[go: up one dir, main page]

Schuchardt et al., 2001 - Google Patents

Cyclohexane oxidation continues to be a challenge

Schuchardt et al., 2001

View PDF
Document ID
7358500280139754848
Author
Schuchardt U
Cardoso D
Sercheli R
Pereira R
Da Cruz R
Guerreiro M
Mandelli D
Spinacé E
Pires E
Publication year
Publication venue
Applied Catalysis A: General

External Links

Snippet

Many efforts have been made to develop new catalysts to oxidize cyclohexane under mild conditions. Herein, we review the most interesting systems for this process with different oxidants such as hydrogen peroxide, tert-butyl hydroperoxide and molecular oxygen. Using …
Continue reading at www.academia.edu (PDF) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the -O-O- group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the -O-O- group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic

Similar Documents

Publication Publication Date Title
Schuchardt et al. Cyclohexane oxidation continues to be a challenge
Brégeault Transition-metal complexes for liquid-phase catalytic oxidation: some aspects of industrial reactions and of emerging technologies
Che et al. Metalloporphyrin-based oxidation systems: from biomimetic reactions to application in organic synthesis
Grigoropoulou et al. Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant
Shulpin et al. Efficient H2O2 oxidation of alkanes and arenes to alkyl peroxides and phenols catalyzed by the system vanadate-pyrazine-2-carboxylic acid
Punniyamurthy et al. Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen
Bart et al. Transiting from adipic acid to bioadipic acid. 1, petroleum-based processes
Mizuno et al. Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates
De Vos et al. Highly selective epoxidation of alkenes and styrenes with H 2 O 2 and manganese complexes of the cyclic triamine 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane
Kirillov et al. Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds
Groves et al. Synthesis, characterization, and reactivity of oxomanganese (IV) porphyrin complexes
Reddy et al. Cobalt catalyzed oxidation of cyclic alkenes with molecular oxygen: allylic oxidation versus double bond attack
Wójtowicz-Młochowska Synthetic utility of metal catalyzed hydrogen peroxide oxidation of CH, CC and C= C bonds in alkanes, arenes and alkenes: Recent advances.
Mohajer et al. Efficient oxygenation of hydrocarbons with tetrabutylammonium monopersulfate catalyzed by manganese meso-tetraphenylporphyrin in the presence of imidazole
Barton et al. The functionalization of saturated hydrocarbons. Part 24. The use of tert-butyl hydroperoxide: GoAggIV and GoAggV.
Tatsumi et al. Hydroxylation of alkanes catalyzed by manganese tetraphenylporphyrin immobilized on imidazole-modified silica gel
Nam et al. Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid
Li et al. Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane
Moghadam et al. Silica supported Mn (Br8TPP) Cl and Mn (TPP) Cl as efficient and reusable catalysts for selective hydrocarbon oxidation under various reaction conditions: The effect of substituted bromines on the catalytic activity and reusability
AU729005B2 (en) A process for the epoxidation of alkenes
Ahmad et al. Metal-porphyrin in epoxidation of olefins: Recent advances
Chandra et al. Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron (v) species
Shen et al. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers
Neumann et al. Vanadium-substituted MCM-41 zeolites as catalysts for oxidation of alkanes with peroxides
Niassary et al. Selective hydroxylation of cyclic ethers with tert-butylhydroperoxide and hydrogen peroxide catalyzed by iron (III) and manganese (II) bipyridine complexes included in zeolite Y and bentonite