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Goda et al., 1978 - Google Patents

Reactions of alkyl diphenylphosphinates and related thio esters with some nucleophiles. SN2 (S) reaction and Wittig type rearrangement.

Goda et al., 1978

Document ID
3330092639515542805
Author
Goda K
Okazaki R
Akiba K
Inamoto N
Publication year
Publication venue
Bulletin of the Chemical Society of Japan

External Links

Snippet

Reactions of alkyl diphenylphosphinates Ph 2 P (= X) YCHR 1 R 2 (X, Y= O, S) with organolithiums and Grignard reagents afforded different types of products depending on the combination of X and Y. When Y= O, the reagents (R 3 M) mainly attacked the phosphorus …
Continue reading at jlc.jst.go.jp (other versions)

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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4056—Esters of arylalkanephosphonic acids
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    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
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    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
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