Yamamoto et al., 1989 - Google Patents
Structural features in electron-deficient (. eta.-pentamethylcyclopentadienyl) titanium-diene complexes and their catalysis in the selective oligomerization of …Yamamoto et al., 1989
- Document ID
- 12203548658056659881
- Author
- Yamamoto H
- Yasuda H
- Tatsumi K
- Lee K
- Nakamura A
- Chen J
- Kai Y
- Kasai N
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
A series of titanium-diene complexes of the type TiX (C5Me5)(s-cts-diene)(X= Cl, Br, I) was synthesized by the stoichiometric reaction of TiX3 (C5Me5) with (2-butene-l, 4-diyl) magnesium derivatives or by the reaction of TiX3 (C6Me5) with RMgX (R= i-Pr, t-Bu, Et; X …
- 150000001993 dienes 0 title abstract description 88
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
- C07F7/006—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages of Group 4 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Yamamoto et al. | Structural features in electron-deficient (. eta.-pentamethylcyclopentadienyl) titanium-diene complexes and their catalysis in the selective oligomerization of conjugated dienes | |
Yasuda et al. | Diene, alkyne, alkene, and alkyl complexes of early transition metals: structures and synthetic applications in organic and polymer chemistry | |
Nagashima et al. | Oxidative addition of allylic halides to ruthenium (II) compounds. Preparation, reactions, and X-ray crystallographic structure of ruthenium (IV)-allyl complexes | |
Winter et al. | A single-source precursor to titanium nitride thin films. Evidence for the intermediacy of imido complexes in the chemical vapor deposition process | |
Erker et al. | Reactions of vinylzirconocene complexes with a zirconium hydride. The unexpected formation of [. mu.-(. beta.-. eta. 1:. alpha.,. beta.-. eta. 2-styryl)]. mu.-chlorobis [bis (. eta. 5-cyclopentadienyl) zirconium], a binuclear (olefin) zirconocene complex | |
Hessen et al. | Chemistry of carbon monoxide free monocyclopentadienylvanadium (I) alkene and alkyne complexes | |
Erker et al. | Synthesis of ansa-metallocenes by intramolecular photochemical [2+ 2] cycloaddition of bis (alkenylcyclopentadienyl) zirconium complexes | |
Erker et al. | (Aryne)-and (alkyne) metallocene derived dimetallic zirconium/aluminum complexes containing planar-tetracoordinate carbon | |
JP2010523543A (en) | 1,4-hydrogenation of dienes using Ru complexes | |
Erker et al. | Group 4 bent metallocenes and functional groups—Finding convenient pathways in a difficult terrain | |
Burger et al. | ansa-metallocene derivatives: XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction | |
Booth et al. | Silica-supported cyclopentadienyl-rhodium (I),-cobalt (I), and-titanium (IV) complexes | |
Fortier et al. | Redox chemistry of discrete low-valent titanium complexes and low-valent titanium synthons | |
Horton | Pentamethylcyclopentadienyl ligand activation in a cationic zirconocene complex: formation of an unusual pendant allyl ligand with 1, 3-butadiene | |
US4469638A (en) | Production of transition metal complexes | |
Albers et al. | Chemistry of cyclopentadienylruthenium and-osmium complexes. 4. The facile synthesis of cyclopentadienylruthenium (IV) and-osmium (IV) allyl complexes and the characterization of a novel ruthenium (IV) intermediate in the dehydrohalogenation and dehydrogenation of 3-bromocyclohexene. The x-ray crystal structure of [(. eta. 5-C5H5) Ru (. eta. 3-C4H4OMe) Cl2] | |
Itoh et al. | Stoichiometric and catalytic dimerization of conjugated dienes with (C5R5) Ru (diene)+ | |
Werner et al. | Synthesis of Octahedral Hydrido (vinyl) iridium (iii) Complexes by C H Activation: An Example of a Thermodynamically Favored Rearrangement [M (CHR CHX)]→[M (H)(CR CHX)] | |
Pertici et al. | A new synthetic method for the preparation of cyclo-olefin ruthenium complexes | |
Yasuda et al. | Facile synthesis and stereochemistry of alkyne complexes of Cp2MH and Cp2MCH2CH2R (M= niobium, tantalum) | |
JPH05503033A (en) | Homogeneous rhenium catalyst for metathesis of olefins | |
Sinnema et al. | Competitive CH activation in (pentamethylcyclopentadienyl)(cyclooctatetraene) alkylzirconium compounds Cp* Zr (COT) R. Selective formation of fulvene or cyclooctatrienyne ligands. Molecular structure of Cp* Zr (. mu.-. eta. 8:. eta. 2-C8H6) ZrCp*(. eta. 4-C8H8), a dinuclear zwitterionic zirconium complex with a bridging cyclooctatrienyne ligand | |
Braun et al. | Halfsandwich‐Type Triisopropylstibane Ruthenium Complexes with 16‐, 17‐, and 18‐Electron Configurations and an Unsymmetrical Binuclear 18/16‐Electron Ru2 (SbiPr3) Species | |
Troyanov et al. | Synthesis and structure of a novel. mu.-dimethyldimethylenecyclopentenyl bis (. mu.-hydrido) mixed-valence titanium (III)/titanium (II) compound | |
Mashima et al. | Reaction of [cyclic](. eta. 5-C5Me5) 2TiOC [: Re (CO) 4Re (CO) 5] CH2CH2 with tert-butyl isocyanide: molecular structure of a new zwitterionic complex involving (. eta. 2-imidoyl) titanium and acyldirhenium carbonyl moieties |