[go: up one dir, main page]

Ichinose et al., 1988 - Google Patents

Application of free radical substitution reaction into interconversion of 1-alkenylsulfides, 1-alkenylgermanes, and 1-alkenylstannanes

Ichinose et al., 1988

Document ID
3169164213607949867
Author
Ichinose Y
Oshima K
Utimoto K
Publication year
Publication venue
Chemistry Letters

External Links

Snippet

Abstract Treatment of 1-alkenylsulfides or 1-alkenylstannanes with Ph3GeH in the presence of Et3B provides 1-alkenyltriphenylgermanes in good yields. 1-Alkenylstannanes are converted into 1-alkenylsulfides easily with PhSH–Et3B, whereas 1 …
Continue reading at academic.oup.com (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2101/00—Systems containing only non-condensed rings
    • C07C2101/12—Systems containing only non-condensed rings with a six-membered ring

Similar Documents

Publication Publication Date Title
Ichinose et al. Et3B induced radical addition of thiols to acetylenes
Ollevier et al. Bismuth triflate-catalyzed mild and efficient epoxide opening by aromatic amines under aqueous conditions
Back et al. Free-radical additions of diselenides to dimethyl acetylenedicarboxylate, methyl propiolate, and dimethyl maleate
Sita et al. Synthesis and crystal structure of the first stannacyclopropene derivative
Uno et al. A new method of synthesis of arylmalononitriles catalysed by a palladium complex
Prez et al. First Nickel-Catalyzed 1, 4-Conjugate Additions to, β-Unsaturated Systems Using Triorganoindium Compounds
Takahashi et al. A Vinylzirconation Reaction of Alkynes
Kim et al. Pauson-Khand reaction catalyzed by Co4 (CO) 12
Nozaki et al. Transition-metal catalyzed regioselective addition of PhMe2SiBEt3Li and Bu3SnBEt3Li to acetylenic compounds in the presence of methanol
Kataoka et al. An efficiemt synthetic method of methyl (±)-jasmonate
Li et al. Haloamidation of alkynes and related reactions using zirconacycles and isocyanates
Munbunjong et al. Indium-mediated mild and efficient one-pot synthesis of alkyl phenyl selenides
Ichinose et al. Application of free radical substitution reaction into interconversion of 1-alkenylsulfides, 1-alkenylgermanes, and 1-alkenylstannanes
Macdonald et al. Chemically modified potassium hydride. Significant improvement in yields in some oxy-Cope rearrangements
Saito et al. A new method for the synthesis of [3]-cumulenes and eneynecumulenes related to neocarzinostatin chromophore
Yamamoto et al. DIELS-ALDER REACTIONS OF TRIMETHYLSILOXY-SUBSTITUTED BUTADIENES WITH DIMETHYL ACETYLENEDICARBOXYLATE
Chatani et al. Conversion of alkyl acetates to (siloxymethylene) alkanes by dicobalt octacarbonyl-catalyzed reaction with a hydrosilane and carbon monoxide
Wang et al. Stereoselective synthesis of enediynes and enynes by condensation of aldehydes with γ-(trialkylsilyl) allenylboranes
Lin et al. Metal-mediated cycloaddition reactions of 1, 1, 2, 2-tetrafluoro-1, 2-disilacyclobutene with cyclohexadiene. Correlation between the stereochemistry of intermediates and reaction pathways
Fugami et al. Carbon–Carbon Bond Formation by Cross Coupling of Enol Phosphates or Enol Triflates with Organomanganese Compounds
Ito et al. Synthesis of ketenimine via (N-alkylimino) acylpalladium complex intermediate
OCHIAI et al. Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane: Allylation of Aromatic Compounds with Allylmetal and Arylthallium Bis (trifluoroacetate)
Seyferth et al. New and Convenient Synthesis of Lithiated Allenes and Ketenimines Based on Readily Available Aryl-Substituted Ketones and Amides
ICHINOSE et al. Ы J3ePh3
Meline et al. An expedient, cost effective large scale synthesis of tetrathiafulvalene