[go: up one dir, main page]

Andersen et al., 1944 - Google Patents

Bromination of Hydrocarbons. II. Photochemical Bromination of Ethane and Ethyl Bromide. Carbon‐Hydrogen Bond Strength in Ethane

Andersen et al., 1944

Document ID
4182561542752499123
Author
Andersen H
Van Artsdalen E
Publication year
Publication venue
The Journal of Chemical Physics

External Links

Snippet

The kinetics of the photochemical bromination of ethane was determined. The mechanism is very similar to the analogous brominations of hydrogen and methane:(1) Br 2+ hν= Br+ Br (2) Br+ C 2 H 6= C 2 H 5+ HBr (3) C 2 H 5+ Br 2= C 2 H 5 Br+ Br (4) C 2 H 5+ HBr= C 2 H 6+ …
Continue reading at pubs.aip.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide

Similar Documents

Publication Publication Date Title
Lewis et al. Decomposition of aliphatic azo compounds
Craig et al. Thermodynamics of cis-trans isomerizations. The 1, 2-difluoroethylenes
Cohen et al. 1-Azo-bis-1-arylalkanes and their Decomposition1
Andersen et al. Bromination of Hydrocarbons. II. Photochemical Bromination of Ethane and Ethyl Bromide. Carbon‐Hydrogen Bond Strength in Ethane
Barton et al. 36. The kinetics of the dehydrochlorination of substituted hydrocarbons. Part II. The mechanism of the thermal decomposition of 1: 2-dichloroethane
Wu et al. The mechanism of decomposition of azo compounds. I. 1, 1'-azocyanocyclohexane and N-(1-cyanocyclohexyl)-pentamethyleneketenimine
Dennis et al. Indium Trimethyl1
Smith et al. Two chemical determinations of the population of conformations in 1, 3-butadiene
Dillard et al. Synthesis and Properties of Some Tin Alkyls1
Taylor et al. The photo-polymerization of styrene and vinyl acetate
Henne Fluoroform
Tong et al. Heats of polymerization. I. An isothermal calorimeter and its application to methyl methacrylate
Hammond et al. Cage effects in thermal and photochemical decomposition of an azo compound
Riesz et al. The Rate of Hydration of Methylenecyclobutane and the Effect of Structure on Thermodynamic Properties for the Hydration of Small Ring Olefins1
Neureiter et al. The Free Radical Addition of Thiolacetic Acid and of Hydrogen Bromide to cis-and trans-2-Chloro-2-butene1
Coppinger et al. Stability of hetero-p-benzoquinones
Lacher et al. Reaction Heats of Organic Halogen Compounds. VI.. The Catalytic Hydrogen-ation of Some Alkyl Fluorides a
Abramson et al. The Effects of Temperature and Various Solutes on the Radiolysis of CCl4
Heidt et al. The Photolysis of Dry Ozone at λ208, at λ254 and at λ280 mμ. I. Quantum Yields
Ray et al. The Heat of formationo of Methyl Nitrate.
Pease Kinetics of the polymerization of ethylene at pressures above one atmosphere
Fletcher et al. The production of free radicals from ethylene oxide and the catalysis of other reactions by them
Booth et al. Cleavage of Silicones by Hydrogen Fluoride1
Castro et al. Thermal decomposition of acrolein. The attack of methyl and t-butoxy free radicals on acrolein
Pines et al. Isomerization of Alkanes. IV. 1 Deuterium Exchange in the Isomerization of n-Butane2