Kalijum fulminat

Kalijum fulminat
Identifikacija
CAS broj	15736-99-9 ;
3D model (Jmol)	interaktivna slika;
ChemSpider	9541865 ;
	SMILES [K+].[O-][N+]#[C-]; ; ; ; ; ;
Svojstva
Hemijska formula	CKNO
Molarna masa	81,115
	Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje materijala (na 25 °C [77 °F], 100 kPa).
	Reference infokutije

Kalijum fulminat je organsko jedinjenje, koje sadrži 1 atom ugljenika i ima molekulsku masu od 81,115 Da.

Kalijum fulminat je kalijumova so fulminatnog jona. Njegova jedina upotreba, osim hemijskih demonstracija, je u udarnim kapislama nekih antičkih pušaka. Obično se priprema reakcijom kalijum amalgama sa živinim fulminatom,^[1] mnogo je manje osetljiv od široko korišćenog živinog fulminata, zbog jonske veze između kalijuma i ugljenika, za razliku od slabije kovalentne veze između žive i ugljenika.

Osobine

Osobina	Vrednost
Broj akceptora vodonika	1
Broj donora vodonika	0
Broj rotacionih veza	0
Particioni koeficijent^[2] (ALogP)	-0,8
Rastvorljivost^[3] (logS, log(mol/L))	0,9
Polarna površina^[4] (PSA, Å²)	148,4

Vidi još

Reference

^ Z. Iqbal and A. D. Yoffe (1967). „Electronic Structure and Stability of the Inorganic Fulminates”. Proceedings of the Royal Society of London. 302 (1468): 35—49. Bibcode:1967RSPSA.302...35I. S2CID 93161907. doi:10.1098/rspa.1967.0225.
^ Ghose, A.K.; Viswanadhan V.N. & Wendoloski, J.J. (1998). „Prediction of Hydrophobic (Lipophilic) Properties of Small Organic Molecules Using Fragment Methods: An Analysis of AlogP and CLogP Methods”. J. Phys. Chem. A. 102: 3762—3772. doi:10.1021/jp980230o.
^ Tetko IV, Tanchuk VY, Kasheva TN, Villa AE (2001). „Estimation of Aqueous Solubility of Chemical Compounds Using E-State Indices”. Chem Inf. Comput. Sci. 41: 1488—1493. PMID 11749573. doi:10.1021/ci000392t.
^ Ertl P.; Rohde B.; Selzer P. (2000). „Fast calculation of molecular polar surface area as a sum of fragment based contributions and its application to the prediction of drug transport properties”. J. Med. Chem. 43: 3714—3717. PMID 11020286. doi:10.1021/jm000942e.

Literatura

Clayden, Jonathan; Greeves, Nick; Warren, Stuart; Wothers, Peter (2001). Organic Chemistry (I изд.). Oxford University Press. ISBN 978-0-19-850346-0.
Smith, Michael B.; March, Jerry (2007). Advanced Organic Chemistry: Reactions, Mechanisms, and Structure (6th изд.). New York: Wiley-Interscience. ISBN 0-471-72091-7.
Katritzky A.R.; Pozharskii A.F. (2000). Handbook of Heterocyclic Chemistry (Second изд.). Academic Press. ISBN 0080429882.

Spoljašnje veze

Potassium fulminate

[1] Z. Iqbal and A. D. Yoffe (1967). „Electronic Structure and Stability of the Inorganic Fulminates”. Proceedings of the Royal Society of London. 302 (1468): 35—49. Bibcode:1967RSPSA.302...35I. S2CID 93161907. doi:10.1098/rspa.1967.0225.

[2] Ghose, A.K.; Viswanadhan V.N. & Wendoloski, J.J. (1998). „Prediction of Hydrophobic (Lipophilic) Properties of Small Organic Molecules Using Fragment Methods: An Analysis of AlogP and CLogP Methods”. J. Phys. Chem. A. 102: 3762—3772. doi:10.1021/jp980230o.

[3] Tetko IV, Tanchuk VY, Kasheva TN, Villa AE (2001). „Estimation of Aqueous Solubility of Chemical Compounds Using E-State Indices”. Chem Inf. Comput. Sci. 41: 1488—1493. PMID 11749573. doi:10.1021/ci000392t.

[4] Ertl P.; Rohde B.; Selzer P. (2000). „Fast calculation of molecular polar surface area as a sum of fragment based contributions and its application to the prediction of drug transport properties”. J. Med. Chem. 43: 3714—3717. PMID 11020286. doi:10.1021/jm000942e.

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