[go: up one dir, main page]

Dikusar et al., 2001 - Google Patents

Synthesis and reactions of ethynyl derivatives of adamantanone, verbanone, and verbenone

Dikusar et al., 2001

Document ID
11811331480367598472
Author
Dikusar E
Kozlov N
Koval'skaya S
Popova L
Moiseichuk K
Publication year
Publication venue
Russian Journal of General Chemistry

External Links

Snippet

Lithium acetylide was reacted with adamantanone, verbanone, and verbenone to obtain their hydroxyethynyl derivatives whose reaction with aqueous ammonia solution of silver nitrate gave the corresponding polycycloaliphatic silver acetylides. The latter react with …
Continue reading at link.springer.com (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1812—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
    • C07F7/1844—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals a being 3, b being 1
    • C07F7/1848—C1 being an unsubstituted acyclic saturated hydrocarbon radical containing less than six carbon atoms, a benzyl radical, a phenyl radical, or a methyl substituted phenyl radical
    • C07F7/1856—C2 containing cycloaliphatic, heterocyclic or condensed aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2103/00—Systems containing at least three condensed rings
    • C07C2103/02—Ortho- or ortho- and peri-condensed systems
    • C07C2103/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, -CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, -CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2101/00—Systems containing only non-condensed rings
    • C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2101/16—The ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2102/00—Systems containing two condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters

Similar Documents

Publication Publication Date Title
KR970009729B1 (en) Process for preparing derivatives of baccatin III and 10-deacetylbaccatin III.
IE64687B1 (en) Process for the enantioselective preparation of phenylisoserine derivatives
JPH0383956A (en) Selective manufacture of enanthio as phenyl isoserine derivative
JPS62145093A (en) Intermediate for producing podophyllotoxin and related compound and its production and utilization
Dikusar et al. Synthesis and reactions of ethynyl derivatives of adamantanone, verbanone, and verbenone
CA2222421C (en) C-2' hydroxyl-benzyl protected, n-carbamate protected (2r,3s)-3-phenylisoserine and production process therefor
Kraus et al. Alkoxy radicals in organic synthesis. A novel approach to spiroketals
US3099660A (en) Synthesis of khellin and intermediates therefor
Trahanovsky et al. Formation of. alpha.,. beta.-unsaturated ketones from the gas-phase pyrolysis of. alpha.-substituted propargyl esters
Kim et al. Use of. beta.-silylethyl vinyl ketone as a. beta.-hydroxyethyl vinyl ketone synthon in the Robinson annulation reaction
US4714777A (en) Cyclopropanone hydrate derivatives
Krow et al. A simple synthesis of 4-cyclohexene-1, 2-cis-diol and its use as the precursor of a functionalized cyclohexenone synthon
Winter et al. 2, 4, 6-Tris [(pentafluorothio) methyl]-1, 3, 5-trioxane
US2705235A (en) Hexachloro-methano-oxa-naphthalene compounds
SU624569A3 (en) Method of obtaining cyclopentane derivatives
Anderson et al. Ester cleavage reactions of bromojuglone acetates with dialkylcuprates: evidence for hemi ortho ester formation promoted by electron transfer reactions
US3341534A (en) Halogenated phenothiazine carboxylate esters
JPS61112069A (en) Tocopherol derivative and manufacture
SU518490A1 (en) Method of producing marcaptocarboxylic acid amides
Dikusar et al. Camphor and isocamphanone in the synthesis of disubstituted acetylene alcohols, ethers, and esters
JP2711762B2 (en) Bicyclo [8.3.0] trideca-9,13-diene-2,7-diyne derivative
US3549679A (en) Myrcene derivatives and process therefor
KR0173315B1 (en) Novel process for producing 6-acyl-7-deacetylforskolin derivatives
CA1042906A (en) Process for the preparation of mono-acyloxy (or aroyl-oxy) alkylen-carbonates and products obtained
Dikusar et al. Synthesis of functionally substituted diacetylenic alcohols and carboxylic acids