Xiaodie et al., 2021 - Google Patents
Transfer Hydrogenation of Ketones into Alcohols Catalyzed by a Novel Chiral Terpyridine Ruthenium (II) ComplexXiaodie et al., 2021
View PDF- Document ID
- 6272872733437164401
- Author
- Xiaodie W
- Chunyu L
- Lingling M
- Bingjie X
- Xinju Z
- Bing S
- Xinqi H
- Guoji L
- Publication year
- Publication venue
- Chinese Journal of Organic Chemistry
External Links
Snippet
A novel cationic ruthenium (II) complex bearing a chiral symmetrical pineno-fused terpyridine ligand was synthesized and structurally characterized by NMR, HRMS, and X-ray crystallographic determinations. This complex exhibited good catalytic activity in the transfer …
- 150000002576 ketones 0 title abstract description 21
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0033—Iridium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D217/00—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems
- C07D217/12—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Wang et al. | Acceptorless dehydrogenation of N-heterocycles and secondary alcohols by Ru (II)-NNC complexes bearing a pyrazoyl-indolyl-pyridine ligand | |
| JP5545756B2 (en) | Novel ligands of benzo [h] quinoline species and transition metal complexes containing them and use of said complexes as catalysts | |
| Dubey et al. | Base free N-alkylation of anilines with ArCH 2 OH and transfer hydrogenation of aldehydes/ketones catalyzed by the complexes of η 5-Cp* Ir (III) with chalcogenated Schiff bases of anthracene-9-carbaldehyde | |
| CN101671365A (en) | Chiral spiro aminophosphine ligand compound and synthesis method as well as application thereof | |
| Wang et al. | Synthesis, structure and catalytic properties of CNN pincer palladium (II) and ruthenium (II) complexes with N-substituted-2-aminomethyl-6-phenylpyridines | |
| CN107954880A (en) | Organometallic catalytic for asymmetric transformation | |
| CN105111208A (en) | Preparation method of tetrahydro 1, 8-naphthyridine compound and chiral product prepared by adopting preparation method | |
| CN101983186B (en) | Ruthenium compound and method for producing optically active aminoalcohol compound | |
| Ma et al. | A New Phosphine‐Amine‐Oxazoline Ligand for Ru‐Catalyzed Asymmetric Hydrogenation of N‐Phosphinylimines | |
| JP2010512379A (en) | process | |
| JP2018519282A (en) | Hydrogenation of aldehyde or ketone compounds using Fe / tridentate complex | |
| CN110183498B (en) | Chiral ferrocene phosphine nitrogen tridentate ligand and preparation method and application thereof | |
| CN114478362A (en) | Preparation method of chiral pyridinol derivative | |
| Xiaodie et al. | Transfer Hydrogenation of Ketones into Alcohols Catalyzed by a Novel Chiral Terpyridine Ruthenium (II) Complex | |
| CN108101755B (en) | A kind of method for preparing chiral 4-(2-propargyl) phenolic compounds | |
| KR20110015412A (en) | Catalytic Asymmetric Hydrogenation | |
| US6187961B1 (en) | Process for the preparation of trans-(R,R)-actinol | |
| CN112824371B (en) | Chiral (E) -2- (1, 3-diaryl allyl) malonic acid dimethyl ester compound and preparation method thereof | |
| CN104693143A (en) | Catalytic asymmetric synthesis method of chiral propargyl amine compounds | |
| CN110143962B (en) | A new method for synthesizing benzimidazo[1,2-a]quinoline derivatives | |
| Gu et al. | Indan-f-amphox: An Efficient PNN Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of β-Aryl β-Ketoesters | |
| KR102636763B1 (en) | chiral metal complexes | |
| CN108148046B (en) | A kind of pyridyl bridged pyrazolyl indole derivative and its preparation and application | |
| CN114539319A (en) | Novel chiral phosphine-dicyclic phosphoramidite ligand and preparation method and application thereof | |
| WO2015002769A1 (en) | Novel ruthenium catalysts and their use for asymmetric reduction of ketones |