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WO2025108865A1 - Compositions herbicides - Google Patents

Compositions herbicides Download PDF

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Publication number
WO2025108865A1
WO2025108865A1 PCT/EP2024/082650 EP2024082650W WO2025108865A1 WO 2025108865 A1 WO2025108865 A1 WO 2025108865A1 EP 2024082650 W EP2024082650 W EP 2024082650W WO 2025108865 A1 WO2025108865 A1 WO 2025108865A1
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WIPO (PCT)
Prior art keywords
cas
methyl
active ingredient
dat
application rate
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German (de)
English (en)
Inventor
Elmar Gatzweiler
Lothar LORENTZ
Hendrik Helmke
Harald Jakobi
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Bayer AG
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Bayer AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides

Definitions

  • the invention lies in the technical field of plant protection agents which can be used against undesired plant growth in non-cultivated land, for seed preparation or in plant crops and which contain as herbicidal active ingredients a combination of at least two herbicides, the compositions containing herbicidally active compounds (Ag) and (B), wherein (A) one or several compounds of the general formula (I) or their agrochemically acceptable salts [Herbicides (A) or component (A)] and (B) means one or more herbicides (component B).
  • herbicides Compounds from the structural class of substituted n-phenyluracils are known as herbicides (see international application with application number PCT/EP2023/077211).
  • the compounds are effective against a broad spectrum of weeds by pre-emergence and post-emergence application, allowing non-selective use to control unwanted plant growth or selective use in plant crops.
  • the effectiveness of these herbicides against weeds is high, but generally depends on the application rate, the respective breeding form, the weed spectrum, the weeds to be controlled, the climate and soil conditions, etc. Another criterion is the duration of the herbicide's effect or degradation rate. Changes in the susceptibility of weeds, which may occur with prolonged use of the herbicide or due to geographical limitations, must also be taken into account.
  • Losses in effectiveness in individual plants can only be compensated to a limited extent by applying high herbicide rates, e.g. B. because it often worsens the selectivity of the herbicide or improves the effectiveness does not occur even with higher application rates.
  • high herbicide rates e.g. B. because it often worsens the selectivity of the herbicide or improves the effectiveness does not occur even with higher application rates.
  • a lower Application rate not only reduces the amount of an active ingredient required for the application, but also generally reduces the amount of formulation aids required. Both reduce the economic outlay and improve the environmental compatibility of the herbicide treatment.
  • One way to improve the application efficiency of a herbicide can be to combine the active ingredient with one or more other ingredients that contribute the desired additional properties.
  • composition comprising herbicidally active compounds (A) and (B), where (A) is one or more compounds of the general formula (I) or their agrochemically acceptable salts [component (A)] and (B) is one or more herbicides [component (B)] selected from the group of herbicidally active compounds (B1) bBi1s1 ().
  • compositions according to the invention act in particularly favorable combinations, e.g., when they are used to control undesirable plant growth in crops such as wheat (durum and soft wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as, for example, bush beans and horse beans), flax, barley, oats, rye, rice, potatoes, and millet (sorghum), non-cultivated pastureland, and green/lawn areas and plantation crops.
  • crops such as wheat (durum and soft wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as, for example, bush beans and horse beans), flax, barley, oats, rye, rice, potatoes, and millet (sorghum), non-cultivated pastureland, and green/lawn areas and plantation crops.
  • the present invention relates to compositions comprising herbicidally active compounds (A) and (B), where (A) represents one or more compounds of the general formula (I) or their
  • (B) represents one or more herbicides [component (aBu)]s from the group of herbicidal active ingredients (B1) to (B11), wherein (B1) represents herbicidal active ingredients from the group of the 1,3-diketo compounds mentioned below (B1.1) Alloxydim, (CAS 55634-91-8), (CAS 55635-13-7) (B1.2) Bicyclopyrone, (CAS 352010-68-5) (B1.3) Butroxydim, (CAS 138164-12-2) (B1.4) Clethodim, (CAS 99129-21-2) (B1.5) Cycloxydim, (CAS 101205-02-1) (B1.6) Fenquinotrione
  • CAS RN Cosmetic Abstract Service Number
  • the CAS RN is a commonly used reference number which allows a unique assignment of the designated Substances are possible because the "CAS RN” distinguishes, among other things, between their isomers, including stereoisomers, as well as salts and esters.
  • the name of the neutral compound is given in the list above.
  • the CAS given in parentheses refers to these, as well as to all other recognized forms of the active ingredient, such as salts or adducts.
  • 2,4-D-ammonium 2,4-D-choline (the choline salt of 2o,n4-D); 2,4-D-BAPMA (N,N-bis-(3-aminopropyl)methylamine salt of 2,4-D); 2,4-D-dimethylammonium; 2,4-D-dimethylammonium; 2,4- D-dodecyl ammonium; 2,4-D-heptylammonium; 2,4-D-Irsopyl ammonium; 2,4-D lithium; 2,4-D Potassium; 2,4-D-sodium; 2,4-D-tetradecylammonium; 2,4-D-triethylammonium; 2,4-D-tris(2-hydroxypropyl)ammonium; 2,4-D-monoethanolammonium (monoethanolamine salt of 2,4-D); 2,4-D-diethanolammonium (the diethanolamine salt of 2,4-D).
  • compositions according to the invention may contain various components, e.g. B.
  • the components can be formulated and applied together (ready-to-use formulation) or can be formulated separately and applied together, e.g., in a tank mix or in sequential application.
  • the individual herbicidal active ingredients of the general formula (I) contained as component (A) are also referred to below as compounds (A), substances (A), components (A) or herbicides (A). Accordingly, the individual herbicidal active ingredients contained as component (B) are hereinafter also referred to as compounds (B), active ingredient (Bs), components (B) or herbicides (B)
  • An advantageous property of the combination of herbicides (A) and (B) according to the invention is that active ingredients (A) and (B) are compatible with each other, i.e. they can be used together without significant chemical incompatibility of the active ingredients (A) and/or (B). occur, which lead to the decomposition of one or more of the active ingredients.
  • the active ingredients (A) and (B) are therefore particularly suitable for use together or in addition to other crop protection active ingredients or agrochemicals.
  • the possible combined use allows the utilization of advantageous effects, such as the expansion of the spectrum of weeds to be controlled or combated in one application, and the reduction of the application rate of the individual herbicides (A) or (B) compared to the respective application rate of the herbicide in question when applied individually. This can influence the degradation behavior of the active ingredients and create more favorable conditions for the subsequent cultivation of crops.
  • a further advantage is that the development of resistance to the active ingredients can be prevented by combining BCS231024-Ausland STR 21 of active ingredients with different modes of action can often be significantly reduced or avoided.
  • the synergistic effects allow a further reduction in the application rate, the control of a broader range of weeds and grasses, a faster onset of the herbicidal effect, a more consistent long-lasting effect, better control of weeds with only one or a few applications, and an extension of the possible application period.
  • the use of the products also reduces the amount of harmful substances, such as nitrogen or oleic acid, and their input into the soil.
  • the properties and advantages mentioned are desirable in practical weed control to keep agricultural crops free of unwanted weeds and thus to ensure and/or increase yields qualitatively and quantitatively.
  • the new combinations significantly exceed the technical standard with regard to the described properties.
  • the synergistic effects are observed when the active ingredients (A) and (B) are applied together, but can also frequently occur with staggered applications (splitting). It is also possible to apply the herbicides (A) or (B) or the herbicidal composition (A) and (B) in several portions (sequential application). For example, one or more pre-emergence applications can be followed by a post-emergence application, or an early post-emergence application can be followed by a mid- or late post-emergence application. The preferred method is the simultaneous or timely application of the active ingredients of the respective combination, if necessary in several portions. However, staggered application of the individual active ingredients of a combination is also possible and can be advantageous in isolation.
  • plant protection products such as the other active ingredients mentioned (other herbicides, fungicides, insecticides, acaricides, etc.) and/or various auxiliary substances, adjuvants and/or fertilizer applications, can also be integrated into the application system.
  • active ingredients other herbicides, fungicides, insecticides, acaricides, etc.
  • auxiliary substances, adjuvants and/or fertilizer applications can also be integrated into the application system.
  • pre-emergence or post-emergence application of the active ingredients is to be avoided or the application of the active ingredients before or after the visible appearance of the weed above the ground, respectively. against the harmful plants before the emergence of the crop or after the emergence of the crop understand.
  • the compounds of formula (I) can, depending on the way in which the substituents are linked, be Stereoisomers exist. For example, if one or more asymmetrically substituted carbon atoms and/or sulfoxides are present, ionomers and diastereomers can occur. Stereoisomers can be obtained from the mixtures obtained during preparation by conventional separation methods, for example by chromatographic separation processes. Stereoisomers can also be prepared selectively by employing stereoselective chromatography using optically active starting materials and/or auxiliaries.
  • the invention also relates to all stereoisomers and mixtures encompassed by formula (I) but not specifically defined.
  • compounds of formula (I) Although both the pure compounds and, where appropriate, mixtures with varying proportions of the isomeric compounds are meant.
  • these compounds of formula (I) have acidic properties and can form salts, optionally also internal salts or adducts, with inorganic or organic bases or with metal ions. If the compounds of formula (I) contain hydroxy, carboxy or other groups with acidic properties, these Compounds with bases are converted to salts.
  • Suitable bases are, for example, hydroxides, Carbonates, hydrogen carbonates of alkali and alkali metal hydroxides, especially those of sodium, potassium, Magnesium and calcium, furthermore ammonia, primary, secondary and tertiary amines with 1- (C 4 -)- Alkyl groups, mono-, di- and trialkanolamines of 1 (-C 4 )-alkanols, choline and chlorocholine, as well as organic amines such as trialkylamines, morpholine, pyridine or pyridine.
  • salts are compounds in which the acidic hydrogen is replaced by a cation suitable for agriculture, for example metal salts, in particular alkali metal salts or alkaline earth metal salts, especially sodium and potassium salts, or ammonium salts, salts with organic amines or quaternary ammonium salts, for example cations of the formula [NRR ⁇ R ⁇ ⁇ R ⁇ ⁇ + ',] wherein R to R''' each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl.
  • Suitable salts include alkylsulfonium and alkylsulfoxonium salts, such as (C 1 -C 4 )-trialkylsulfonium and (C 1 -C 4 )-trialkylsulfoxonium salts.
  • the compounds of formula (I) can be prepared by annealing with a suitable inorganic or organic acid, such as mineral acids, for example HCl, HBr,2 HSO4, H3PO4 or HNO3, or organic acids, e.g., carboxylic acids, such as acetic acid, propionic acid, Oxalic acid, lactic acid or salicylic acid or sulfonic acids, such as p-toluenesulfonic acid, BCS231024-Ausland STR 23 a basic group, such as amino, alkylamino, alkylamino, piperidino, morpholino, or pyridino, can form salts. These salts contain the conjugate base of the acid as an anion.
  • a suitable inorganic or organic acid such as mineral acids, for example HCl, HBr,2 HSO4, H3PO4 or HNO3, or organic acids, e.g., carboxylic acids, such as acetic acid, propionic acid, Ox
  • Suitable substituents which are present in deprotonated form, e.g., sulfonic acids or carboxylic acids, can form internal salts with prone-to-protonation groups, such as amino groups. If a group is multiply substituted by residues, this means that this group is substituted by one or more several identical or different ones of the mentioned s Ruebsstituiert.
  • prone-to-protonation groups such as amino groups. If a group is multiply substituted by residues, this means that this group is substituted by one or more several identical or different ones of the mentioned s Ruebsstituiert.
  • the situations and symbols defined has the same meaning as described under the general formula (I) of the herbicides (A). Arrows in a chemical formula indicate the points of connection to the remaining molecule.
  • herbicidally active substances are compounds of the formula (I), where R 1 stands for hydrogen, R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine, bromine, cyano, N2O, BCS231024-Foreign STR 24 R 5 stands for hydrogen, R 6 for hydrogen, fluorine, chlorine, bromine or cyano oh st,t R 7 represents hydrogen, G represents methylene or (methyl)methylene, X represents O (oxygen) or S (sulfur), Y represents O (oxygen), and Q represents one of the groups Q-1 to Q-25 specifically mentioned above.
  • R 1 stands for hydrogen
  • R 2 stands for fluorine
  • R 3 stands for fluorine
  • R 4 stands for chlorine, bromine, cyano, N2O
  • R 5 stands for hydrogen
  • R 6 for hydrogen, fluorine, chlorine, bromine or cyano oh st
  • t represents hydrogen
  • G represents methylene or
  • herbicidally active substances are compounds of the formula (I), where R 1 stands for hydrogen, R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine, bromine, cyano, R 5 stands for hydrogen, R 6 stands for hydrogen, fluorine, BCS231024-Foreign STR 25
  • R 7 represents hydrogen
  • G represents methylene
  • X represents O (oxygen)
  • Y represents O (oxygen)
  • Q represents one of the groups Q-1, Q-2, Q-4, Q-5, Q-6, Q-7, Q-8, Q-9, Q-10, Q-12, Q-13, Q-14, Q-15, Q-16, Q-18 or Q-t1e9ht specifically mentioned above.
  • the herbicidal composition contains, in addition to at least one component (B) as above, preferably a compound [component (A)] of the general formula (I) or its agriculturally acceptable salts, where R 1 stands for hydrogen, R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine, R 5 stands for hydrogen, R 6 stands for hydrogen, R 7 stands for hydrogen, G stands for methylene, X stands for O (oxygen), Y stands for O (oxygen) BCS231024-Ausland STR 26 and Q represents the above-mentioned group Q-1.
  • This preferred compound (“A1" hereinafter) is listed below by its structural formula and corresponding IUPAC name.
  • the application rates of the herbicides (A) are in the range from 0.02 to 750 g of active substance per hectare (hereinafter g a.i./ha), preferably 0.05 to 40 g a.i./ha, in particular 0.25 to 300 g a.i./ha.
  • the application rates are in the range from 0.02 to 750 g of active substance per hectare (hereinafter g a.i./ha), preferably 0.05 to 40 g a.i./ha, in particular 0.25 to 300 g a.i./ha.
  • herbicides (B) have surprisingly proven to be particularly good combination partners.
  • the preferred, least preferred, and most preferred herbicides (B) are listed below as further embodiments of the invention.
  • BCS231024-Ausland STR 27 the herbicidal active ingredients (B1) are preferred: (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.10) sethoxydim, (B1.11) sulcotrione, (B1.14) tembotrione, (B1.16) tralkoxydim.
  • group B1 Particularly preferred from group B1 are the herbicidal active ingredients (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.14) tembotrione. Particularly preferred from group B1 are the following active ingredients: (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.14) tembotrione.
  • the herbicidal active ingredients (B2) are preferred: (B2.1) acetochlor, (B2.4) asulam, (B2.6) beflubutamid, (B2.10) chlorimuron, (B2.12) chlorsulfuron, (B2.14) chloransulam, (B2.17) diclosulam, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.23) ethoxysulfuron, BCS231024-Abroad STR 28 (B2.24) Flazasulfuron, (B2.25) Florasulam, (B2.26) Flucarbazone, (B2.28) Flufenacet, (B2.29) Flumetsulam, (B2.30) Flupyrsulfuron, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.41) Metosulam, (B2.41) Metosulam,
  • group B2 Particularly preferred from group B2 are the active ingredients (B2.1) acetochlor, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.24) flazasulfuron, (B2.28) flufenacet, (B2.31) foramsulfuron, (B2.34) iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.43) Nicosulfuron, BCS231024-Ausland STR 30 (B2.48) Phenmedipham, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.68) Thiencarbazone, (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophelne)-y5-methoxy-4H-isoxazol-5-carbonyl]amino]tetrahydrofuran-2-carboxylate
  • BCS231024-Ausland STR 31 Particularly preferred from group B2 are active ingredients (B2.1) acetochlor, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.28) flufenacet, (B2.31) foramsulfuron, (B2.34) iodosulfuron, (B2.37) Mesosulfuron, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.68) Thiencarbazone, (B2.81) Icafolin-methyl.
  • the herbicidal active ingredients (B3) preferred: (B3.1) Bromoxynil, (B3.4) Ioxynil.
  • herbicidal active ingredients (B3.1) are: (B3.1) Bromoxynil.
  • preferred herbicidal active ingredients (B4) are: (B4.2) Amitrole, (B4.8) Carfentrazone, (B4.10) Imazamethabenz, (B4.11) Imazamox, (B4.12) Imazapic, (B4.13) Imazapyr, (B4.15) Imazethapyr, (B4.17) Isoxaben, (B4.18) Isoxaflutole, (B4.20) Oxadiazon, (B4.21) Pyraflufen, (B4.22) Pyrasulfotole, (B4.23) B4.25) Pyroxasulfones, BCS231024-Abroad STR 32 (B4.26) Sulfentrazone, (B4.27) Tolpyralate, (B4.28) Topramezone, (B4.33) Flupoxam Particularly preferred from group B4 are the hidden active ingredients (B4.8) Carfentrazone, (B4.27) Tolpyr
  • the herbicidal active ingredients (B5) are preferred: (B5.1) Aminocyclopyrachlor, (B5.2) Aminopyralid, (B5.3) Benazolin, (B5.5) Bentazone, (B5.7) Bixlozone, (B5.12) Cinidon, (B5.13) Cinmethylin, BCS231024-Ausland STR 33 (B5.14) Clomazone, (B5.20) Ethalfluralin, (B5.21) Ethofumesate, (B5.22) Flamprop, (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.27) Fluridone, (B5.28) Flurochloridone, (B5.29) Flurtamone, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, (B5.32) Indanofan, (B5.37) Paraquat, (B5.38) Pelargonic acid, (B5.39) Pendimethalin, (B5.45) Tria
  • Particularly preferred active ingredients from group B5 are (B5.5) Bentazone, (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, BCS231024-Ausland STR 34 (B5.37) Paraquat, (B5.38) Pelargonic acid, (B5.39) Pendimethalin, (B5.55) MSMA.
  • Particularly preferred from group B5 are the following active ingredients: (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.37) Paraquat, (B5.39) Pendimethalin.
  • the herbicidal active ingredients (B6) are preferred: (B6.2) Clopyralid, (B6.3) Dicamba, (B6.4) Fluroxypyr, (B6.5) Picloram. Particularly preferred from group B6 is the following active ingredient: (B6.3) Dicamba.
  • the herbicidal active ingredients (B7) are preferred: (B7.2) bialaphos, (B7.4) glufosinate, (B7.5) glyphosate, (B7.7) sulfosate.
  • group B7 Particularly preferred from group B7 are these herbicidal active ingredients (B7.4) glufosinate, (B7.5) glyphosate, (B7.7) sulfosate. Particularly preferred from group B7 are these herbicidal active ingredients (B7.4) glufosinate, (B7.5) glyphosate.
  • the herbicidal active ingredients (B8) are preferred: (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) Acifluorfen, (B8.5) Aclonifen, (B8.8) Clodinafop, (B8.11) Diclofop, (B8.13) Fenoxaprop, (B8.16) Fomesafen, (B8.19) Lactofen, (B8.20) MCPA, (B8.22) Mecoprop, (B8.24) Oxyfluorfen, (B8.26) Quizalofop, (B8.27) Quizalofop-P.
  • Particularly preferred active ingredients from group B8 are (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) acifluorfen, (B8.5) aclonifen, (B8.16) fomesafen, (B8.19) lactofen, and (B8.24) oxyfluorfen.
  • Particularly preferred active ingredients from group B8 are (B8.1) 2,4-D, (B8.5) aclonifen, (B8.16) fomesafen, and (B8.24) oxyfluorfen.
  • the herbicidal active ingredients (B9) are preferred: (B9.3) Butafenacil, (B9.9) Pyrithiobac-sodium, (B9.10) Saflufenacil, (B9.11) Terbacil, (B9.12) Tiafenacil, (B9.13) Trifludimoxazine, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (B9.15) Ethyl 3- ⁇ 2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)- 3,6-dihydropyrimidin-1(2H)-yl]phenyl
  • active ingredients from group B9 are (B9.3) butafenacil, (B9.10) saflufenacil, (B9.12) tiafenacil, (B9.13) trifludimoxazine, BCS231024-Ausland STR 37 (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (B9.15) Ethyl-3- ⁇ 2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]phenyl ⁇ -5-methyl-4,5-dihydro-1,2-oxazole-5-carboxylate (B9.16) 3-[2-chloro
  • the herbicidal active ingredients (B10) are preferred: (B10.1) Chlorobromuron, (B10.2) Chlorotoluron, (B10.5) Diuron, (B10.7) Fluometuron, (B10.8) Isoproturon, (B10.9) Linuron, (B10.10) Methabenzthiazuron, (B10.11) Metobromuron, (B10.12) Metoxuron, (B10.13) Monolinuron BCS231024-Ausland STR 38 Particularly preferred from group B10 are the following active ingredients: (B10.5) Diuron, (B10.7) Fluometuron, (B10.8) Isoproturon.
  • herbicidal active ingredients (B10.5) Diuron, (B10.7) Fluometuron.
  • the herbicidal active ingredients (B11) are preferred: (B11.1) Ametryne, (B11.2) Atrazine, (B11.5) Hexazinone, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11.12) Simazine, (B11.15) Terbuthylazine, (B11.16) Terbutryne.
  • herbicidal active ingredients from group B11 are (B11.2) atrazine, (B11.6) indaziflam, (B11.8) metribuzin, (B11.15) terbuthylazine.
  • herbicidal compositions comprising (A) one or more compounds of the general formula (I) or their agrochemically acceptable salts [pCo component (A)] and (B) one or more Herbicides [component (B)] selected from the group consisting of herbicidal active ingredients (B1) to (B11) of of the present invention, in which the disclosed, preferred, particularly preferred and most preferred versions can be combined as listed above.
  • compositions containing (A) one or more herbicidally active compounds (A) of the general formula (I) or their agrochemically acceptable salts [herbicides (A)], as well as a herbicide (B), have surprisingly proven advantageous.
  • the preferred, particularly preferred, and most preferred binary systems are listed below as further embodiments of the present invention.
  • the composition preferably contains (A) a compound of the general formula (I) or its agrochemically acceptable salts [herbicides (A)].
  • R 1 stands for hydrogen
  • R 2 stands for fluorine
  • R 3 stands for fluorine
  • R 4 represents chlorine, bromine or cyano
  • R 5 stands for hydrogen
  • R 6 represents hydrogen
  • R 7 stands for hydrogen
  • G stands for methylene
  • X stands for O (oxygen)
  • BCS231024-Ausland STR 40 Y stands for O (oxygen)
  • Q stands for one of the groups Q-1, Q-2, Q-4, Q-5, Q-6, Q-7, Q-8, Q-9, Q-10, Q-12, Q-13, Q-14, Q-15, Q-16, Q-18, or Q-t1e9ht specifically mentioned above.
  • compositions in the sense of the present invention are the Compositions as listed in the following table 2f.: Table 2.1: Particularly preferred binary compositions containing (A1) Binary compound (A) Compound (B) Composition Z1-1 A1 2,4-D Z1-2 A1 Acetochlor Z1-3 A1 Aclonifen Z1-4 A1 Atrazine Ethyl 3- ⁇ 2-chloro-4-fluoro-5-[3-methyl- 2,6-dioxo-4-(trifluoromethyl)-3,6- Z1-5 A1 dihydropyrimidin-1(2H)-yl]phenyl ⁇ -5-methyl-4,5-dihydro-1,2-oxazole-5-carboxylate BCS231024-Ausland STR 47 Binary Compound (A) Compound (B) Composition 3-[2-chloro-5-(3,5-dimethyl-2,6-dioxo-4-sulfanyliden-1,3,5-triazinan-1-yl)-4- fluoropheny
  • the combinations according to the invention can be used together with other active ingredients such as the active ingredients mentioned (herbicides, fungicides, insecticides, acaricides, etc.) and/or plant growth regulators or auxiliaries from the group of additives customary in plant protection, such as adjuvants and formulation aids.
  • the combination of plant protection product active ingredients, which contain the active ingredients (fA) and (B) and, if applicable, other active ingredients, is referred to here as "herbicide combination.”
  • BCS231024-Ausland STR 49 Application forms such as formulations or tank mixtures represent herbicidal compositions (compositions).
  • the invention therefore also relates to herbicidal compositions which combine the active ingredient combinations according to the invention with additives commonly used in plant protection, such as adjuvants and formulation aids and, where appropriate, other plant protection product active ingredients.
  • the invention also relates to the use or application method using the active ingredient combinations according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically effective content of the respective active ingredient combination.
  • the application rates of the herbicides (B) are known in principle and are generally in the range of 0.01 to 4000 g ai/ha, preferably in the range 0.02 to 3000 g ai/ha, in particular 0.1 to 0.2 g a.i./ha.
  • the application rate is preferably in the range from 0.1 to 3000 g a.i./ha, in particular in the range from 0.127 to 0.50 g a.i./ha, and most preferably in the range from 1 to 2200 g a.i./ha.
  • the application rate is preferably in the range from 10 to 1000 g a.i./ha, in particular in the range from 10 to 50 g a.i./ha, and most preferably in the range from 10 to 300 g a.i./ha.
  • the application rate is preferably in the range from 1 to 1500 g a.i.
  • the application rate is preferably in the range of 1 to 1500 g a.i.
  • the Application rate is preferably 1 to 100,000 g a.i./ha, more preferably 1 to 40,000 g a.i./ha and in particular in the range from 1 to 30,000 g a.i./ha.
  • the application rate is preferably in the range from 1 to 1000 g a.i./ha, in particular in the range from 1 to 80 a.i./ha, and most preferably in the range from 5 to 600 g a.i./ha.
  • the application rate is preferably in the range from 20 to 3000 g a.i./ha, in particular in the range from 20 to 20 g a.i./ha, and most preferably in the range from 30 to 1300 g a.i./ha.
  • the application rate is preferably in the range from 1 to 1500 g a.i./ha, in particular in the range from 1 to 1 g a.i./ha and most preferably in the range from 1 to 800 g a.i./ha.
  • the application rate is preferably in the range from 0.1 to 500 g a.i./ha, in particular in the range from 0.1 to 25 g a.i./ha and most preferably in the range from 0.2 to 100 g a.i./ha.
  • the application rate is preferably in the range from 20 to 2500 g a.i. /ha, in particular in the range of 20 to 1500 g a.i./ha, and most preferably in the range of 20 to 1500 g a.i./ha.
  • the application rate is preferably in the range of 5 to 2000 g a.i./ha, in particular in the range of 5 to 1500 g a.i./ha, and most preferably in the range of 5 to 1000 g a.i./ha.
  • the proportions (A):(B) related to the Gchetw depend on the effective Application rates are generally in the range of 1:100 to 3000:1, preferably 1:80,000 to 2000:1, in particular in the range of 1:15,000 to 1000:1.
  • the preferred weight ratios (A):(B) are as follows: BCS231024-Ausland STR 51 (A):(B1) preferably in the range of 150:1 to 10:02.5, in particular 24:1 to 1:400; (A):(B2) preferably in the range of 1500:1 to 510:040, in particular 120:1 to 1:9000; (A):(B3) preferably in the range of 15:1 to 1:08.5, in particular 12:1 to 1:1200; (A):(B4) preferably in the range of 150:1 to 10:020, in particular 120:1 to 1:4000; (A):(B5) preferably in the range from 150:1 to 10:0107, in particular 120:1 to 1:2400; (A):(B6) preferably in the range from 150:1 to 15:0103, in particular 24:1 to 1:2400; (A):(B7) preferably in the range from 7:1 to 1:1
  • active ingredients C*
  • Suitable combination agents for the compounds according to the invention in mixture formulations or in tank mixes are, for example, known active ingredients which act on the inhibition of, for example, acetolactate synthase, cellulose synthase, Enolpyruvylshikimate-3-phosphate synthase, glutamyin-tShetase, p-hydroxyphenylpyruvate- Dioxygenase, phytoene desaturase, photosystem Io,s Physsotetm II, protoporphyrinogen oxidase, as described, for example, in Weed Research 26) (1494816-445 or "The Pesticide Manual", 14th edition, The British Crop Protection Council and Rhoyal Soc.
  • Known herbicides that can be combined with the compounds of the invention include, for example, the following active ingredients (Note: The compounds are to be identified either by the common name according to the International Organization for Standardization (ISO) or by the chemical name). BCS231024-Foreign STR 52 possibly together with a common code number benzei tc)h and always include all Application forms such as acids, salts, esters and irseom such as stereoisomers and optical isomers.
  • ISO International Organization for Standardization
  • BCS231024-Foreign STR 52 possibly together with a common code number benzei tc)h and always include all Application forms such as acids, salts, esters and irseom such as stereoisomers and optical isomers.
  • acifluorfen allidochlor, amidochlor, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methylphenyl)-5- fluoropyridine-2-carboxylic acid, ammonium sulfame, a bte nfuresate, bensulide, bipyrazone, bromobutide, busoxinone, butenachlor, butylate, b ceanmdichlor, chlorfenac, chlrofenac-ammonium, chlorfenac-sodium, chlorfenprop, chlrofenprop-mel,th chylorflurenol, chlorflurenol-methyl, chlorophthalim, clacyfos, cumyluron, cyanamide, lo caycte, cyprazine, dalapon, dalapon calcium, dalapon magnesium, dalapon sodium, dazomet, daz-s
  • the combinations can be used both pre-emergence and post-emergence.
  • the safeners which are used in an antidote-effective concentration, reduce the phytotoxic side effects of the pesticides used, e.g., in economically important crops such as cereals (wheat, wheat, corn, rice, millet), sugar beet, sugar cane, rapeseed, cotton, and soybeans, preferably fermented cereals.
  • S1 Compounds from the group of heterocyclic benzoic acid derivatives: S1 a ) Compounds of the type dichlorophenylpyrazoli-nc-a3rboxylic acid (S a )1, preferably compounds such as 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-lp-2yrazoline-3-carboxylic acid, 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-lp-2yrazoline-3-carboxylic acid ethyl ester (S1-1) ("Mefenpyr-diethyl”), and related compounds as described in WO-A-91/07874; S1 b ) Derivatives of dichlorophenylpyrazolecarboxylic acid b ) (,S preferably compounds such as 1-(2,4-d
  • S2 a Compounds from the group of 8-quinoline hydroxy acids (S2): S2 a ) Compounds of the 8-quinolinoxyacetic acid type (uSr2e a ), preferably (5-chloro-8-quinolinoxy)acetic acid (1-methylhexyl)ester ("Cloquintocet-mexyl") (S2-1), (5-chloro-8-quinolinoxy)acetic acid (1,3-dimethyl--b1u-yl)ester (S2-2), (5-chloro-8-quinolinoxy)acetic acid 4-allyloxybutylester (S2-3), (5-chloro-8-quinolinoxy)acetic acid 1-allyloxyprop-y-12ester (S2-4), (5-chloro-8-quinolinoxy)acetate ethyl ester (S2-5), (5-chloro-8-quinolinoxy)acetate methyl ester (S2-6) (5-chloro-8-quinolinoxy)acetate
  • S3 Active substances of the dichloroacetamide type (S3ie), often used as pre-emergence safeners (soil-effective safeners) can be used, such as: B “Dichlormid” (N,N-diallyl-2,2-dichloroacetamide) (S31-), "R-29148” (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxoalizdin) from Stauffer (S3-2), "R-28725" (3-dichloroacetyl-2,2,-dimethyl-1,3-oxaizdoinl) from Stauffer (S3-3), "Benoxacor” (4-dichloroacetyl-3,4-dihydro-3-methyHl--21,4-benzoxazine) (S3-4), "PPG-1292" (N-allyl-N-[(1,3-dioxolan-2-yl)-methyld]-ichloroacetamide) from PPG
  • Active ingredients from the class of hydroxyaromatics of aromatic-aliphatic carboxylic acid derivatives (S5), e.g. BCS231024-Ausland STR 59 3,4,5-Triacetoxybenzoic acid ethyl ester, 3,5-Dimeyt-h4o-hydroxybenzoic acid, 3,5-Dihydroxybenzoic acid, 4-Hydroxysalicylic acid, 4-Fsluaolicyclic acid, 2-Hydroxycinnamic acid, 2,4-Dichlorocinnamic acid, as described in WO-A-2004/0846 W310, WO-A-2005/015994, WO-A-2005/016001.
  • S6 Active ingredients from the class of 1,2-dihydroquinoxalin-2-ones (S6), e.g. 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one, 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-thione, 1-(2-aminoethyl)-3-(2-thienyl)-2-dihydroquinoxalin-2-one hydrochloride, 1-(2-methylsulfonylaminoethyl)-3-(2-thienyl)-1,2-hydroquinoxalin-2-one, as described in WO-A-2005/112630.
  • S6 1,2-dihydroquinoxalin-2-ones
  • S7 Compounds from the class of diphenylmethoxyacetic acid derivatives (S7), e.g., methyl diphenylmethoxyacetate (CAS Reg. No. 1N8r.548-19-9) (S7-1), ethyl diphenylmethoxyacetate, or diphenylmethoxyacetic acid, as described in WO-A-98/38856.
  • Active ingredients from the class of 3-(5-tetrazolylcarboxyl)-2-quinolones e.g. 1,2-dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarboxyl)n-2-quinolone (CAS Reg. No.: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3-(5-tetrazolylcarboxyl)-2-quinolone (CAS Reg. No. 95855-00-8), as described in WO-A-1999/000020.
  • S11 Active ingredients of the oxyimino compound type Sn1 (1), which are known as seed dressing agents, such as "Oxabetrinil” ((Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile) (S11-1), which is known as S millet safener against damage from Mcehtlol ra is known, "Fluxofenim” (1-(4-chlorophenyl)-2,2,2-trifluoro-1-heptone-O-(1,3-dioxolan-2-ylmethyl)-oxime) (S11-2), which is known as a seed dressing safener for millet compared to metolachlor, and "Cyometrinil” or “CGA-43089” ((Z)-cyanomethoxyimino(phenyl)acetonitrile) (S11-3), which is known as S millet safener known to be effective against damage from Mcehtlo
  • Active ingredients from the class of isothiochromes such as methyl [(3-oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetate (CAS-R.Nerg. 205121-04-6) (S12-1) and related compounds from WO-A-1998/13361.
  • S13 One or more compounds from group): (S13 BCS231024-Foreign STR 61 "Naphthalic anhydride” (1,8-naphthalenedicarboxylic acid rheohydride) (S13-1), which is known as a seed dressing safener for corn against damage from thiocarbamate herbicides; "Fenclorim” (4,6-dichloro-2-phenylpyrimidine) (S13-,2-d), which is known as a safener for pretilachlor in seeded rice; “Flurazole” (benzyl 2-chloro-4-trifluoromethyl-1,3-iazole-5-carboxylate) (S13-3), which is known as a seed dressing safener for millet against damage from aolrac and metolachlor; "CL 304415” (CAS Reg.
  • Active ingredients which are primarily used as herbicides but also have a safener effect on crop plants e.g. E.g. (2,4-Dichlorophenoxy)acetic acid (2,4-D), (4-Chlorophenoxy)acetic acid, (R,S)-2-(4-Chloro-o-tolyloxy)propionic acid (Mecopro, p) 4-(2,4-Dichlorophenoxy)butyric acid (2,4-DB), (4-Chloro-o-tolyloxy)acetic acid (MCPA), 4-(4-Chloro-o-tolyloxy)butyric acid, 4-(4-Chlorophenoxy)butyric acid, 3,6-Dichloro-2-methoxybenzoic acid (Dicamba), 1-(Ethoxycarbonyl)ethyl-3,6-dichloro-2-methoxybenzoic acid (Lactic acid dichloroethyl).
  • Preferred safeners in combination with the herbicide combinations according to the invention are: Cloquintocet-mexyl, Cyprosulfamide, Fenchlorazole-yelethester, Isoxadifen-ethyl, Mefenpyr-diethyl, Fenclorim, Cumyluron, S4-1 and S4-5, and particularly preferred safeners are: Cloquintocet-mexyl, Cyprosulfamide, Isoxadifen-ethyl and Mefenpyr-dielt.hy
  • the herbicide combinations according to the invention may contain other components, e.g.
  • Plant growth regulators or other active substances that affect harmful organisms such as weeds, Plant-harming animals or plants, particularly active ingredients from the group of herbicides, fungicides, insecticides, acaricides, nematodes, miticides, and related substances.
  • plant growth regulators that can be used as mixing partners are: acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancymidol, 6-benzylaminopurine, brassinolide, catechin, chlormequat chloride, clopp, cocyclonilide, 3-(cycloprop-1-enyl)propionic acid.
  • Fungicidal compounds which, in combination with the inventive Herbicide combinations can be used, preferably commercially available active ingredients, for example (analogous to herbicides, compounds are generally referred to by their common names referred to, here in the usual English spelling iisbe): 1) Inhibitors of ergosterol biosynthesis, for example (1,001) cyproconazole, (1,002) difenoconazole, (1,003) Epoxiconazole, (1,004) Fenhexamide, (1,00e5n)p Fropidine, (1,006) Fenpropimorph, (1,007) Fenpyrazamine, (1,008) Fluquinconazole, (1,009) Fialufotrl, (1,010) Imazalil, (1,011) Imazalil Sulfate, (1,012) Ipconazole, (1,013) Metconazole, (1,014) Moybcultanil, (1,015) Paclobutrazol, (1,016) Prochlo
  • Inhibitors of the respiratory chain on complex I or Ie bre Ii for example (2,001) benzovinindiflupyr, (2,002) bixafen, (2,003) boscalid, (2,004) carboxin, (2,000 F5luopyram, (2,006) flutolanil, (2,007) fluxapyroxad, (2.008) Furametpyr, (2.009) Isofetda,m (2i.010) Isopyrazam (anti-epimeric enantiomer 1R,4S,9S), (2.011) Isopyrazam (anti-epimeric Eonmanetri 1S,4R,9R), (2.012) Isopyrazam (anti-epimeric racemate 1RS,4SR,9SR), (2,013) IsopyraMzaismch (ung of the syn-epimeric racemate 1RS,4SR,9RS and the anti-epimeric racemate 1R,S9S,4RS)
  • Inhibitors of the respiratory chain at complex III for example (3.001) Ametoctradin, (3.002) Amisulbrom, (3.003) Azoxystrobin, (3.004) Coumetyhsotxrobin, (3.005) Coumoxystrobin, (3.006) Cyazofamid, (3.007) Dimoxystrobin, (3.008) Enoxoabsitn, (3.009) Famoxadone, (3.010) Fenamidone, (3.011) Flufenoxystrobin, (3.012) Fluoxastrobin, (3.013) Kresoxim-Methyl, (3.014) Metominostrobin, (3.015) Orysastrobin, (3.016) Picoxystrobin, (3.)0 P17yraclostrobin, (3.018) Pyrametostrobin, (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin (3.021) ()2-2E- ⁇ 2-[( ⁇ [(1E)-1-(3- ⁇ [(E)
  • Inhibitors of mitosis and cell division for example (4.001) Carbendazim, (4.002) Diethofencarb, (4.003) Ethaboxam, (4.004) Fluopicolide, (4.005)c Pyecnuron, (4.006) Thiabendazole, (4.007) Thiophanate-Methyl, (4.008) Zoxamide, (4.009) 3-chloro-4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.010) 3-chloro-5-(4-chlorophenyl)-(-2,6-difluorophenyl)-6-methylpyridazine, (4.011) 3- Chloro-5-(6-chloropyridin-3-yl)-6-methyl-4-(2,4,6-tfluorophenyl)pyridazine, (4,012) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-
  • Inhibitors of amino acid and/or protein synthesis for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3,3,4,4-tetramethyl-t3h, ⁇ 4-dihydroisoquinolin-1-yl)quinoline.
  • Inhibitors of ATP production for example (6.001) silthiofam.
  • Cell wall synthesis inhibitors for example (9is.0e01) Benthiavalicarb, (9.002) Dimethomorph, (9.003) Flumorph, (9.004) Iprovalicarb, (9.005) Medaipnropamid, (9.006) Pyrimorph, (9.007) Valifenalate, (9.008) (2E)-3-(4-tert.-Butylphenyl)--(32-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphenyl)-3-(2-cohrplyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.
  • Inhibitors of lipid and membrane synthesis for example (10.001) Propamocarb, (10.002) Propamocarb hydrochloride, (10,003) tolclofos-methyl.
  • Inhibitors of melanin biosynthesis for example (11,001) tricyclazole, (11,002) 2,2,2-trifluoroethyl- ⁇ 3-methyl-1-[(4-methylbenzoyl)aminou]btan-2-yl ⁇ carbamate.
  • Inhibitors of nucleic acid synthesis for example (12.001) Benalaxyl, (12.002) Benalaxyl-M (Kiralaxyl), (12.003) Metalaxyl, (12.004) Metalaxyl (Mefenoxam).
  • Inhibitors of signal transduction for example (13.001) Fludioxonil, (13.002) Iprodione, (13.00) Procymidone, (13.004) Proquinazid, (13.005) Quinoexy, (13.006) Vinclozolin.
  • Compounds that can act as uncouplers for example (14.001) Fluazinam, (14.002) Meptyldinocap.
  • Preferred fungicides are selected from the group consisting of Benalaxyl, Bitertanol, Bromuconazole, Captafol, Carbendazim, Carpropamyida, z Cofamid, Cyproconazole, Diethofencarb, Edifenphos, Fenpropimorph, Fentine, Fluquincona Fzo sl,etyl, Fluoroimide, Folpet, Iminoctadine, Iprodionem, Iprovalicarb, Kasugamycin, Maneb, Nab, and Pmencycuron, Prochloraz, Propamocarb, Propineb, Pyrimethanil, Sprioxamine, Quintozeneb, and Tceonazole, Tolylfluanid, Triadimefon, Triadimenol, Trifloxystrobin, Zineb.
  • Insecticides, acaricides, nematicides, miticides, and other similar active ingredients are, for example (analogous to herbicides and fungicides, the compounds are linked to their common names where possible).
  • Acetylcholinesterase (AChE) inhibitors preferably carbamates selected from alanylcarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetan, Washrea, thiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodic, triazamate, trimethacarb, XMC and xylylcarb, or organophosphates selected from AChE inhibitors, preferably carbamates selected from alanyl
  • GABA-gated chloride channel blockers preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fleip)r selected from ethiprol and fipronil.
  • nAChR nicotinic acetyolin receptor
  • nAChR nicotinic acetyolin receptor
  • Allosteric modulators of the nicotinic acylcholine receptor (nAChR) preferably spinosyns selected from spinetoram and spinosad.
  • Allosteric modulators of the glutamate-dependent glucocorticoid channel preferably avermectins/milbemycins selected from abamectin, emectin benzoate, lepimectin, and milbemectin.
  • Juvenile hormone mimetics preferably juvenile hormone analogues selected from hydroprene, Kinoprene and methoprene, or fenoxycarb or polyxriyprene.
  • BCS231024-Ausland STR 72 Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, chlorpromazine or sulfuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from diazomet and metam.
  • alkyl halides selected from methyl bromide and other alkyl halides, chlorpromazine or sulfuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from diazomet and metam.
  • TRPV channel modulators of chordotonal organs selected from pymetrozine and pyrifluquinazone.
  • Mite growth inhibitors selected from chlorofen, hexythiazox, diflovidazine, and etoxazole.
  • Microbial disruptors of the insect gut membrane selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies saizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and B.t. plant proteins selected from Cry1Ab, Cry1Ac,1 CFary, Cry1A.105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1/35Ab1.
  • Inhibitors of mitochondrial ATP synthesis preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin, and fenbutatin oxide, or propargite or tetradifon.
  • Uncouplers of oxidative phosphorylation by disrupting the proton gradient selected from chlorfenapyr, DNOC, and sulfluramide.
  • Blockers of the nicotinic acetylcholine receptor selected from bensultap, cartap hydrochloride, thiocyclam, and thiosultap sodium.
  • Inhibitors of chitin biosynthesis type 0, selected from bistrifluron, chlorfluazuron, Diflubenzuron, Flucycloxuron, Flufenoxuron, Hexamflu ron, Lufenuron, Novaluron, Noviflumuron, Teflubenzuron and triflumuron.
  • Inhibitors of chitin biosynthesis type 1 derived from buprofen.
  • Moulting disruptor particularly in Dipte dre. nh,. Diptera selected from cyromazine.
  • Ecdysone receptor agonists selected from cafreonozide, halofenozide, methoxyfenozide, and tebufenozide.
  • Octopamine receptor agonists selected from amz.
  • Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl, and fluacrypyrim.
  • Mitochondrial complex I electron transport inhibitors preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimni, pifeyridaben, tebufenpyrad, and tolfenpyrad, or rotenone (Derris).
  • Inhibitors of mitochondrial complex II ectreon transport preferably beta-ketonitrile derivatives selected from cyenopyrafen, cyanflumetofen, or carboxanilides selected from pyflubumide.
  • Ryanodine receptor modulators preferably derivatives selected from chlorantraniliprole, cyantraniliprole, and flubendiamide.
  • Modulators of chordotonal organs (with undetermined target structure) selected from flonicamid.
  • the active ingredient combinations according to the invention are suitable for controlling a broad spectrum of weeds in non-cultivated land, on paths, railway lines, industrial areas ("industrial weed control"), or in plantation crops in temperate, subtropical, tropical climates or geographies.
  • plantation crops include oil palm, nuts (e.g. almonds, hazelnuts, walnuts, macadamia), coconut, berries, oil palm, gum berries, fruits (e.g. orange, lemon, mandarin), bananas, pineapple, cotton, sugar cane, tea, coffee, caffeine, and the like.
  • fruits e.g. orange, lemon, mandarin
  • bananas pineapple
  • cotton sugar cane
  • tea tea
  • coffee coffee
  • caffeine caffeine
  • the products can also be used for pre-sowing (burn-down, no-till, or zero-till methods) or for post-harvest treatment (chalk fail-low).
  • the application possibilities of the active ingredient combination also extend to weed control in tree crops, e.g. B. young Christmas tree plantations or Edible vines, before or after planting (also with overhead cover).
  • the products can also be used to control unwanted vegetation in economically important crops such as wheat (durum and wheat), corn, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as bush beans and horse beans), flax, barley, oats, rye, triticale, potatoes, and sorghum, in woodland and grassland/lawn areas, and plantation crops.
  • Plantation weeds include, among others, pomefruits (apple, pear, quince), Ribes-type plants (blackberry, raspberry), Citrus purpureus plants (cherries, nectarines, almonds), Nuts (walnut, pecan, hazelnut, cashew, macadam), mango, cocoa, coffee, wine (table, BCS231024-Ausland STR 76 Grapes), palms (such as oil palm, date palm, oats palm,), eucalyptus, kaki, persimmon, rubber, pineapple, banana, avocado, lychee, flowering plants (Eucalyptus, Piniaceae, Piceae, Meliaceae, etc.)
  • the herbicidal active ingredient combinations according to the invention in the respective application forms show synergies in terms of herbicidal activity and selectivity and favorable Effectiveness across the weed spectrum.
  • the active ingredient combinations can be applied to the plants (e.g., weeds such as monocotyledonous or dicotyledonous weeds or undesirable cultivated plants), the seed (e.g., grains, seeds, or vegetative propagation organs such as tubers or late stalks with buds), or the area on which the plants grow (e.g., the cultivated area).
  • weeds such as monocotyledonous or dicotyledonous weeds or undesirable cultivated plants
  • the seed e.g., grains, seeds, or vegetative propagation organs such as tubers or late stalks with buds
  • the area on which the plants grow e.g., the cultivated area.
  • the substances can be used in the pre-sowing (if necessary by incorporation into the soil), Pre-emergence or post-emergence application is preferred. Application is in the early reseeding pre-emergence method or in the post-emergence method of plantation crops against not yet accrued or already accrued pests.
  • the application can also be used in Weed management systems with multiple applications (Sequence applications, "sequentials") integrated wne.rd
  • Sequentials Sequence applications, "sequentials” integrated wne.rd
  • some representatives of the deono- and dicotyledonous weed flora are mentioned as examples, which can be controlled by the active ingredient combination according to the invention without the Mentioning a restriction to certain speciesg eernfo sloll.
  • the active ingredient combination according to the invention is applied to the soil surface before germination, either the emergence of the weeds is completely prevented or the weeds grow to the cotyledon stage, but then stop growing and finally die after three to four weeks.
  • the active ingredients are applied to the green parts of the plants using the post-emergence method, growth stops after treatment and the pests remain in the growth stage present at the time of application or die completely after a certain time, so that in this way weed competition that is harmful to the crop plants is eliminated very early and sustainably.
  • the herbicidal compositions according to the invention are characterized by a rapid onset and long lasting herbicidal action.
  • the rain resistance of the active ingredients in the Combinations are generally favorable.
  • a particular advantage is that the effective dosages of compounds (A) and (B) used in the combinations can be adjusted so low that their soil effectiveness is generally low. This not only makes their use in sensitive crops possible, but also virtually prevents groundwater contamination.
  • the combination of active ingredients according to the invention enables a significant reduction in the required application rate of the active ingredients.
  • application properties which go beyond what is expected based on the known properties of the individual herbicides for whose combination was to be expected. For example, the herbicidal effects of a certain harmful plant species the expected value according to standard procedures, e.g. Colby or other extrapolation methods.
  • the expected effect for a given combination of two active ingredients can be calculated according to S.R. Colby (“Calculating Synergistic and Antagonistic Response of a Herbicide Combination”, Weeds 15 (1967), 20-22) (see below).
  • BCS231024-Foreign STR 78 The synergistic effects therefore allow, for example, a reduction in the application rates of Single active ingredients, higher potency at lower application rates, control of previously uncontrolled weed species (gaps), higher residual effect, increased long-term efficacy, increased speed of action, extension of the application period and/or reduction of the number of necessary applications and - as a result for the user - economically and ecologically advantageous weed control systems.
  • the combinations according to the invention have a marked herbicidal activity against mono- and dicotyledonous weeds, economically important crop plants are only insignificantly or not at all affected, depending on the structure of the active ingredient combinations according to the invention and their application rate.
  • Economically important crops include, for example, dicotyledonous crops of the genera Arachnid, Bies,ta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Li,n Lymcopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia, or monocotyledonous cultures of Gagtteun Allium, pineapple, asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorbus Triticum, Triticum, and Zea. Furthermore, the compounds according to the invention exhibit excellent growth-regulating properties in crop plants.
  • the agents regulate the plant's own metabolism and can thus be used to specifically influence plant components and facilitate harvesting, for example, by inducing desiccation and growth suppression. Furthermore, they are suitable They are also used for the general control and inhibition of unwanted vegetative growth, without killing the plants. Inhibition of nutrient growth plays a role in many mono- and dicotyledonous cultures play a major role, as the storage is thereby reduced or completely can be prevented. Due to their herbicidal and plant growth inhibitory properties, the agents can be used to control weeds in known plant varieties or in tolerant crops yet to be developed, modified by conventional mutagenesis or genetically modified.
  • the transgenic plants are generally characterized by particularly advantageous properties, in addition to resistance to the agents according to the invention, for example, resistance to plant pathogens and the cause of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses.
  • Other special properties relate, for example, to the harvested product with regard to density, quality, storability, composition, and special ingredients. Strain-genic plants with increased starch content or altered starch quality or those with an altered fatty acid composition of the harvested product Other special properties could be tolerance or resistance to abiotic Stressors include heat, cold, dryness, salt and intraviolet radiation.
  • the active ingredient combinations according to the invention can preferably be used as herbicides in Crops which are more susceptible to the phytotoxic effects of are resistant to herbicides or have been genetically modified.
  • Conventional methods for producing new plants that have modified characteristics compared to previously existing plants, for example in classical breeding methods and the production of mutants, can be used to create new plants with modified characteristics using genetic engineering techniques (see, for example, EP-A-0221044, EP-A- 0131624). For example, several cases were described - genetic modifications of crop plants by modifying the starch synthesized in the plants (e.g.
  • nitric acid molecules can be introduced into plasmids that allow mutagenesis or sequence alteration through recombination of DNA sequences. Using standard procedures, base exchanges can be performed, partial sequences can be removed, or natural or synthetic sequences can be added. To connect the DNA fragments to one another, adapters or linkers can be used, see, for example, Sambrook et al., "M90819ecular Cloning, A Laboratory Manual, 2nd ed.
  • the production of plant cells with an increased activity of a gene product can be achieved, for example, by the expression of at least one corresponding antisense RNA, a sense RNA to achieve a cosuppressive function or the expression of at least one an appropriately constructed ribozyme that cleaves specific transcripts of the above-mentioned gene product.
  • DNA molecules can be used that comprise the entire coding sequence of a gene product, including any potentially present cross-sense sequences, or DNA molecules that contain only parts of the coding sequence. These parts must be long enough to produce an antisense effect in the cells.
  • DNA sequences that exhibit a high degree of homology to coding sequences of a gene product, but are not completely identical.
  • the synthesized protein can be expressed in any compartment of the plant cell.
  • the corresponding region can be linked to DNA sequences that ensure localization in a specific compartment.
  • sequences are known to the person skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA (815988), 846-850; Sonnewald et al., Plant J. 1 (1), 991 95-106).
  • transgenic plant cells can be regenerated into whole plants using known techniques.
  • Transgenic plants can be plants of any plant species, i.e., both monocotyledonous and dicotyledonous.
  • BCS231024-Ausland STR 81 The active compound combinations according to the invention can preferably be used in transgenic cultures that are tolerant or have been rendered tolerant to the genetically modified organisms used.
  • the active compound combinations according to the invention can preferably also be used in transgenic cultures that are resistant to growth promoters, such as e.g., icamba, or herbicides that inhibit essential plant enzymes, e.g., acetolactate synthases (ALSP), P E synthases, glutamine synthases (GS). Inhibit hydroxyphenylpyruvate dioxygenases (HPPD) or pro-rtophyrinogen oxidase (PPO), or against herbicides from the group of sulfoforms, glyphosate, glufosinate or Benzoylisoxazoles and analogous active ingredients, resis stein dt.
  • acetolactate synthases e.g., acetolactate synthases (ALSP), P E synthases, glutamine synthases (GS).
  • HPPD hydroxyphenylpyruvate dioxygenases
  • PPO pro-rtophyrinogen oxidase
  • the invention therefore also relates to a method for controlling undesirable plant growth, optionally in crops, preferably in non-cultivated land or in plantation crops, characterized in that one or more herbicides of type (A) are applied with one or more herbicides of type (B) to the target plants, plant parts or plant seeds (seed) thereof, or to the cultivated area.
  • the invention also relates to the use of these combinations of compounds (A)+(B) for controlling weeds, optionally in crops, preferably in non-cultivated land and plantation crops, but also for controlling weeds prior to sowing the following crop, in particular for sowing preparation ("burn-down application").
  • the active ingredient combinations according to the invention can either be present as mixed formulations of the two components, optionally with further active ingredients, additives, and/or customary formulation auxiliaries, which are then applied diluted with water, or as so-called tank-mixed formulations, i.e., joint dilution of the separately formulated or partially separately formulated components with water.
  • Compounds (A) and (B) or their combinations can be formulated in various ways, depending on the biological and/or chemical-physical parameters specified.
  • General formulation options include, for example: wettable powder (WP), Water-soluble powders (SP), emulsifiable concentrates (REACT), water-soluble concentrates, aqueous solutions (SL), emulsions (EW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, oil-based dispersions, oil dispersions (OD), suspoemulsions, suspension concentrates (SC), oily solutions, capsule suspensions (CS), dusting agents (DP), seed dressings, granules for soil-based scattering, granules (GR) in the form of BCS231024-Ausland STR 82 Micro-, spray-, lift-, and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulation, microcapsules, or waxes.
  • WP wettable powder
  • SP Water-soluble powders
  • REACT e
  • the invention therefore also relates to plant growth regulating agents, which contain the active ingredient combination according to the invention.
  • the individual formulation types are listed in the principle chapter and are described, for example, in: Winnacker-kuchler, "Chemische Technologie,” Volume C.7 H, anser Verlag Kunststoff, 4th ed. 1986; van Valkenburg, "Pesticides Formulations,” Marcel Derk Nke.Y., 1973; K. Martens, “Spray Drying Handbook,” 3rd ed. 1979, G. Goodwin Ltd. London.
  • Wettable powders are preparations that are evenly dispersible in water and which, in addition to the active ingredient and a diluent or inert substance, also contain ionic and/or non-ionic surfactants (wetting agents, dispersants), e.g.
  • the herbicidal active ingredients are finely ground in conventional equipment such as hammer mills, blower mills and air jet mills and simultaneously mixed with the formulation auxiliaries.
  • Emulsifiable concentrates are produced by dissolving the active ingredient in an organic solvent, e.g., butanol, cyclohexanone, dimethylformamide, xylene, or higher-boiling aromatics or hydrocarbons, or mixtures of these organic solvents, with the addition of one or more surfactants, ionic and/or non-ionic surfactants (emulsifiers).
  • organic solvent e.g., butanol, cyclohexanone, dimethylformamide, xylene, or higher-boiling aromatics or hydrocarbons, or mixtures of these organic solvents.
  • surfactants ionic and/or non-ionic surfactants (emulsifiers).
  • emulsifiers examples include: alkylaryl sulfonic acid, calcium salts such as calcium dodecylbenzenesulfonate, or non-ionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide, ethylene oxide. Condensation products, alkyl polyethers, sorbitan residues, e.g. sorbitan fatty acid esters or such as Polyoxyethylene sorbitan fatty acid ester.
  • Dusts are obtained by grinding the dust with finely divided solid substances, e.g., talc, natural clays such as kaolin, bentonite, pyrolytic clay, or diatomaceous earth.
  • Suspension concentrates can be based on water or oil. They can be produced, for example, by wet grinding using commercially available bead mills and, if necessary, with the addition of surfactants, such as those listed above for the other formulation types.
  • Emulsions e.g., oil-in-water emulsions (EW)
  • EW oil-in-water emulsions
  • surfactants such as those listed above for the other formulation types.
  • Granules can be produced either by spraying the Wofirfekst onto adsorbable, granulated Inert material or by applying active ingredient concentrates using adhesives, e.g., polyvinyl alcohol, sodium polyacrylate, or mineral oils, onto the surface of carrier materials such as sand, kaolinite, or granular inert materials. Suitable active ingredients can also be granulated in the usual manner for the production of fertilizer granules—if desired, mixed with fertilizers. Water-dispersible granules are used in R neagcehl processes such as spray drying, fluidized bed Granulation, disc granulation, mixing with high-speed mixers, and extrusion without solid inert material.
  • the agrochemical preparations contain, in particular, 0.1 to 99% by weight, in particular 0.2 to 95% by weight, of active ingredients of types (A) and/or (B).
  • active ingredients of types (A) and/or (B).
  • concentrations are usual: BCS231024-Ausland STR 84
  • the active ingredient concentration is, for example, approximately 10 to 95 wt.%, the remainder to 100 wt.%.
  • % consists of usual formulation ingredients.
  • Bile in emulsifiable concentrates can Active ingredient concentration about 1 to 90 wt.%, preferably 5 to 80 wt.%.
  • Dust-like formulations usually contain 5 to 20 wt.% of active ingredient
  • sprayable Solutions contain approximately 0.05 to 80, preferably up to 520 weight percent (wt.%) of active ingredient.
  • the active ingredient content depends partly on whether the active compound is liquid or solid and whether granulation aids and fillers are used. As a rule, the content in dispersible granules is between 1 and 95 wt.%, preferably between 10 and 80 wt.%.
  • the active ingredient formulations mentioned may contain the usual adhesives, wetting agents, dispersants, emulsifiers, penetration agents, grain viscosifiers, antifreeze agents, solvents, fillers, dyes, carriers, defoamers, evaporation agents, and agents that affect pH or viscosity.
  • the formulations available in commercially available forms are diluted, if necessary, in the usual way, e.g., in the case of wettable powders, dispersible concentrates, dispersions, and water-dispersible granules, using water.
  • Formulated preparations, soil or broadcast granules, and sprayable solutions are not usually diluted with other inert substances before use.
  • the active ingredients can be applied to the plants, plant nets, plant seeds, or the cultivated area (arable soil), preferably to the thin plants and plant parts and, if necessary, also to the arable soil.
  • One possible application is the combined application of the active ingredients in the form of tank mixes, whereby the optimally formulated, concentrated formulations of the individual active ingredients mixed together with water in the tank and then applied as a spray mixture.
  • a joint herbicidal formulation of the inventive combination of active ingredients (A) and (B) has the advantage of being easier to use, as the amounts of the components are already adjusted in the correct ratio to one another.
  • the auxiliaries in the formulation can be optimally matched to one another, while a herbicidal mix of different formulations undesirable combinations of excipients could result.
  • a dust is obtained by mixing 10 parts by weight of an active ingredient (A) or (B) or an active ingredient mixture (A) + (B) (and optionally other active ingredients) and/or their salts and 90 parts by weight of talc as talc, and grinding the mixture in a hammer mill.
  • a wettable dust that is easily dispersible in water is obtained by mixing 25 parts by weight of an active ingredient/active ingredient mixture, 64 parts by weight of kaolin-containing quartz as an inert material, 10 parts by weight of potassium ligninsulfonate, and 1 part by weight of sodium methyl taurine as wetting and dispersing agents, and grinding the mixture in a pin mill.
  • a dispersion concentrate which is easily dispersible in water is obtained by mixing 20 wt. Parts of an active ingredient/active ingredient mixture with 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether E (08) and 71 parts by weight of paraffinic mineral oil (boiling range, for example, approx. 255 to 277 °C) are mixed and ground in a ball mill to a fineness of less than 5 microns.
  • An emulsifiable concentrate is obtained from 1 part by weight of an active ingredient/active ingredient mixture, 75 parts by weight of cyclohexane as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.
  • Water-dispersible granules are obtained by mixing 75 parts by weight of an active ingredient/active ingredient mixture, 10 parts by weight of calcium ligninsulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol, and 7 parts by weight of kaolin, grinding the mixture on a pin mill, and granulating the powder in a fluidized bed by spraying water as the granulating liquid.
  • Water-dispersible granules are obtained by mixing 25 parts by weight of an active ingredient/active ingredient mixture, 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfurous sodium, 2 parts by weight of oleoylmethyltaurine sodium, 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate, andBCS231024-Ausland STR 86 50 parts by weight of water are homogenized and pre-compounded in a colloid mill, then ground in a bead mill, and the resulting suspension is atomized and dried in a spray tower with a single-component nozzle.
  • E C A+B - (A ⁇ B/100)
  • A effect of the active ingredient (A) in % at an application rate of a [g a.i./ha]
  • B effect of the active ingredient (B) in % at an application rate of b [g a.i./ha]
  • E C Expected value of the effect of the combination (A(B)+) in % at the combined application rate a+b [g a.i./ha].
  • the observed values A ()E of the experiments show, at suitable low druonsgies, an effect of the combinations that exceeds the expected values ch n Caolby (E C )lie ( ⁇ ).
  • Post-emergence weed activity Seeds of monocotyledonous and dicotyledonous weeds were sown in pots in sandy loam soil, covered with soil, and grown in a greenhouse under favorable growing conditions (temperature, humidity, water supply). Three weeks after sowing, the test plants were treated with the agents according to the invention at the two- to four-leaf stage.
  • the agents according to the invention emulated as wettable powders or as emulsion concentrates, were applied in BCS231024-Ausland STR 87 were sprayed onto the green parts of the plants at various dosages with a water application rate equivalent to 300 l/ha. After 3 weeks of standing in the greenhouse under optimal growth conditions, the effectiveness of the preparations was visually assessed in comparison to untreated controls.
  • AMAPA or AMAPA_R sensitive (AMAPA) or resistant (AMAPA_R) Biopt), Avena fatua (AVEFA), Bidens pilosa (BIDPI), Centaurea cyanus (CENCY), Brachiaria pplahtylla (BRAPP), Echinochloa crus-galli (ECHCG), Eleusine inidca (ELEIN), Kochia scoparKiaC (HSC), Lolium rigidum (LOLRI), Pharbitis purpurea (PHBPU), Sorghum halepense (SORHA), which are above the expected values according to Colby.
  • AVEFA Avena fatua
  • BIDPI Bidens pilosa
  • CENCY Centaurea cyanus
  • CENCY Centaurea cyanus
  • BRAPP Brachiaria pplahtylla
  • EHCG Echinochloa crus-galli
  • ELEIN Eleusine inidca
  • HSC Eleusine ini

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Abstract

La présente invention concerne des compositions comprenant des composés à activité herbicide (A) et (B), (A) représentant un ou plusieurs composés de formule générale (I) ou des sels agrochimiquement compatibles de ceux-ci [composant (A)], et (B) représentant un ou plusieurs herbicides [composant (B)]. L'invention concerne en outre un procédé et l'utilisation de la composition herbicide de l'invention pour lutter contre des plantes nuisibles ou pour la régulation de la croissance.
PCT/EP2024/082650 2023-11-23 2024-11-18 Compositions herbicides Pending WO2025108865A1 (fr)

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Citations (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0086750A2 (fr) 1982-02-17 1983-08-24 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0094349A2 (fr) 1982-05-07 1983-11-16 Ciba-Geigy Ag Utilisation de dérivés de quinoléine pour protéger des plantes cultivées
EP0131624A1 (fr) 1983-01-17 1985-01-23 Monsanto Co Plasmides de transformation de cellules vegetales.
JPS6087254A (ja) 1983-10-19 1985-05-16 Japan Carlit Co Ltd:The 新規尿素化合物及びそれを含有する除草剤
EP0142924A2 (fr) 1983-09-26 1985-05-29 Mycogen Plant Science, Inc. Plantes resistantes aux insectes
EP0174562A2 (fr) 1984-09-11 1986-03-19 Hoechst Aktiengesellschaft Agents pour la protection de plantes basés sur des dérivés de 1,2,4- briazole ainsi que dérivés 1,2,4-triazole
EP0191736A2 (fr) 1985-02-14 1986-08-20 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0221044A1 (fr) 1985-10-25 1987-05-06 Monsanto Company Vecteurs de plantes
EP0257993A2 (fr) 1986-08-26 1988-03-02 E.I. Du Pont De Nemours And Company Fragment d'acide nucléique codant la synthase acétolactate végétale résistante aux herbicides
EP0268554A2 (fr) 1986-10-22 1988-05-25 Ciba-Geigy Ag Dérivés d'acide diphényl-1,5-pyrazol-3-carbonique pour la protection de plantes de culture
EP0269806A1 (fr) 1986-10-04 1988-06-08 Hoechst Aktiengesellschaft Dérivés d'acide phénylpyrazolcarbonique, leur préparation et leur utilisation comme agents régulateurs de croissance des plantes et antidote
EP0305398A1 (fr) 1986-05-01 1989-03-08 Honeywell Inc Agencement d'interconnexion de plusieurs circuits integres.
EP0333131A1 (fr) 1988-03-17 1989-09-20 Hoechst Aktiengesellschaft Agent de protection des plantes à base de dérivés d'acide pyrazolcarboxylique
EP0346620A1 (fr) 1988-05-20 1989-12-20 Hoechst Aktiengesellschaft Agents phytoprotecteurs contenant des dérivés du 1,2,4-triazole ainsi que dérivés du 1,2,4-triazole
EP0365484A1 (fr) 1988-10-20 1990-04-25 Ciba-Geigy Ag Sulfamoylphénylurées
US5013659A (en) 1987-07-27 1991-05-07 E. I. Du Pont De Nemours And Company Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase
WO1991007874A1 (fr) 1989-11-30 1991-06-13 Hoechst Aktiengesellschaft Pyrazoline pour la protection de plantes cultivees contre les herbicides
WO1991008202A1 (fr) 1989-11-25 1991-06-13 Hoechst Aktiengesellschaft Isoxazolines, procede de preparation et application comme produits phytosanitaires
WO1991013972A1 (fr) 1990-03-16 1991-09-19 Calgene, Inc. Desaturases de plantes - compositions et emplois
WO1991019806A1 (fr) 1990-06-18 1991-12-26 Monsanto Company Plantes a teneur en amidon augmentee
EP0492366A2 (fr) 1990-12-21 1992-07-01 Hoechst Schering AgrEvo GmbH Nouveaux dérivés de chloro-5-quinoline-8-acide oxyalkanecarboniques, procédé pour leur préparation et leur utilisation comme antidote d'herbicides
WO1992011376A1 (fr) 1990-12-21 1992-07-09 Amylogene Hb Modification de la pomme de terre par manipulation genetique permettant la formation de fecule du type amylopectine
WO1992014827A1 (fr) 1991-02-13 1992-09-03 Institut Für Genbiologische Forschung Berlin Gmbh Plasmides contenant des sequences d'adn provoquant des changements dans la concentration et la composition glucidiques de plantes, cellules de plantes et plantes contenant ces plasmides
EP0582198A2 (fr) 1992-08-01 1994-02-09 Hoechst Schering AgrEvo GmbH Composés (hétéro-)aryliques substitués, procédé pour leur préparation, compositions les contenant et leur utilisation comme agents de protection
WO1995007897A1 (fr) 1993-09-16 1995-03-23 Hoechst Schering Agrevo Gmbh Isoxazolines substituees, leur procede de preparation, agents les contenant et leur utilisation comme reducteurs de phytotoxicite
WO1997045016A1 (fr) 1996-05-29 1997-12-04 Hoechst Schering Agrevo Gmbh Nouveaux n-acylsulfonamides, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998013361A1 (fr) 1996-09-26 1998-04-02 Novartis Ag Composition herbicide
WO1998027049A1 (fr) 1996-12-19 1998-06-25 Hoechst Schering Agrevo Gmbh Nouveaux derives d'acide 2-fluoroacrylique, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998038856A1 (fr) 1997-03-04 1998-09-11 Zeneca Limited Compositions pour proteger du riz contre l'acetochlore
WO1999000020A1 (fr) 1997-06-27 1999-01-07 Hoechst Schering Agrevo Gmbh 3-(5-tetrazolylcarbonyle)-2-quinolones et produits phytosanitaires pour plantes utiles les contenant
WO1999016744A1 (fr) 1997-09-29 1999-04-08 Aventis Cropscience Gmbh Amides d'acide benzoique d'acylsulfamoyle, agents phytosanitaires les contenant et procede permettant de les preparer
WO2002034048A1 (fr) 2000-10-23 2002-05-02 Syngenta Participations Ag Compositions agrochimiques avec des phytoprotecteurs a base de quinoline
WO2003106457A1 (fr) 2002-06-14 2003-12-24 Syngenta Limited Derives de spiroindolinepiperidine
WO2004084631A1 (fr) 2003-03-26 2004-10-07 Bayer Cropscience Gmbh Utilisation de composés aromatiques hydroxy comme phytoprotecteurs
WO2004099160A1 (fr) 2003-05-12 2004-11-18 Sumitomo Chemical Company, Limited Composes de pyrimidine et compostion de lutte contre les animaux nuisibles contenant ces composes
WO2005016001A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Agents phytoprotecteurs a base de derives d'acide carboxylique aromatiques-aliphatiques
WO2005015994A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Utilisation d'aromates hydroxy comme phytoprotecteurs
WO2005112630A1 (fr) 2004-05-12 2005-12-01 Bayer Cropscience Gmbh Derives de quinoxalin-2-one, phytoprotecteurs pour plantes utiles contenant ces derives, procede de production et utilisation desdits derives
WO2006003494A2 (fr) 2004-06-28 2006-01-12 Syngenta Participations Ag Composes chimiques
WO2006043635A1 (fr) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. Dérivé de 3-triazolylphénylsulfide et insecticide/acaricide/nématicide incluant ledit dérivé au titre de principe actif
WO2007023719A1 (fr) 2005-08-22 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire l'attaque chimique et composition herbicide produisant une attaque chimique réduite
WO2007023764A1 (fr) 2005-08-26 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire les effets nocifs d’un herbicide et composition d’herbicide ayant des effets nocifs réduits
WO2007040282A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Compose d'amine cyclique et agent pesticide
WO2008131860A2 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Pyridone-carboxamides, phytoprotecteurs contenant ces composés, procédés pour leur production et leur utilisation
WO2008131861A1 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Utilisation de pyridin-2-oxy-3-carbonamides comme phytoprotecteurs
CN101337940A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具杀虫活性的含氮杂环二氯烯丙醚类化合物
CN101337937A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具有杀虫活性的n-苯基-3-取代氨基吡唑类化合物
JP2010018586A (ja) 2008-07-14 2010-01-28 Meiji Seika Kaisha Ltd Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
WO2010051926A2 (fr) 2008-11-05 2010-05-14 Bayer Cropscience Aktiengesellschaft Nouveaux composés substitués par halogène
WO2010052161A2 (fr) 2008-11-06 2010-05-14 Syngenta Participations Ag Compositions herbicides
CN101715774A (zh) 2008-10-09 2010-06-02 浙江化工科技集团有限公司 一个具有杀虫活性化合物制备及用途
WO2010066780A1 (fr) 2008-12-12 2010-06-17 Syngenta Participations Ag N-oxypipéridines spirohétérocycliques utilisées comme pesticides
CN101838227A (zh) 2010-04-30 2010-09-22 孙德群 一种苯甲酰胺类除草剂的安全剂
WO2011067272A1 (fr) 2009-12-01 2011-06-09 Syngenta Participations Ag Composés insecticides à base de dérivés isoxazoline
WO2011085575A1 (fr) 2010-01-15 2011-07-21 江苏省农药研究所股份有限公司 Composés de formanilide hétérocyclique, leurs procédés de synthèse et leur utilisation
WO2011151146A1 (fr) 2010-05-31 2011-12-08 Syngenta Participations Ag Procédé d'amélioration du rendement d'un produit cultivé
WO2012034403A1 (fr) 2010-09-14 2012-03-22 中化蓝天集团有限公司 Composés de fluorométhoxypyrazole et d'anthranilamide, leurs procédés de synthèse et leurs utilisations
CN102391261A (zh) 2011-10-14 2012-03-28 上海交通大学 一种n-取代噁二嗪类化合物及其制备方法和应用
WO2013050317A1 (fr) 2011-10-03 2013-04-11 Syngenta Limited Formes polymorphes d'un dérivé d'isoxazoline
WO2013050302A1 (fr) 2011-10-03 2013-04-11 Syngenta Participations Ag Dérivés d'isoxazoline utilisés comme composés insecticides
CN103109816A (zh) 2013-01-25 2013-05-22 青岛科技大学 硫代苯甲酰胺类化合物及其应用
CN103232431A (zh) 2013-01-25 2013-08-07 青岛科技大学 一种二卤代吡唑酰胺类化合物及其应用
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
CN103265527A (zh) 2013-06-07 2013-08-28 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物及其制备方法和应用
WO2013144213A1 (fr) 2012-03-30 2013-10-03 Basf Se Composés de pyridylidène n-substitués et dérivés destinés à lutter contre les animaux nuisibles
EP2647626A1 (fr) 2012-04-03 2013-10-09 Syngenta Participations AG. Dérivés de 1-aza-spiro[4.5]déc-3-ène and 1,8-diaza-spiro[4.5]déc-3-ène en tant que pesticides
WO2013162716A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
CN103524422A (zh) 2013-10-11 2014-01-22 中国农业科学院植物保护研究所 苯并咪唑衍生物及其制备方法和用途
US20140213448A1 (en) 2012-04-27 2014-07-31 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
US20140275503A1 (en) 2013-03-13 2014-09-18 Dow Agrosciences Llc Process for the preparation of certain triaryl rhamnose carbamates
WO2014187846A1 (fr) 2013-05-23 2014-11-27 Syngenta Participations Ag Formulations de mélange en cuve
WO2015058028A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de composés pesticides
WO2015058021A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de de composés pesticides
WO2021105101A1 (fr) 2019-11-26 2021-06-03 Bayer Aktiengesellschaft Dérivés d'acide acétique [(1,5-diphényl-1h-1,2,4-triazol-3-yl)oxy] et sels de ceux-ci, compositions de protection des cultures les comprenant, leurs procédés de production et utilisation de ceux-ci en tant que phytoprotecteurs
WO2022043205A1 (fr) * 2020-08-24 2022-03-03 Bayer Aktiengesellschaft N-phényluraciles substitués et sels de ceux-ci et utilisation associée en tant que substances actives herbicides
WO2023030935A1 (fr) * 2021-08-31 2023-03-09 Basf Se Procédé de lutte contre les mauvaises herbes résistantes aux ppo-i
WO2023030934A1 (fr) * 2021-08-31 2023-03-09 Basf Se Composition herbicide comprenant des phényluraciles
EP4230620A1 (fr) * 2022-02-22 2023-08-23 Bayer Aktiengesellschaft Uracile d'acide n-amino-n´-benzoïque substitués, ainsi que leurs sels et leur utilisation comme herbicides
WO2023161172A1 (fr) * 2022-02-22 2023-08-31 Bayer Aktiengesellschaft Uraciles d'acide n-benzoïque substitués et leurs sels, et leur utilisation en tant que substances actives herbicides
WO2024078906A1 (fr) * 2022-10-10 2024-04-18 Bayer Aktiengesellschaft N-phényluraciles substitués et leurs sels, et leur utilisation en tant que principes actifs herbicides

Patent Citations (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0086750A2 (fr) 1982-02-17 1983-08-24 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0094349A2 (fr) 1982-05-07 1983-11-16 Ciba-Geigy Ag Utilisation de dérivés de quinoléine pour protéger des plantes cultivées
EP0131624A1 (fr) 1983-01-17 1985-01-23 Monsanto Co Plasmides de transformation de cellules vegetales.
EP0142924A2 (fr) 1983-09-26 1985-05-29 Mycogen Plant Science, Inc. Plantes resistantes aux insectes
JPS6087254A (ja) 1983-10-19 1985-05-16 Japan Carlit Co Ltd:The 新規尿素化合物及びそれを含有する除草剤
EP0174562A2 (fr) 1984-09-11 1986-03-19 Hoechst Aktiengesellschaft Agents pour la protection de plantes basés sur des dérivés de 1,2,4- briazole ainsi que dérivés 1,2,4-triazole
EP0191736A2 (fr) 1985-02-14 1986-08-20 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0221044A1 (fr) 1985-10-25 1987-05-06 Monsanto Company Vecteurs de plantes
EP0305398A1 (fr) 1986-05-01 1989-03-08 Honeywell Inc Agencement d'interconnexion de plusieurs circuits integres.
EP0257993A2 (fr) 1986-08-26 1988-03-02 E.I. Du Pont De Nemours And Company Fragment d'acide nucléique codant la synthase acétolactate végétale résistante aux herbicides
EP0269806A1 (fr) 1986-10-04 1988-06-08 Hoechst Aktiengesellschaft Dérivés d'acide phénylpyrazolcarbonique, leur préparation et leur utilisation comme agents régulateurs de croissance des plantes et antidote
EP0268554A2 (fr) 1986-10-22 1988-05-25 Ciba-Geigy Ag Dérivés d'acide diphényl-1,5-pyrazol-3-carbonique pour la protection de plantes de culture
US5013659A (en) 1987-07-27 1991-05-07 E. I. Du Pont De Nemours And Company Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase
EP0333131A1 (fr) 1988-03-17 1989-09-20 Hoechst Aktiengesellschaft Agent de protection des plantes à base de dérivés d'acide pyrazolcarboxylique
EP0346620A1 (fr) 1988-05-20 1989-12-20 Hoechst Aktiengesellschaft Agents phytoprotecteurs contenant des dérivés du 1,2,4-triazole ainsi que dérivés du 1,2,4-triazole
EP0365484A1 (fr) 1988-10-20 1990-04-25 Ciba-Geigy Ag Sulfamoylphénylurées
WO1991008202A1 (fr) 1989-11-25 1991-06-13 Hoechst Aktiengesellschaft Isoxazolines, procede de preparation et application comme produits phytosanitaires
WO1991007874A1 (fr) 1989-11-30 1991-06-13 Hoechst Aktiengesellschaft Pyrazoline pour la protection de plantes cultivees contre les herbicides
WO1991013972A1 (fr) 1990-03-16 1991-09-19 Calgene, Inc. Desaturases de plantes - compositions et emplois
WO1991019806A1 (fr) 1990-06-18 1991-12-26 Monsanto Company Plantes a teneur en amidon augmentee
EP0492366A2 (fr) 1990-12-21 1992-07-01 Hoechst Schering AgrEvo GmbH Nouveaux dérivés de chloro-5-quinoline-8-acide oxyalkanecarboniques, procédé pour leur préparation et leur utilisation comme antidote d'herbicides
WO1992011376A1 (fr) 1990-12-21 1992-07-09 Amylogene Hb Modification de la pomme de terre par manipulation genetique permettant la formation de fecule du type amylopectine
WO1992014827A1 (fr) 1991-02-13 1992-09-03 Institut Für Genbiologische Forschung Berlin Gmbh Plasmides contenant des sequences d'adn provoquant des changements dans la concentration et la composition glucidiques de plantes, cellules de plantes et plantes contenant ces plasmides
EP0582198A2 (fr) 1992-08-01 1994-02-09 Hoechst Schering AgrEvo GmbH Composés (hétéro-)aryliques substitués, procédé pour leur préparation, compositions les contenant et leur utilisation comme agents de protection
WO1995007897A1 (fr) 1993-09-16 1995-03-23 Hoechst Schering Agrevo Gmbh Isoxazolines substituees, leur procede de preparation, agents les contenant et leur utilisation comme reducteurs de phytotoxicite
WO1997045016A1 (fr) 1996-05-29 1997-12-04 Hoechst Schering Agrevo Gmbh Nouveaux n-acylsulfonamides, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998013361A1 (fr) 1996-09-26 1998-04-02 Novartis Ag Composition herbicide
WO1998027049A1 (fr) 1996-12-19 1998-06-25 Hoechst Schering Agrevo Gmbh Nouveaux derives d'acide 2-fluoroacrylique, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998038856A1 (fr) 1997-03-04 1998-09-11 Zeneca Limited Compositions pour proteger du riz contre l'acetochlore
WO1999000020A1 (fr) 1997-06-27 1999-01-07 Hoechst Schering Agrevo Gmbh 3-(5-tetrazolylcarbonyle)-2-quinolones et produits phytosanitaires pour plantes utiles les contenant
WO1999016744A1 (fr) 1997-09-29 1999-04-08 Aventis Cropscience Gmbh Amides d'acide benzoique d'acylsulfamoyle, agents phytosanitaires les contenant et procede permettant de les preparer
WO2002034048A1 (fr) 2000-10-23 2002-05-02 Syngenta Participations Ag Compositions agrochimiques avec des phytoprotecteurs a base de quinoline
WO2003106457A1 (fr) 2002-06-14 2003-12-24 Syngenta Limited Derives de spiroindolinepiperidine
WO2004084631A1 (fr) 2003-03-26 2004-10-07 Bayer Cropscience Gmbh Utilisation de composés aromatiques hydroxy comme phytoprotecteurs
WO2004099160A1 (fr) 2003-05-12 2004-11-18 Sumitomo Chemical Company, Limited Composes de pyrimidine et compostion de lutte contre les animaux nuisibles contenant ces composes
WO2005016001A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Agents phytoprotecteurs a base de derives d'acide carboxylique aromatiques-aliphatiques
WO2005015994A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Utilisation d'aromates hydroxy comme phytoprotecteurs
WO2005112630A1 (fr) 2004-05-12 2005-12-01 Bayer Cropscience Gmbh Derives de quinoxalin-2-one, phytoprotecteurs pour plantes utiles contenant ces derives, procede de production et utilisation desdits derives
WO2006003494A2 (fr) 2004-06-28 2006-01-12 Syngenta Participations Ag Composes chimiques
WO2006043635A1 (fr) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. Dérivé de 3-triazolylphénylsulfide et insecticide/acaricide/nématicide incluant ledit dérivé au titre de principe actif
WO2007023719A1 (fr) 2005-08-22 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire l'attaque chimique et composition herbicide produisant une attaque chimique réduite
WO2007023764A1 (fr) 2005-08-26 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire les effets nocifs d’un herbicide et composition d’herbicide ayant des effets nocifs réduits
WO2007040282A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Compose d'amine cyclique et agent pesticide
WO2007040280A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Cyclic amine compound and pest control agent
WO2008131860A2 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Pyridone-carboxamides, phytoprotecteurs contenant ces composés, procédés pour leur production et leur utilisation
WO2008131861A1 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Utilisation de pyridin-2-oxy-3-carbonamides comme phytoprotecteurs
JP2010018586A (ja) 2008-07-14 2010-01-28 Meiji Seika Kaisha Ltd Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
CN101337937A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具有杀虫活性的n-苯基-3-取代氨基吡唑类化合物
CN101337940A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具杀虫活性的含氮杂环二氯烯丙醚类化合物
CN101715774A (zh) 2008-10-09 2010-06-02 浙江化工科技集团有限公司 一个具有杀虫活性化合物制备及用途
WO2010051926A2 (fr) 2008-11-05 2010-05-14 Bayer Cropscience Aktiengesellschaft Nouveaux composés substitués par halogène
WO2010052161A2 (fr) 2008-11-06 2010-05-14 Syngenta Participations Ag Compositions herbicides
WO2010066780A1 (fr) 2008-12-12 2010-06-17 Syngenta Participations Ag N-oxypipéridines spirohétérocycliques utilisées comme pesticides
WO2011067272A1 (fr) 2009-12-01 2011-06-09 Syngenta Participations Ag Composés insecticides à base de dérivés isoxazoline
WO2011085575A1 (fr) 2010-01-15 2011-07-21 江苏省农药研究所股份有限公司 Composés de formanilide hétérocyclique, leurs procédés de synthèse et leur utilisation
CN101838227A (zh) 2010-04-30 2010-09-22 孙德群 一种苯甲酰胺类除草剂的安全剂
WO2011151146A1 (fr) 2010-05-31 2011-12-08 Syngenta Participations Ag Procédé d'amélioration du rendement d'un produit cultivé
WO2012034403A1 (fr) 2010-09-14 2012-03-22 中化蓝天集团有限公司 Composés de fluorométhoxypyrazole et d'anthranilamide, leurs procédés de synthèse et leurs utilisations
WO2013050317A1 (fr) 2011-10-03 2013-04-11 Syngenta Limited Formes polymorphes d'un dérivé d'isoxazoline
WO2013050302A1 (fr) 2011-10-03 2013-04-11 Syngenta Participations Ag Dérivés d'isoxazoline utilisés comme composés insecticides
CN102391261A (zh) 2011-10-14 2012-03-28 上海交通大学 一种n-取代噁二嗪类化合物及其制备方法和应用
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
WO2013144213A1 (fr) 2012-03-30 2013-10-03 Basf Se Composés de pyridylidène n-substitués et dérivés destinés à lutter contre les animaux nuisibles
EP2647626A1 (fr) 2012-04-03 2013-10-09 Syngenta Participations AG. Dérivés de 1-aza-spiro[4.5]déc-3-ène and 1,8-diaza-spiro[4.5]déc-3-ène en tant que pesticides
WO2013162716A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
US20140213448A1 (en) 2012-04-27 2014-07-31 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
WO2013162715A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
CN103109816A (zh) 2013-01-25 2013-05-22 青岛科技大学 硫代苯甲酰胺类化合物及其应用
CN103232431A (zh) 2013-01-25 2013-08-07 青岛科技大学 一种二卤代吡唑酰胺类化合物及其应用
US20140275503A1 (en) 2013-03-13 2014-09-18 Dow Agrosciences Llc Process for the preparation of certain triaryl rhamnose carbamates
WO2014187846A1 (fr) 2013-05-23 2014-11-27 Syngenta Participations Ag Formulations de mélange en cuve
CN103265527A (zh) 2013-06-07 2013-08-28 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物及其制备方法和应用
CN103524422A (zh) 2013-10-11 2014-01-22 中国农业科学院植物保护研究所 苯并咪唑衍生物及其制备方法和用途
WO2015058021A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de de composés pesticides
WO2015058028A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de composés pesticides
WO2021105101A1 (fr) 2019-11-26 2021-06-03 Bayer Aktiengesellschaft Dérivés d'acide acétique [(1,5-diphényl-1h-1,2,4-triazol-3-yl)oxy] et sels de ceux-ci, compositions de protection des cultures les comprenant, leurs procédés de production et utilisation de ceux-ci en tant que phytoprotecteurs
WO2022043205A1 (fr) * 2020-08-24 2022-03-03 Bayer Aktiengesellschaft N-phényluraciles substitués et sels de ceux-ci et utilisation associée en tant que substances actives herbicides
WO2023030935A1 (fr) * 2021-08-31 2023-03-09 Basf Se Procédé de lutte contre les mauvaises herbes résistantes aux ppo-i
WO2023030934A1 (fr) * 2021-08-31 2023-03-09 Basf Se Composition herbicide comprenant des phényluraciles
EP4230620A1 (fr) * 2022-02-22 2023-08-23 Bayer Aktiengesellschaft Uracile d'acide n-amino-n´-benzoïque substitués, ainsi que leurs sels et leur utilisation comme herbicides
WO2023161172A1 (fr) * 2022-02-22 2023-08-31 Bayer Aktiengesellschaft Uraciles d'acide n-benzoïque substitués et leurs sels, et leur utilisation en tant que substances actives herbicides
WO2024078906A1 (fr) * 2022-10-10 2024-04-18 Bayer Aktiengesellschaft N-phényluraciles substitués et leurs sels, et leur utilisation en tant que principes actifs herbicides

Non-Patent Citations (16)

* Cited by examiner, † Cited by third party
Title
"Gene Transfer to Plants, Springer Lab Manual", 1995, SPRINGER VERLAG
BRAUN ET AL., EMBO J., vol. 11, 1992, pages 3219 - 3227
K. MARTENS: "Spray Drying Handbook", 1979, G. GOODWIN LTD
MCCUTCHEON'S: "Encyclopedia of Surface Active Egents", 1964, CHEM. PUBL. CO. INC
N.Y. MARSDEN: "Handbook of Insecticide Dust Diluents and Carriers", 1963, J. WILEY & SONS
REFERENZSTELLE: "The Pesticide Manual", 2006, THE BRITISH CROP PROTECTION COUNCIL AND THE ROYAL SOC. OF CHEMISTRY
S. R. COLBY, WEEDS, vol. 15, 1967, pages 20 - 22
S.R. COLBY: "Calculating Synergistic and Antagonistic Responses of Herbicide Combination", WEEDS, vol. 15, no. 1309959-62-3, 1967, pages 20 - 22, XP001112961
SAMBROOK ET AL.: "Molecular Cloning, A Laboratory Manual", 1989, COLD SPRING HARBOR LABORATORY PRESS
SCHÖNFELDT: "Grenzflächenaktive Äthylenoxidaddukte", 1976, VERLAGSGESELLSCHAFT
SONNEWALD ET AL., PLANT J, vol. 1, 1991, pages 95 - 106
VAN VALKENBURG: "Pesticides Formulations", 1973, MARCEL DEKKER
WEED RESEARCH, vol. 26, 1986, pages 441 - 445
WINNACKER: "Trends in Plant Science", vol. 1, 1996, VCH WEINHEIM, pages: 423 - 431
WINNACKER-KÜCHLER: "Chemische Technologie", vol. 7, 1986, C. HANSER VERLAG
WOLTER ET AL., PROC. NATL. ACAD. SCI. USA, vol. 85, 1988, pages 846 - 850

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