International Journal of Scientific & Engineering Research, Volume 4, Issue 6, June-2013
ISSN 2229-5518
654
Biodiesel Fuel from Differently Sourced
Local Seed Oils: Characterization, Effects of
Catalysts, Total Glycerol Content and Flow
Rates
Anuoluwa A. Akinsiku*, Enock O. Dare, Michael S. Ayodele, Fatai O. Oladoyinbo,
Kehinde A. Akinlabi, Kolawole O. Ajanaku, Tolutope O. Siyanbola and Joseph A. Adekoya.
Abstract— The recently observed depletion in the petroleum resources, which also mainly constituted carbon dioxide emission and global
warming problems call for renewable and sustainable alternative fuels. Oils were extracted from various seeds: Jatropha curcas (Botuje),
Pentaclethra macrophylla (Apara) and soybean, using petroleum ether (40-60℃). Alkali catalyzed transesterification of the oils (biodiesel production) in the presence of different kinds of alcohol (methanol, ethanol and propanol) were carried out using sodium hydroxide as catalyst.
In the case of Jatropha oil, potassium hydroxide served as catalyst. Effect of catalysts to obtain optimum biofuel was established. In the case
of soybean oil, fatty acid methyl ester, FAME, (96%), fatty acid ethyl ester, FAEE, (84%) and fatty acid propyl ester, FAPE, (37.50%) were produced. In waste palm kernel oil, methyl ester (72.92%) and ethyl ester (46.25%) were obtained. In refined palm kernel oil, methyl ester
(70.83%), ethyl ester (66.67%) and (14.17%) propyl ester were produced. However, only methyl ester conversion (20.83%) was possible in Pentaclethra macrophylla oil. In Jatropha curcas using KOH catalyst, only methyl ester (80%) formation was possible. Moreover, yields were affected as the alcohol alkyl became bulkier giving relatively lower value of biodiesel. Sulphur content (0.01) obtained for each of the biofuel
was satisfactory when compared with ASTM standard (0.05 maximum). The cetane value of soybean oil (45.5), refined palm kernel oil (46) and
used oil (44.6) were quite reasonable compared with the special standard (47). The combustion energy of the fuels from refined palm kernel
oil, waste palm kernel oil and soybean are 39, 36 and 45.5 respectively. The total glycerol content (Gc) of the methyl and ethyl esters emanated from soybean are quite reasonable and fell within standard.
IJSER
Keywords: biodiesel, flow rates, local seed oils, total glycerol content, transesterification
—————————— ——————————
1 INTRODUCTION
Among liquid biofuels, biodiesel is gaining acceptance and market share as diesel fuel in Europe and the United states. Biodiesel
has become more attractive recently because of its environmental
benefits and the fact that is made from renewable resources [1].
Moreover, they have practically no sulfur content, offer no storage
difficulty, and they have good lubrication properties.
The substitutions of petrodiesel oil by renewable fuels produced
within some countries generate high foreign exchange savings,
even for the major oil exporting countries. Consequently, project
or research in this direction potentially would serve to solve economical problems and improve economy of developing countries.
Considerable research has been done on vegetable oils as diesel
fuel. Feedstock commonly used includes: palm oil, sunflower oil,
——————————————
Corresponding Author: Akinsiku, Anuoluwa Abimbola
Chemistry Department, Covenant University, Canaanland,
Ota. P.M.B.1023, Ota, Ogun State, Nigeria.
E mail: anu.akinsiku@covenantuniversity.edu.ng
omosotomi2000@yahoo.com
coconut oil, rapeseed oil and tung oil. Animal fats, although mentioned frequently, have not been studied to the same extent as
vegetable oils. Some methods applicable to vegetable oils are not
applicable to animal fats because of natural property differences.
Oils from algae, bacteria and fungi also have been investigated
[2]. Microalgae have been examined as a source of methyl ester
diesel fuel [3]. Terpenes and latexes also were studied as diesel
fuels [4].
Some natural glycerides contain higher levels of unsaturated fatty
acids. Their direct uses as biodiesel fuel are precluded by high
viscosities. Fats, however, contain more saturated fatty acids.
They cannot be used as fuel in a diesel engine in their original
form. Because of the problems, such as carbon deposits in the
engine, engine durability and lubricating oil contamination, associated with the use of oils and fats as diesel fuels, they must be
derivatized to be compatible with existing engines. Therefore, the
work reported herein describe the formation of biodiesel in its
various derivatives (methyl-, ethyl- and propyl-) from local seed
oils while studying the effects of catalysts and glycerol as it affect
flow rates on conversion.
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International Journal of Scientific & Engineering Research, Volume 4, Issue 6, June-2013
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2
MATERIALS AND METHODS
2.1
Seeds collection, extraction and analysis
Seeds were collected from different locations. Pentaclethra microcarpa (Apara) seeds were collected from Ijebu ode and Lafenwa
market in Abeokuta, Ogun state. Refined palm kernel oil (PKO)
was bought from Adatan market, Abeokuta. Soybean was obtained from Kuto market in Abeokuta, Ogun state. Waste/used
cooking oils were obtained from different beans cake sellers from
Sabo and Carwash; Abeokuta, in Ogun state. Jatropha curcas was
collected from University of Agriculture Abeokuta and Asero,
Abeokuta in Ogun state. These places are located in the Western
part of Nigeria.
The seed shells were cracked to remove the seeds, sun dried and
later oven dried to constant weight. Oil from the seeds was obtained by the method of soxhlet extraction using petroleum ether
(40-60OC).
Physical analyses of vegetable oils were conducted according to
the AOCS standard test methods. The following parameters: iodine value, acid value, peroxide value, saponification value, refractive index and free fatty acid were determined on each sample
of the extracted oil as well as used/ waste cooking oil. These routine analyses on different seed oils were carried out using AOCS
(1978) and Cordex Alimentarious (CAC/RM 9/14-1969).
655
diesel fuel were carried out by Nigeria liquefied Natural Gas
company (NLNG), Bonny Island at International Energy Services
Limited. Port Harcourt, in Nigeria.
Total glycerol content Gs (wt% on mass of biodiesel fuel) was determined using the formula:
Gs = 0.1044WTG + 0.1488WDG + 0.2591WMG + WG, where WTG, WDG,
WMG and WG are amounts of triglycerides, diglycerides, monoglycerides and free glycerol respectively.
3
RESULTS AND DISCUSSION
Biodiesel has become more attractive recently because of its environmental benefits and the fact that it is made from renewable
resources [1].
In this study, potential of locally sourced seed oils and
waste/used cooking oils were established for the development of
biodiesel using alkali-catalysed transesterification. The transesterification experiments using methanol, ethanol and propanol (solvents) were carried out on oils from; Jatropha curcas (Botuje), Pentaclethra macrophylla (Apara) and soybean. Refined palm kernel oil
and used palm kernel oil were used as well. Sodium hydroxide
(NaOH) was used as catalyst in all the oils for transesterification
processes with the exception Jatropha oil where potassium hydroxide (KOH) was used instead. The two catalysts were used
effectively with the hope to optimizing biodiesel conversion condition. The catalysts exhibited a pronounced effect on methyl ester, ethyl ester and propyl ester formation with evidence of good
conversion. However, in the transesterification process, addition
of excess amount of catalyst gave rise to the formation of an emulsion, which increased the flow rate and led to the formation of
gels. Ramadhas, et al., reported [5] failure in transesterification
process and the phenomenon was attributed to insufficient
amount of catalyst added.
Alkali-catalysed transesterification of soybean oil was studied.
Successful transesterification reaction produced two liquid phases: ester and glycerine. Phase separation was observed within 5
minutes. Complete separation took about 20 hours as expected in
the alkali-catalyzed transesterification process.
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2.2
Alkali- catalyzed transesterification process
2.2.1
Preparation of Alkoxide
The solvents (methanol, ethanol and propanol) were distilled before use to ascertain purity. Sodium methoxide, ethoxide and
propoxide (Na+CH3O-) were prepared by dissolving 0.20g, NaOH
(catalyst) in 20ml methanol, 20ml ethanol or 20ml propanol respectively. The solutions were thoroughly mixed until the whole
alkali dissolved in each solvent. The procedure was repeated using 0.35g, 0.50g, 0.75g and 1.0g NaOH.
Also, potassium methoxide, ethoxide and propoxide (K+CH3O-)
were created by mixing 0.20g KOH (catalyst) in 20ml methanol,
0.20g KOH in ethanol and 0.2g KOH in 20ml propanol respectively. The procedure was repeated by dissolving 0.35g, 0.50g, 0.75g
and 1.0g KOH in methanol, ethanol or propanol.
2.3
Fuel Characterization
The fatty acid alkyl esters were characterized for their physicochemical and fuel properties. The parameters includes: total acid
value, cetane number (CN), iodine number and saponification
value. Chemical analyses of vegetable oils were conducted according to the standard test methods: Bomb calorimeter was used to
determine HHV in KJ/g, ASTM D613 for CN and ASTM D5453 for
sulphur content, while AOCS (1978) and Cordex Alimentarious
(CAC/RM 9/14-1969) was used for IV, saponification value (SV),
acid value and free fatty acid. Instrumental analyses of the bio-
3.1
Effect of catalyst (NaOH) on Ester Formation
Using soybean oil
The transesterfication of soybean oil with methanol, ethanol and
butanol, using 1% concentrated sulfuric acid, was unsatisfactory
when the molar ratios were 6:1 and 20:1 [6]. A 30:1 ratio resulted
in a high conversion to methyl ester. In this study, alkaline transesterification of soybean oil using NaOH in methanol, ethanol and
propanol was considered to produce sodium alkoxide (Na+ CH3O).
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Fig. 1: Effect of NaOH (catalyst) on biodiesel conversion from
soybean oil in different solvent media.
Result in figure 1 indicates highest conversion (96%) in the case of
methyl ester derivative of the oil at catalyst concentration of 6.25 x
10-1M. Lower conversions were also obtained at catalyst concentrations of 4.38 x 10-1M and 0.25 x 10-1 M giving 72% and 84% for
The seed shells were cracked to remove the seeds, sun dried and
later oven dried to constant weight. Oil from the seeds was obtained by the method of soxhlet extraction using petroleum ether
(40-60OC).
656
value, cetane number (CN), iodine number and saponification
value. Chemical analyses of vegetable oils were conducted according to the standard test methods: Bomb calorimeter was used to
determine HHV in KJ/g, ASTM D613 for CN and ASTM D5453 for
sulphur content, while AOCS (1978) and Cordex Alimentarious
(CAC/RM 9/14-1969) was used for IV, saponification value (SV),
acid value and free fatty acid. Instrumental analyses of the biodiesel fuel were carried out by Nigeria liquefied Natural Gas
company (NLNG), Bonny Island at International Energy Services
Limited. Port Harcourt, in Nigeria.
Total glycerol content Gs (wt% on mass of biodiesel fuel) was determined using the formula:
Gs = 0.1044WTG + 0.1488WDG + 0.2591WMG + WG, where WTG, WDG,
WMG and WG are amounts of triglycerides, diglycerides, monoglycerides and free glycerol respectively.
4
RESULTS AND DISCUSSION
Biodiesel has become more attractive recently because of its environmental benefits and the fact that it is made from renewable
resources [1].
In this study, potential of locally sourced seed oils and
waste/used cooking oils were established for the development of
biodiesel using alkali-catalysed transesterification. The transesterification experiments using methanol, ethanol and propanol (solvents) were carried out on oils from; Jatropha curcas (Botuje), Pentaclethra macrophylla (Apara) and soybean. Refined palm kernel oil
and used palm kernel oil were used as well. Sodium hydroxide
(NaOH) was used as catalyst in all the oils for transesterification
processes with the exception Jatropha oil where potassium hydroxide (KOH) was used instead. The two catalysts were used
effectively with the hope to optimizing biodiesel conversion condition. The catalysts exhibited a pronounced effect on methyl ester, ethyl ester and propyl ester formation with evidence of good
conversion. However, in the transesterification process, addition
of excess amount of catalyst gave rise to the formation of an emulsion, which increased the flow rate and led to the formation of
gels. Ramadhas, et al., reported [5] failure in transesterification
process and the phenomenon was attributed to insufficient
amount of catalyst added.
Alkali-catalysed transesterification of soybean oil was studied.
Successful transesterification reaction produced two liquid phases: ester and glycerine. Phase separation was observed within 5
minutes. Complete separation took about 20 hours as expected in
the alkali-catalyzed transesterification process.
IJSER
Physical analyses of vegetable oils were conducted according to
the AOCS standard test methods. The following parameters: iodine value, acid value, peroxide value, saponification value, refractive index and free fatty acid were determined on each sample
of the extracted oil as well as used/ waste cooking oil. These routine analyses on different seed oils were carried out using AOCS
(1978) and Cordex Alimentarious (CAC/RM 9/14-1969).
2.2
2.2.1
Alkali- catalyzed transesterification process
Preparation of Alkoxide
The solvents (methanol, ethanol and propanol) were distilled before use to ascertain purity. Sodium methoxide, ethoxide and
propoxide (Na+CH3O-) were prepared by dissolving 0.20g, NaOH
(catalyst) in 20ml methanol, 20ml ethanol or 20ml propanol respectively. The solutions were thoroughly mixed until the whole
alkali dissolved in each solvent. The procedure was repeated using 0.35g, 0.50g, 0.75g and 1.0g NaOH.
Also, potassium methoxide, ethoxide and propoxide (K+CH3O-)
were created by mixing 0.20g KOH (catalyst) in 20ml methanol,
0.20g KOH in ethanol and 0.2g KOH in 20ml propanol respectively. The procedure was repeated by dissolving 0.35g, 0.50g, 0.75g
and 1.0g KOH in methanol, ethanol or propanol.
2.3
Fuel Characterization
The fatty acid alkyl esters were characterized for their physicochemical and fuel properties. The parameters includes: total acid
4.1
Effect of catalyst (NaOH) on Ester Formation
Using soybean oil
The transesterfication of soybean oil with methanol, ethanol and
butanol, using 1% concentrated sulfuric acid, was unsatisfactory
when the molar ratios were 6:1 and 20:1 [6]. A 30:1 ratio resulted
in a high conversion to methyl ester. In this study, alkaline trans-
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International Journal of Scientific & Engineering Research, Volume 4, Issue 6, June-2013
ISSN 2229-5518
esterification of soybean oil using NaOH in methanol, ethanol and
propanol was considered to produce sodium alkoxide (Na+ CH3O).
fatty acid in the triglyceride of waste oil [5].
Fig. 2:
Fig. 1: Effect of NaOH (catalyst) on biodiesel conversion from
soybean oil in different solvent media.
Result in figure 1 indicates highest conversion (96%) in the case of
methyl ester derivative of the oil at catalyst concentration of 6.25 x
10-1M. Lower conversions were also obtained at catalyst concentrations of 4.38 x 10-1M and 0.25 x 10-1 M giving 72% and 84% for
methyl ester derivatives respectively.
Moreover, the experiment optimally produced ethyl ester at 4.38 x
10-1M NaOH concentration, with 84% conversion. Reasonable
biodiesel yields are also obtained at the catalyst concentrations of
0.25 x 10-1M, 6.25 x 10 -1M, 9.38 x 10 -1M and 12.5 x 10-1M NaOH
concentrations with ethyl ester conversions of 72%, 80%, 64% and
72% respectively.
However, propyl ester was obtainable at catalyst concentrations of
4.38 x 10-1M and 6.25 x 10-1 M only. With 4.38 x 10-1M catalyst concentration, 37.50% conversion resulted which was its highest. This
result of propyl ester formation was relatively low.
Ayhan in 2002 reported that catalyst improved the yield and rate
of transesterification. This is observed in methyl ester, ethyl ester
and propyl ester production using soybean oil. The reduction in
the trend of ester yield from methanol to propanol media plausibly due to stearic effect on the hydrocarbon chain and polarity of
the alcohol.
657
Effect of NaOH (catalyst) on transesterification of waste
oil in different solvents.
However, at increased concentrations of 4.38 x 10-1M, 6.25 x 10-1M,
9.38 x 10 -1M and 12.5 x 10-1M, conversions of 72.92%, 60.40%,
59.25% and 41.67% respectively were obtained. Optimal condition
for methyl ester production in waste oil was evident at 4.38 x 101M NaOH (catalyst) concentration, with 72.92% conversion.
Ethyl ester formation in waste oil was highest at a very low catalyst concentration of 0.25x 10-1M with 46.25% yield.
However, propyl ester formation was not successful. Thus, only
methyl ester and ethyl esters were obtained from used cooking oil
using alkali-catalyzed transesterification method.
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4.3
Effect of catalyst on biodiesel formation in refined
palm kernel oil using NaOH (catalyst) in alcohol
Figure 3 is the graph showing optimal condition for methyl ester,
ethyl ester and propyl ester conversion as a function of catalyst in
refined palm kernel oil. The amount of catalyst used in transesterification process affects the efficiency of the process as reported by
Ramadhas, et. al., [5].
4.2 Effect of catalyst (NaOH) on transesterification of
used/waste palm kernel oil (PKO)
Figure 2 reveals the significant effect of catalyst on biodiesel formation from used or waste PKO. The alcoholysis of used/waste
cooking oil was successful in methyl ester and ethyl ester formation but failed in propanol as solvent. At NaOH concentration
of 0.25 x 10-1 M, methyl ester produced was insignificant, and this
shows that the catalyst concentration was not enough to break the
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Fig. 3:
Effect of NaOH (catalyst) on biodiesel conversion from
refined palm kernel oil in different solvent media.
Methyl ester was produced at NaOH concentrations of 0.25 x 10M , 4.38 x 10-1M , 6.25 x 10-1M, 9.38 x 10 -1M and 12.5 x 10-1M, with
biodiesel conversions of 25%, 41.67%, 70.83%, 64% and 60.42%
respectively.
Moreover, ethyl esters were obtained at two NaOH (catalyst) concentrations; 4.38 x 10-1M and 6.25 x 10-1M, with conversions of
66.67% and 40% respectively.
Propyl ester was obtained at 0.25 x 10-1M and 4.38 x 10-1M catalyst
concentrations. The percentage conversions at these concentrations were 10% and 14.17% respectively. However, these conversions were very low relatively.
Thus, optimal biodiesel conversion was evident at NaOH concentration of 6.25 x 10-1M (70.83%) in CH3OH, 4.38 x 10-1M (66.67%) in
C2H5OH and 4.38 x 10-1M (14.17%) in C3H7OH.
658
er catalyst concentrations of 4.46 x 10-1M and 8.90 x10-1M; conversions of 53.33% and 62.50% were obtained respectively. There was
no evidence of fuel formation in ethanol and propanol solvent
media.
1
4.5 Biodiesel fuel properties
Table 1: Characteristics of biodiesel fuel from differently
sourced feedstock.
Test
Method
Specification
(B100) ASTM
PKO
bio-
PKO
diesel
oil bi
D6751 – 07B
Sulphur
ASTM D5453
0.05 max
0.01
0.01
ASTM 613
47
46
44.6
Combus-
Bomb calorim-
39
39.6
ND
tion energy
eter
Content
4.4
Effect of catalyst on biodiesel formation in
Pentaclethra macrophylla (Apara)
Cetane
number
Pentaclethra macrophylla (Apara); locally sourced seed oil was investigated as an alternative feedstock for fatty acid alkyl ester
production. The oil content of 45% proves the oil to be promising
as one of the feedstock considered for biofuel. This is because
seeds with high oil content are considered for biodiesel as reported by Karaosmanoglu [7].
Biodiesel production using Pentaclethra macrophylla was not satisfactory. Only methyl ester conversion was possible at 0.25 x 10-1M
NaOH concentration with 20.83% conversion. At other catalyst
concentrations, in different solvent media; ethanol and propanol,
there was no evident of biodiesel conversion.
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Fig 4:
Effect of KOH (catalyst) on biodiesel formation from
Jatropha oil
The effect of catalyst (KOH) in methanol, ethanol and propanol
media is shown in figure 4. Only methyl ester formation was possible in Jatropha curcas using KOH catalyst. NaOH Catalyst was
unable to catalyze the reaction. Optimal yield was obtained at 6.70
x 10-1M concentration of the catalyst with 80% conversion. At oth-
ND:
Not determined
The results of the analyses shown in table 1 reveals sulphur content of 0.01 for all the biodiesel emanated from soybean oil, Pentaclethra oil, Jatropha oil, used palm kernel oil and refined palm
kernel oil. The maximum sulphur content according to USA
ASTM D-6751 is 0.05. Judging from this view, the fuels are satisfactory due to low sulphur in them. This means that they are not
prone to knocking in combustion ignition engine [8].
Cetane number is a measure of the ignition performance of a diesel fuel obtained by comparing it to reference fuels in standardized engine test. The higher the cetane number, the better the ignition ability of the fuel. Cetane number scale of diesel fuel covers
the range from 0- 100. However, typical testing is in the range of
30-65 cetane number. (Destination: D 613-05). The cetane number
of biodiesel varies, usually in the range of 48-67 depending on the
feedstock [9]
The cetane number of biodiesel fuel from soybean oil, waste/used
cooking oil and palm kernel oil were found to be 45.5, 44.6 and 46
respectively. Therefore, the cetane value of soybean oil and that of
palm kernel oil are quite reasonable compared with the special
standard (47). Niehaus et. al. [10] and Schwab et. al., [11] reported
the cetane number of biodiesel from soybean oil that was thermally decomposed and distilled in air and nitrogen sparged with a
standard ASTM distillation apparatus to be 43.3. Fangrui et. al.
reported [12] that the cetane number of transesterification reaction
is still better and higher than those of thermally cracked oil. This
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is demonstrated in this study where the value of cetane number of
soybean oil is 45.5, higher than biodiesel obtained by thermal decomposition.
However, from table 1, the combustion energy (high heating energy) of the fuels from refined palm kernel oil, waste palm kernel
oil and soybean are; 39, 36 and 45.5 respectively. Biodiesel obtained from soybean oil has high combustion power of 45.5.
4.6
Biodiesel flow rates
The essence of transesterification process is to lower the viscosity
of oil. Table 2 shows the flow rates of feedstock with their corresponding biodiesel at their optimal conditions. Flow rate is dependent on viscosity. It is evident that there is reduction in the
viscosity of biodiesel compared with their corresponding feedstock, due to the increase in the flow rate of biodiesel compared
with their corresponding feedstock. These results further indicate
a complete transesterification and derivatization.
659
ing feedstock is encouraging and may not constitute blockage in
diesel engine.
4.7
Total Glycerol content (Gc) of soybean biodiesel
Among the specification standards of biodiesel fuel, total glycerol
content(Gc) is one of the most important characters, since glycerides significantly affect other fuel properties such as viscosity,
pour point, amount of carbon residue etc. causing problems on
filterability and deposition on the injection and combustion
chamber.
4
CONCLUSIONS
Of the several methods available for producing biodiesel, transesterification of natural oils and fats is currently the method of
choice. The purpose of the process is to lower the viscosity of the
oil or fat. Although blending of oils and other solvents lowers the
viscosity, engine performance problems, such as carbon deposit
TABLE 2:
Comparison of the Flowrates of Biodiesel
and lubricating oil contamination, still exist. In this present study,
Fuel with Feedstock Input
a high efficient transesterification has been described; optimal
condition for alkyl conversion in each sample oil has been determined. Therefore, catalysts concentration significantly affects
overall conversion of biodiesel. It has been evaluated in this work
Flow rate (cm3/min)
also the influence of various fatty acid derivatives (methyl-, ethylFeedstock
Original oil Methyl
Ethyl
Propyl and propyl esters) on biodiesel flow rate. Methyl esters of most of
the oils increases oil flow rates significantly when compared to
other.
ester
ester
ester
The results on the total glycerin content of the biodiesel emanated
from
soybean are quite impressive and conform favourably to
Jatropha curcas
2.00
3.67
standard. This phenomenon hopefully is another factor that
would justify preclusion of unwanted combustion chamber depoPentaclethra
macro- 1.60
2.50
sition and filterability problems.
IJSER
phylla
5
Waste palm kernel oil
2.40
4.00
2.00
1.00
palm kernel oil
2.33
2.33
2.00
1.00
Soybean oil
2.30
3.63
2.50
0.50
Result obtained (table 2), to a large extent shows significant increase in the flow rate of the biodiesel as the oil was transformed.
The result in the case of methyl ester from Jatropha (3.67), methyl
ester from used oil (4.00), ester from refined palm kernel oil (3.33),
ester from soybean oil (3.63) and ester from Pentaclethra oil (2.50),
clearly indicates transesterified oil in its various derivatives. In all
cases, FAME exhibited a general increase in flow rate over other
derivatives (FAEE, FAPE) and this phenomenon accounts for reduction in oil viscosity.
The increase in the flow of ester compared with their correspond-
AKNOWLEGMENTS
The authors want to use this medium to appreciate;
•
The Research Development Centre (RESDEC), University of Agriculture, Abeokuta; for their financial support.
•
International Energy Services Limited, Port Harcourt Nigeria.
•
Nigeria Liquified Natural Gas (NLNG), Rivers State, Nigeria.
6
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