[go: up one dir, main page]

Balquist et al., 1971 - Google Patents

Cyclialkylation of phenol with 1, 5-hexadiene

Balquist et al., 1971

Document ID
13610284968208638712
Author
Balquist J
Degginger E
Publication year
Publication venue
The Journal of Organic Chemistry

External Links

Snippet

Phenol and 1, 5-hexadiene (6) in carbon disulfide (4: 1 mole ratio) at 30 react in the presence of boron trifluoride etherate to produce 5, 6, 7, 8-tetrahydro-5, 8-dimethyl-1-and-2- naphthol (7 and 8) and 2, 5-diphenoxyhexane (9). A study of this reaction suggests that 5 …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2101/00—Systems containing only non-condensed rings
    • C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2101/16—The ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having -CHO groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

Similar Documents

Publication Publication Date Title
Hirsch et al. Base-catalyzed alkylation of cyclopentadiene rings with alcohols and amines
Morizawa et al. Pd (O) promoted rearrangement of 2-(1, 3-butadienyl) cyclopropane-1, 1-dicarboxylate esters to 2-alkenyl-3-cyclopentene-1, 1-dicarboxylate esters
Overman et al. Chair topology of the palladium dichloride catalyzed Cope rearrangement of acyclic 1, 5-dienes
Parham et al. The reaction of dichlorocarbene with 2, 3-Chromene and 3, 4-Chromene
White et al. The total synthesis of. alpha.-and. beta.-Bourbonene
Damico et al. Isomerization of Unsaturated Alcohols with Iron Pentacarbonyl. Preparation of Ketones and Aldehydes
Dominianni et al. Synthesis of 5-(tert-alkyl) resorcinols
Ireland et al. Total synthesis of terpenes, XVIII. Convergent, stereoselective total synthesis of the unsymmetrical pentacyclic triterpene alnusenone
Schaefer et al. Selenium dioxide oxidations. III. Oxidation of olefins
Morizawa et al. Pd (O) Promoted Transformation of 1, 1‐Dialkoxycarbonyl‐2‐(1, 3‐butadienyl) cyclopropanes into 2‐Ethenyl‐3‐cyclopentenes
Eisenbraun et al. Synthesis of polyalkyl-1-tetralones and the corresponding naphthalenes
Erman The condensation of camphene and phenol. Product formation via a direct 2, 6-hydride transfer
Gassman et al. Reactions of trans-fused cyclopropanes. Synthesis and solvolysis of 4-hydroxy-trans-bicyclo [5.1. 0] octane p-bromobenzenesulfonate
Balquist et al. Cyclialkylation of phenol with 1, 5-hexadiene
Spangler et al. Synthesis and characterization of representative octa-1, 3, 5, 7-tetraenes and deca-1, 3, 5, 7, 9-pentaenes
Braude et al. 205. The preparation and ultra-violet light absorption of some substituted phenylpropenyl-and styrylmethyl-carbinols and 1-phenylbutadienes
Rose et al. Reactions of organometallic reagents with unsaturated epoxides. II. Control of product ratios
TOMBOULIAN Preparation of cis-and trans-1, 2-Diphenyl-1, 2-cyclohexanediol1
Crombie et al. 346. Stereochemical studies of olefinic compounds. Part II. Ring scission of 2–1′-halogenoalkyltetrahydrofurans and 3-halogeno-2-alkyl-tetrahydropyrans as a route to alk-4-en-1-ols of known configuration and as a method of chain extension by five methylene groups
Farmer et al. Isomerization of Propargylic Amines to Conjugated Dienes. 2-Dialkylamino-1, 3-butadienes
Misumi et al. The Preparation of Stereoisomeric α, ω-Diphenylpolyenes and Related Compounds by Means of the Wittig Reaction
US2705728A (en) Process for the preparation of unsaturated alicyclic 2-methylbutanal compounds
Mirrington et al. Diels-Alder adducts of 1, 3-dimethyl-1, 3-cyclohexadiene
Ogawa et al. Isomerization of cyclooctatetraene oxide in the reaction with organometallic reagents: Possible involvement of homotropylium cation intermediate
Clarke et al. Solvent effects in the decomposition of diazocamphane