[go: up one dir, main page]

Peake et al., 1970 - Google Patents

Phosphorus–flurine chemistry. Part XXIV. Preparation and nuclear magnetic resonance investigation of the fluorophosphate anions,[RPF 5]–and [R 1 R 2 PF 4]–, and …

Peake et al., 1970

Document ID
17566134519785967483
Author
Peake S
Hewson M
Schmutzler R
Publication year
Publication venue
Journal of the Chemical Society A: Inorganic, Physical, Theoretical

External Links

Snippet

Caesium fluoride reacts with tetrafluorophosphoranes, RPF4 (R= Me, Ph, or Me2N), and trifluorophosphoranes, R1R2PF3 (R1= Me, R2= Ph, and R1= R2= Ph, but not R1= R2= Me), to give the anionic species Cs+ [RPF5]–and Cs+ [R1R2PF4]–respectively. In the aminolysis …
Continue reading at pubs.rsc.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P-C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6503—Five-membered rings
    • C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
    • C07F9/65061—Five-membered rings having the nitrogen atoms in positions 1 and 3 the phosphorus atom is bonded to a cyclic nitrogen atom, directly, through one or more heteroatoms or through a hydrocarbon chain which may be broken by one or more heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P-C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/30—Phosphinic acids R2P(=O)(OH); Thiophosphinic acids, i.e. R2P(=X)(XH) (X = S, Se)
    • C07F9/305—Poly(thio)phosphinic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
    • C07F9/6539—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/025—Silicon compounds without C-silicon linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids

Similar Documents

Publication Publication Date Title
Gupta et al. Phenylarsenic (III) and phenylantimony (III) bis (dialkyl dithiophosphates): synthesis and multinuclear (proton, carbon-13, phosphorus-31) NMR and mass spectral studies. Crystal and molecular structures of C6H5M [S2P (OCHMe2) 2] 2 [M= Sb (III) and As (III)]
Sisler et al. The Reaction of Chloramine with Some Trisubstituted Phosphines1
Marans et al. Preparation of Organofluorosilanes Using Aqueous Hydrofluoric Acid1
Engle et al. Phosphorus-31 NMR kinetic studies of the intra-and intermolecular alkylation chemistry of phosphoramide mustard and cognate N-phosphorylated derivatives of N, N-bis (2-chloroethyl) amine
Peake et al. Phosphorus–flurine chemistry. Part XXIV. Preparation and nuclear magnetic resonance investigation of the fluorophosphate anions,[RPF 5]–and [R 1 R 2 PF 4]–, and of the dialkyl (or diaryl) dialkylaminodifluorophosphoranes, R 1 R 2 PF 2 NR 3 2
Seyferth et al. Neopentyl Group Analogs. IV. Trimethylsilylmethyldichlorophosphorine
Gilson et al. The Reaction of Diphenylchlorophosphine with Ammonia-Free Chloramine
Egorova et al. Antimony Complexes {[2, 6-(OM e) 2 C 6 H 3] 3 S b CH 2 C (O) OE t} 2+[H g 2 I 6] 2− and {[2, 6−(OM e) 2 C 6 H 3] 3 S b ME} 2+[H g 2 I 4] 2−·: Synthesis and Structure
Glidewell et al. Ambidentate nucleophiles. Part 3. Reactions of phosphoroselenoates with molecular halides: the use of 1 J (PSe) as a structural diagnostic
Forsman et al. The Reactions of Phenyl Esters of Phosphorous Acid with Iodine1
Szafraniec et al. Reaction of (R)-(+)-isopropyl methylphosphinate with methyl triflate. Stereospecific synthesis of (R)-(+)-isopropyl methyl methylphosphonite
Nemtarev et al. Reaction of arylenedioxytrihalophosphoranes with acetylenes 11. Electronic effect of the substituent in arylacetylene on the reaction rate
US3083222A (en) New cyclic di-imide organo-phosphorus compounds and process for their production
Mukaiyama et al. A Selective Phosphorylation by Means of Dibromomalonamide and Trialkyl Phosphites
Amonoo-Neizer et al. 1163. Sulphoxides. Part II. Reactions of dimethyl sulphoxide with inorganic and organic acid halides
Ayed et al. From Allenic Phosphorus Derivatives to Heterocyclic Compounds. synthesis of a 1, 2, 3-Diazaphosphole Compound with a Strongly Polar NH Group Linked to a Dicoordinate Phosphorus Atom
Nizamov et al. Reactions of dithioxo‐1, 3, 2λ5, 4λ5‐dithiadiphosphetanes with triorganolead derivatives
Osman et al. The behaviour of N-t-butyl-2, 2′-iminodiethanol towards some trivalent phosphorus compounds
Markovski et al. THE INTERACTION OF PHOSPHENIMIDOUS AMIDES AND PHOSPHENODIIMIDIC AMIDES WITH AMINES
US3555125A (en) Production of mono- and di-alkylphosphites
Aylett et al. N-silyl derivatives of cyclic secondary amines
Zawadzki The reaction of ethyl-[N-(diethoxyphosphoryl)] formimidate with Grignard reagents: a new approach to electrophilic amination
Nizamov et al. New methods of synthesis of boron, germanium, and tin derivatives of pentavalent phosphorus thioacids
Dimukhametov et al. Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water
US4473509A (en) Process for making phosphonic anhydrides