Atwood et al., 1977 - Google Patents
Silylmethyl and related complexes. 5. Metallocene bis (trimethylsilyl) methyls and benzhydryls of early transition metals [M (. eta. 5-C5H5) 2R](M= T or V) and [M (. eta …Atwood et al., 1977
- Document ID
- 17242390907382232094
- Author
- Atwood J
- Barker G
- Holton J
- Hunter W
- Lappert M
- Pearce R
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
The reactions of some d or d1 metallocene dichlorides or [ĄVfi^-CsHs^ Brb] with the sterically hindered (J-hydrogen-free lithium alkyls LiCHPh2 or LiCH (SiMe3) 2 have been investigated. The following new compounds were isolated as an-alytically pure, thermally …
- -1 Silylmethyl 0 title description 28
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
- C07F7/006—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages of Group 4 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/025—Silicon compounds without C-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P-C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/22—Tin compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic System
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic System compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Atwood et al. | Silylmethyl and related complexes. 5. Metallocene bis (trimethylsilyl) methyls and benzhydryls of early transition metals [M (. eta. 5-C5H5) 2R](M= T or V) and [M (. eta. 5-C5H5) 2 (X) R](M= Z or H and X= C or R), and the crystal and molecular structures of [M (. eta. 5-C5H5) 2 (CHPh2) 2](M= Z or H) | |
Samuel et al. | . pi.-Cyclopentadienyl and. pi.-indenyl compounds of titanium, zirconium, and hafnium containing. sigma.-bonded organic substituents | |
Erker et al. | Dimeric (. eta. 2-benzophenone) zirconocene: its remarkable structure and chemistry | |
Gountchev et al. | Yttrium Complexes of the Chelating, C 2-Symmetric, Bis (silylamido) biphenyl Ligand [DADMB] 2-(={[6, 6 ‘-Me2-(C6H3) 2](2, 2 ‘-NSiMe2tBu) 2} 2-) | |
Atwood et al. | The molecular structure of 1, 1-bis (. eta. 5-cyclopentadienyl)-2, 3, 4, 5-tetraphenyltitanole and its hafnium analogue | |
Arney et al. | Terminal vs bridging imido ligation in complexes of zirconium (IV) and hafnium (IV): structural characterization of a. mu.-[. eta. 1 (N):. eta. 2 (N, C)] imido ligand | |
Warren et al. | Neutral and Cationic Group 4 Complexes Containing Bis (borylamide) Ligands,[R2BNCH2CH2NBR2] 2-(R= 2, 4, 6-i-Pr3C6H2, M= Zr; R= Cyclohexyl, M= Ti, Zr, Hf) | |
Bradley et al. | Tert-butylindium compounds. X-ray crystal structure of (tert-Bu2InOEt) 2 | |
Erker et al. | Reactions of vinylzirconocene complexes with a zirconium hydride. The unexpected formation of [. mu.-(. beta.-. eta. 1:. alpha.,. beta.-. eta. 2-styryl)]. mu.-chlorobis [bis (. eta. 5-cyclopentadienyl) zirconium], a binuclear (olefin) zirconocene complex | |
Enders et al. | 8‐quinolylcyclopentadienyl, a ligand with a tailored fit for chelate complexes | |
Zybill et al. | Mononuclear complexes of copper (I) and silver (I) featuring the metals exclusively bound to carbon. Synthesis and structure of (. eta. 5-pentamethylcyclopentadienyl)[(triphenylphosphonio)(triphenylphosphoranylidene) methyl] copper (I) | |
Winter et al. | Synthesis, structure, and reactivity of stable alkyl and aryl iodide complexes of the formula [(. eta. 5-C5H5 (Re (NO)(PPh3)(IR)]+ BF4 | |
Fryzuk et al. | Mechanistic Studies of the Formation of Zirconium Alkylidene Complexes [η5-C5H3-1, 3-(SiMe2CH2PPri2) 2] Zr CHR (Cl)(R= Ph, SiMe3) | |
Deacon et al. | Organolanthanoids. XVII. The Synthesis of Bis (diphenylphosphinocyclopentadienyl) ytterbium (II) and Derived Heterobimetallic Complexes [Yb (thf) n (C5H4PPh2) 2Z][Z= Ni (CO) 2, Mo (CO) 4 or PtMe2; n= 1 or 2; thf= Tetrahydrofuran]. The X-Ray Crystal-Structure of [Yb (thf) 2 (C5H4PPh2) 2Ni (CO) 2] | |
Pocheim et al. | Rare-Earth–Silyl ate-Complexes Opening a Door to Selective Manipulations | |
Lukens Jr et al. | Synthesis, Structure, and Reactions of (. eta. 5-C5H5) 3Zr | |
Calabrese et al. | Conversion of a (methoxymethyl) iridium (I) acetylene complex to a metallacyclobutene iridium (III) complex. Crystal and molecular structures of Ir (CH2OMe)(p-tol-C. tplbond. Cp-tol)(PMe3) 3 and [cyclic] fac-Ir [CH2C (p-tol): C (p-tol)] Br (PMe3) 3 (p-tol= p-tolyl) | |
Mattia et al. | The syntheses and molecular structures of two metalloindene complexes: 1, 1-bis (. eta. 5-cyclopentadienyl)-2, 3-bis (pentafluorophenyl) benzotitanole and 1, 1-bis (. eta. 5-cyclopentadienyl)-2-trimethylsilyl-3-phenylbenzotitanole | |
Arnold et al. | Preparation and reaction chemistry of trimethylsilyl derivatives of tantalum. X-ray structures of d0 (. eta. 5-C5Me5) Ta (SiMe3) Cl3 and d1 (. eta. 5-C5Me5) Ta (SiMe3)(PMe3) Cl2 | |
Kang et al. | Synthesis and characterization of new hypho-dithiaborane clusters: structural and bonding links between electron-deficient and electron-precise cage systems | |
Van Rooyen et al. | . pi.-Arene complexes. 8. Early/late heterobimetallic complexes in chromium with. sigma.,. pi.-bridged arene ligands | |
Phillips et al. | Reactions of perfluoromethyl-substituted cyclopolyphosphines with zerovalent group 10 metal complexes. Crystal and molecular structure of a [palladium] complex with a coordinated diphosphene,[Pd (. eta. 2-CF3P: PCF3)(PPh3) 2] | |
Chang et al. | Synthesis of ruthenium vinylidene complexes with dppe ligand and their cyclopropenation reaction | |
EP2227479A2 (en) | CYCLOPENTADIENYLPHOSPHAZENE COMPLEXES (CpPN COMPLEXES) OF METALS OF THE THIRD AND FOURTH GROUP AND OF THE LANTHANOIDS | |
Beshouri et al. | Synthesis and crystal and molecular structures of M (OAr') 2 (CH2-py-6Me) 2 [M= Hf, Th; OAr'= 2, 6-di-tert-butylphenoxide; CH2-py-6Me= 2-(6-methylpyridyl) methyl], complexes containing two carbon-nitrogen chelating pyridylmethyl ligands |