[go: up one dir, main page]

Kurita et al., 1993 - Google Patents

A versatile synthetic route to 1-benzometalloles involving the first examples of several C-unsubstituted benzometalloles

Kurita et al., 1993

Document ID
1793628598176014700
Author
Kurita J
Ishii M
Yasuike S
Tsuchiya T
Publication year
Publication venue
Journal of the Chemical Society, Chemical Communications

External Links

Snippet

The group 14 (Si, Ge, Sn), group 15 (P, As, Sb, Bi) and group 16 (S, Se, Te)(2-trimethylsilyl)- 1-benzometalloles 5 have been prepared from phenylacetylene via three steps and converted into the corresponding C-unsubstituted benzometalloles 7 by …
Continue reading at pubs.rsc.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C07F7/0814—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring is substituted at a C ring atom by Si
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1812—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
    • C07F7/1844—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals a being 3, b being 1
    • C07F7/1848—C1 being an unsubstituted acyclic saturated hydrocarbon radical containing less than six carbon atoms, a benzyl radical, a phenyl radical, or a methyl substituted phenyl radical
    • C07F7/1856—C2 containing cycloaliphatic, heterocyclic or condensed aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/025—Silicon compounds without C-silicon linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D517/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium or halogen atoms as ring hetero atoms
    • C07D517/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium or halogen atoms as ring hetero atoms in which the condensed system contains two hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D497/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having oxygen and sulfur atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds

Similar Documents

Publication Publication Date Title
Fagan et al. Metallacycle transfer from zirconium to main group elements: a versatile synthesis of heterocycles
EP1464724B1 (en) Organometallic germanium compounds suitable for use in vapor deposition processes
Tebbe et al. Titanium-catalyzed olefin metathesis
Kurita et al. A versatile synthetic route to 1-benzometalloles involving the first examples of several C-unsubstituted benzometalloles
EP1464725B1 (en) Germanium compounds suitable for use in vapor deposition processes
Kaur et al. Synthesis, characterisation and reactions of bis [2-(dimethylaminomethyl)-phenyl] diselenide: its structure and that of [2-(dimethylaminomethyl) phenyl]-selenium bromide
Krempner et al. Synthesis of Transient Silenes by a Modified Peterson Reaction
Foreman et al. Organo-P–S and P–Se heterocycles
Murai et al. Imidazo [1, 5-a] pyridine-1-ylalkylalcohols: synthesis via intramolecular cyclization of N-thioacyl 1, 2-aminoalcohols and their silyl ethers and molecular structures
Wrackmeyer et al. 1, 1-Carboboration of alkynylgermanes–New germoles
Maercker et al. Polylithiumorganic Compounds-19.: Regioselective carbon-carbon σ-bond scission followed by a 1, 6-proton shift upon the reductive metalation of benzylidenecyclopropane derivatives with lithium metal
Jones et al. Preparation and crystal structure of the four-co-ordinate gold (I) complex chlorotris (triphenylphosphine) gold (I)
Yasuike et al. A versatile synthesis of 1-benzoheteroepines containing group 14, 15, and 16 heavier elements via a common 1, 6-dilithium intermediate
Magnus et al. Silicon in synthesis. 19. 1-(Trimethylsilyl)-1-(phenylthio) ethylene and 1-(trimethylsilyl)-2-(phenylthio) ethylene: reagents for thiophenyl-functionalized cyclopentenone annulations
Wustrack et al. The reaction of tris (trimethylsilyl) silyllithium with aliphatic ketones
CA2106794A1 (en) Tetrathiafulvalene derivative precursors, tetrathiafulvalene derivatives, and processes for producing them
Wegner et al. Chemistry of ring-bridged bis (. eta. 5-cyclopentadienyl) ligands. Derivatives of. alpha.,. alpha.'-dicyclopentadienyl-m-xylene
Volz et al. Heteropentalenes and Heterocyclic Ferrocenes
Fischer et al. Thietane and Selenetane Complexes by Thermal Cycloaddition of Vinyl Ethers to Transition‐Metal‐Coordinated Thio‐and Selenoaldehydes–Crystal Structure of Pentacarbonyl (7‐phenyl‐2‐oxa‐8‐thiabicyclo [4.2. 0] octane‐S) tungsten (0)
Lobanova et al. Competitive metalation of η5-indenyl-and η5-cyclopentadienyltricarbonyl complexes of manganese and rhenium
Mass et al. Cyclic isomers and cyclodimers of 3-oxo-1-silaprop-1-enes
Beez et al. Transformation of 3, 4‐Bis (isopropylidene)‐2, 5‐dichloro‐1, 2, 5‐thiadiborolane into nido‐2, 4, 5‐Thiadicarbahexaborane (5) Derivatives–Formation and Computational Elucidation of a Thiadicarbanonaborane (8) with a ni‐9< IV+ IV> Configuration
Murai et al. Reductive cyclization of γ, δ-unsaturated selenothioic acid S-esters leading to tetrahydroselenophenes
US3395167A (en) Preparation of silalactones
Meller et al. 1, 4, 6-Tris (di-isopropylamino)-1, 4, 6-triboraspiro [4.4] nona-2, 8-diene from the reaction of benzene with subvalent boron species