Mimoun, 1983 - Google Patents
Heterolytic and Homolytic Oxygen Transfer Reactions from d0 Metal Peroxides to HydrocarbonsMimoun, 1983
- Document ID
- 1539107048666461135
- Author
- Mimoun H
- Publication year
- Publication venue
- Israel Journal of Chemistry
External Links
Snippet
An attempt is made to correlate the catalytic activity of d0 metal complexes in the oxidation of hydrocarbons by H2O2 and ROOH with the oxidizing properties of their peroxidic derivatives. The triangular structure of bound peroxo and alkylperoxidic groups is a common …
- 150000002430 hydrocarbons 0 title abstract description 10
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Mimoun et al. | Selective epoxidation of olefins by oxo [N-(2-oxidophenyl) salicylidenaminato] vanadium (V) alkylperoxides. On the mechanism of the halcon epoxidation process | |
Yamada et al. | Direct Epoxidation of Olefins Catalyzed by Nickel (II) Complexes with Molecular Oxygen and Aldehydes. | |
Saussine et al. | Cobalt (III) alkylperoxy complexes. Synthesis, X-ray structure, and role in the catalytic decomposition of alkyl hydroperoxides and in the hydroxylation of hydrocarbons | |
Mimoun | Heterolytic and Homolytic Oxygen Transfer Reactions from d0 Metal Peroxides to Hydrocarbons | |
Katsuki | Unique asymmetric catalysis of cis-β metal complexes of salen and its related Schiff-base ligands | |
Barf et al. | Ruthenium catalyzed epoxidations: mechanistic and synthetic aspects | |
Palucki et al. | Asymmetric oxidation of sulfides with H2O2 catalyzed by (salen) Mn (III) complexes | |
De Bruin et al. | Functional Models for Rhodium‐Mediated Olefin‐Oxygenation Catalysis | |
De Vos et al. | Selective Alkene Oxidation with H2O2 and a Heterogenized Mn Catalyst: Epoxidation and a New Entry to Vicinal cis‐Diols | |
Groves et al. | Electrochemical generation of an iron (IV) porphyrin | |
Wahl et al. | Peroxomolybdenum complexes as epoxidation catalysts in biphasic hydrogen peroxide activation: raman spectroscopic studies and density functional calculations | |
Mimoun | Activation of molecular oxygen and selective oxidation of olefins catalyzed by group VIII transition metal complexes | |
US3806467A (en) | Organic tin compound containing catalyst system useful for producing epoxy compounds | |
Quici et al. | Synthesis of perfluoroalkylated bipyridines—new ligands for oxidation reactions under fluorous triphasic conditions | |
US4822899A (en) | Metallic porphyrin complexes as catalysts in epoxidation reactions | |
Puddephatt et al. | Comprehensive organometallic chemistry II: a review of the literature 1982-1994 | |
Wang et al. | New molybdenum (VI) catalysts for the epoxidation of cyclohexene: synthesis, reactivity and crystal structures | |
Fellmann et al. | Trigonal-bipyramidal bis (neopentylidene), neopentylidene/ethylene, and bis (ethylene) complexes of tantalum and how they react with ethylene. A catalyst for rapidly dimerizing ethylene to 1-butene | |
Herrmann et al. | The “Peroxo Perrhenic Acid” H4Re2O13: An Oxygen‐Rich Metal Peroxide and Oxidation Catalyst | |
Stoop | Asymmetric epoxidation of olefins. The first enantioselective epoxidation of unfunctionalised olefins catalysed by a chiral ruthenium complex with H 2 O 2 as oxidant | |
Mimoun | Do metal peroxides as homolytic and heterolytic oxidative reagents. Mechanism of the halcon epoxidation process | |
CA2229344A1 (en) | Peroxo-containing metal complexes having amine oxide, phosphine oxide, arsine oxide, pyridine n-oxide or pyridine ligands as epoxidation catalysts | |
Adams | Heteronuclear Metal-Metal Bonds | |
US6229028B1 (en) | Process for the epoxidation of alkenes | |
Zhou et al. | Molybdenum (VI) cis-dioxo complexes with chiral Schiff base ligands: Synthesis, characterization, and catalytic applications |