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Hurst et al., 1969 - Google Patents

SOLVENT EXTRACTION OF URANIUM FROM WET-PROCESS PHOSPHORIC ACID.

Hurst et al., 1969

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Document ID
14710285842318321453
Author
Hurst F
Crouse D
Brown K
Publication year

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ABSTRACT A large number of reagents were screened, in laboratory tests, for possible use as extractants for recovering uranium from commercial wet-process phosphoric acid „Results indicated that the syner gistic extraction combination of di (2-ethylhexyl) phosphoric …
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/026Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/0004Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/0005Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like
    • C22B3/0006Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using acyclic or carbocyclic compounds
    • C22B3/0008Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using acyclic or carbocyclic compounds using acyclic or carbocyclic compounds of a single type
    • C22B3/0031Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using acyclic or carbocyclic compounds using acyclic or carbocyclic compounds of a single type using organic compounds containing sulfur atom(s), e.g. sulfonium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0221Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/0004Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/0005Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like
    • C22B3/004Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim
    • C22B3/0041Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim using organo-metallic compounds of a single type
    • C22B3/0043Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim using organo-metallic compounds of a single type using phosphorus-based acid derivatives
    • C22B3/0044Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim using organo-metallic compounds of a single type using phosphorus-based acid derivatives of a single type
    • C22B3/0045Acyclic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/16Oxyacids of phosphorus; Salts thereof
    • C01B25/18Phosphoric acid
    • C01B25/234Purification; Stabilisation; Concentration
    • C01B25/237Selective elimination of impurities
    • C01B25/238Cationic impurities, e.g. arsenic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/16Oxyacids of phosphorus; Salts thereof
    • C01B25/18Phosphoric acid
    • C01B25/22Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/2208Preparation by reacting phosphate-containing material with an acid, e.g. wet process with an acid or a mixture of acids other than sulfuric acid
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/0004Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/0005Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like
    • C22B3/004Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim
    • C22B3/0095Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds, e.g. acyclic or carbocyclic compounds, heterocyclic compounds, organo- metallic compounds, alcohols, ethers, or the like using organo-metallic compounds or organo compounds of boron, silicon, phosphorus, selenium or tellurim using a mixture of organic agents wherein one agent at least is an organo-metallic compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/12Oxides of phosphorus
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/16Extraction of metal compounds from ores or concentrates by wet processes by leaching in organic solutions
    • C22B3/1608Leaching with acyclic or carbocyclic agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G43/00Compounds of uranium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/082Compounds containing nitrogen and non-metals and optionally metals

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