Publicly Available Published by De Gruyter January 1, 2009

Defect-fluorite oxides M1-yLnyO2-y/2(Ln = lanthanide; M = Hf, Zr, Ce, U, Th): Structure, property, and applications

Akio Nakamura , Nobuyuki Masaki , Haruyoshi Otobe , Yukio Hinatsu , Junhu Wang and Masuo Takeda

From the journal Pure and Applied Chemistry

https://doi.org/10.1351/pac200779101691

Abstract

An up-to-date summary of our coupled macroscopic (lattice parameter, a₀) and microscopic (Mössbauer) studies on the entitled systems is given, shedding new light on the basic phase and structure properties of these technologically important, highly defective oxides. Through these studies, the intermediate-pyrochlore (P)-based local structure nature of the so-called stabilized-zirconia (SZ)- and stabilized-hafnia (SH)-type defect-fluorite (DF) phases in the M⁴⁺ = Zr and Hf systems seems to be almost unambiguously established with different (from the conventional) approaches: These are (1) the presence of a broad lattice parameter (a₀) hump over the extended stabilized cubic DF region (y = ~0.3-~0.7); (2) the microscopic ¹⁵¹Eu-Mössbauer evidence of Eu³⁺ isomer shifts (ISs) showing characteristic V-shaped minima around the ideal-P area (y ~ 0.50) for both the M⁴⁺ = Zr and Hf systems; and (3) rich ¹⁵⁵Gd-Mössbauer data on the Zr_1-yGd_yO_2-y/2 system [IS, quadrupole splitting (QS), line width, peak height, and relative absorption area (RAA)], revealing detailed features of its ordered P-disordered DF phase and structure relationships. These results are discussed with reported basic-property data of these systems.

Keywords: C-type structure; defect-fluorite oxides; fluorite structure; lattice parameter; local structure; Mössbauer spectroscopy; non-Vegardian behavior; powder X-ray diffraction; pyrochlore structure; stabilized zirconia (hafnia)

Conference

International IUPAC Conference on High Temperature Materials Chemistry (HTMC-XII), High Temperature Materials Chemistry, HTMC, High Temperature Materials Chemistry, 12th, Vienna, Austria, 2006-09-18–2006-09-22

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Published Online: 2009-01-01

Published in Print: 2007-01-01

Defect-fluorite oxides M1-yLnyO2-y/2(Ln = lanthanide; M = Hf, Zr, Ce, U, Th): Structure, property, and applications

Abstract

Conference

References

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