[go: up one dir, main page]

Zhao et al., 1994 - Google Patents

Grafting mechanism in SBR–St–MMA core–shell emulsion copolymerization

Zhao et al., 1994

Document ID
1745378927371939185
Author
Zhao J
Yuan H
Pan Z
Publication year
Publication venue
Journal of applied polymer science

External Links

Snippet

The graft copolymerization of styrene and methyl methacrylate on SBR latex particles in the core–shell emulsion process was conducted in a 600 mL glass stirred vessel with the BPO Fe2+ redox initiator. The effects of the principal factors such as the polymerization …
Continue reading at onlinelibrary.wiley.com (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds

Similar Documents

Publication Publication Date Title
CA1339325C (en) Stable emulsion polymers and methods of preparing same
US4200563A (en) Method of producing aqueous polymer emulsion with improved stability
US4130523A (en) High solids latexes
Mouran et al. Miniemulsion polymerization of methyl methacrylate with dodecyl mercaptan as cosurfactant
Kangwansupamonkon et al. Modification of natural rubber by grafting with hydrophilic vinyl monomers
US4910229A (en) Process for producing hollow polymer latex particles
JPH01500438A (en) A method for agglomerating latex, the resulting agglomerated latex, and the application of the latex to modify the thermoplastic matrix to impart impact resistance.
Zhao et al. Grafting mechanism in SBR–St–MMA core–shell emulsion copolymerization
Daniels et al. Preparation of ABS (acrylonitrile/butadiene/styrene) latexes using hydroperoxide redox initiators
Guillot Some thermodynamic aspects in emulsion copolymerization
US3523111A (en) Emulsion polymerization of vinyl chloride with redox initiator system components and emulsifier prepared before monomer addition
Šňupárek Principles and limits of polymer latex tailoring
Capek et al. Emulsion polymerization of butyl methacrylate initiated by 2, 2′‐azoisobutyronitrile, 3. On the applicability of the modified Smith‐Ewart model
Mendoza et al. Kinetics of the styrene emulsion polymerization using n‐dodecyl mercaptan as chain‐transfer agent
Guillot Modelling and simulation of emulsion copolymerization of monomers of different polarities‐relationship polymerization process‐microstucture‐properties
Ge et al. Studies of inverse emulsion copolymerization of (2‐methacryloyloxyethyl) trimethyl ammonium chloride and acrylamide
Lee et al. Kinetics studies of two‐stage soapless emulsion polymerization of butyl acrylate and methyl methacrylate
Capek et al. Emulsion copolymerization of methyl methacrylate with ethyl acrylate, 1. Effect of the initiator concentration on the polymerization behaviour
Aramendia et al. Polymerization of high‐solids‐content acrylic latexes using a nonionic polymerizable surfactant
US20030032741A1 (en) Method for producing caoutchouc particles
Sayer et al. Kinetics of the seeded semicontinuous emulsion copolymerization of methyl methacrylate and butyl acrylate
Sudol Dispersion polymerization
Shaffei et al. Kinetics and polymerization characteristics for some polyvinyl acetate emulsions prepared by different redox pair initiation systems
Amalvy et al. Reactive surfactants in heterophase polymerization. 11. Particle nucleation
Guo et al. Experimental study of emulsion polymerization with crosslinking