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Bennett et al., 2009 - Google Patents

Synthesis and interconversions of digold (I), tetragold (I), digold (II), gold (I)–gold (III) and digold (III) complexes of fluorine-substituted aryl carbanions

Bennett et al., 2009

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Document ID
14077127163161046121
Author
Bennett M
Bhargava S
Mirzadeh N
Privér S
Wagler J
Willis A
Publication year
Publication venue
Dalton Transactions

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Snippet

Treatment of [AuXL](X= Br, L= AsPh3; X= Cl, L= tht) with the lithium or trimethyltin derivatives of the carbanions [2-C6F4PPh2]− and [C6H3-nF-2-PPh2]−(n= 5, 6) gives digold (I) complexes [Au2 (μ-carbanion) 2](carbanion= 2-C6F4PPh22, C6H3-5-F-2-PPh23, C6H3-6-F …
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
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    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System

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