WO2024164228A1 - Bipolar plate, electrolysis cell, fuel cell, and device for hydrogen production by water electrolysis - Google Patents
Bipolar plate, electrolysis cell, fuel cell, and device for hydrogen production by water electrolysis Download PDFInfo
- Publication number
- WO2024164228A1 WO2024164228A1 PCT/CN2023/075193 CN2023075193W WO2024164228A1 WO 2024164228 A1 WO2024164228 A1 WO 2024164228A1 CN 2023075193 W CN2023075193 W CN 2023075193W WO 2024164228 A1 WO2024164228 A1 WO 2024164228A1
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- Prior art keywords
- cathode
- anode
- flow channel
- bipolar plate
- reaction zone
- Prior art date
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 36
- 239000000446 fuel Substances 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000001257 hydrogen Substances 0.000 title claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title abstract description 55
- 238000006243 chemical reaction Methods 0.000 claims abstract description 89
- 239000000758 substrate Substances 0.000 claims abstract description 65
- 238000007789 sealing Methods 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 25
- 238000001746 injection moulding Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- 238000009792 diffusion process Methods 0.000 claims description 12
- 239000012528 membrane Substances 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 17
- 238000012986 modification Methods 0.000 description 10
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- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
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- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/036—Bipolar electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
Definitions
- the present application relates to the technical field of fuel cells, and in particular to a bipolar plate, an electrolysis chamber, a fuel cell and a water electrolysis hydrogen production device.
- Bipolar plates are one of the important components of fuel cells and water electrolysis hydrogen production devices. Bipolar plates can separate fuel and oxidant, prevent gas from penetrating, and collect and conduct current. They have high conductivity. Through the flow channels designed and processed on the bipolar plates, the gas can be evenly distributed to the reaction layer of the electrode for electrode reaction, and heat can be discharged to keep the battery temperature field uniform.
- the current bipolar plate manufacturing process requires the production of anode plates with anode side channels and cathode plates with cathode side channels.
- the positive plate, anode diffusion layer, membrane electrode, cathode diffusion layer and negative plate need to be stacked.
- a bipolar plate needs to be buckled outside the bipolar plate of the electrode chamber, and the cycle repeats. This results in a more complicated manufacturing process for bipolar plates, a larger number of bipolar plates, a higher production cost, and a single side of the bipolar plate needs to withstand a larger fluid pressure.
- the technical problem to be solved by the present application is to overcome the problem that the number of bipolar plates used in the prior art fuel cell and water electrolysis hydrogen production device is large, and one side needs to withstand a large fluid pressure.
- the defect of the relatively complicated manufacturing process of the electrode plate is overcome, so as to provide a bipolar plate, an electrolysis chamber, a fuel cell and a water electrolysis hydrogen production device, whose manufacturing process is relatively simple, the number of plates expressing the flow channel characteristics is small, the production cost is low, and the bipolar plate has better pressure-bearing capacity.
- the first aspect of the present application provides a bipolar plate, comprising: a substrate; an anode side flow channel, which includes an anode main flow channel and an anode reaction zone flow channel connected to each other, the anode main flow channel passes through the substrate, and the anode reaction zone flow channel is formed on a first side of the substrate;
- the cathode side flow channel comprises a cathode main flow channel and a cathode reaction zone flow channel which are connected to each other.
- the cathode main flow channel penetrates the substrate, and the cathode reaction zone flow channel is formed on the second side of the substrate.
- anode side flow channel also includes an anode flow guide structure formed on the first side of the substrate and adapted to connect the anode main flow channel and the anode reaction zone flow channel; and/or,
- the cathode side flow channel also includes a cathode flow guiding structure formed on the second side of the substrate and suitable for connecting the cathode main flow channel and the cathode reaction zone flow channel.
- the anode flow guiding structure includes an anode equal flow channel and multiple anode flow guiding channels, each anode flow guiding channel is suitable for connecting an anode reaction zone channel with the anode main flow channel, and the anode equal flow channel is suitable for connecting multiple anode flow guiding channels; and/or,
- the cathode guide structure includes a cathode equal flow channel and multiple cathode guide channels.
- Each cathode guide channel is suitable for connecting a cathode reaction zone flow channel with the cathode main flow channel, and the cathode equal flow channel is suitable for connecting multiple cathode guide channels.
- anode guide structure is formed on the first side of the substrate by a stamping process; or,
- the anode guide structure is formed on the first side of the bipolar plate by an injection molding process; or,
- the bipolar plate further includes a bridge covering the first side of the substrate, and an anode flow guide structure is formed between the substrate and the bridge.
- the cathode guide structure is formed on the second side of the substrate by a stamping process; or,
- the cathode guide structure is formed on the second side of the substrate by an injection molding process; or,
- the bipolar plate further includes a bridge covering the second side of the substrate, and a cathode flow guiding structure is formed between the substrate and the bridge.
- anode main channels and cathode main channels there are two groups of anode main channels and cathode main channels, one group of anode main channels and one group of cathode main channels are respectively arranged at the two ends of the bipolar plate, and the anode main channels and the cathode main channels are staggered, the anode reaction zone flow channel is arranged between the two groups of anode main channels, and the cathode reaction zone flow channel is arranged between the two groups of cathode main channels.
- anode reaction zone flow channel and the cathode reaction zone flow channel are located at the same position on both sides of the substrate and are formed by a stamping process.
- the substrate includes a metal plate and an injection-molded frame wrapped around the outside of the metal plate, the anode reaction zone flow channel, the anode guide structure, the cathode reaction zone flow channel and the cathode guide structure are formed on the metal plate, the anode main flow channel and the cathode main flow channel are formed on the injection-molded frame, and the injection-molded frame is also formed with a first notch suitable for exposing the anode reaction zone flow channel and a second notch suitable for exposing the cathode reaction zone flow channel; or,
- the bipolar plate also includes a metal plate and an injection-molded frame wrapped around the outside of the metal plate.
- the anode reaction zone flow channel, the anode guide structure, the cathode reaction zone flow channel, the cathode guide structure, the anode main channel and the cathode main channel are formed on the metal plate.
- the injection-molded frame is formed with a first notch suitable for exposing the anode reaction zone flow channel, a second notch suitable for exposing the cathode reaction zone flow channel, a third notch suitable for exposing the anode main channel and a fourth notch suitable for exposing the cathode main channel.
- the injection molding frame is suitable for exposing a first sealing structure arranged around the first notch, a second sealing structure arranged around the second notch, a third sealing structure arranged around the third notch, and a fourth sealing structure arranged around the fourth notch.
- the second aspect of the present application relates to an electrolysis chamber, comprising:
- a first bipolar plate and a second bipolar plate wherein the first bipolar plate and the second bipolar plate are both the bipolar plates provided by the first aspect of the present application, and the first side of the first bipolar plate is arranged toward the second side of the second bipolar plate;
- the anode diffusion layer, the membrane electrode and the cathode diffusion layer are sequentially sandwiched between the first bipolar plate and the second between the bipolar plates.
- the third aspect of the present application relates to a fuel cell, comprising the bipolar plate provided in the first aspect of the present application.
- the fourth aspect of the present application relates to a water electrolysis hydrogen production device, including the bipolar plate involved in the first aspect of the present application.
- the bipolar plate of the embodiment of the present application mainly forms an anode side flow channel and a cathode side flow channel on both sides of the substrate, so that one side of the bipolar plate can be used to guide the anode gas, and the other side can be used to guide the cathode gas, and the anode gas and the cathode gas can be reliably separated. Therefore, when the bipolar plate of the embodiment of the present application is used to manufacture a water electrolysis hydrogen production device or a fuel cell, the anode plate of each electrolysis chamber can be used as the cathode plate of the previous electrolysis chamber, and the cathode plate of each electrolysis chamber can be used as the anode plate of the next electrolysis chamber. On the premise that the number of electrolysis chambers remains unchanged, the use of the bipolar plate of the embodiment of the present application can greatly reduce the number of bipolar plates in the device, thereby reducing the cost of the device.
- the step of buckling the two bipolar plates is omitted, thereby simplifying the manufacturing process.
- the inventors found that during the use of the bipolar plate of the embodiment of the present application, the two sides of the bipolar plate are respectively subjected to the pressure of the cathode gas and the anode gas, and the pressure of the cathode gas and the anode gas can offset each other, which makes the bipolar plate only need to bear the pressure difference of the gas on both sides, thereby greatly reducing the pressure borne by the bipolar plate and effectively improving the pressure-bearing capacity of the bipolar plate.
- the bipolar plate of the embodiment of the present application can be used as both an anode plate and a cathode plate, which enables manufacturers to use a set of molds to simultaneously manufacture cathode plates and anode plates, thereby reducing mold costs and helping to shorten the design cycle of molds for manufacturing bipolar plates.
- the bipolar plate of the embodiment of the present application can overcome the defects of the bipolar plate in the prior art, such as the relatively complex manufacturing process, large quantity, high production cost, and the need to withstand a large fluid pressure on one side.
- Its manufacturing process is relatively simple, the number of plates expressing the flow channel characteristics is small, the production cost is low, and it has better pressure-bearing capacity.
- the electrode chamber of the second aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, namely, its manufacturing process is relatively simple, the number of plates expressing flow channel characteristics used is small, the production cost is low, and it has better pressure bearing capacity.
- the fuel cell of the third aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, namely, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics is small while the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
- the water electrolysis hydrogen production device of the fourth aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, that is, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics used is small while the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
- FIG1 shows a bipolar plate of Example 1 of the present application
- FIG2 shows a bipolar plate of Example 1 of the present application, and hides its first sealing structure, second sealing structure, third sealing structure and fourth sealing structure;
- FIG3 is a transverse cross-sectional view of a bipolar plate of Example 1 of the present application.
- FIG4 is the anode side of the metal plate of the bipolar plate of Example 1 of the present application.
- FIG5 is a diagram showing the cathode side of the metal plate of the bipolar plate of Example 1 of the present application.
- FIG6 is a partial side sectional view of the electrolysis chamber of Example 2 of the present application.
- the terms “installed”, “connected”, and “connected” should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components.
- installed should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components.
- FIG1 shows a bipolar plate of Example 1 of the present application.
- FIG2 shows a bipolar plate of Example 1 of the present application, and hides its first sealing structure, second sealing structure, third sealing structure and fourth sealing structure.
- FIG3 is a transverse cross-sectional view of the bipolar plate of Example 1 of the present application.
- the present embodiment relates to a bipolar plate 100, comprising a substrate, an anode side flow channel and a cathode side flow channel.
- the anode side flow channel comprises an anode main flow channel 11 and an anode reaction zone flow channel 12 connected to each other, the anode main flow channel 11 passes through the substrate, and the anode reaction zone flow channel 12 is formed on the first side of the substrate.
- the cathode side flow channel comprises a cathode main flow channel 21 and a cathode reaction zone flow channel 22 connected to each other.
- the cathode main flow channel 21 passes through the substrate, and the cathode reaction zone flow channel 22 is formed on the second side of the substrate.
- the bipolar plate of the embodiment of the present application mainly forms an anode side flow channel and a cathode side flow channel on both sides of the substrate.
- the bipolar plate of the embodiment of the present application is used in a water electrolysis hydrogen production device or a fuel cell, and the anode plate of each electrolysis chamber can be used as the cathode plate of the previous electrolysis chamber, and the cathode plate of each electrolysis chamber can be used as the anode plate of the next electrolysis chamber.
- the use of the bipolar plate of the embodiment of the present application can greatly reduce the number of bipolar plates in the device, thereby reducing the cost of the device.
- the step of buckling the two bipolar plates is omitted, thereby simplifying the manufacturing process.
- the inventors found that during the use of the bipolar plate of the embodiment of the present application, the two sides of the bipolar plate are respectively subjected to the pressure of the cathode gas and the anode gas, and the pressure of the cathode gas and the anode gas can offset each other. This allows the bipolar plate to only bear the pressure difference of the gas on both sides, thereby greatly reducing the pressure on the bipolar plate and effectively improving the pressure-bearing capacity of the bipolar plate.
- the bipolar plate of the embodiment of the present application can be used as both an anode plate and a cathode plate, which enables manufacturers to use a set of molds to simultaneously manufacture the cathode plate and the anode plate, thereby reducing the cost of the molds and helping to shorten the design cycle of the molds for manufacturing the bipolar plates.
- the bipolar plate of the embodiment of the present application can overcome the defects of the bipolar plate in the prior art, such as the relatively complex manufacturing process, large quantity, high production cost, and the need to withstand a large fluid pressure on one side.
- Its manufacturing process is relatively simple, the production cost is low, and the number of plates expressing the flow channel characteristics is small while the number of electrolytic chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
- the anode reaction zone flow channel 12 may be arranged to be directly connected to the anode main flow channel 11.
- the anode side flow channel further includes an anode flow guiding structure 14.
- the anode flow guiding structure 14 is disposed on the first side of the substrate and is adapted to connect the anode main flow channel 11 and the anode reaction zone flow channel 12.
- the anode reaction zone flow channel 12 is multiple and arranged in parallel with each other.
- the anode flow guiding structure 14 includes an anode equal flow channel 141 and multiple anode flow guiding channels 142.
- Each anode flow guiding channel 142 is suitable for connecting an anode reaction zone channel with the anode main flow channel 11.
- the anode equal flow channel 141 is suitable for connecting multiple anode flow guiding channels 142.
- the anode flow guiding channel 142 can connect the anode main flow channel 11 with the anode reaction zone flow channel 12.
- the anode equal flow channel 141 can balance the pressure and ensure that the liquid in the multiple anode flow guiding channels 142 flows out as evenly as possible, so that the anode gas in the anode reaction zone flow channel is as uniform as possible, which helps to improve the reaction efficiency of the anode reaction.
- the anode flow guiding structure 14 can be optionally formed with multiple rectangular bumps or circular bumps, and the anode equal flow channel 141 and the anode flow guiding channel 142 are formed around the rectangular bumps or circular bumps.
- the cathode reaction zone flow channel 22 may be directly connected to the cathode main flow channel.
- the cathode side flow channel further includes a cathode flow guiding structure 24.
- the cathode flow guiding structure 24 is formed on the second side of the substrate and is suitable for connecting the cathode main flow channel 21 and the cathode reaction zone flow channel 22.
- the cathode flow guiding structure 24 includes a cathode equal flow channel 241 and multiple cathode flow guiding channels 242.
- Each cathode flow guiding channel 242 is suitable for connecting a cathode reaction zone flow channel with the cathode main flow channel 21.
- the cathode equal flow channel 241 is suitable for connecting multiple cathode flow guiding channels 242.
- the cathode flow guiding channel 242 is suitable for connecting the cathode main flow channel 21 and the cathode reaction zone flow channel 22.
- the cathode equal flow channel 241 can balance the pressure to ensure that the liquid in the multiple cathode flow guiding channels 242 flows out as smoothly as possible.
- the cathode flow guiding structure 24 may be optionally formed with multiple rectangular protrusions or circular protrusions. shaped protrusions, the cathode equalizing channel 241 and the cathode guide channel 242 are formed around the rectangular protrusions or the circular protrusions.
- the anode flow guide structure 14 may be formed on the first side of the substrate by a stamping process.
- the anode flow guide structure 14 may also be formed on the first side of the bipolar plate 100 by an injection molding process.
- the injection molding material is preferably plastic, such as PEEK modification, PTFE modification, PSU modification, PI modification, etc.; it has sufficient strength and rigidity to ensure the mechanical properties, corrosion resistance and insulation properties of the electrolytic cell under working conditions.
- the bipolar plate 100 may also be selected to include a bridge covered on the first side of the substrate, and the anode flow guide structure 14 is formed between the substrate and the bridge.
- the bridge is preferably but not limited to being made of materials such as plastic or metal.
- the anode flow guide structure 14 may be formed on the substrate, may be formed on the bridge, and may be partially formed on the substrate and partially formed on the bridge.
- the bridge preferably but not limited to includes a cover plate and a flow guide channel formed under the cover plate. When the cover plate is covered on the substrate, an anode flow guide structure 14 is formed between the cover plate and the substrate.
- the cathode flow guiding structure 24 may be formed on the second side of the substrate by a stamping process.
- the cathode flow guiding structure 24 may also be formed on the second side of the substrate by an injection molding process.
- the injection molding material is preferably plastic, such as PEEK modification, PTFE modification, PSU modification, PI modification, etc.; it has sufficient strength and rigidity to ensure the mechanical properties, corrosion resistance and insulation properties of the electrolyzer under working conditions.
- the bipolar plate 100 also includes a bridge covered on the second side of the substrate, and the cathode flow guiding structure 24 is formed between the substrate and the bridge.
- the bridge is preferably but not limited to being made of materials such as plastic or metal.
- the cathode flow guiding structure 24 may be formed on the substrate, may be formed on the bridge, or may be partially formed on the substrate and partially formed on the bridge.
- the bridge preferably but not limited to includes a cover plate and a flow guiding channel formed under the cover plate. When the cover plate is covered on the substrate, a cathode flow guiding structure 24 is formed between the cover plate and the substrate.
- the anode main channel 11 and the cathode main channel 21 are both provided in two groups.
- a group of anode main channels 11 and a group of cathode main channels 21 are provided at both ends of the bipolar plate 100, and
- the anode main flow channel 11 and the cathode main flow channel 21 are arranged alternately.
- the anode reaction zone flow channel 12 is arranged between two groups of the anode main flow channels 11, and the cathode reaction zone flow channel 22 is arranged between two groups of the cathode main flow channels 21.
- anode main flow channel 11 and the cathode main flow channel 21 to be connected to the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 respectively through a guide structure of moderate length, and enables the space of the reaction zone to be fully utilized.
- the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 are located at the same position on both sides of the substrate and are formed by a stamping process.
- the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 can be formed on both sides of the substrate at the same time by a single stamping.
- the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 on the bipolar plate 100 in the prior art are generally made by an etching process.
- the material thickness used in the etching process is generally about 3 mm, and the process cost is relatively high (generally about 2,000 yuan), and it takes a long time.
- the bipolar plate 100 of this embodiment is made by a stamping process, which greatly reduces the thickness of the bipolar plate 100 (the thickness of the bipolar plate 100 can be reduced to about 0.5 mm. Therefore, the bipolar plate of this embodiment uses a stamping process to form the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 on both sides of the substrate at one time, which not only saves material costs, but also the stamping process itself is relatively cheap, thereby greatly reducing the manufacturing cost of the bipolar plate and improving the manufacturing efficiency of the bipolar plate.
- the bipolar plate 100 of the present embodiment is thin, since the anode side flow channel and the cathode side flow channel are formed on both sides, the pressure on both sides of the bipolar plate 100 can offset each other, which makes the pressure that the bipolar plate 100 of the present embodiment needs to withstand much less than the bipolar plate 100 in the prior art. Therefore, the pressure bearing capacity of the bipolar plate of the present embodiment is still better than the pressure bearing capacity of the bipolar plate in the prior art, and the material cost of the bipolar plate is saved without shortening the service life of the bipolar plate 100.
- the substrate includes a metal plate 3 and an injection molding frame 4 wrapped around the outside of the metal plate 3.
- the anode reaction zone flow channel 12, the anode flow guide structure 14, the cathode reaction zone flow channel 22 and the cathode flow guide structure 24 are formed on the metal plate 3.
- the anode main flow channel 11 and the cathode main flow channel 21 are formed on the injection molding frame 4.
- the injection molding frame 4 also has a first notch 41 and a second notch 42 for exposing the anode reaction zone flow channel 12.
- the second notch 42 is suitable for exposing the cathode reaction zone flow channel 22.
- the metal plate 3 is preferably but not limited to being made of pure titanium or stainless steel plated with titanium.
- the bipolar plate 100 further includes a metal plate 3 and an injection molding frame 4 wrapped around the outside of the metal plate 3.
- the anode reaction zone flow channel 12, the anode flow guide structure 14, the cathode reaction zone flow channel 22, the cathode flow guide structure 24, the anode main flow channel 11, the anode main flow channel 11 and the cathode main flow channel 21 are formed on the metal plate 3.
- the injection molding frame 4 is formed with a first notch 41 suitable for exposing the anode reaction zone flow channel 12, a second notch 42 suitable for exposing the cathode reaction zone flow channel 22, a third notch 43 suitable for exposing the anode main flow channel 11 and a fourth notch 44 suitable for exposing the cathode main flow channel 21.
- the injection molding frame 4 is formed with a first sealing structure 51 disposed around the first notch 41, a second sealing structure 52 disposed around the second notch 42, a third sealing structure 53 disposed around the third notch 43, and a fourth sealing structure 54 disposed around the fourth notch 44.
- the first sealing structure 51, the second sealing structure 52, the third sealing structure 53, and the fourth sealing structure 54 are preferably, but not limited to, sealing gaskets, or waterlines disposed around the notches of the injection molding frame 4.
- the bipolar plate 100 of this embodiment forms a sealing structure on the injection molding frame 4, thereby reducing the thickness of the sealing structure. At this time, applying a pressure of about 3 MPA to the bipolar plate 100 can ensure that the fluid does not leak, reducing the pressure that needs to be applied to the sealing structure to ensure sealing. In addition, water lines are easily formed on the injection molding frame 4, which helps to increase the number of water lines, thereby further improving the sealing effect.
- Embodiment 2 relates to an electrolysis chamber.
- the electrolysis chamber of Embodiment 2 includes a first bipolar plate, a second bipolar plate, an anode diffusion layer 200, a membrane electrode 201, and a cathode diffusion layer 202.
- the first bipolar plate and the second bipolar plate are both bipolar plates 100 of Embodiment 1 of the utility model.
- the first side of the first bipolar plate faces the second side of the second bipolar plate.
- the anode diffusion layer 200, the membrane electrode 201, and the cathode diffusion layer 202 are sequentially sandwiched between the first bipolar plate and the second bipolar plate.
- the electrolysis chamber of embodiment 2 includes or uses the electrolysis chamber of embodiment 1 of the present application, and thus has its beneficial effects, its manufacturing process is relatively simple, and its production cost is low.
- the number of plates expressing the flow channel characteristics is kept constant, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
- Embodiment 3 relates to a fuel cell, which includes the bipolar plate 100 involved in Embodiment 1 of the present application, and thus has its beneficial effects, namely, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing flow channel characteristics is small under the premise of the same number of electrolytic chambers, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
- Embodiment 4 relates to a water electrolysis hydrogen production device, which includes the bipolar plate 100 involved in Embodiment 1 of the present application, and thus has the beneficial effects of the bipolar plate 100 of Embodiment 1, and its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics is small under the premise that the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
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Abstract
Description
本申请涉及燃料电池技术领域,具体涉及一种双极板、电解小室、燃料电池和电解水制氢装置。The present application relates to the technical field of fuel cells, and in particular to a bipolar plate, an electrolysis chamber, a fuel cell and a water electrolysis hydrogen production device.
双极板是燃料电池和电解水制氢装置的重要部件之一。双极板能够分隔燃料与氧化剂,阻止气体透过,并收集、传导电流,电导率高,通过在双极板上设计与加工的流道,可将气体均匀分配到电极的反应层进行电极反应,并能排出热量,保持电池温场均匀。Bipolar plates are one of the important components of fuel cells and water electrolysis hydrogen production devices. Bipolar plates can separate fuel and oxidant, prevent gas from penetrating, and collect and conduct current. They have high conductivity. Through the flow channels designed and processed on the bipolar plates, the gas can be evenly distributed to the reaction layer of the electrode for electrode reaction, and heat can be discharged to keep the battery temperature field uniform.
然而,目前的双极板在制造过程中需要分别制作出具有阳极侧流道的阳极板和具有阴极侧流道的阴极板,在制造电解小室时,需要将正极板、阳极扩散层、膜电极、阴极扩散层和负极板层叠设置,每一个电极小室制作完成后,需要在电极小室的双极板外对扣一个双极板,周而复始。这就导致了双极板的制造工艺较为复杂,数量较多,生产成本较高,且双极板的单侧需要承受较大的流体压力。However, the current bipolar plate manufacturing process requires the production of anode plates with anode side channels and cathode plates with cathode side channels. When manufacturing the electrolytic chamber, the positive plate, anode diffusion layer, membrane electrode, cathode diffusion layer and negative plate need to be stacked. After each electrode chamber is completed, a bipolar plate needs to be buckled outside the bipolar plate of the electrode chamber, and the cycle repeats. This results in a more complicated manufacturing process for bipolar plates, a larger number of bipolar plates, a higher production cost, and a single side of the bipolar plate needs to withstand a larger fluid pressure.
发明内容Summary of the invention
因此,本申请要解决的技术问题在于克服现有技术中燃料电池和电解水制氢装置使用的双极板数量较多,且单侧需要承受较大的流体压力,双 极板制造工艺较为复杂的缺陷,从而提供一种双极板、电解小室、燃料电池和电解水制氢装置,其制造流程较为简单,表达流道特征的板的使用数量较少,生产成本较低,且双极板具有更好的承压能力。Therefore, the technical problem to be solved by the present application is to overcome the problem that the number of bipolar plates used in the prior art fuel cell and water electrolysis hydrogen production device is large, and one side needs to withstand a large fluid pressure. The defect of the relatively complicated manufacturing process of the electrode plate is overcome, so as to provide a bipolar plate, an electrolysis chamber, a fuel cell and a water electrolysis hydrogen production device, whose manufacturing process is relatively simple, the number of plates expressing the flow channel characteristics is small, the production cost is low, and the bipolar plate has better pressure-bearing capacity.
为了解决上述问题,本申请第一方面提供了一种双极板,包括:基板;阳极侧流道,其包括相互连接的阳极主流道和阳极反应区流道,阳极主流道贯穿基板,阳极反应区流道形成在基板的第一侧;In order to solve the above problems, the first aspect of the present application provides a bipolar plate, comprising: a substrate; an anode side flow channel, which includes an anode main flow channel and an anode reaction zone flow channel connected to each other, the anode main flow channel passes through the substrate, and the anode reaction zone flow channel is formed on a first side of the substrate;
阴极侧流道,其包括相互连接的阴极主流道和阴极反应区流道,阴极主流道贯穿基板,阴极反应区流道形成在基板的第二侧。The cathode side flow channel comprises a cathode main flow channel and a cathode reaction zone flow channel which are connected to each other. The cathode main flow channel penetrates the substrate, and the cathode reaction zone flow channel is formed on the second side of the substrate.
进一步地,阳极侧流道还包括形成在基板的第一侧,并适于连通阳极主流道和阳极反应区流道的阳极导流结构;和/或,Further, the anode side flow channel also includes an anode flow guide structure formed on the first side of the substrate and adapted to connect the anode main flow channel and the anode reaction zone flow channel; and/or,
阴极侧流道还包括形成在基板的第二侧,并适于连通阴极主流道和阴极反应区流道的阴极导流结构。The cathode side flow channel also includes a cathode flow guiding structure formed on the second side of the substrate and suitable for connecting the cathode main flow channel and the cathode reaction zone flow channel.
进一步地,阳极反应区通道为多条且相互平行设置,阳极导流结构包括阳极均流通道和多条阳极导流通道,每条阳极导流通道适于将一条阳极反应区通道与阳极主流道相连通,阳极均流通道适于连通多条阳极导流通道;和/或,Furthermore, there are multiple anode reaction zone channels arranged in parallel with each other, the anode flow guiding structure includes an anode equal flow channel and multiple anode flow guiding channels, each anode flow guiding channel is suitable for connecting an anode reaction zone channel with the anode main flow channel, and the anode equal flow channel is suitable for connecting multiple anode flow guiding channels; and/or,
阴极反应区流道为多条且相互平行设置,阴极导流结构包括阴极均流通道和多条阴极导流通道,每条阴极导流通道适于将一条阴极反应区流道与阴极主流道相连通,阴极均流通道适于连通多条阴极导流通道。There are multiple cathode reaction zone flow channels that are arranged in parallel with each other. The cathode guide structure includes a cathode equal flow channel and multiple cathode guide channels. Each cathode guide channel is suitable for connecting a cathode reaction zone flow channel with the cathode main flow channel, and the cathode equal flow channel is suitable for connecting multiple cathode guide channels.
进一步地,阳极导流结构通过冲压工艺形成在基板的第一侧;或,Further, the anode guide structure is formed on the first side of the substrate by a stamping process; or,
阳极导流结构通过注塑工艺形成在双极板的第一侧;或,The anode guide structure is formed on the first side of the bipolar plate by an injection molding process; or,
双极板还包括盖设在基板的第一侧的过桥,阳极导流结构形成在基板与过桥之间。The bipolar plate further includes a bridge covering the first side of the substrate, and an anode flow guide structure is formed between the substrate and the bridge.
进一步地,阴极导流结构通过冲压工艺形成在基板的第二侧;或, Further, the cathode guide structure is formed on the second side of the substrate by a stamping process; or,
阴极导流结构通过注塑工艺形成在基板的第二侧;或,The cathode guide structure is formed on the second side of the substrate by an injection molding process; or,
双极板还包括盖设在基板的第二侧的过桥,阴极导流结构形成在基板与过桥之间。The bipolar plate further includes a bridge covering the second side of the substrate, and a cathode flow guiding structure is formed between the substrate and the bridge.
进一步地,阳极主流道和阴极主流道均为两组,双极板的两端分别设置有一组阳极主流道和一组阴极主流道,且阳极主流道和阴极主流道交错设置,阳极反应区流道设置在两组阳极主流道之间,阴极反应区流道设置在两组阴极主流道之间。Furthermore, there are two groups of anode main channels and cathode main channels, one group of anode main channels and one group of cathode main channels are respectively arranged at the two ends of the bipolar plate, and the anode main channels and the cathode main channels are staggered, the anode reaction zone flow channel is arranged between the two groups of anode main channels, and the cathode reaction zone flow channel is arranged between the two groups of cathode main channels.
进一步地,阳极反应区流道和阴极反应区流道位于基板的两侧的相同位置,且由冲压工艺形成。Furthermore, the anode reaction zone flow channel and the cathode reaction zone flow channel are located at the same position on both sides of the substrate and are formed by a stamping process.
进一步地,基板包括金属板和包裹在金属板外侧的注塑边框,阳极反应区流道、阳极导流结构、阴极反应区流道和阴极导流结构形成在金属板上,阳极主流道和阴极主流道形成在注塑边框上,注塑边框上还形成有适于暴露阳极反应区流道的第一豁口和适于暴露阴极反应区流道的第二豁口;或,Further, the substrate includes a metal plate and an injection-molded frame wrapped around the outside of the metal plate, the anode reaction zone flow channel, the anode guide structure, the cathode reaction zone flow channel and the cathode guide structure are formed on the metal plate, the anode main flow channel and the cathode main flow channel are formed on the injection-molded frame, and the injection-molded frame is also formed with a first notch suitable for exposing the anode reaction zone flow channel and a second notch suitable for exposing the cathode reaction zone flow channel; or,
双极板还包括金属板和包裹在金属板外侧的注塑边框,阳极反应区流道、阳极导流结构、阴极反应区流道、阴极导流结构、阳极主流道和阴极主流道形成在金属板上,注塑边框上形成有适于暴露阳极反应区流道的第一豁口、适于暴露阴极反应区流道的第二豁口、适于暴露阳极主流道的第三豁口和适于暴露阴极主流道的第四豁口。The bipolar plate also includes a metal plate and an injection-molded frame wrapped around the outside of the metal plate. The anode reaction zone flow channel, the anode guide structure, the cathode reaction zone flow channel, the cathode guide structure, the anode main channel and the cathode main channel are formed on the metal plate. The injection-molded frame is formed with a first notch suitable for exposing the anode reaction zone flow channel, a second notch suitable for exposing the cathode reaction zone flow channel, a third notch suitable for exposing the anode main channel and a fourth notch suitable for exposing the cathode main channel.
适于暴露注塑边框上形成有环绕第一豁口设置的第一密封结构、环绕第二豁口设置的第二密封结构、环绕第三豁口设置的第三密封结构、环绕第四豁口设置的第四密封结构。The injection molding frame is suitable for exposing a first sealing structure arranged around the first notch, a second sealing structure arranged around the second notch, a third sealing structure arranged around the third notch, and a fourth sealing structure arranged around the fourth notch.
本申请第二方面涉及了一种电解小室,包括:The second aspect of the present application relates to an electrolysis chamber, comprising:
第一双极板和第二双极板,第一双极板和第二双极板均为本申请第一方面所提供的双极板,第一双极板的第一侧朝向第二双极板的第二侧设置;A first bipolar plate and a second bipolar plate, wherein the first bipolar plate and the second bipolar plate are both the bipolar plates provided by the first aspect of the present application, and the first side of the first bipolar plate is arranged toward the second side of the second bipolar plate;
阳极扩散层、膜电极和阴极扩散层,其依次夹设在第一双极板和第二 双极板之间。The anode diffusion layer, the membrane electrode and the cathode diffusion layer are sequentially sandwiched between the first bipolar plate and the second between the bipolar plates.
本申请第三方面涉及了一种燃料电池,包括本申请第一方面所提供的双极板。The third aspect of the present application relates to a fuel cell, comprising the bipolar plate provided in the first aspect of the present application.
本申请第四方面涉及了一种电解水制氢装置,包括本申请第一方面所涉及的双极板。The fourth aspect of the present application relates to a water electrolysis hydrogen production device, including the bipolar plate involved in the first aspect of the present application.
本申请具有以下优点:This application has the following advantages:
1、本申请实施例的双极板主要在基板的两侧分别形成了阳极侧流道和阴极侧流道,使双极板的一侧能够用于对阳极气体进行导流,另一侧能够用于对阴极气体进行导流,且能够对阳极气体和阴极气体进行可靠地分隔,因此,当使用本申请实施例的双极板制造电解水制氢装置或燃料电池时,每个电解小室的阳极板能够作为前一个电解小室的阴极板,每个电解小室的阴极板能够作为下一个电解小室的阳极板,在电解小室的数量不变的前提下,使用本申请实施例的双极板能够大大减少装置内的双极板的数量,从而降低了装置的成本。1. The bipolar plate of the embodiment of the present application mainly forms an anode side flow channel and a cathode side flow channel on both sides of the substrate, so that one side of the bipolar plate can be used to guide the anode gas, and the other side can be used to guide the cathode gas, and the anode gas and the cathode gas can be reliably separated. Therefore, when the bipolar plate of the embodiment of the present application is used to manufacture a water electrolysis hydrogen production device or a fuel cell, the anode plate of each electrolysis chamber can be used as the cathode plate of the previous electrolysis chamber, and the cathode plate of each electrolysis chamber can be used as the anode plate of the next electrolysis chamber. On the premise that the number of electrolysis chambers remains unchanged, the use of the bipolar plate of the embodiment of the present application can greatly reduce the number of bipolar plates in the device, thereby reducing the cost of the device.
又由于每两个电解小室之间只需设置一个双极板,这就省略了将两个双极板对扣的步骤,由此简化了制造工艺,另外,发明人发现,本申请实施例的双极板在使用过程中,双极板的两侧分别受到阴极气体和阳极气体的压力,阴极气体和阳极气体的压力能够相互抵消,这使得双极板仅需承担两侧气体的压力差,由此大大降低了双极板所承受的压力,有效地提升了双极板的承压能力。Furthermore, since only one bipolar plate needs to be arranged between every two electrolytic chambers, the step of buckling the two bipolar plates is omitted, thereby simplifying the manufacturing process. In addition, the inventors found that during the use of the bipolar plate of the embodiment of the present application, the two sides of the bipolar plate are respectively subjected to the pressure of the cathode gas and the anode gas, and the pressure of the cathode gas and the anode gas can offset each other, which makes the bipolar plate only need to bear the pressure difference of the gas on both sides, thereby greatly reducing the pressure borne by the bipolar plate and effectively improving the pressure-bearing capacity of the bipolar plate.
另外,本申请实施例的双极板既能够作为阳极板,也能够作为阴极板,这就使得生产厂商能够用一组模具同时制造成阴极板和阳极板,由此降低了模具的成本,并有助于缩短制造双极板的模具的设计周期。 In addition, the bipolar plate of the embodiment of the present application can be used as both an anode plate and a cathode plate, which enables manufacturers to use a set of molds to simultaneously manufacture cathode plates and anode plates, thereby reducing mold costs and helping to shorten the design cycle of molds for manufacturing bipolar plates.
同时,综上所述,本申请实施例的双极板能够克服现有技术中的双极板制造工艺较为复杂,数量较多,生产成本较高,且单侧需要承受较大的流体压力的缺陷,其制造流程较为简单,表达流道特征的板的使用数量较少,生产成本较低,且具有更好的承压能力。At the same time, to sum up, the bipolar plate of the embodiment of the present application can overcome the defects of the bipolar plate in the prior art, such as the relatively complex manufacturing process, large quantity, high production cost, and the need to withstand a large fluid pressure on one side. Its manufacturing process is relatively simple, the number of plates expressing the flow channel characteristics is small, the production cost is low, and it has better pressure-bearing capacity.
2、本申请第二方面的电极小室包括或使用了本申请第一方面的双极板,因此具有了本申请第一方面的双极板的有益效果,即其制造流程较为简单,表达流道特征的板的使用数量较少,生产成本较低,且具有更好的承压能力。2. The electrode chamber of the second aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, namely, its manufacturing process is relatively simple, the number of plates expressing flow channel characteristics used is small, the production cost is low, and it has better pressure bearing capacity.
3、本申请第三方面的燃料电池包括或使用了本申请第一方面的双极板,因此具有了本申请第一方面的双极板的有益效果,即其制造流程较为简单,生产成本较低,在电解小室的数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。3. The fuel cell of the third aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, namely, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics is small while the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
4、本申请第四方面的电解水制氢装置包括或使用了本申请第一方面的双极板,因此具有了本申请第一方面的双极板的有益效果,即其制造流程较为简单,生产成本较低,在电解小室的数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。4. The water electrolysis hydrogen production device of the fourth aspect of the present application includes or uses the bipolar plate of the first aspect of the present application, and therefore has the beneficial effects of the bipolar plate of the first aspect of the present application, that is, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics used is small while the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
为了更清楚地说明本申请具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图是本申请的一些实施方式,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。 In order to more clearly illustrate the specific implementation methods of the present application or the technical solutions in the prior art, the drawings required for use in the specific implementation methods or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are some implementation methods of the present application. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative work.
图1示出了本申请实施例1的双极板;FIG1 shows a bipolar plate of Example 1 of the present application;
图2示出了本申请实施例1的双极板,并隐藏了其第一密封结构、第二密封结构、第三密封结构和第四密封结构;FIG2 shows a bipolar plate of Example 1 of the present application, and hides its first sealing structure, second sealing structure, third sealing structure and fourth sealing structure;
图3为本申请实施例1的双极板的横向剖视图;FIG3 is a transverse cross-sectional view of a bipolar plate of Example 1 of the present application;
图4为本申请实施例1的双极板的金属板的阳极侧;FIG4 is the anode side of the metal plate of the bipolar plate of Example 1 of the present application;
图5为本申请实施例1的双极板的金属板的阴极侧;FIG5 is a diagram showing the cathode side of the metal plate of the bipolar plate of Example 1 of the present application;
图6为本申请实施例2的电解小室的局部侧剖图。FIG6 is a partial side sectional view of the electrolysis chamber of Example 2 of the present application.
附图标记说明:Description of reference numerals:
100、双极板;11、阳极主流道;12、阳极反应区流道;14、阳极导流结构;141、阳极均流通道;142、阳极导流通道;21、阴极主流道;22、阴极反应区流道;24、阴极导流结构;241、阴极均流通道;242、阴极导流通道;3、金属板;4、注塑边框;41、第一豁口;42、第二豁口;43、第三豁口;44、第四豁口;51、第一密封结构;52、第二密封结构;53、第三密封结构;54、第四密封结构;200、阳极扩散层;201、膜电极;202、阴极扩散层。100, bipolar plate; 11, anode main flow channel; 12, anode reaction zone flow channel; 14, anode guide structure; 141, anode equal flow channel; 142, anode guide channel; 21, cathode main flow channel; 22, cathode reaction zone flow channel; 24, cathode guide structure; 241, cathode equal flow channel; 242, cathode guide channel; 3, metal plate; 4, injection molding frame; 41, first notch; 42, second notch; 43, third notch; 44, fourth notch; 51, first sealing structure; 52, second sealing structure; 53, third sealing structure; 54, fourth sealing structure; 200, anode diffusion layer; 201, membrane electrode; 202, cathode diffusion layer.
下面将结合附图对本申请的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。The technical solution of the present application will be described clearly and completely below in conjunction with the accompanying drawings. Obviously, the described embodiments are part of the embodiments of the present application, rather than all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present application.
在本申请的描述中,需要说明的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附 图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二”、“第三”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of this application, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer" and the like indicate positions or location relationships based on the attached The orientation or positional relationship shown in the figure is only for the convenience of describing the present application and simplifying the description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operate in a specific orientation, and therefore cannot be understood as limiting the present application. In addition, the terms "first", "second", and "third" are only used for descriptive purposes and cannot be understood as indicating or implying relative importance.
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components. For ordinary technicians in this field, the specific meanings of the above terms in this application can be understood according to specific circumstances.
此外,下面所描述的本申请不同实施方式中所涉及的技术特征只要彼此之间未构成冲突就可以相互结合。In addition, the technical features involved in the different embodiments of the present application described below can be combined with each other as long as they do not conflict with each other.
实施例1Example 1
图1示出了本申请实施例1的双极板。图2示出了本申请实施例1的双极板,并隐藏了其第一密封结构、第二密封结构、第三密封结构和第四密封结构。图3为本申请实施例1的双极板的横向剖视图。如图1、图2和图3所示,本实施例涉及了一种双极板100,包括基板、阳极侧流道和阴极侧流道。其中,阳极侧流道包括相互连接的阳极主流道11和阳极反应区流道12,阳极主流道11贯穿基板,阳极反应区流道12形成在基板的第一侧。阴极侧流道包括相互连接的阴极主流道21和阴极反应区流道22。阴极主流道21贯穿基板,阴极反应区流道22形成在基板的第二侧。FIG1 shows a bipolar plate of Example 1 of the present application. FIG2 shows a bipolar plate of Example 1 of the present application, and hides its first sealing structure, second sealing structure, third sealing structure and fourth sealing structure. FIG3 is a transverse cross-sectional view of the bipolar plate of Example 1 of the present application. As shown in FIG1, FIG2 and FIG3, the present embodiment relates to a bipolar plate 100, comprising a substrate, an anode side flow channel and a cathode side flow channel. Among them, the anode side flow channel comprises an anode main flow channel 11 and an anode reaction zone flow channel 12 connected to each other, the anode main flow channel 11 passes through the substrate, and the anode reaction zone flow channel 12 is formed on the first side of the substrate. The cathode side flow channel comprises a cathode main flow channel 21 and a cathode reaction zone flow channel 22 connected to each other. The cathode main flow channel 21 passes through the substrate, and the cathode reaction zone flow channel 22 is formed on the second side of the substrate.
本申请实施例的双极板主要在基板的两侧分别形成了阳极侧流道和阴 极侧流道,这使得使双极板的一侧能够用于对阳极气体进行导流,另一侧能够用于对阴极气体进行导流,且能够对阳极气体和阴极气体进行可靠地分隔。因此,当本申请实施例的双极板被应用在电解水制氢装置或燃料电池中时,每个电解小室的阳极板能够作为前一个电解小室的阴极板,每个电解小室的阴极板能够作为下一个电解小室的阳极板。在电解小室的数量不变的前提下,使用本申请实施例的双极板能够大大减少装置内的双极板的数量,从而降低了装置的成本。The bipolar plate of the embodiment of the present application mainly forms an anode side flow channel and a cathode side flow channel on both sides of the substrate. The bipolar plate of the embodiment of the present application is used in a water electrolysis hydrogen production device or a fuel cell, and the anode plate of each electrolysis chamber can be used as the cathode plate of the previous electrolysis chamber, and the cathode plate of each electrolysis chamber can be used as the anode plate of the next electrolysis chamber. Under the premise that the number of electrolysis chambers remains unchanged, the use of the bipolar plate of the embodiment of the present application can greatly reduce the number of bipolar plates in the device, thereby reducing the cost of the device.
又由于每两个电解小室之间只需设置一个双极板,这就省略了将两个双极板对扣的步骤,由此简化了制造工艺。另外,发明人发现,本申请实施例的双极板在使用过程中,双极板的两侧分别受到阴极气体和阳极气体的压力,阴极气体和阳极气体的压力能够相互抵消。这使得双极板仅需承担两侧气体的压力差,由此大大降低了双极板所承受的压力,有效地提升了双极板的承压能力。Since only one bipolar plate is required between each two electrolytic chambers, the step of buckling the two bipolar plates is omitted, thereby simplifying the manufacturing process. In addition, the inventors found that during the use of the bipolar plate of the embodiment of the present application, the two sides of the bipolar plate are respectively subjected to the pressure of the cathode gas and the anode gas, and the pressure of the cathode gas and the anode gas can offset each other. This allows the bipolar plate to only bear the pressure difference of the gas on both sides, thereby greatly reducing the pressure on the bipolar plate and effectively improving the pressure-bearing capacity of the bipolar plate.
另外,本申请实施例的双极板既能够作为阳极板,也能够作为阴极板。这就使得生产厂商能够用一组模具同时制造成阴极板和阳极板,由此降低了模具的成本,并有助于缩短制造双极板的模具的设计周期。In addition, the bipolar plate of the embodiment of the present application can be used as both an anode plate and a cathode plate, which enables manufacturers to use a set of molds to simultaneously manufacture the cathode plate and the anode plate, thereby reducing the cost of the molds and helping to shorten the design cycle of the molds for manufacturing the bipolar plates.
同时,综上所述,本申请实施例的双极板能够克服现有技术中的双极板制造工艺较为复杂,数量较多,生产成本较高,且单侧需要承受较大的流体压力的缺陷,其制造流程较为简单,生产成本较低,在电解小室的数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。At the same time, to sum up, the bipolar plate of the embodiment of the present application can overcome the defects of the bipolar plate in the prior art, such as the relatively complex manufacturing process, large quantity, high production cost, and the need to withstand a large fluid pressure on one side. Its manufacturing process is relatively simple, the production cost is low, and the number of plates expressing the flow channel characteristics is small while the number of electrolytic chambers remains unchanged, and the bipolar plate has better pressure-bearing capacity.
阳极反应区流道12可被设置成直接与阳极主流道11相连通,可选地, 在本实施例中,阳极侧流道还包括阳极导流结构14。阳极导流结构14设置在基板的第一侧,并适于连通阳极主流道11和阳极反应区流道12。The anode reaction zone flow channel 12 may be arranged to be directly connected to the anode main flow channel 11. Optionally, In this embodiment, the anode side flow channel further includes an anode flow guiding structure 14. The anode flow guiding structure 14 is disposed on the first side of the substrate and is adapted to connect the anode main flow channel 11 and the anode reaction zone flow channel 12.
可选地,在本实施例中,如图4所示,阳极反应区流道12为多条且相互平行设置。阳极导流结构14包括阳极均流通道141和多条阳极导流通道142。每条阳极导流通道142适于将一条阳极反应区通道与阳极主流道11相连通。阳极均流通道141适于连通多条阳极导流通道142。阳极导流通道142能够将阳极主流道11和阳极反应区流道12连通,当阳极导流通道142局部有非理想状况时,阳极均流通道141能够平衡压力,保证多条阳极导流通道142内的液体尽量均匀地流出,以使阳极反应区流道内的阳极气体尽量均匀,有助于提升阳极反应的反应效率。阳极导流结构14处可选为形成有多个矩形凸块或圆形凸点,阳极均流通道141和阳极导流通道142形成在矩形凸块或圆形凸点周围。Optionally, in the present embodiment, as shown in FIG4 , the anode reaction zone flow channel 12 is multiple and arranged in parallel with each other. The anode flow guiding structure 14 includes an anode equal flow channel 141 and multiple anode flow guiding channels 142. Each anode flow guiding channel 142 is suitable for connecting an anode reaction zone channel with the anode main flow channel 11. The anode equal flow channel 141 is suitable for connecting multiple anode flow guiding channels 142. The anode flow guiding channel 142 can connect the anode main flow channel 11 with the anode reaction zone flow channel 12. When the anode flow guiding channel 142 is partially in an undesirable condition, the anode equal flow channel 141 can balance the pressure and ensure that the liquid in the multiple anode flow guiding channels 142 flows out as evenly as possible, so that the anode gas in the anode reaction zone flow channel is as uniform as possible, which helps to improve the reaction efficiency of the anode reaction. The anode flow guiding structure 14 can be optionally formed with multiple rectangular bumps or circular bumps, and the anode equal flow channel 141 and the anode flow guiding channel 142 are formed around the rectangular bumps or circular bumps.
阴极反应区流道22可选为直接与阴极主流道相连。可选地,在本实施例中,阴极侧流道还包括阴极导流结构24。阴极导流结构24形成在基板的第二侧,并适于连通阴极主流道21和阴极反应区流道22。The cathode reaction zone flow channel 22 may be directly connected to the cathode main flow channel. Optionally, in this embodiment, the cathode side flow channel further includes a cathode flow guiding structure 24. The cathode flow guiding structure 24 is formed on the second side of the substrate and is suitable for connecting the cathode main flow channel 21 and the cathode reaction zone flow channel 22.
在如图5所示的实施例中,阴极反应区流道22为多条且相互平行设置,阴极导流结构24包括阴极均流通道241和多条阴极导流通道242。每条阴极导流通道242适于将一条阴极反应区流道与阴极主流道21相连通。阴极均流通道241适于连通多条阴极导流通道242。阴极导流通道242适于连通阴极主流道21和阴极反应区流道22。当阴极导流通道242局部有非理想状况时,阴极均流通道241能够平衡压力,保证多条阴极导流通道242内的液体尽量顺利地流出。阴极导流结构24处可选为形成有多个矩形凸块或圆 形凸点,阴极均流通道241和阴极导流通道242形成在矩形凸块或圆形凸点周围。In the embodiment shown in FIG. 5 , there are multiple cathode reaction zone flow channels 22 which are arranged in parallel with each other, and the cathode flow guiding structure 24 includes a cathode equal flow channel 241 and multiple cathode flow guiding channels 242. Each cathode flow guiding channel 242 is suitable for connecting a cathode reaction zone flow channel with the cathode main flow channel 21. The cathode equal flow channel 241 is suitable for connecting multiple cathode flow guiding channels 242. The cathode flow guiding channel 242 is suitable for connecting the cathode main flow channel 21 and the cathode reaction zone flow channel 22. When there is a non-ideal condition in a part of the cathode flow guiding channel 242, the cathode equal flow channel 241 can balance the pressure to ensure that the liquid in the multiple cathode flow guiding channels 242 flows out as smoothly as possible. The cathode flow guiding structure 24 may be optionally formed with multiple rectangular protrusions or circular protrusions. shaped protrusions, the cathode equalizing channel 241 and the cathode guide channel 242 are formed around the rectangular protrusions or the circular protrusions.
在本实施例中,阳极导流结构14可选为通过冲压工艺形成在基板的第一侧。阳极导流结构14也可选择为通过注塑工艺形成在双极板100的第一侧。注塑材料优选为塑料,例如PEEK改性、PTFE改性、PSU改性、PI改性等;其具有足够的强度和刚度,可保证电解槽在工作条件下的机械性能,耐腐蚀性能和绝缘性能。双极板100还可选为包括盖设在基板的第一侧的过桥,阳极导流结构14形成在基板与过桥之间。过桥优选但不限于由塑料或金属等材料制成。阳极导流结构14可选为形成在基板上、也可选为形成在过桥上,还可选择为部分形成在基板上,部分形成在过桥上。过桥优选但不限于包括盖板和形成在盖板下的导流通道,当盖板被盖设在基板上时,盖板与基板之间形成阳极导流结构14。In this embodiment, the anode flow guide structure 14 may be formed on the first side of the substrate by a stamping process. The anode flow guide structure 14 may also be formed on the first side of the bipolar plate 100 by an injection molding process. The injection molding material is preferably plastic, such as PEEK modification, PTFE modification, PSU modification, PI modification, etc.; it has sufficient strength and rigidity to ensure the mechanical properties, corrosion resistance and insulation properties of the electrolytic cell under working conditions. The bipolar plate 100 may also be selected to include a bridge covered on the first side of the substrate, and the anode flow guide structure 14 is formed between the substrate and the bridge. The bridge is preferably but not limited to being made of materials such as plastic or metal. The anode flow guide structure 14 may be formed on the substrate, may be formed on the bridge, and may be partially formed on the substrate and partially formed on the bridge. The bridge preferably but not limited to includes a cover plate and a flow guide channel formed under the cover plate. When the cover plate is covered on the substrate, an anode flow guide structure 14 is formed between the cover plate and the substrate.
在本实施例中,阴极导流结构24可选为通过冲压工艺形成在基板的第二侧。阴极导流结构24也可选择为通过注塑工艺形成在基板的第二侧。注塑材料优选为塑料,例如PEEK改性、PTFE改性、PSU改性、PI改性等;其具有足够的强度和刚度,可保证电解槽在工作条件下的机械性能,耐腐蚀性能和绝缘性能。双极板100还包括盖设在基板的第二侧的过桥,阴极导流结构24形成在基板与过桥之间。过桥优选但不限于由塑料或金属等材料制成。阴极导流结构24可选为形成在基板上、也可选为形成在过桥上,还可选择为部分形成在基板上,部分形成在过桥上。过桥优选但不限于包括盖板和形成在盖板下的导流通道。当盖板被盖设在基板上时,盖板与基板之间形成阴极导流结构24。In this embodiment, the cathode flow guiding structure 24 may be formed on the second side of the substrate by a stamping process. The cathode flow guiding structure 24 may also be formed on the second side of the substrate by an injection molding process. The injection molding material is preferably plastic, such as PEEK modification, PTFE modification, PSU modification, PI modification, etc.; it has sufficient strength and rigidity to ensure the mechanical properties, corrosion resistance and insulation properties of the electrolyzer under working conditions. The bipolar plate 100 also includes a bridge covered on the second side of the substrate, and the cathode flow guiding structure 24 is formed between the substrate and the bridge. The bridge is preferably but not limited to being made of materials such as plastic or metal. The cathode flow guiding structure 24 may be formed on the substrate, may be formed on the bridge, or may be partially formed on the substrate and partially formed on the bridge. The bridge preferably but not limited to includes a cover plate and a flow guiding channel formed under the cover plate. When the cover plate is covered on the substrate, a cathode flow guiding structure 24 is formed between the cover plate and the substrate.
可选地,本实施例中,阳极主流道11和阴极主流道21为均为两组。双极板100的两端分别设置有一组阳极主流道11和一组阴极主流道21,且 所述阳极主流道11和阴极主流道21交错设置。所述阳极反应区流道12设置在两组所述阳极主流道11之间,所述阴极反应区流道22设置在两组所述阴极主流道21之间。这使得在阳极主流道11和阴极主流道21能够通过长度适中的导流结构分别与阳极反应区流道12和阴极反应区流道22相连,并使得反应区的空间能够得到充分的利用。Optionally, in this embodiment, the anode main channel 11 and the cathode main channel 21 are both provided in two groups. A group of anode main channels 11 and a group of cathode main channels 21 are provided at both ends of the bipolar plate 100, and The anode main flow channel 11 and the cathode main flow channel 21 are arranged alternately. The anode reaction zone flow channel 12 is arranged between two groups of the anode main flow channels 11, and the cathode reaction zone flow channel 22 is arranged between two groups of the cathode main flow channels 21. This enables the anode main flow channel 11 and the cathode main flow channel 21 to be connected to the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 respectively through a guide structure of moderate length, and enables the space of the reaction zone to be fully utilized.
可选地,在本实施例中,阳极反应区流道12和阴极反应区流道22位于基板的两侧的相同位置,且由冲压工艺形成。通过一次冲压能够同时在基板的两侧分别形成阳极反应区流道12和阴极反应区流道22。现有技术中的双极板100上的阳极反应区流道12和阴极反应区流道22一般采用刻蚀工艺制成。刻蚀工艺所采用的材料厚度一般为3mm左右,且工艺成本较高(一般为2000元左右),耗时较长。本实施例的双极板100使用冲压工艺制成,大大减小了双极板100的厚度(双极板100的厚度可降低至0.5mm左右。因此,本实施例的双极板使用冲压工艺一次性在基板的两侧分别形成了阳极反应区流道12和阴极反应区流道22,不仅节约了材料成本,而且冲压工艺本身成本也较为低廉,由此大大降低了双极板的制造成本,并提升了双极板的制造效率。Optionally, in this embodiment, the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 are located at the same position on both sides of the substrate and are formed by a stamping process. The anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 can be formed on both sides of the substrate at the same time by a single stamping. The anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 on the bipolar plate 100 in the prior art are generally made by an etching process. The material thickness used in the etching process is generally about 3 mm, and the process cost is relatively high (generally about 2,000 yuan), and it takes a long time. The bipolar plate 100 of this embodiment is made by a stamping process, which greatly reduces the thickness of the bipolar plate 100 (the thickness of the bipolar plate 100 can be reduced to about 0.5 mm. Therefore, the bipolar plate of this embodiment uses a stamping process to form the anode reaction zone flow channel 12 and the cathode reaction zone flow channel 22 on both sides of the substrate at one time, which not only saves material costs, but also the stamping process itself is relatively cheap, thereby greatly reducing the manufacturing cost of the bipolar plate and improving the manufacturing efficiency of the bipolar plate.
另外,虽然本实施例的双极板100的厚度较薄,但由于其在两侧分别形成了阳极侧流道和阴极侧流道,这使得双极板100两侧的压力能够相互抵消,这就使得本实施例的双极板100所需承受的压力也远远小于现有技术中的双极板100。因此,本申请实施例的双极板的承压能力仍优于现有技术中的双极板的承压能力,在节约了双极板的材料成本的同时不会导致缩短双极板100的使用寿命。In addition, although the bipolar plate 100 of the present embodiment is thin, since the anode side flow channel and the cathode side flow channel are formed on both sides, the pressure on both sides of the bipolar plate 100 can offset each other, which makes the pressure that the bipolar plate 100 of the present embodiment needs to withstand much less than the bipolar plate 100 in the prior art. Therefore, the pressure bearing capacity of the bipolar plate of the present embodiment is still better than the pressure bearing capacity of the bipolar plate in the prior art, and the material cost of the bipolar plate is saved without shortening the service life of the bipolar plate 100.
在本实施例中,基板包括金属板3和包裹在金属板3外侧的注塑边框4。阳极反应区流道12、阳极导流结构14、阴极反应区流道22和阴极导流结构24形成在金属板3上。阳极主流道11和阴极主流道21形成在注塑边框4上。注塑边框4上还形成有适于暴露阳极反应区流道12的第一豁口41和 适于暴露阴极反应区流道22的第二豁口42。其中,金属板3优选但不限于为由纯钛或不锈钢镀钛等材料制成。In this embodiment, the substrate includes a metal plate 3 and an injection molding frame 4 wrapped around the outside of the metal plate 3. The anode reaction zone flow channel 12, the anode flow guide structure 14, the cathode reaction zone flow channel 22 and the cathode flow guide structure 24 are formed on the metal plate 3. The anode main flow channel 11 and the cathode main flow channel 21 are formed on the injection molding frame 4. The injection molding frame 4 also has a first notch 41 and a second notch 42 for exposing the anode reaction zone flow channel 12. The second notch 42 is suitable for exposing the cathode reaction zone flow channel 22. The metal plate 3 is preferably but not limited to being made of pure titanium or stainless steel plated with titanium.
双极板100还包括金属板3和包裹在金属板3外侧的注塑边框4。阳极反应区流道12、阳极导流结构14、阴极反应区流道22、阴极导流结构24、阳极主流道11、阳极主流道11和阴极主流道21形成在金属板3上。注塑边框4上形成有适于暴露所述阳极反应区流道12的第一豁口41、适于暴露所述阴极反应区流道22的第二豁口42、适于暴露所述阳极主流道11的第三豁口43和适于暴露所述阴极主流道21的第四豁口44。The bipolar plate 100 further includes a metal plate 3 and an injection molding frame 4 wrapped around the outside of the metal plate 3. The anode reaction zone flow channel 12, the anode flow guide structure 14, the cathode reaction zone flow channel 22, the cathode flow guide structure 24, the anode main flow channel 11, the anode main flow channel 11 and the cathode main flow channel 21 are formed on the metal plate 3. The injection molding frame 4 is formed with a first notch 41 suitable for exposing the anode reaction zone flow channel 12, a second notch 42 suitable for exposing the cathode reaction zone flow channel 22, a third notch 43 suitable for exposing the anode main flow channel 11 and a fourth notch 44 suitable for exposing the cathode main flow channel 21.
在本实施例中,注塑边框4上形成有环绕第一豁口41设置的第一密封结构51、环绕第二豁口42设置的第二密封结构52、环绕第三豁口43设置的第三密封结构53、环绕第四豁口44设置的第四密封结构54。第一密封结构51、第二密封结构52、第三密封结构53和第四密封结构54优选但不限于为密封垫,或者是环绕注塑边框4的豁口设置的水线。In this embodiment, the injection molding frame 4 is formed with a first sealing structure 51 disposed around the first notch 41, a second sealing structure 52 disposed around the second notch 42, a third sealing structure 53 disposed around the third notch 43, and a fourth sealing structure 54 disposed around the fourth notch 44. The first sealing structure 51, the second sealing structure 52, the third sealing structure 53, and the fourth sealing structure 54 are preferably, but not limited to, sealing gaskets, or waterlines disposed around the notches of the injection molding frame 4.
本实施例的双极板100在注塑边框4上形成密封结构,由此减小了密封结构的厚度,此时对双极板100施加3MPA左右的压力能够保证流体不会泄露,减小了为保证密封需要向密封结构施加的压力。另外,注塑边框4上易于形成水线,有助于增加水线的数量,从而进一步提升密封效果。The bipolar plate 100 of this embodiment forms a sealing structure on the injection molding frame 4, thereby reducing the thickness of the sealing structure. At this time, applying a pressure of about 3 MPA to the bipolar plate 100 can ensure that the fluid does not leak, reducing the pressure that needs to be applied to the sealing structure to ensure sealing. In addition, water lines are easily formed on the injection molding frame 4, which helps to increase the number of water lines, thereby further improving the sealing effect.
实施例2Example 2
实施例2涉及了一种电解小室,如图6所示,实施例2的电解小室包括第一双极板、第二双极板、阳极扩散层200、膜电极201和阴极扩散层202。其中,第一双极板和第二双极板均为本实用新型实施例1的双极板100。第一双极板的第一侧朝向第二双极板的第二侧。阳极扩散层200、膜电极201和阴极扩散层202,依次夹设在第一双极板和第二双极板之间。Embodiment 2 relates to an electrolysis chamber. As shown in FIG6 , the electrolysis chamber of Embodiment 2 includes a first bipolar plate, a second bipolar plate, an anode diffusion layer 200, a membrane electrode 201, and a cathode diffusion layer 202. The first bipolar plate and the second bipolar plate are both bipolar plates 100 of Embodiment 1 of the utility model. The first side of the first bipolar plate faces the second side of the second bipolar plate. The anode diffusion layer 200, the membrane electrode 201, and the cathode diffusion layer 202 are sequentially sandwiched between the first bipolar plate and the second bipolar plate.
实施例2的电解小室包括或使用了本申请实施例1的电解小室,因此具有了其有益效果,其制造流程较为简单,生产成本较低,在电解小室的 数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。其制造流程较为简单且具有更好的承压能力。The electrolysis chamber of embodiment 2 includes or uses the electrolysis chamber of embodiment 1 of the present application, and thus has its beneficial effects, its manufacturing process is relatively simple, and its production cost is low. The number of plates expressing the flow channel characteristics is kept constant, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
实施例3Example 3
实施例3涉及了一种燃料电池,其包括本申请实施例1所涉及的双极板100,因此具有了其有益效果,即其制造流程较为简单,生产成本较低,在电解小室的数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。其制造流程较为简单且具有更好的承压能力。Embodiment 3 relates to a fuel cell, which includes the bipolar plate 100 involved in Embodiment 1 of the present application, and thus has its beneficial effects, namely, its manufacturing process is relatively simple, the production cost is low, the number of plates expressing flow channel characteristics is small under the premise of the same number of electrolytic chambers, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
实施例4Example 4
实施例4涉及了一种电解水制氢装置,其包括本申请实施例1所涉及的双极板100,因此具有了实施例1的双极板100的有益效果,其制造流程较为简单,生产成本较低,在电解小室的数量不变的前提下表达流道特征的板的使用数量较少,且双极板具有更好的承压能力。其制造流程较为简单且具有更好的承压能力。Embodiment 4 relates to a water electrolysis hydrogen production device, which includes the bipolar plate 100 involved in Embodiment 1 of the present application, and thus has the beneficial effects of the bipolar plate 100 of Embodiment 1, and its manufacturing process is relatively simple, the production cost is low, the number of plates expressing the flow channel characteristics is small under the premise that the number of electrolysis chambers remains unchanged, and the bipolar plate has better pressure bearing capacity. Its manufacturing process is relatively simple and has better pressure bearing capacity.
显然,上述实施例仅仅是为清楚地说明所作的举例,而并非对实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。而由此所引伸出的显而易见的变化或变动仍处于本申请的保护范围之中。 Obviously, the above embodiments are merely examples for the purpose of clear explanation, and are not intended to limit the implementation methods. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. The obvious changes or modifications derived therefrom are still within the scope of protection of this application.
Claims (12)
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