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Finnegan et al., 1963 - Google Patents

An analogue of the photo-fries rearrangement; the photolysis of vinyl benzoate.

Finnegan et al., 1963

Document ID
1272697765668526188
Author
Finnegan R
Hagen A
Publication year
Publication venue
Tetrahedron Letters

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6 that the initial step is the photo-dissociation of the ester to a radical pair which undergoes subsequent reaction within a solvent cage. Formal structural considerations suggest that the reaction need not be limited to the case of phenyl esters. For example, the bond undergoing …
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    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
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    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
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