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Nakamoto et al., 1986 - Google Patents

Protonation on the core sites of [Fe 4 X 4 (YnC 12 H 25) 4] 2–(X, Y= S and Se) in aqueous micellar solutions

Nakamoto et al., 1986

Document ID
260587901927417166
Author
Nakamoto M
Tanaka K
Tanaka T
Publication year
Publication venue
Journal of the Chemical Society, Chemical Communications

External Links

Snippet

The pKa values of [Fe4S4 (Yn-C12H25) 4] 2–and [Fe4Se4 (Yn-C12H25) 4] 2–(Y= S and Se) in non-ionic micellar solutions have been determined as 8.9–9.1 and 7.7, respectively, suggesting that the protonation of the clusters takes place on the sulphur or selenium atoms …
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