[go: up one dir, main page]

Margarita et al., 2018 - Google Patents

Transition‐Metal‐Catalyzed Regioselective Asymmetric Mono‐Hydrogenation of Dienes and Polyenes

Margarita et al., 2018

Document ID
2213698334516602188
Author
Margarita C
Rabten W
Andersson P
Publication year
Publication venue
Chemistry–A European Journal

External Links

Snippet

Organic compounds containing multiple C= C bonds are attractive substrates for catalytic asymmetric hydrogenation. The full saturation of prochiral double bonds, controlling the creation of two or more stereocenters in one step, is obviously a remarkable goal. However …
Continue reading at chemistry-europe.onlinelibrary.wiley.com (other versions)

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses

Similar Documents

Publication Publication Date Title
Zhou et al. Asymmetric hydrogenation routes to deoxypolyketide chirons
Nurttila et al. Supramolecular approaches to control activity and selectivity in hydroformylation catalysis
Woodmansee et al. Asymmetric hydrogenation of alkenes lacking coordinating groups
Quintard et al. Catalytic enantioselective OFF↔ ON activation processes initiated by hydrogen transfer: concepts and challenges
Hilt Hydrovinylation Reactions–Atom‐Economic Transformations with Steadily Increasing Synthetic Potential
Romano et al. Remote Functionalization of α, β-Unsaturated Carbonyls by Multimetallic Sequential Catalysis
Crozet et al. Recent advances in amine synthesis by catalytic hydroaminomethylation of alkenes
Longmire et al. Highly efficient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation
Belger et al. A selective Ru‐catalyzed semireduction of alkynes to Z olefins under transfer‐hydrogenation conditions
Lu et al. Highly Chemo‐and Enantioselective Hydrogenation of Linear α, β‐Unsaturated Ketones
Jennerjahn et al. Benign catalysis with iron: unique selectivity in catalytic isomerization reactions of olefins
Polet et al. Enantioselective Iridium‐Catalyzed Allylic Arylation
Yang et al. Palladium catalyzed asymmetric hydrophosphination of α, β-and α, β, γ, δ-unsaturated malonate esters–efficient control of reactivity, stereo-and regio-selectivity
Margarita et al. Transition‐Metal‐Catalyzed Regioselective Asymmetric Mono‐Hydrogenation of Dienes and Polyenes
Pannetier et al. Cyclometalated complexes of ruthenium, rhodium and iridium as catalysts for transfer hydrogenation of ketones and imines
Madec et al. Asymmetric hydrogenation reactions using a practical in situ generation of chiral ruthenium–diphosphine catalysts from anhydrous RuCl3
Witzig et al. Stereoselective arene‐forming aldol condensation: catalyst‐controlled synthesis of axially chiral compounds
Biosca et al. Extending the Substrate Scope of Bicyclic P‐Oxazoline/Thiazole Ligands for Ir‐Catalyzed Hydrogenation of Unfunctionalized Olefins by Introducing a Biaryl Phosphoroamidite Group
Yang et al. Recent progress in cobalt-catalyzed enantioselective hydrogenation and hydroboration reactions of alkenes
Roseblade et al. Recent advances in iridium-catalysed asymmetric hydrogenation of unfunctionalised olefins
Wu et al. Site‐and Enantioselective Iridium‐Catalyzed Desymmetric Mono‐Hydrogenation of 1, 4‐Dienes
Genet Recent studies on asymmetric hydrogenation. New catalysts and synthetic applications in organic synthesis
De‐Botton et al. Regioselective isomerization of terminal alkenes catalyzed by a PC (sp3) pincer complex with a hemilabile pendant arm
Császár et al. Chelate ring size effects of Ir (P, N, N) complexes: Chemoselectivity switch in the asymmetric hydrogenation of α, β-unsaturated ketones
Luo et al. Metal–ligand cooperation with thiols as transient cooperative ligands: acceleration and inhibition effects in (de) hydrogenation reactions