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Mallion et al., 1964 - Google Patents

1175. The mechanism of the reduction of diphenylphosphinic acid and its ethyl ester by lithium aluminium hydride

Mallion et al., 1964

Document ID
7901507170787042361
Author
Mallion K
Mann F
Publication year
Publication venue
Journal of the Chemical Society (Resumed)

External Links

Snippet

A secondary reaction of the lithium aluminium hydride on the solvent must be noted first. When the powdered hydride (1 mol. equiv.) was added to diphenylphosphinic acid in tetrahydrofuran, a vigorous evolution of hydrogen occurred. The mixture, when boiled, soon …
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
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