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ZA201504215B - Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins - Google Patents

Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Info

Publication number
ZA201504215B
ZA201504215B ZA2015/04215A ZA201504215A ZA201504215B ZA 201504215 B ZA201504215 B ZA 201504215B ZA 2015/04215 A ZA2015/04215 A ZA 2015/04215A ZA 201504215 A ZA201504215 A ZA 201504215A ZA 201504215 B ZA201504215 B ZA 201504215B
Authority
ZA
South Africa
Prior art keywords
oxygenates
olefins
conversion
production
zeolitic material
Prior art date
Application number
ZA2015/04215A
Inventor
Kerem Bay
Kirsten Braunsmann
Milan Kostur
Ulrich Müller
Manuela Gaab
Andrei-Nicolae Parvulescu
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of ZA201504215B publication Critical patent/ZA201504215B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
ZA2015/04215A 2012-11-13 2015-06-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins ZA201504215B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12192407 2012-11-13
PCT/IB2013/060057 WO2014076625A1 (en) 2012-11-13 2013-11-11 Production and Use of a Zeolitic Material in a Process for the Conversion of Oxygenates to Olefins

Publications (1)

Publication Number Publication Date
ZA201504215B true ZA201504215B (en) 2017-11-29

Family

ID=47143770

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2015/04215A ZA201504215B (en) 2012-11-13 2015-06-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Country Status (6)

Country Link
EP (1) EP2920112A4 (en)
JP (1) JP6461807B2 (en)
KR (1) KR102171666B1 (en)
CN (1) CN104918886B (en)
WO (1) WO2014076625A1 (en)
ZA (1) ZA201504215B (en)

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JP6538039B2 (en) 2013-10-23 2019-07-03 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Molding for hydrophobic zeolitic material and method for producing the same
JP6519943B2 (en) * 2015-03-25 2019-05-29 株式会社豊田中央研究所 Spherical silica-based mesoporous material and method for producing the same
EP3341329B1 (en) * 2015-08-27 2024-11-13 Chevron U.S.A. Inc. Molecular sieve ssz-91 and uses for ssz-91
JP2017114755A (en) * 2015-12-25 2017-06-29 ユニオン昭和株式会社 Zeolite and manufacturing method therefor
EP3417929A4 (en) * 2016-02-19 2019-10-23 Hitachi Zosen Corporation ZEOLITE SEPARATION MEMBRANE AND METHOD FOR PRODUCING THE SAME
CN106064822B (en) * 2016-05-30 2018-03-23 中国科学院大连化学物理研究所 A kind of MWW/MEL cocrystallization molecular sieve and its synthetic method
CN109311687B (en) * 2016-06-17 2022-10-14 巴斯夫欧洲公司 Method for continuous synthesis of zeolitic materials
WO2018046481A1 (en) * 2016-09-06 2018-03-15 Basf Se Solidothermal synthesis of a boron-containing zeolite with an mww framework structure
US10682635B2 (en) 2016-09-30 2020-06-16 Johnson Matthey Public Limited Company Zeolite synthesis with a fluoride source
EP3600653A1 (en) 2017-03-29 2020-02-05 ExxonMobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
WO2019030279A1 (en) * 2017-08-08 2019-02-14 Basf Se A composition comprising a mixed metal oxide and a molding comprising a zeolitic material having framework type cha and an alkaline earth metal
CN108751219B (en) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 Hierarchical porous EU-1 molecular sieve and synthesis method thereof
CN108946762B (en) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 Hierarchical porous EU-1 molecular sieve and preparation method thereof
WO2020221683A1 (en) 2019-04-29 2020-11-05 Basf Se Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst
US20230008221A1 (en) * 2019-12-11 2023-01-12 Basf Se Process for preparing a molding comprising a zeolite catalyst and method for converting oxygenates to olefins using the catalytic molding
CN111573694B (en) * 2020-06-17 2021-10-15 浙江大学 Method for one-step synthesis of aluminum-rich *MRE zeolite molecular sieve with organic template agent
CN116422362B (en) * 2021-12-30 2024-12-20 卓悦环保新材料（上海）有限公司 A kind of methanol to propylene catalyst with anti-crushing property and its preparation method and application
TW202436270A (en) * 2023-01-30 2024-09-16 日商旭化成股份有限公司 Ethanol conversion method, catalyst containing zeolite, method for producing catalyst containing zeolite, and method for producing hydrocarbons, etc.

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US4851605A (en) * 1984-07-13 1989-07-25 Exxon Research & Engineering Co. Process for synthesizing a zeolite catalyst on a pH controlled sodium free basis
DE4131448A1 (en) * 1991-09-21 1993-03-25 Basf Ag METHOD FOR THE PRODUCTION OF ESSENTIALLY ALKALIFE BORSILICATE CRYSTALS WITH ZEOLITE STRUCTURE
JP2005138000A (en) * 2003-11-05 2005-06-02 Jgc Corp Catalyst, method for preparing catalyst and method for producing lower hydrocarbon using the same catalyst
DE10356184A1 (en) * 2003-12-02 2005-07-07 Basf Ag Pentasil-type zeolitic material, its preparation and its use
JP5717447B2 (en) * 2008-02-22 2015-05-13 エクソンモービル・ケミカル・パテンツ・インク Large crystal molecular sieve and its manufacture
KR20120085718A (en) * 2009-07-13 2012-08-01 유니버시떼 드 리에즈 Solid inorganic composition, method for preparing same, and use thereof for reducing dioxins and heavy metals in flue gases
EP2348004A1 (en) * 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process

Also Published As

Publication number Publication date
CN104918886B (en) 2018-08-10
EP2920112A1 (en) 2015-09-23
WO2014076625A1 (en) 2014-05-22
KR20150086300A (en) 2015-07-27
EP2920112A4 (en) 2016-12-07
KR102171666B1 (en) 2020-10-29
JP6461807B2 (en) 2019-01-30
JP2016502487A (en) 2016-01-28
CN104918886A (en) 2015-09-16

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