[go: up one dir, main page]

Carman et al., 1994 - Google Patents

2-α, 4-Dihydroxy-1, 8-cineole. A new possum urinary metabolite

Carman et al., 1994

View PDF
Document ID
1082866037013125809
Author
Carman R
Rayner A
Publication year
Publication venue
Australian Journal of Chemistry

External Links

Snippet

2α, 4-Dihydroxy-1, 8-cineole (2a) is present in the urine of brushtail possums fed a diet enhanced with 1, 8-cineole (1). Chemical syntheses of this novel metabolite (2a) and its 2β- epimer (19a) are described. The nmr spectra of various 1, 8-and 1, 4-cineoles are reported …
Continue reading at www.researchgate.net (PDF) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring heteroatom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/16—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D309/28—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2103/00—Systems containing at least three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2101/00—Systems containing only non-condensed rings
    • C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton

Similar Documents

Publication Publication Date Title
Johnson et al. Stereo-and regioselective methods for the synthesis of three consecutive asymmetric units found in many natural products
Tamura et al. Isolation of helminthosporol as a natural plant growth-regulator and its chemical structure
Urabe et al. An efficient total synthesis of optically active tetrodotoxin from levoglucosenone
Jana et al. Asymmetric total syntheses of cochliomycin A and zeaenol
Naya et al. The structural elucidation of sesquiterpene lactones from Petasites japonicus Maxim
Carman et al. 2-α, 4-Dihydroxy-1, 8-cineole. A new possum urinary metabolite
Clark et al. Synthesis of medium-sized cyclic allylic ethers by ring-closing metathesis and subsequent elaboration to sub-units found in the brevetoxins and ciguatoxins
ITOKAWA et al. Agarofuran-, eudesmane-and eremophilane-type sesquiterpenoids from alpinia japonica (THUNB.) MIQ.
Trost et al. Atom‐Economic and Stereoselective Syntheses of the Ring A and B Subunits of the Bryostatins
Zong et al. Enantioselective total syntheses of manginoids A and C and guignardones A and C
Krohn et al. Synthesis of xyloketals, natural products from the mangrove fungus Xylaria sp
Kharitonov et al. Synthetic transformations of higher terpenoids. XXXIII.* Preparation of 15, 16-dihydroisopimaric acid and methyl dihydroisopimarate and their transformations
Raghavan et al. Total Synthesis of (+)‐(2′ S, 3′ R)‐Zoapatanol Exploiting the B‐Alkyl Suzuki Reaction and the Nucleophilic Potential of the Sulfinyl Group
Ma et al. Ring‐Closing Metathesis in the Synthesis of BC Ring‐Systems of Taxol
Kim et al. Stereoselective Synthesis of (−)‐Amphidinolide E
Esquivel et al. Salvigenane and isosalvipuberulan diterpenoids from Salvia leucantha.
Kometani et al. Pyranonaphthoquinone antibiotics. 3. Synthesis of (+)-9-deoxygriseusin B and absolute configuration revision of griseusins A and B
Silva et al. Towards the total synthesis of mycaperoxide B: Probing biosynthetic rationale
Chakraborty et al. Synthesis of highly substituted tetrahydropyrans: preparation of the C20–C28 moiety of phorboxazoles
Zanato et al. Highly Stereoselective Total Synthesis of (+)‐9‐epi‐Dictyostatin and (–)‐12, 13‐Bis‐epi‐dictyostatin
Giorgi et al. A one-pot sequence for the efficient synthesis of highly functionalized macrocarbocycles or bridged 2, 8-dioxabicyclo [3.2. 1] octanes from 1-nitrobicyclic compounds
Bouzbouz et al. Enantioselective synthesis of cordiachromene
Álvarez et al. Synthesis of enantiomerically pure 2, 5-disubstituted 3-oxygenated tetrahydrofurans
Khandekar et al. Asymmetric total syntheses of aspilactonol F and aspiketolactonol and synthetic studies toward diplofuranoxin
Honda DEVELOPMENT OF SAMARIUM DIIODIDE-PROMOTED REGIOSELECTIVE CARBON-CARBON BOND CLEAVAGE REACTION