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ZA201404092B - Process for producing methanation catalyst and process for methanation of synthesis gas - Google Patents

Process for producing methanation catalyst and process for methanation of synthesis gas

Info

Publication number
ZA201404092B
ZA201404092B ZA2014/04092A ZA201404092A ZA201404092B ZA 201404092 B ZA201404092 B ZA 201404092B ZA 2014/04092 A ZA2014/04092 A ZA 2014/04092A ZA 201404092 A ZA201404092 A ZA 201404092A ZA 201404092 B ZA201404092 B ZA 201404092B
Authority
ZA
South Africa
Prior art keywords
methanation
synthesis gas
producing
catalyst
methanation catalyst
Prior art date
Application number
ZA2014/04092A
Inventor
Guido Wasserschaff
Andreas Strasser
Stephan Schunk
Claudia Querner
Thomas Roussière
Andrian Milanov
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of ZA201404092B publication Critical patent/ZA201404092B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B01J27/236—Hydroxy carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0081—Preparation by melting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/73—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline having a two-dimensional layered crystalline structure, e.g. layered double hydroxide [LDH]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ZA2014/04092A 2011-11-08 2014-06-05 Process for producing methanation catalyst and process for methanation of synthesis gas ZA201404092B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11188238 2011-11-08
PCT/IB2012/056208 WO2013068931A1 (en) 2011-11-08 2012-11-07 Process for producing methanation catalyst and process for methanation of synthesis gas

Publications (1)

Publication Number Publication Date
ZA201404092B true ZA201404092B (en) 2016-06-29

Family

ID=48288611

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2014/04092A ZA201404092B (en) 2011-11-08 2014-06-05 Process for producing methanation catalyst and process for methanation of synthesis gas

Country Status (8)

Country Link
EP (1) EP2776164A4 (en)
JP (1) JP6125518B2 (en)
KR (1) KR20140097308A (en)
CN (1) CN104039452B (en)
CA (1) CA2854914A1 (en)
RU (1) RU2014123057A (en)
WO (1) WO2013068931A1 (en)
ZA (1) ZA201404092B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140099475A (en) * 2011-11-08 2014-08-12 바스프 에스이 Process for producing reforming catalyst and reforming of methane
CN104028270A (en) * 2014-06-10 2014-09-10 中国华能集团清洁能源技术研究院有限公司 Methanation catalyst and preparation method thereof
CN105817219B (en) * 2015-01-04 2018-10-16 神华集团有限责任公司 A kind of methanation catalyst and its preparation method and application
WO2018219992A1 (en) 2017-06-02 2018-12-06 Basf Se Method for carbon dioxide hydrogenation in the presence of a nickel- and magnesium-spinel-containing catalyst
US20230108996A1 (en) * 2020-01-31 2023-04-06 Institute Of Chemical Technology Catalyst for co2 methanation reaction having high activity and long term stability and process thereof
CN114250357B (en) * 2020-09-22 2023-07-25 中冶长天国际工程有限责任公司 High-hydrogen low-carbon sintering material layer structure, sintering system and method
CN113368851A (en) * 2021-06-09 2021-09-10 中国科学院青岛生物能源与过程研究所 Method for preparing oxide-supported metal and application
KR102619167B1 (en) * 2022-02-25 2023-12-27 포항공과대학교 산학협력단 MANUFACTURING METHOD of METHANE REFORMING REACTION CATALYST WITH IMPROVED THERMAL STABILITY AND CATALYSTS THEREOF

Family Cites Families (17)

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Publication number Priority date Publication date Assignee Title
NL302476A (en) * 1962-12-29
DE2231317A1 (en) * 1972-06-27 1974-01-10 Basf Ag CATALYST AND ITS USE IN THE MANUFACTURE OF METHANE
DE2314804C3 (en) * 1973-03-24 1982-01-21 Metallgesellschaft Ag, 6000 Frankfurt Process for generating methane-containing gases from hydrocarbons
US4217295A (en) * 1975-07-16 1980-08-12 Nl Industries, Inc. Process of catalytic methanation
CA1078878A (en) * 1975-07-16 1980-06-03 Nl Industries Process of catalytic methanation
DE2729921C3 (en) * 1977-07-02 1985-01-03 Metallgesellschaft Ag, 6000 Frankfurt Process for generating a gas that is exchangeable with natural gas
DE2952683A1 (en) * 1979-12-29 1981-07-02 Ruhrchemie Ag, 4200 Oberhausen METHANIZATION CATALYST AND METHOD FOR PRODUCING IT
GB2222963B (en) * 1988-09-23 1992-01-02 British Gas Plc Catalysts
US5399537A (en) * 1992-12-21 1995-03-21 Amoco Corporation Method for preparing synthesis gas using nickel catalysts
EP1013603A1 (en) * 1998-12-22 2000-06-28 Haldor Topsoe A/S Process for catalytical steam reforming of a hydrocarbon feedstock
WO2001025142A1 (en) * 1999-10-01 2001-04-12 Bp Amoco Corporation Preparing synthesis gas using hydrotalcite-derived nickel catalysts
FR2809030B1 (en) * 2000-05-22 2002-08-16 Univ Pasteur CATALYST FOR GASIFICATION OF BIOMASS IN A FLUIDIZED BED, PROCESS FOR OBTAINING AND USES OF SUCH A CATALYST
KR100398058B1 (en) * 2001-05-18 2003-09-19 주식회사 경동도시가스 Modified θ-alumina-supported nickel reforming catalysts and its use for producing synthesis gas from natural gas
JP4488178B2 (en) * 2004-02-26 2010-06-23 戸田工業株式会社 Methanation catalyst and method for producing the same, and method for methanation of carbon monoxide using the methanation catalyst
KR100892033B1 (en) * 2007-10-08 2009-04-07 한국에너지기술연구원 Nickel-based reforming catalyst supported on a nanoscale in a large-sized spinel-structured nanosized crystal with nanoscale crystals and a method for producing syngas from natural gas by steam-carbon dioxide complex reforming using the same
EP2226308B1 (en) * 2007-12-28 2018-10-17 Toda Kogyo Corp. Molded porous article, method for production thereof, catalyst carrier, and catalyst
KR100991263B1 (en) * 2008-08-01 2010-11-01 현대중공업 주식회사 Nickel-based catalyst for mixed reforming to reform natural gas into steam and carbon dioxide simultaneously

Also Published As

Publication number Publication date
JP2015502247A (en) 2015-01-22
WO2013068931A1 (en) 2013-05-16
JP6125518B2 (en) 2017-05-10
CN104039452A (en) 2014-09-10
RU2014123057A (en) 2015-12-20
CN104039452B (en) 2017-03-08
EP2776164A1 (en) 2014-09-17
KR20140097308A (en) 2014-08-06
EP2776164A4 (en) 2015-08-19
CA2854914A1 (en) 2013-05-16

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