[go: up one dir, main page]

Boury et al., 1999 - Google Patents

Hybrid organic− inorganic xerogel access to meso-and microporous silica by thermal and chemical treatment

Boury et al., 1999

Document ID
1953282940409606073
Author
Boury B
Chevalier P
Corriu R
Delord P
Moreau J
Chiman M
Publication year
Publication venue
Chemistry of materials

External Links

Snippet

Hybrid xerogels of general formula (O) 1, 5Si− C⋮ C−(CH2) n− C⋮ C− Si (O) 1, 5 were prepared by sol− gel polycondensation in THF of the corresponding precursors (H3CO) 3Si− C⋮ C−(CH2) n− C⋮ C− Si (OCH3) 3, without catalyst. Treatment of the hybrid xerogels was …
Continue reading at pubs.acs.org (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/12Organo silicon halides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/38Polysiloxanes modified by chemical after-treatment
    • C08G77/382Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/398Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating; Solid sorbent compositions obtained from processes involving impregnating or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281Sorbents specially adapted for preparative, analytical or investigative chromatography

Similar Documents

Publication Publication Date Title
Boury et al. Hybrid organic− inorganic xerogel access to meso-and microporous silica by thermal and chemical treatment
Corriu et al. Hybrid silica gels containing 1, 3-butadiyne bridging units. Thermal and chemical reactivity of the organic fragment
Shea et al. Arylsilsesquioxane gels and related materials. New hybrids of organic and inorganic networks
Loy et al. Sol− gel synthesis of hybrid organic− inorganic materials. Hexylene-and phenylene-bridged polysiloxanes
Shimojima et al. Self-assembly of designed oligomeric siloxanes with alkyl chains into silica-based hybrid mesostructures
Burleigh et al. Amine-functionalized periodic mesoporous organosilicas
Kuroki et al. Synthesis and properties of 1, 3, 5-benzene periodic mesoporous organosilica (PMO): Novel aromatic PMO with three point attachments and unique thermal transformations
Kruk et al. Metamorphosis of ordered mesopores to micropores: periodic silica with unprecedented loading of pendant reactive organic groups transforms to periodic microporous silica with tailorable pore size
Cerveau et al. Nanostructured organic− inorganic hybrid materials: kinetic control of the texture
Shea et al. A mechanistic investigation of gelation. The sol− gel polymerization of precursors to bridged polysilsesquioxanes
Cho et al. Macromolecular templating approach for the synthesis of hydrothermally stable mesoporous organosilicas with high periodicity and thick framework walls
Ji et al. Synthesis and characterization of functionalized mesoporous silica by aerosol-assisted self-assembly
Chaikittisilp et al. Porous siloxane–organic hybrid with ultrahigh surface area through simultaneous polymerization–destruction of functionalized cubic siloxane cages
Burleigh et al. Direct synthesis of periodic mesoporous organosilicas: functional incorporation by co-condensation with organosilanes
Harrison Silicate cages: precursors to new materials
Oviatt Jr et al. Alkylene-bridged silsesquioxane sol-gel synthesis and xerogel characterization. Molecular requirements for porosity
Kruk et al. Characterization of high-quality MCM-48 and SBA-1 mesoporous silicas
Corriu et al. Direct synthesis of functionalized mesoporous silica by non-ionic assembly routes. Quantitative chemical transformations within the materials leading to strongly chelated transition metal ions
Burleigh et al. A new family of copolymers: Multifunctional periodic mesoporous organosilicas
Cho et al. Mesoporous organosilicas prepared with PEO-containing triblock copolymers with different hydrophobic moieties
Hu et al. Surfactant-templated organic functionalized mesoporous silica with phosphino ligands
Wang et al. Synthesis of periodic mesoporous phenylenesilica under acidic conditions with novel molecular order in the pore walls
Huesing et al. Periodically mesostructured silica monoliths from diol-modified silanes
Hunks et al. Periodic Mesoporous Organosilicas with Phenylene Bridging Groups, 1, 4-(CH2) n C6H4 (n= 0− 2)
Boury et al. Control of the anisotropic organization of nanostructured silica-based hybrid materials