phreeqc software with the lnll.dat thermodynamic database. Owing to the complexity of this task, the subsystems Cu–O–H, Sn–O–H, Cu–S–O–H and Sn–S–O–H were firstly considered. The first Pourbaix diagram for the two naturally relevant ternary phases is then proposed. Full article
(This article belongs to the Special Issue Advanced Research on Accessory Minerals)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Ternary Cu–Sn–S system, reporting the phases found in nature (purple spheres), those reported as stable at room temperature (RT, black spheres) and those reported as stable at temperature values &gt; 400 °C (HT, high temperature, blue diamonds).</p>
Full article ">Figure 2
<p>Eh-pH diagrams of: (<b>a</b>) the Cu–O–H system, calculated assuming [Cu] = 10<sup>−6</sup> mol/kgw; (<b>b</b>) the Sn–O–H system, calculated assuming [Sn] = 10<sup>−8</sup> mol/kgw.</p>
Full article ">Figure 3
<p>Eh-pH diagrams of: (<b>a</b>) the Cu–S–O–H system, calculated assuming [Cu] = 10<sup>−6</sup> mol/kgw and [S] = 10<sup>−3</sup> mol/kgw; (<b>b</b>) the Sn–S–O–H system, calculated assuming [Sn] = 10<sup>−8</sup> mol/kgw and [S] = 10<sup>−3</sup> mol/kgw.</p>
Full article ">Figure 4
<p>Eh-pH diagrams of the Cu–Sn–S–O–H system, calculated assuming [Cu] = 10<sup>−6</sup> mol/kgw, [Sn] = 10<sup>−6</sup> mol/kgw and [S] = 10<sup>−3</sup> mol/kgw. (<b>a</b>) Diagram for the Cu species; (<b>b</b>) diagram for the Sn species.</p>
Full article ">Figure 5
<p>Stability fields for mohite (<b>a</b>) and kuramite (<b>b</b>) evaluated with respect to the Cu (<b>black</b> boundaries) and Sn (<b>red</b> boundaries) species. The calculation conditions are the same of the <a href="#minerals-06-00079-f005" class="html-fig">Figure 5</a>.</p>
Full article ">
11065 KiB  
Article
Characterization of Coal Micro-Pore Structure and Simulation on the Seepage Rules of Low-Pressure Water Based on CT Scanning Data
by Gang Zhou, Qi Zhang, Ruonan Bai and Guanhua Ni
Minerals 2016, 6(3), 78; https://doi.org/10.3390/min6030078 - 26 Jul 2016
Cited by 50 | Viewed by 7777
Abstract
This paper used the X-ray three-dimensional (3D) microscope and acquired, through CT scanning, the 3D data of the long-frame coal sample from the Daliuta Coal Mine. Then, the 3D datacube reconstructed from the coal’s CT scanning data was visualized with the use of [...] Read more.
This paper used the X-ray three-dimensional (3D) microscope and acquired, through CT scanning, the 3D data of the long-frame coal sample from the Daliuta Coal Mine. Then, the 3D datacube reconstructed from the coal’s CT scanning data was visualized with the use of Avizo, an advanced visualization software (FEI, Hillsboro, OR, USA). By means of a gray-scale segmentation technique, the model of the coal’s micro-pore structure was extracted from the object region, and the precise characterization was then conducted. Finally, the numerical simulation on the water seepage characteristics in the coal micro-pores model under the pressure of 3 MPa was performed on the CFX platform. Results show that the seepage of low-pressure water exhibited preference to the channels with large pore radii, short paths, and short distance from the outlet. The seepage pressure of low-pressure water decreased gradually along the seepage direction, while the seepage velocity of low-pressure water decreased gradually along the direction from the pore center to the wall. Regarding the single-channel seepage behaviors, the seepage velocity and mass flow rate of water seepage in the X direction were the largest, followed by the values of the seepage in the Y direction, and the seepage velocity and mass flow rate of water seepage in the Z direction were the smallest. Compared with the results in single-channel seepage, the dual-channel seepage in the direction of (X + Y) and the multi-channel seepage in the direction of (X + Y + Z) exhibited significant increases in the overall seepage velocity. The present study extends the application of 3D CT scanning data and provides a new idea and approach for exploring the seepage rules in coal micro-pore structures. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>X-ray 3D microscope (NanoVoxel-2000).</p>
Full article ">Figure 2
<p>Diameter measurement of the ore core.</p>
Full article ">Figure 3
<p>Profile image of the reconstructed 3D model: (<b>a</b>) Four-View; (<b>b</b>) 512th layer profile on the <span class="html-italic">XY</span> plane; and (<b>c</b>) 420th layer profile on the <span class="html-italic">ZY</span> plane.</p>
Full article ">Figure 4
<p>Component distribution.</p>
Full article ">Figure 5
<p>Original Pore image.</p>
Full article ">Figure 6
<p>Pore image after processing.</p>
Full article ">Figure 7
<p>Data cube selected in the reconstructed digital coal body.</p>
Full article ">Figure 8
<p>Model of micro-pore structure: (<b>a</b>) Before the optimization; and (<b>b</b>) after the optimization.</p>
Full article ">Figure 9
<p>Optimization of coal micro-pore model and mesh generation on the ICEM platform:(<b>a</b>) Repair on the micro-pore structure model; (<b>b</b>) segmentation of islands; (<b>c</b>) deletion of islands;(<b>d</b>) establishment of topological structure; (<b>e</b>) setting of the import and export conditions; and (<b>f</b>) mesh generation.</p>
Full article ">Figure 10
<p>Distributions of pressure subject to low-pressure water along a single-channel in <span class="html-italic">X</span>, <span class="html-italic">Y</span>, and <span class="html-italic">Z</span> directions: (<b>a</b>) <span class="html-italic">X</span> direction; (<b>b</b>) <span class="html-italic">Y</span> direction; and (<b>c</b>) <span class="html-italic">Z</span> direction.</p>
Full article ">Figure 11
<p>Distributions of seepage velocity subject to low-pressure water along single-channel in <span class="html-italic">X</span>, <span class="html-italic">Y</span>, and <span class="html-italic">Z</span> directions: (<b>a</b>) <span class="html-italic">X</span> direction; (<b>b</b>) <span class="html-italic">Y</span> direction; and (<b>c</b>) <span class="html-italic">Z</span> direction.</p>
Full article ">Figure 12
<p>Water seepage velocity distribution of different sections of the single channel in the <span class="html-italic">X</span> direction: (<b>a</b>) <span class="html-italic">x</span> = 0 μm; (<b>b</b>) <span class="html-italic">x</span> = 12 μm; (<b>c</b>) <span class="html-italic">x</span> = 24 μm; (<b>d</b>) <span class="html-italic">x</span> = 36 μm; (<b>e</b>) <span class="html-italic">x</span> = 48 μm; and (<b>f</b>) <span class="html-italic">x</span> = 60 μm.</p>
Full article ">Figure 13
<p>Water seepage velocity distribution of different sections of the single channel in the <span class="html-italic">Y</span> direction: (<b>a</b>) <span class="html-italic">x</span> = 0 μm; (<b>b</b>) <span class="html-italic">x</span> = 12 μm; (<b>c</b>) <span class="html-italic">x</span> = 24 μm; (<b>d</b>) <span class="html-italic">x</span> = 36 μm; (<b>e</b>) <span class="html-italic">x</span> = 48 μm; and (<b>f</b>) <span class="html-italic">x</span> = 60 μm.</p>
Full article ">Figure 14
<p>Water seepage velocity distribution of different sections of the single channel in the <span class="html-italic">Z</span> direction: (<b>a</b>) <span class="html-italic">x</span> = 0 μm; (<b>b</b>) <span class="html-italic">x</span> = 12 μm; (<b>c</b>) <span class="html-italic">x</span> = 24 μm; (<b>d</b>) <span class="html-italic">x</span> = 36 μm; (<b>e</b>) <span class="html-italic">x</span> = 48 μm; and (<b>f</b>) <span class="html-italic">x</span>= 60 μm.</p>
Full article ">Figure 15
<p>Mean pressure at different cross-sections.</p>
Full article ">Figure 16
<p>Mean seepage velocity at different cross-sections.</p>
Full article ">Figure 17
<p>Mean mass flow at different cross-sections.</p>
Full article ">Figure 18
<p>Seepage velocity distribution of dual-channels in the <span class="html-italic">X</span> and <span class="html-italic">Y</span> directions: (<b>a</b>) <span class="html-italic">X</span> direction; and (<b>b</b>) <span class="html-italic">Y</span> direction.</p>
Full article ">Figure 19
<p>Seepage velocity distribution of multi-channel in the <span class="html-italic">X</span>, <span class="html-italic">Y</span>, and <span class="html-italic">Z</span> directions: (<b>a</b>) <span class="html-italic">X</span> direction; (<b>b</b>) <span class="html-italic">Y</span> direction; and (<b>c</b>) <span class="html-italic">Z</span> direction.</p>
Full article ">
8768 KiB  
Article
Agates from Kerrouchen (The Atlas Mountains, Morocco): Textural Types and Their Gemmological Characteristics
by Lucyna Natkaniec-Nowak, Magdalena Dumańska-Słowik, Jaroslav Pršek, Marek Lankosz, Paweł Wróbel, Adam Gaweł, Joanna Kowalczyk and Jacek Kocemba
Minerals 2016, 6(3), 77; https://doi.org/10.3390/min6030077 - 26 Jul 2016
Cited by 12 | Viewed by 8587
Abstract
Agate nodules from Kerrouchen (Khénifra Province, Meknés-Tafilalet Region) in Morocco occur in Triassic basalts and reach up to 30 cm in diameter. Monocentric, banded agates—mainly in pastel pink, grey, white and yellow—with infiltration canals (osculum) are observed. Raman microspectroscopy revealed that [...] Read more.
Agate nodules from Kerrouchen (Khénifra Province, Meknés-Tafilalet Region) in Morocco occur in Triassic basalts and reach up to 30 cm in diameter. Monocentric, banded agates—mainly in pastel pink, grey, white and yellow—with infiltration canals (osculum) are observed. Raman microspectroscopy revealed that the agates mainly consist of low quartz and subordinately moganite with distinctive 460 and 501 cm−1 marker bands, respectively. Linear mapping indicated that moganite mainly concentrates in grey zones of the monocentric agate nodules. The other types, polycentric and pseudostalactitic agates, are usually brown and red and contain minerals such as hematite and goethite. They form both regular and irregular mosaics rich in ornamentation. Occasionally, aggregates of copper sulphides or titanium oxides (rutile) can also be observed. These minerals are sometimes accompanied by carbonaceous material marked by 1320 and 1585 cm−1 Raman bands. It seems that formation of agates from Kerrouchen was induced by Si-rich and Fe-moderate fluids. Copper sulphides, rutile, and carbonates (possibly calcite) were most likely incorporated during post-magmatic processes. The origin of solid bitumen can be the result of hydrothermal or hypergenic processes. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Simplified geological map of the Kerrouchen area, modified after Arboleya et al. [<a href="#B16-minerals-06-00077" class="html-bibr">16</a>]. Legend: Miocen and Quaternary: different sediments—alluvial sands, gravels and clays; Cretaceous: conglomerates, flysch, detritic facies; Jurassic: different limestones; Triassic: different types of limestones, basaltic volcanics with agates; Permian: acidic volcanics; Devonian: detritic facies; Ordovician: different shales; Cambrian: limestones and detritic facies.</p>
Full article ">Figure 2
<p>Kerrouchen agates: (<b>A</b>) monocentric agate with osculum, 3.5 × 5.5 × 2.9 cm, greyish white internal and reddish to dark-brown external zone; (<b>B</b>) monocentric agate, 3.2 × 4.1 × 2.1 cm, greyish white to pinkish internal and reddish to dark-brown external zone; (<b>C</b>) pseudostalactie agate, 3.2 × 5.8 × 1.1 cm, light-brown, reddish, orange to greyish-white interior and light-brown external zone; (<b>D</b>) polycentric agate, 6.1 × 4.5 × 1.5 cm, pink, red to orange interior and light-brown external zone; (<b>E</b>) pseudostalactite agate, 3.4 × 4.4 × 0.9 cm, orange, red, brown to greyish-white interior and light-brown external zone; (<b>F</b>) pseudostalactite agate, 2.9 × 6.6 × 1.3 cm, orange, red, brown to greyish-white interior and light-brown external zone; (<b>G</b>) monocentric agate, 3.5 × 6.0 × 1.3 cm, light-brown, orange to greyish-white interior and dark-brown external zone; (<b>H</b>) monocentric agate, 4.0 × 4.3 × 1.1 cm, light-brown to greyish-white interior and dark-brown to red external zone; (<b>I</b>) pseudostalactite agate, 6.2 × 11.5 × 0.5 cm, light-brown, orange to greyish-white interior and light-brown external zone.</p>
Full article ">Figure 3
<p>Images of microtextures in various agate types from Kerrouchen, observed in transmitted and polarized light; 1N and NX: monocentric (<b>A</b>,<b>B</b>); pseudostalactic (<b>C</b>,<b>D</b>,<b>G</b>,<b>H</b>); polycentric (<b>E</b>,<b>F</b>).</p>
Full article ">Figure 4
<p>Backscattered electron (BSE) images of Fe compounds forming different aggregates (<b>A</b>,<b>B</b>,<b>C</b>) and locally accompanied by Cu sulphides (<b>D</b>) in agates from Kerrouchen.</p>
Full article ">Figure 5
<p>3D (<b>B</b>) plots of micro-Raman line map of monocentric agate nodule from the center core towards the outer rim (<b>A</b>) with a diagram showing the ratio of the 501/463 intensities based on peak area measurements along the scan line (<b>C</b>).</p>
Full article ">Figure 6
<p>Microphoto of complex inclusion of hematite, calcite, and organic substance in agate with the related Raman bands.</p>
Full article ">Figure 7
<p>Microphoto of goethite in agate with its Raman spectrum.</p>
Full article ">Figure 8
<p>Microphoto of rutile in agate with its Raman spectrum.</p>
Full article ">Figure 9
<p>The photo of polycentric agate together with maps of characteristic Kα X-ray intensities showing spatial distribution of Fe, Mn, Ti and Cu.</p>
Full article ">Figure 10
<p>Correlations between characteristic X-ray intensities of Fe, Mn, Ti and Cu for polycentric agate.</p>
Full article ">Figure 11
<p>The photo of monocentric agate together with maps of characteristic Kα X-ray intensities showing spatial distribution of Fe, Mn, Ti and Cu.</p>
Full article ">Figure 12
<p>Correlations between characteristic X-ray intensities of Fe, Mn, Ti and Cu for monocentric agate.</p>
Full article ">
3762 KiB  
Article
Influence of Sulfobacillus thermosulfidooxidans on Initial Attachment and Pyrite Leaching by Thermoacidophilic Archaeon Acidianus sp. DSM 29099
by Jing Liu, Qian Li, Wolfgang Sand and Ruiyong Zhang
Minerals 2016, 6(3), 76; https://doi.org/10.3390/min6030076 - 21 Jul 2016
Cited by 13 | Viewed by 4997
Abstract
At the industrial scale, bioleaching of metal sulfides includes two main technologies, tank leaching and heap leaching. Fluctuations in temperature caused by the exothermic reactions in a heap have a pronounced effect on the growth of microbes and composition of mixed microbial populations. [...] Read more.
At the industrial scale, bioleaching of metal sulfides includes two main technologies, tank leaching and heap leaching. Fluctuations in temperature caused by the exothermic reactions in a heap have a pronounced effect on the growth of microbes and composition of mixed microbial populations. Currently, little is known on the influence of pre-colonized mesophiles or moderate thermophiles on the attachment and bioleaching efficiency by thermophiles. The objective of this study was to investigate the interspecies interactions of the moderate thermophile Sulfobacillus thermosulfidooxidans DSM 9293T and the thermophile Acidianus sp. DSM 29099 during initial attachment to and dissolution of pyrite. Our results showed that: (1) Acidianus sp. DSM 29099 interacted with S. thermosulfidooxidansT during initial attachment in mixed cultures. In particular, cell attachment was improved in mixed cultures compared to pure cultures alone; however, no improvement of pyrite leaching in mixed cultures compared with pure cultures was observed; (2) active or inactivated cells of S. thermosulfidooxidansT on pyrite inhibited or showed no influence on the initial attachment of Acidianus sp. DSM 29099, respectively, but both promoted its leaching efficiency; (3) S. thermosulfidooxidansT exudates did not enhance the initial attachment of Acidianus sp. DSM 29099 to pyrite, but greatly facilitated its pyrite dissolution efficiency. Our study provides insights into cell-cell interactions between moderate thermophiles and thermophiles and is helpful for understanding of the microbial interactions in a heap leaching environment. Full article
(This article belongs to the Special Issue Biotechnologies and Mining)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Initial attachment of cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 and <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> to pyrite in pure and mixed cultures. The initial cell number was 1 × 10<sup>8</sup> cells/mL for each pure cultureand Mix 1, and 2 × 10<sup>8</sup> cells/mL for Mix 2, respectively. Cells were cultivated in 50 mL MAC medium (pH 1.7) with 0.2 g/L yeast extract containing 10% pyrite grains (200–500 μm) at 45 °C and 120 rpm.</p>
Full article ">Figure 2
<p>Initial attachment of cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 to pyrite pre-colonized by cells of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup>. Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 (1 × 10<sup>8</sup> cells/mL) were incubated in 50 mL MAC medium (pH 1.7) containing 0.2 g/L yeast extract and 10% (<span class="html-italic">w</span>/<span class="html-italic">v</span>) pyrite grains (200–500 μm) at 65 °C and 120 rpm.</p>
Full article ">Figure 3
<p>Influence of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> exudates on the initial attachment of cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 to pyrite. Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 with an initial cell number of 1 × 10<sup>8</sup> cells/mL were incubated at 65 °C and 120 rpm.</p>
Full article ">Figure 4
<p>Biofilm formation of <span class="html-italic">Acidianus</span> sp. DSM 29099 on pyrite pre-colonized by <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> cells. Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 with an initial cell number of 1 × 10<sup>8</sup> cells/mL were incubated at 65 °C and 120 rpm. A: Biofilms on pyrite pre-colonized by active <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup>. B: Biofilms on pyrite pre-colonized by inactivated <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup>. C: Biofilms on clean pyrite. Numbers behind the letters: days of incubation. Red arrows indicate <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> cells and white arrows indicate <span class="html-italic">Acidianus</span> sp. DSM 29099 cells. All samples were stained by SYTO 9.</p>
Full article ">Figure 5
<p>Influence of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> exudates on biofilms formation of <span class="html-italic">Acidianus</span> sp. DSM 29099 on pyrite. Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 with an initial cell number of 1 × 10<sup>8</sup> cells/mL were incubated at 65 °C and 120 rpm. A: Biofilms on pyrite in the presence of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> exudates. B: Biofilms on pyrite in the culture with additional iron(III) ions (0.5 g/L). C: Biofilms formation with no additions. Numbers behind the letters: days of incubation. All samples were stained by SYTO 9.</p>
Full article ">Figure 6
<p>Pyrite leaching by cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 and <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> in pure and mixed cultures. (<b>A</b>) total iron concentrations; and (<b>B</b>) planktonic cell numbers (solid lines) and pH changes (dot lines).</p>
Full article ">Figure 7
<p>Influence of pre-established biofilms of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> on pyrite leaching by <span class="html-italic">Acidianus</span> sp. DSM 29099. (<b>A</b>) Total iron concentration; and (<b>B</b>) planktonic cell (solid lines) and pH changes (dot lines). Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 with an initial cell number of 1 × 10<sup>8</sup> cells/mL were incubated with 10% (<span class="html-italic">w</span>/<span class="html-italic">v</span>) pyrite grains (200–500 μm) and cultivated at 65 °C and 120 rpm.</p>
Full article ">Figure 8
<p>Influence of <span class="html-italic">S. thermosulfidooxidans</span><sup>T</sup> exudates on pyrite leaching by <span class="html-italic">Acidianus</span> sp. DSM 29099. (<b>A</b>) total iron concentration; and (<b>B</b>) planktonic cell (solid lines) and pH change (dot lines). Cells of <span class="html-italic">Acidianus</span> sp. DSM 29099 with an initial cell number of 1 × 10<sup>8</sup> cells/mL were incubated with 10% (<span class="html-italic">w</span>/<span class="html-italic">v</span>) pyrite grains (200–500 μm) and cultivated at 65 °C and 120 rpm.</p>
Full article ">
2764 KiB  
Article
Selective Leaching of Vanadium from Roasted Stone Coal by Dilute Sulfuric Acid Dephosphorization-Two-Stage Pressure Acid Leaching
by Jun Huang, Yimin Zhang, Jing Huang, Tao Liu, Zhenlei Cai and Nannan Xue
Minerals 2016, 6(3), 75; https://doi.org/10.3390/min6030075 - 21 Jul 2016
Cited by 12 | Viewed by 5155
Abstract
A novel staged leaching process has been reported in this paper to selectively extract vanadium from roasted stone coal and the mechanisms have been clarified. Results showed that the leaching efficiency of V, Al, P and Fe was 80.46%, 12.24%, 0.67% and 3.12%, [...] Read more.
A novel staged leaching process has been reported in this paper to selectively extract vanadium from roasted stone coal and the mechanisms have been clarified. Results showed that the leaching efficiency of V, Al, P and Fe was 80.46%, 12.24%, 0.67% and 3.12%, respectively, under the optimum dilute sulfuric acid dephosphorization (DSAD)-two-stage pressure acid leaching (PAL) conditions. The efficient separation of V from Fe, Al and P was realized. As apatite could be leached more easily than mica, the apatite could completely react with sulfuric acid, while the mica had almost no change in the DSAD process, which was the key aspect in realizing the effective separation of V from P. Similarly, the hydrolyzation of Fe and Al could be initiated more easily than that of V by decreasing the residual acid of leachate. The alunite and iron-sulphate compound generated in the first-stage PAL process resulted in the effective separation of V from Fe and Al. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>X-ray diffraction (XRD) pattern for roasted stone coal.</p>
Full article ">Figure 2
<p>Quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) analysis result for the stone coal roasted residue.</p>
Full article ">Figure 3
<p>Flow sheet of the dilute sulfuric acid dephosphorization (DSAD)-two-stage pressure acid leaching (PAL) process.</p>
Full article ">Figure 4
<p>Effects of sulfuric acid concentration (<b>a</b>); and temperature (<b>b</b>) on the dephosphorization rate and the vanadium loss rate.</p>
Full article ">Figure 5
<p>Effects of the acid pressure leaching (I) parameters on leaching efficiency of V, Al, P, Fe. (<b>a</b>) The initial sulfuric acid concentration of the first stage; (<b>b</b>) the leaching temperature of the first stage.</p>
Full article ">Figure 6
<p>Effects of the acid pressure leaching (II) parameters on leaching efficiency of V, Al, P, Fe. (<b>a</b>) The sulfuric acid concentration of the second stage; (<b>b</b>) the leaching temperature of the second stage.</p>
Full article ">Figure 7
<p>The XRD patterns for roasted stone coal (<b>a</b>); dephosphorization sample (<b>b</b>); leaching residue (I) (<b>c</b>); and leaching residue (II) (<b>d</b>).</p>
Full article ">Figure 8
<p>X-ray photoelectron P 2p, Ca 2p, Fe 2p and Al 2p spectra from roasted stone coal (<b>a</b>); dephosphorization sample (<b>b</b>); leaching residue (I) (<b>c</b>); and leaching residue (II) (<b>d</b>).</p>
Full article ">
35658 KiB  
Article
Origin of Minerals and Elements in the Late Permian Coal Seams of the Shiping Mine, Sichuan, Southwestern China
by Yangbing Luo and Mianping Zheng
Minerals 2016, 6(3), 74; https://doi.org/10.3390/min6030074 - 19 Jul 2016
Cited by 20 | Viewed by 6766
Abstract
Volcanic layers in coal seams in southwestern China coalfields have received much attention given their significance in coal geology studies and their potential economic value. In this study, the mineralogical and geochemical compositions of C19 and C25 coal seams were examined, and the [...] Read more.
Volcanic layers in coal seams in southwestern China coalfields have received much attention given their significance in coal geology studies and their potential economic value. In this study, the mineralogical and geochemical compositions of C19 and C25 coal seams were examined, and the following findings were obtained. (1) Clay minerals in sample C19-r are argillized, and sedimentary layering is not observed. The acicular idiomorphic crystals of apatite and the phenocrysts of Ti-augite coexisting with magnetite in roof sample C19-r are common minerals in basaltic rock. The rare earth elements (REE) distribution pattern of C19-r, which is characterized by positive Eu anomalies and M-REE enrichment, is the same as that of high-Ti basalt. The concentrations of Ti, V, Co, Cr, Ni, Cu, Zn, Nb, Ta, Zr, and Hf in C19-r are closer to those of high-Ti basalt. In conclusion, roof sample C19-r consists of tuffaceous clay, probably with a high-Ti mafic magma source. (2) The geochemical characteristics of the C25 coals are same as those reported for coal affected by alkali volcanic ash, enrichment in Nb, Ta, Zr, Hf, and REE, causing the C25 minable coal seams to have higher potential value. Such a vertical study of coals and host rocks could provide more information for coal-forming depositional environment analysis, for identification of volcanic eruption time and magma intrusion, and for facilitating stratigraphic subdivision and correlation. Full article
(This article belongs to the Special Issue Minerals in Coal)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Distribution of Late Permian Emeishan basalts in southwestern China [<a href="#B13-minerals-06-00074" class="html-bibr">13</a>].</p>
Full article ">Figure 2
<p>The sedimentary sequences of the Shiping mine.</p>
Full article ">Figure 3
<p>Macerals in the coal samples, reflected light, and oil immersion. (<b>A</b>) collodetrinite, collotelinite, semifusinite, and inertodetrinite in sample C25-1; (<b>B</b>) telinite in sample C25-2; (<b>C</b>) vitrodetrinite in sample C25-1; (<b>D</b>) fusinite with swelling cells in sample C25-3; (<b>E</b>) micrinite in sample C25-3; (<b>F</b>) macrinite in sample C25-3.</p>
Full article ">Figure 4
<p>SEM back-scattered electron images of discrete particles and fracture-filling kaolinite in sample C19-1 (<b>A</b>); and cell-filling kaolinite and quartz in sample C25-2 (<b>B</b>).</p>
Full article ">Figure 5
<p>Pyrite in the C25 coal. (<b>A</b>) Particles of pyrite in sample C25-2; (<b>B</b>) cell-filling pyrite in sample C25-3; (<b>C</b>) framboidal pyrite in sample C25-3; (<b>D</b>) needle-like forms combined with marcasite in sample C25-3. Optical microscope, reflected light.</p>
Full article ">Figure 5 Cont.
<p>Pyrite in the C25 coal. (<b>A</b>) Particles of pyrite in sample C25-2; (<b>B</b>) cell-filling pyrite in sample C25-3; (<b>C</b>) framboidal pyrite in sample C25-3; (<b>D</b>) needle-like forms combined with marcasite in sample C25-3. Optical microscope, reflected light.</p>
Full article ">Figure 6
<p>Quartz in sample C19-1. (<b>A</b>) Particles of quartz; (<b>B</b>) fracture-filling quartz. Optical microscope, reflected light.</p>
Full article ">Figure 7
<p>Calcite in C25-2. Optical microscope, reflected light. (<b>A</b>) Fracture-filling calcite and; (<b>B</b>) Fracture-filling calcite.</p>
Full article ">Figure 8
<p>Back-scattered electron images of (<b>A</b>) Ti-oxide and (<b>B</b>) fluocerite in C25-3.</p>
Full article ">Figure 9
<p>SEM back-scattered electron images of (<b>A</b>) fracture-filling chalcopyrite; (<b>B</b>) irregular granular of titaniferous magnetite and a vermicular texture in the kaolinite; (<b>C</b>) acicular idiomorphic crystals of apatite; and (<b>D</b>) phenocrysts of Ti-augite in C19-r.</p>
Full article ">Figure 10
<p>SEM back-scattered electron images of marcasite in C25-f. (<b>A</b>) Marcasite and claystone; (<b>B</b>) Marcasite.</p>
Full article ">Figure 11
<p>Variations of ash yield and selected major elements (%) through the roof, coal seam, and floor section of the Shiping C19 and C25 coal.</p>
Full article ">Figure 12
<p>Concentration coefficients (CCs) of trace elements in the Shiping coals, normalized by average trace element concentrations in hard coals of the world [<a href="#B28-minerals-06-00074" class="html-bibr">28</a>] and based on the trace-element enrichment classification [<a href="#B29-minerals-06-00074" class="html-bibr">29</a>].</p>
Full article ">Figure 13
<p>Concentration coefficients (CCs) of trace elements in the Shiping roof and floor samples, normalized by average trace element concentrations in clay of the world [<a href="#B30-minerals-06-00074" class="html-bibr">30</a>].</p>
Full article ">Figure 14
<p>Distribution patterns of REE in the coal samples from the Shiping mine. REE are normalized by Upper Continental Crust (UCC) [<a href="#B32-minerals-06-00074" class="html-bibr">32</a>]. (<b>A</b>) Distribution patterns of REE in sample C19-1 and C25-1; (<b>B</b>) Distribution patterns of REE in sample C25-2; (<b>C</b>) Distribution patterns of REE in sample C25-3.</p>
Full article ">Figure 15
<p>Distribution patterns of REE in the roof and floor samples from the Shiping mine. REE are normalized by Upper Continental Crust (UCC) [<a href="#B32-minerals-06-00074" class="html-bibr">32</a>]. (<b>A</b>) Distribution patterns of REE in sample C19-r; (<b>B</b>) Distribution patterns of REE in sample C25-f.</p>
Full article ">Figure 16
<p>Images of C19-r and C25-f samples collected from the Shiping mine.</p>
Full article ">Figure 17
<p>Distribution patterns of REE in the (<b>A</b>) high-Ti basalts [<a href="#B10-minerals-06-00074" class="html-bibr">10</a>] and C19-r; and (<b>B</b>) the coal in Lvshuidong [<a href="#B5-minerals-06-00074" class="html-bibr">5</a>] and C25-3. REE are normalized by Upper Continental Crust (UCC) [<a href="#B32-minerals-06-00074" class="html-bibr">32</a>].</p>
Full article ">
1659 KiB  
Article
N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México
by Karla Quiroz-Estrada, Miguel Ángel Hernández-Espinosa, Fernando Rojas, Roberto Portillo, Efraín Rubio and Lucía López
Minerals 2016, 6(3), 73; https://doi.org/10.3390/min6030073 - 14 Jul 2016
Cited by 15 | Viewed by 5960
Abstract
Carbon dioxide (CO2) is considered one of the most important greenhouse gases in the study of climate change. CO2 adsorption was studied using the gas chromatography technique, while the Freundlich and Langmuir adsorption models were employed for processing isotherm data [...] Read more.
Carbon dioxide (CO2) is considered one of the most important greenhouse gases in the study of climate change. CO2 adsorption was studied using the gas chromatography technique, while the Freundlich and Langmuir adsorption models were employed for processing isotherm data in the temperature range of 473–573 K. The isosteric heat of adsorption was calculated from the Clausius–Clapeyron equation. Moreover, the thermodynamic properties ΔG, ΔU, and ΔS were evaluated from the adsorption isotherms of Langmuir using the Van’t Hoff Equation. The four soil samples were recollected from San Juan Amecac, Puebla, Mexico, and their morphologies were investigated through X-ray diffraction (XRD) and N2 adsorption at 77 K. The SJA4 soil has a crystalline Kaolinite phase, which is one of its non-metallic raw materials, and N2 isotherms allowed for the determination of pore size distributions and specific surface areas of soil samples. The Barrett–Joyner–Halenda (BJH) distribution of pore diameters was bimodal with peaks at 1.04 and 3.7 nm, respectively. CO2 adsorption showed that the SJA1 soil afforded a higher amount of adsorbed CO2 in the temperature range from 453 to 573 K followed by SJA4 and finally SJA2, classifying this process as exothermic physisorption. Full article
(This article belongs to the Special Issue CO2 Sequestration by Mineral Carbonation: Challenges and Advances)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>X-ray diffraction (XRD) patterns of soil samples. K = Kaolinite–Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>, Q = Quartz–SiO<sub>2</sub>, A = Albite–Na(AlSi<sub>3</sub>O<sub>8</sub>).</p>
Full article ">Figure 2
<p>N<sub>2</sub> adsorption isotherms of soil samples from San Juan Amecac, Puebla, México.</p>
Full article ">Figure 3
<p>Pore size distribution of soils samples.</p>
Full article ">Figure 3 Cont.
<p>Pore size distribution of soils samples.</p>
Full article ">Figure 4
<p>Adsorption isotherms of CO<sub>2</sub> at different temperatures (<b>a</b>) 473 K; (<b>b</b>) 523 K; and (<b>c</b>) 573 K.</p>
Full article ">Figure 5
<p>Linear fit of (<b>a</b>) the Freundlich model and (<b>b</b>) the Langmuir model for the CO<sub>2</sub> adsorption in soils.</p>
Full article ">Figure 6
<p>Isoteric heat of CO<sub>2</sub> adsorption of soil samples.</p>
Full article ">
6910 KiB  
Article
Assessment of Excavation Broken Zone around Gateways under Various Geological Conditions: A Case Study in Sichuan Province, China
by Hongyun Yang, Shugang Cao, Yong Li, Yingchong Fan, Shuai Wang and Xianzhe Chen
Minerals 2016, 6(3), 72; https://doi.org/10.3390/min6030072 - 13 Jul 2016
Cited by 7 | Viewed by 4654
Abstract
To study common failure characteristics of gateways, a total of 55 typical gateways at coal mines, in Sichuan Province, China, were selected for investigating the rules of broken widths based on the ground-penetrating radar (GPR) technique and numerical model. Results indicated that the [...] Read more.
To study common failure characteristics of gateways, a total of 55 typical gateways at coal mines, in Sichuan Province, China, were selected for investigating the rules of broken widths based on the ground-penetrating radar (GPR) technique and numerical model. Results indicated that the broken width values around the gateways were larger than 1.5 m, and those in the roof and high side wall were larger than those in the low side wall, as a whole. The width values had close relationships with the thickness of the coal seam and immediate roof, angle of the coal seam, and depth of the gateways. Furthermore, combined with the plastic zone of numerical models in 3-Dimensional Distinct Element Code (3DEC) and the broken width, we obtained the excavation broken zone (EBZ) cross-section diagram for each gateway and determined that the EBZ appeared to have a basically elliptical shape—with the long axis along the seam inclination direction and the short axis along the vertical direction of the rock layer—and that this elliptical shape was only slightly affected by the gateway cross-section shape. It was observed that the failure extent was greater in the seam inclination direction than in the vertical direction of the rock layer. Obviously, the gateways presented asymmetric failure characteristics and implied that an asymmetric support system should be provided when using bolts, cables, and shotcrete combined with steel mesh and steel belts. Such a support system could improve material parameters and form a combined arch structure in surrounding rocks, with arch crown and arch springing thicknesses that are larger in the roof and high side wall. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Surrounding rock failure mode of gateway. (<b>a</b>) Schematic diagram of failure zone; (<b>b</b>) failure zone in the view of stress–strain curve obtained by triaxial compression test.</p>
Full article ">Figure 2
<p>Investigate field. (<b>a</b>) and (<b>b</b>) the location of the test coal mines, in Sichuan Province, China; (<b>c</b>) gateways cross-section shape.</p>
Full article ">Figure 3
<p>Test location. (<b>a</b>) The test location in the gateway; (<b>b</b>) the cross-section of test location.</p>
Full article ">Figure 4
<p>Test of ground-penetrating radar (GPR). (<b>a</b>) The measuring principle of electromagnetic wave; and (<b>b</b>) SIR-20 Model multi-channel perspective radar.</p>
Full article ">Figure 5
<p>Broken width and the geological conditions of tested gateways.</p>
Full article ">Figure 6
<p>One gateway three-dimensional distinct element code (3DEC) mode. (<b>a</b>) Numerical model, (<b>b</b>) Plastic zone.</p>
Full article ">Figure 7
<p>Excavation broken zone (EBZ) cross-section diagram for gateways.</p>
Full article ">Figure 7 Cont.
<p>Excavation broken zone (EBZ) cross-section diagram for gateways.</p>
Full article ">Figure 8
<p>EBZ distribution characteristics. (<b>a</b>) For small coal seam dip angle; (<b>b</b>) For large coal seam dip angle.</p>
Full article ">Figure 9
<p>The cross-section of the support system. (<b>a</b>) Support for trapezoid cross-section; (<b>b</b>) Support for special cross-section; (<b>c</b>) Support for arch or inclined arch cross-section.</p>
Full article ">
10268 KiB  
Article
Enhancement of Biofilm Formation on Pyrite by Sulfobacillus thermosulfidooxidans
by Qian Li, Wolfgang Sand and Ruiyong Zhang
Minerals 2016, 6(3), 71; https://doi.org/10.3390/min6030071 - 9 Jul 2016
Cited by 26 | Viewed by 6414
Abstract
Bioleaching is the mobilization of metal cations from insoluble ores by microorganisms. Biofilms can enhance this process. Since Sulfobacillus often appears in leaching heaps or reactors, this genus has aroused attention. In this study, biofilm formation and subsequent pyrite dissolution by the Gram-positive, [...] Read more.
Bioleaching is the mobilization of metal cations from insoluble ores by microorganisms. Biofilms can enhance this process. Since Sulfobacillus often appears in leaching heaps or reactors, this genus has aroused attention. In this study, biofilm formation and subsequent pyrite dissolution by the Gram-positive, moderately thermophilic acidophile Sulfobacillus thermosulfidooxidans were investigated. Five strategies, including adjusting initial pH, supplementing an extra energy source or ferric ions, as well as exchanging exhausted medium with fresh medium, were tested for enhancement of its biofilm formation. The results show that regularly exchanging exhausted medium leads to a continuous biofilm development on pyrite. By this way, multiply layered biofilms were observed on pyrite slices, while only monolayer biofilms were visible on pyrite grains. In addition, biofilms were proven to be responsible for pyrite leaching in the early stages. Full article
(This article belongs to the Special Issue Biotechnologies and Mining)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Amounts of attached cells of <span class="html-italic">Sb. thermosulfiooxidans</span> to pyrite grains within 4 h (<b>A</b>) and their biofilm development on pyrite grains after one day (<b>B</b>); 20 days (<b>C</b>) and 40 days (<b>D</b>) incubation. Scale bar, 20 µm.</p>
Full article ">Figure 2
<p>Biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite slice after one day (<b>A</b>); seven days (<b>B</b>) and 14 days (<b>C</b>) incubation. Scale bar, 20 µm.</p>
Full article ">Figure 3
<p>Biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite grains after one week of incubation with initial pH 1.5 (<b>A</b>) or 3.5 (<b>B</b>); or with 2 mM K<sub>2</sub>S<sub>4</sub>O<sub>6</sub> (<b>C</b>); 2 mM Na<sub>2</sub>O<sub>3</sub>S<sub>2</sub>·5H<sub>2</sub>O (<b>D</b>) or 1 mM FeCl<sub>3</sub> (<b>E</b>) supplanted, or under condition of phosphate starvation (<b>F</b>). Scale bar, 20 µm.</p>
Full article ">Figure 4
<p>Biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite grains after one day (<b>A</b>); 20 days (<b>B</b>); 40 days (<b>C</b>) and 60 days (<b>D</b>) incubation. Scale bar, 20 µm.</p>
Full article ">Figure 5
<p>Biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite slice after one month (<b>A</b>); five months (<b>B</b>) and 10 months (<b>D</b>) incubation; (<b>C</b>) shows the enlarged area from the frame in (<b>B</b>); (<b>E</b>) is the cross-section view of surface topography in the area indicated by the red dashed line in (<b>C</b>); Formation of pits up to 35 µm in depth can be seen in (<b>E</b>); Scale bar in (<b>A</b>, <b>B</b> and <b>D</b>) is 100 µm and in (<b>C</b>) is 20 µm.</p>
Full article ">Figure 6
<p>3D Atomic force microscopy images showing the biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite slice after one month (<b>A</b>); three months (<b>B</b>) and five months (<b>C</b>) incubation.</p>
Full article ">Figure 7
<p>Cell numbers of subcultures of one day biofilms of <span class="html-italic">Sb. thermosulfiooxidans</span> on pyrite in suspension.</p>
Full article ">Figure 8
<p>Cell numbers of <span class="html-italic">Sb. thermosulfiooxidans</span> and leached iron concentration as function of time during bioleaching under standard conditions (<b>A</b>) or regularly changing medium (<b>B</b> and <b>C</b>).</p>
Full article ">
5697 KiB  
Article
The Desulfurization of Magnetite Ore by Flotation with a Mixture of Xanthate and Dixanthogen
by Jun Yu, Yingyong Ge and Xinwei Cai
Minerals 2016, 6(3), 70; https://doi.org/10.3390/min6030070 - 8 Jul 2016
Cited by 18 | Viewed by 7305
Abstract
The contamination of sulfur emanating from pyrrhotite in magnetite concentrates has been a problem in iron ore processing. This study utilized froth flotation to float pyrrhotite away from magnetite using collectors of xanthate and dixanthogen. It was found that xanthate or dixanthogen alone [...] Read more.
The contamination of sulfur emanating from pyrrhotite in magnetite concentrates has been a problem in iron ore processing. This study utilized froth flotation to float pyrrhotite away from magnetite using collectors of xanthate and dixanthogen. It was found that xanthate or dixanthogen alone could not achieve selective separation between pyrrhotite and magnetite in flotation. A high loss of magnetite was obtained with xanthate, while a low desulfurization degree was obtained with dixanthogen. It was interesting that a high desulfurization ratio was achieved with little loss of magnetite when xanthate was mixed with dixanthogen as the collector. The synergistic effect of the mixed collector on pyrrhotite was studied by electrokinectic studies and FTIR measurements. It was found that xanthate was the anchor on pyrrhotite and determined its selectivity against magnetite, while dixanthogen associated with xanthate, enhancing its hydrophobicity. This study provides new insights into the separation of iron minerals. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Flow sheet of flotation tests.</p>
Full article ">Figure 2
<p>The flow sheet of industrial flotation in the Baotou iron Mine.</p>
Full article ">Figure 3
<p>Flotation recoveries of magnetite with individual collector NaBX, (BX)<sub>2</sub> and mixed collector <math display="inline"> <semantics> <mrow> <mrow> <mo>(</mo> <mrow> <msub> <mi mathvariant="normal">m</mi> <mrow> <mtext>NaBX</mtext> </mrow> </msub> <mo>:</mo> <msub> <mi mathvariant="normal">m</mi> <mrow> <msub> <mrow> <mrow> <mo>(</mo> <mrow> <mtext>BX</mtext> </mrow> <mo>)</mo> </mrow> </mrow> <mn>2</mn> </msub> </mrow> </msub> <mo>=</mo> <mn>3</mn> <mo>:</mo> <mn>2</mn> </mrow> <mo>)</mo> </mrow> </mrow> </semantics> </math> as a function of collector concentration (NaSiF<sub>6</sub> 500 g/t, pine oil 46 g/t, pH = 6).</p>
Full article ">Figure 4
<p>Desulfurization ratio of flotation performance with individual collector NaBX, (BX)<sub>2</sub> and mixed collector <math display="inline"> <semantics> <mrow> <mrow> <mo>(</mo> <mrow> <msub> <mi mathvariant="normal">m</mi> <mrow> <mtext>NaBX</mtext> </mrow> </msub> <mo>:</mo> <msub> <mi mathvariant="normal">m</mi> <mrow> <msub> <mrow> <mrow> <mo>(</mo> <mrow> <mtext>BX</mtext> </mrow> <mo>)</mo> </mrow> </mrow> <mn>2</mn> </msub> </mrow> </msub> <mo>=</mo> <mn>3</mn> <mo>:</mo> <mn>2</mn> </mrow> <mo>)</mo> </mrow> </mrow> </semantics> </math> as a function of collector concentration (NaSiF<sub>6</sub> 500 g/t, pine oil 46 g/t, pH = 6).</p>
Full article ">Figure 5
<p>The magnetite recovery and desulfurization ratio in flotation concentrate with mixed collector at different combinations (mixed collector 125 g/t, NaSiF<sub>6</sub> 500 g/t, pine oil 46 g/t, pH = 6).</p>
Full article ">Figure 6
<p>The magnetite recovery and desulfurization ratio in flotation concentrate as a function of pH with mixed collector (NaBX 75 g/t, (BX)<sub>2</sub> 50 g/t, NaSiF<sub>6</sub> 500 g/t, pine oil 46 g/t).</p>
Full article ">Figure 7
<p>The zeta potential of pyrrhotite in the absence and presence of NaBX, (BX)<sub>2</sub>, and their mixture as a function of pH value, respectively.</p>
Full article ">Figure 8
<p>The zeta potential of magnetite in the absence and presence of NaBX, (BX)<sub>2</sub>, and their mixture as a function of pH value, respectively.</p>
Full article ">Figure 9
<p>FTIR spectrum of sodium butyl xanthate.</p>
Full article ">Figure 10
<p>FTIR spectrum of dibutyl dixanthogen.</p>
Full article ">Figure 11
<p>FTIR spectra of pyrrhotite after reacting with NaBX at pH = 6.</p>
Full article ">Figure 12
<p>FTIR spectra of pyrrhotite after reacting with mixed collector (NaBX + (BX)<sub>2</sub>) at pH = 6.</p>
Full article ">Figure 13
<p>Contact angle vs. mass fraction of (BX)<sub>2</sub> for pyrrhotite with mixed collectors at pH 6.0.</p>
Full article ">
2391 KiB  
Article
Preparation of High Purity V2O5 from a Typical Low-Grade Refractory Stone Coal Using a Pyro-Hydrometallurgical Process
by Xiao Yang, Yimin Zhang and Shenxu Bao
Minerals 2016, 6(3), 69; https://doi.org/10.3390/min6030069 - 8 Jul 2016
Cited by 25 | Viewed by 5922
Abstract
The recovery of vanadium from a typical low-grade refractory stone coal was investigated using a pyro-hydrometallurgical process specifically including blank roasting, acid leaching, solvent extraction, and chemical precipitation. The appropriate role of parameters in each process was analyzed in detail. Roasting temperature and [...] Read more.
The recovery of vanadium from a typical low-grade refractory stone coal was investigated using a pyro-hydrometallurgical process specifically including blank roasting, acid leaching, solvent extraction, and chemical precipitation. The appropriate role of parameters in each process was analyzed in detail. Roasting temperature and roasting time during the roasting process showed a significant effect on leaching efficiency of vanadium. Using H2SO4 as a leaching agent, vanadium leaching efficiency can achieve above 90% under the optimum leaching conditions of CaF2 dosage of 5%, sulfuric acid concentration of 4 mol/L, liquid to solid ratio of 2:1 mL/g, leaching time of 2 h, and leaching temperature of 95 °C. 99.10% of vanadium can be extracted from the leaching solution in three stages under the conditions of initial pH of 1.6, trioctylamine (TOA) extractant concentration of 20% (vol), phase ratio (A/O) of 2, and reaction time of 2 min. 1.0 mol/L NaOH was used to strip vanadium from the extracted solvent phase. After purification and precipitation, vanadium can be crystallized as ammonium metavanadate. The V2O5 product with a purity of 99.75% is obtained after ammonium metavanadate thermal decomposition at 550 °C for 2 h. The total vanadium recovery in the whole process is above 88%. This process has advantages of short operation time, high vanadium extraction efficiency, and high purity of the product. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>XRD (X-ray diffraction) patterns of raw stone coal.</p>
Full article ">Figure 2
<p>SEM image of raw stone coal.</p>
Full article ">Figure 3
<p>Effects of roasting conditions on vanadium leaching. (<b>a</b>) Roasting temperature; (<b>b</b>) roasting time.</p>
Full article ">Figure 4
<p>XRD patterns of raw ore and roasted samples under different roasting temperatures.</p>
Full article ">Figure 5
<p>Effect of leaching parameters on vanadium leaching efficiency. (<b>a</b>) Effect of sulfuric acid concentration on vanadium leaching efficiency without CaF<sub>2</sub> addition; (<b>b</b>) effect of CaF<sub>2</sub> dosage on vanadium leaching efficiency; (<b>c</b>) effect of sulfuric acid concentration on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>d</b>) effect of liquid to solid ratio on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>e</b>) effect of leaching temperature on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>f</b>) effect of leaching time on vanadium leaching efficiency with and without CaF<sub>2</sub> addition.</p>
Full article ">Figure 5 Cont.
<p>Effect of leaching parameters on vanadium leaching efficiency. (<b>a</b>) Effect of sulfuric acid concentration on vanadium leaching efficiency without CaF<sub>2</sub> addition; (<b>b</b>) effect of CaF<sub>2</sub> dosage on vanadium leaching efficiency; (<b>c</b>) effect of sulfuric acid concentration on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>d</b>) effect of liquid to solid ratio on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>e</b>) effect of leaching temperature on vanadium leaching efficiency with and without CaF<sub>2</sub> addition; (<b>f</b>) effect of leaching time on vanadium leaching efficiency with and without CaF<sub>2</sub> addition.</p>
Full article ">Figure 6
<p>Effects of extraction conditions on the vanadium extraction percentage. (<b>a</b>) Effect of pH on vanadium and other ions extraction; (<b>b</b>) effect of TOA concentration on vanadium extraction; (<b>c</b>) effect of reaction time on vanadium extraction; (<b>d</b>) vanadium extraction distribution isotherms.</p>
Full article ">Figure 7
<p>Effects of stripping conditions on vanadium stripping. (<b>a</b>) Effect of NaOH concentration on vanadium stripping; (<b>b</b>) vanadium stripping distribution isotherms.</p>
Full article ">Figure 8
<p>Vanadium recovery process flow sheet.</p>
Full article ">
837 KiB  
Article
Effect of Particle Size and Grinding Time on Gold Dissolution in Cyanide Solution
by Jessica Egan, Claude Bazin and Daniel Hodouin
Minerals 2016, 6(3), 68; https://doi.org/10.3390/min6030068 - 7 Jul 2016
Cited by 13 | Viewed by 8333
Abstract
The recovery of gold by ore leaching is influenced by the size of the particles and the chemical environment. The effect of particle size on the dissolution of gold is usually studied using mono-size particles as the gold in solution comes from the [...] Read more.
The recovery of gold by ore leaching is influenced by the size of the particles and the chemical environment. The effect of particle size on the dissolution of gold is usually studied using mono-size particles as the gold in solution comes from the ore of a unique leached particle size. This paper proposes a method to estimate the gold dissolution as a function of particle size using a bulk ore sample, i.e., with the dissolved gold coming from the various sizes of particles carried by the ore. The results are consistent with the fact that gold dissolution increases with the decreasing particle size but results also indicate that gold dissolution of the ore within a size interval is not significantly affected by the grinding time used for the ore size reduction. Results also show a good dissolution of the gold contained in the fine-size fractions without oxidation and lead nitrate pre-treatment for an ore that is known to require such pre-treatment. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Test procedure for the leaching tests.</p>
Full article ">Figure 2
<p>Preparation of the solids samples for size distribution and assaying.</p>
Full article ">Figure 3
<p>Reactor used for the cyanide leaching of the samples.</p>
Full article ">Figure 4
<p>Gold dissolved as a function of particle size and leaching time: (<b>a</b>) 15 min grinding; (<b>b</b>) 35 min grinding; (<b>c</b>) 65 min grinding.</p>
Full article ">
Previous Issue
Next Issue
Back to TopTop