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Tolbert et al., 1982 - Google Patents

High optical yields in a photochemical cycloaddition. Lack of cooperativity as a clue to mechanism

Tolbert et al., 1982

Document ID
5135036974829665452
Author
Tolbert L
Ali M
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

Figure 3. Symmetry of concerted pathway. stopped at ca. 90% conversion. The rather complex reaction mixture exhibited substantial (> 80%) isomerization of stilbene and also significant maleate formation. After solvent removal the resulting esters were hydrolyzed with …
Continue reading at pubs.acs.org (other versions)

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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
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    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
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    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/28—Phosphorus compounds with one or more P-C bonds
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