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Tori et al., 1984 - Google Patents

Acid-catalyzed backbone rearrangement of 5, 6-epoxyalnusanes and preparation of daturadiol.

Tori et al., 1984

Document ID
4721875781884746583
Author
Tori M
Takai M
Matsumoto Y
Moriyama Y
Tsuyuki T
Takahashi T
Ohnishi H
Itai A
Iitaka Y
Publication year
Publication venue
Bulletin of the Chemical Society of Japan

External Links

Snippet

Epoxidation of alnus-5-en-3β-yl acetate with m-chloroperbenzoic acid gave a 5β, 6β- epoxide as a main product together with a 5α, 6α-epoxide as a minor product. Treatment of the α-epoxide with BF 3· OEt 2 afforded a 1 (10), 5-diene and a mixture of 6α-hydroxy-12 …
Continue reading at jlc.jst.go.jp (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J71/00—Steroids in which the cyclopenta(a)hydrophenanthrene skeleton is condensed with a heterocyclic ring
    • C07J71/0005—Oxygen-containing hetero ring
    • C07J71/001—Oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J71/00—Steroids in which the cyclopenta(a)hydrophenanthrene skeleton is condensed with a heterocyclic ring
    • C07J71/0036—Nitrogen-containing hetero ring
    • C07J71/0042—Nitrogen only

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