[go: up one dir, main page]

Coxon et al., 1973 - Google Patents

A study of hydroxyl participation in acyclic epoxide systems. Acid-catalysed rearrangements of trans-and cis-3, 4-Epoxypentan-1-ols, 4, 5-Epoxyhexan-1-ols, and 5, 6 …

Coxon et al., 1973

Document ID
13853992813678761085
Author
Coxon J
Hartshorn M
Swallow W
Publication year
Publication venue
Australian Journal of Chemistry

External Links

Snippet

The acid-catalysed rearrangements of trans-and cis-4, 5-epoxyhexan-1-ols and 5, 6- epoxyheptan-1-ols demonstrate a preference for cyclic ether formation: tetrahydrofuran> tetrahydropyran> oxepan. The ether products arise by intramolecular hydroxyl displacement …
Continue reading at www.publish.csiro.au (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/08—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/16—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D309/28—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. -COOH
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O-metal, -CHO, keto, ether, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2103/00—Systems containing at least three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02—Monosaccharides

Similar Documents

Publication Publication Date Title
Coxon et al. A study of hydroxyl participation in acyclic epoxide systems. Acid-catalysed rearrangements of trans-and cis-3, 4-Epoxypentan-1-ols, 4, 5-Epoxyhexan-1-ols, and 5, 6-Epoxyheptan-1-ols
Ferrier et al. The conversion of carbohydrate derivatives into functionalized cyclohexanes and cyclopentanes
Lewis et al. Reaction of α-Pinene Oxide with Zinc Bromide and Rearrangement of 2, 2, 3-Trimethyl-3-cyclopentene Products Derived Therefrom1
Lythgoe The taxus alkaloids
Naya et al. The structural elucidation of sesquiterpene lactones from Petasites japonicus Maxim
Smith et al. Reduction of the Products of Periodate Oxidation of Carbohydrates. I. Hydrogenation with Raney Nickel of the Dialdehydes from the Methyl Glycopyranosides1
Agosta et al. Solution photolysis of camphor
Elliger et al. Structure and stereochemistry of simmondsin
Tipson et al. Cyclic acetals of ketoses: Part IV. Re-investigation of the oxidation of 1, 2: 4, 5-DI-O-isopropylidene-β-D-fructopyranose with methyl sulfoxide—acetic anhydride
Crandall et al. Small-ring epoxides. I. Synthesis and reactions of a 4-methylene-1-oxaspiro [2.2] pentane derivative
Cheney et al. Studies directed toward the total synthesis of trixikingolide. Analysis of the capacity for transannular carbon-carbon bond formation in various bicyclic and tricyclic intermediates
Baker et al. Synthesis of branched-chain sugar derivatives related to aldgarose
Schmitz et al. Chemistry of coelenterates. XXI. Lactones from the gorgonian Pterogorgia guadalupensis
Snyder et al. Stereochemistry of quinate-shikimate conversions. Synthesis of (-)-4-epi-shikimic acid
Kirson et al. Withaphysalin C, a naturally occurring 13, 14-seco-steroid
Horton et al. Enolization of aldosulose derivatives. 4-O-acetyl-1, 6-anhydro-2-3-O-isopropylidene-β-D-threo-hex-3-enopyranose, the 3, 4-enediol acetate of a fused-ring keto sugar, and formation of a branched-chain sugar derivative
Lohmar et al. The hexitols and some of their derivatives
Barton et al. Oxidation of ketone acetals by hydride transfer
McDonald et al. Triasteranetrione
Heathcock et al. Photochemistry of 1, 6-cyclodecadienes. II. Synthesis and photochemistry of 6-methyl-1, 6-cyclodecadien-3-one
Woo et al. The structure of chalcomycin
JPH0211563A (en) Preparation of 1beta-hydroxyvitamin d2 and d3
Warnhoff New rearrangements of the caryophyllene skeleton: The dinitrophenylhydrazones from caryophyllene oxide
Ceccherelli et al. Biogenetic-type transformation of 3-keto-4, 5-epoxy-eudesmanes: synthesis of cyperanes, eremophilanes and spirovetivanes
Lavie et al. The Constituents of Ecballium elaterium L. XVI. Stereochemical Problems in the Cucurbitacins1, 2