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Kobayashi et al., 1977 - Google Patents

Configurational stability of the unsubstituted cyclopropyl radical in the Hunsdiecker reaction

Kobayashi et al., 1977

Document ID
8492197113817813001
Author
Kobayashi K
Lambert J
Publication year
Publication venue
The Journal of Organic Chemistry

External Links

Snippet

0 0 0 19 0.017 0.010 34 0.024 0.017 50 0.032 0.022 72 0.045 0.031 94 0.058 0.044 110 0.061 0.051 124 0.055 132 0.061 149 0.066 value for &2V&2 based upon the expected radical stabilities. Radical 4 is produced exclusively in both the di-tert-butyl peroxide …
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07C2101/14—The ring being saturated
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