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Tobe et al., 1981 - Google Patents

Adamantane rearrangement of [3.3. 2] propellanes

Tobe et al., 1981

Document ID
13163574243690798021
Author
Tobe Y
Terashima K
Sakai Y
Odaira Y
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

For elucidation of the isomerization pathway of the [3.3. 2] propellane ring system into “adamantaneland” by effective skeletal transformations, hydride-transfer reduction of [3.3. 2] propellanols [(exo-4) and (endo-4)] and [3.3. 2] propellene (5) was carried out. It was found …
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    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
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